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By R. Gerritsen, Erwin de Jong, E. van der Velde, C. te Boekhorst

"In recent years the market for Mixed-In-Place soil mix techniques in the Netherlands has been growing rapidly. Initially the technique was used to create cut-off walls near river dikes and as a vibration free method to create retaining walls for building pits. Studies have been undertaken and projects are executed in order to strengthen the dike itself by the use of Mixed-In-Place techniques. In February 2012 Bauer Funderingstechniek started the construction of the first polder in the Netherlands with their approved Mixed-In-Place cut-off walls. This article explains the background of the use of this cost-effective and durable construction method and discusses how the challenging requirements from the client were fulfilled, both in design and execution. The quality assurance and quality control consisted of preliminary soil and mixture investigations, extensive measurements during construction and leakage detection through geophysical methods. The information is presented in 3 case histories, all subprojects of a large infrastructural project ‘Leeuwarden Vrij-Baan’ in the Netherlands.INTRODUCTIONThe Netherlands have a worldwide reputation in creating their own country by reclaiming land from the sea. Since the 15th century the Dutch have been creating “polders”, areas of reclaimed land below sea level, surrounded by dykes and with a mechanically maintained water level. In the 20th century the use of artificial polders became an interesting construction method for creating underpasses below motorways and canals using watertight geomembranes to create an impermeable layer that separated the polder from its surroundings. These kinds of structures have one big disadvantage, they need a lot of space. The main idea of such a structure is that the upward water pressure under the geomembrane has to be in balance with the remaining soil on top of it. For this reason, the geomembrane has to be placed at a depth significantly deeper than the polder surface, depending on the hydraulic head in the aquifer. Slopes of 1:3 (1 vertical : 3 horizontal) are most commonly used, resulting in very large open excavations and massive earthworks, even for relatively small underpasses. Special measures can be taken to reduce the spatial use with vertical limits, but these measures will increase the building costs (Gerritsen et al. 2014)."

Jan 1, 2015

By N. B. Greninger

The U.S. Bureau of Mines conducted explosion tests on various full-scale cementitious bulkheads used in abandoned mine areas to evaluate the ability of the bulkheads to withstand gas explosion over-pressures of 20 psig. Tests were performed on 120-ft2 solid-concrete-block seals of varying thicknesses and designs. Of the seven solid-concrete-block seals tested, only the standard-type seal, having a 16-in thickness, keyed at the floor and ribs, all joints mortared, wedged at the roof, and a center pilaster, maintained its integrity when subjected to a 20-psig pressure wave. After being subjected to repeated explosions, the standard seal only showed a small hairline crack and had an air leakage of 87 ft3/min at a pressure differential of 1 in H2O. Tests were performed on cementitious foam seals of varying thicknesses and compressive strengths. Explosion tests have shown that 200-psi strength, 4-and 8-ft-thick seals can withstand a 20-psig pressure wave. At a pressure differential of 1 in H20, no air leakage was detected through the 200-psi, 8-ft-thick foam seal.

Jan 1, 2010

By Adam Mackenzie, Dan Payne, Yass-Marie Rutty

"Historically, the Crinum mine has experienced significant falls of ground when longwall production slowed to prepare for recovery in weak roof areas. These conditions continue through the recovery process and result in both safety concerns and delays. When mine plans and exploration revealed that most of the mine's future longwall recoveries were located in weak roof areas, a decision was made to try pre-driven recovery roads as a solution to the problem. After completing eight pre-driven recovery roads with varying degrees of success and numerous lessons, the Crinum North mine now utilizes a modified Pre-driven Recovery Roadway (PDRR) to improve the longwall take-off process in weak roof areas. During mine development, a standard roadway is driven where the final recovery location of each longwall is planned. After the installation of secondary support, the PDRR is backfilled with a cement-flyash mix to provide support to the roof, and confinement to the ribs and floor of the roadway. The method has been refined over the last four years to provide greater strata stability and improved operational and safety performance compared with conventional take-offs at Crinum, and has resulted in a site record of longwall relocation in 11.5 days (pull mesh to picks in coal). This paper describes the evolution of the PDRRs from Crinum East to Crinum North, including lessons from initial attempts and changes to the secondary support regime, the operational approach during the final stages of retreat, the backfill strategy and plans for the future.INTRODUCTIONThe Crinum mine is the underground component of BHP Billiton Mitsubishi Alliance's (BMA) Gregory Crinum mine, located northeast of Emerald, Queensland (Figure 1).The Crinum mine has a history of roof control problems coming into and during longwall recoveries. Weak roof, combined with the slow mining, which is a consequence of preparing for equipment recovery, pulling mesh (which also creates tip-to-face issues), and the lengthy bolt-up process, often results in loss of immediate roof and subsequent roof falls. In fact, approximately 50% of the first 13 longwall recoveries (which were at depths of 180 to 200m) experienced roof fall delays, the longest of which took four months to mine the last pillar and recover the longwall. This recurring problem prompted the mine to investigate options to reduce or eliminate the problem."

Jan 1, 2016

By B Broad

"Establishing ventilation in the early stages of a new mine is an essential step to achieve scheduled outcomes that ultimately drive the financial success of an operation. If the primary ventilation is not in place in time to support a contractorÆs work output, then the ore delivery is likely to be severely impacted. Options to increase ventilation in order to address shortfalls are limited. This in turn can lead to reduced revenue generation at a time when a mine is at its highest capital outlay. This can have implications for any company, but even more for an explorer moving to producer. The ventilation put in place to cover the start-up period is also unlikely to cover any extended or increased load required to meet schedule delays.The following paper examines two issues in relation to ventilation with a focus on small to medium projects where the company is establishing a mine using a mining contractor. The issues being: potential impacts on the contract and tender process when using a mining contractor key mine design considerations, such as æcrunch timeÆ, as they interact with ventilation achieving a successful ramp up.A recommendation is made for higher levels of detail around secondary ventilation leading up to the primary fan installation. The information should be included as part of the tendering process and preliminary project execution planning. Understanding the æcrunch timeÆ concept can lead to strategies, as well as back up plans, to minimise any negative impact.By understanding key risks around primary ventilation establishment for a new mine, detailed design work can be completed where it is needed most. Value is added by reducing uncertainty and a payback with better contract terms and a more robust ramp up plan. This will improve the economic return for the company and reduce the risk.CITATION:Broad, B, 2013. Contract considerations and other critical ventilation aspects in achieving a new mine ramp up, in Proceedings The Australian Mine Ventilation Conference, pp 207-214 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 1, 2013

By Xingang Wang

Spontaneous combustion is one of the most important safety issues in the global coal industry. It is considered to be a trigger for explosions in underground mines, especially for gassy mines. This thermal event is not easily detectable in the gob and sealed area. It is also a tough job to find the most likely hot point accurately. Admittedly, determination of the propensity for spontaneous combustion before mining activity should be a necessary step in the design of a mine and ventilation plan. However, due to the complexity of the chemical and physical properties of coal, spontaneous combustion has not been fully understood. According to a proximate analysis of coal, it is believed that sulfur and volatile matter in coal are the main intrinsic factors that cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal?s self-heating should be quantified. This study aims to improve the previous mathematical model developed by the authors for studying a coal?s propensity for spontaneous combustion. It enhances the model?s ability to consider the effects of sulfur, volatile matter and moisture content in the coal ? three important factors affecting a coal?s self-heating process. Based on the law of energy conservation, heat release rates for pyrite oxidation and moisture condensation are built into the model. Finally, the simulation results in terms of time versus temperature are calibrated with adiabatic testing data extracted from the literature for pyrite oxidation and moisture condensation, respectively. From the modeling results, it is found that the higher the pyrite content the coal contains and the more moisture that condenses in an environment with high relative humidity and initial temperature, the higher the potential for spontaneous combustion.

Jan 1, 2014

By Geoffrey S. Plumlee

The Summitville gold mine, located in southwestern Colorado, received tremendous publicity in the 1980's and 1990's for leaks of cyanide solutions from its heap leach facility. As is typical with cyanide spills, real time, geochemically rigorous assessments of the environmental effects were not performed. Past United States Geological Survey (USGS) research used simple mixing experiments to model the influx of alkaline cyanide heap leach solutions from Summitville into a nearby stream, whose waters were highly acidic due to severe acid-rock drainage (ARD) from the mine. These experiments indicated WAD cyanide rapidly degraded due to formation of Fe-Cu-CN solids and lesser HCN volatilization. The alkaline heap leach solutions also precipitated hydrous iron-and aluminum, oxides and hydroxysulfates (iron and aluminum 'supplied by the acid. rock drainage (ARD]), which then sorbed copper and other heavy metals from the ARD. These results indicate that mixing of cyanide heap leach solutions with ARD may be a cost-effective remedial method at mine sites where treatment of both is required. New experiments are currently in progress to further refine a potential remedial process.

Jan 1, 1998

By Raoul Fernandez, Bernard Catalano, Guillaume Roux

The Thaumasia Joint-Venture, composed of Bouygues Travaux Publics, Soletanche- Bachy and Bessac, completed the construction of the underground section of line 2 of the Nice tramway, which comprised a 3.2 km twin track tunnel and four underground stations, in a particularly complex urban and geotechnical context. The density of the surface structures, as well as the presence of many historic buildings on its route made the construction of the tunnel even more sensitive, with a settlement threshold of Half an Inch. The joint venture faced a complex subsoil, varying from one extreme to another from highly plastic clay layers to fibrous peat and to cobbles with very high permeability, with artesian ground water, and with unforeseen anthropogenic obstacles in the tunnel section Due to the diversity of the problems encountered and their variability over short distances, the construction of the underground section of the Nice tramway, in its very sensitive urban context, undeniably constituted an unprecedented challenge.

Jun 13, 2023

By V. F. Parry, W. S. Landers, John B. Goodman

"INTRODUCTION The object of this investigation was to demonstrate a satisfactory method of storing slack subbituminous coal in open pits in a manner,that would minimize the cause of the physical deterioration and would have a practical application.The storage of coal by industrial plants is to their advantage, since an adequate operating supplying of fuel is available at all times as insurance against transportation delays, shortages, and strikes. Furthermore, it is possible to participate in low seasonal freight rates and mine costs by permitting the railroads to utilize idle equipment and by taking advantage of the off-peak production at the mines. For a number of years, one of the larger beet-sugar companies operating in the Rocky Mountain region has taken advantage of the lower prices and seasonal production of subbituminous slack coal during the summer months and purchased a large proportion of its requirements for the annual winter campaign. This company, operating sugar-refining plants in the 1943 campaign, used 256,613 tons of subbituminous coal. Of this quantity, 166,636 tons was purchased during the off-peak season and stored for use during the winter. It is the practice of this concern to place coal purchased through the months of January to October in underwater storage for use in the beet-sugar campaign, which lasts from October to as late as, January. The beet-sugar refining ""campaign"" period starts immediately after the beginning of the beet harvest and lasts 60 to 70 days."

Aug 1, 1946

By David G. Adam

Syncrude Canada Ltd. is currently mining over 120 million tons per year of overburden and oil sands to produce 40 million barrels per year of synthetic crude oil. Production increases are planned. This paper reviews the technical and economic assessments of feeder breaker applications in both ore and waste mining which led to an extensive testing and development program and finally to the procurement of full scale production equipment.

Jan 1, 1985

By C. E. Silverblatt

The advent of larger quantities of -1/4 inch coal in the raw feed to the preparation plant and the necessity of recovering this material has made the problem of meeting product moisture specifications more difficult. For a number of years thermal dryers have been used advantageously as a means of reducing fine coal moisture content where the over-all economics would justify such an installation. However, these units are not without their drawbacks because of high capital and operating costs, safety hazards and possible degradation of the product, and thus an alternative method of moisture reduction is highly desirable. After the various mechanical variables associated with filtration have been optimized, an examination of theory shows that surface tension and liquid viscosity are the only two remaining variables which might be altered to reduce moisture content.

Jan 1, 1964

By P D. Kasbanis, Lyall Workman

"The energy output of an explosive is typically calculated using an equation of state and computerapplications. Results are reported as weight and bulk strength, either in absolute terms or relative toANFO. The effect of the equation of state selected and the assumptions regarding the energy calculation are considered and interpreted for the purpose of blast design. It appears that variations in the heat of detonation which result from the selection of the equation of state and parameters associated with it are not sufficient to significantly affect blast patterns, explosive consumption and costs. However variations stemming from the use of “available energy” associated with a cut-off pressure are significant, suggesting in many cases large pattern expansions. The validity of the various approaches is discussed and blast design results based on the energy calculated by the different approaches are presented and evaluated."

Jan 1, 1996

By Evelynn Stirling

"The paper/presentation will review the evolution of diesel technology from older diesel engines (1990 vintage) through to the latest technology as a result of the ever changing emissions regulations. It will encompass the EPA Tier levels as well as the latest Euro Stage V emissions. The next step with technology will be to address the CO2 emissions, which translates to improving fuel efficiencies of the product as well as other technologies like battery electric, hybrid and fuel cells. As technology progresses it also becomes important to improve connective diagnostic systems to support maintenance practices and improve efficiencies. What will also be presented will be the key emissions changes to the different gaseous and particle mass elements as the products have transitioned from the EPA Tier 3 through to Tier 4 Final regulations. Offering a range of different technologies to the underground mining market matters as not all pieces of equipment will perform optimally due to its duty cycle and application. INTRODUCTION Rudolf Diesel built his first well-known prototype of the high-compression engine in 1897. Since that time, the diesel engine has evolved into one of the world’s most capable and reliable forms of power generation. Diesel engines can be found in a wide variety of vehicles and equipment, powering everything from agriculture and construction equipment to power generators and marine vessels. In the early days the emissions from diesels was very poor and extensive work has been accomplished over the decades to make the product more environmentally friendly. This is more important in underground mining where the space is limited and ventilation is expensive and challenging. DISCUSSION The key driver of the development of diesel technology is the legislation globally around engine emissions. The emission level requirements over the years has forced diesel engine manufacturers to build a deep technical understanding of the system and how to innovate and optimize key elements of the engine. Cummins expertise has been built over the years as the diesel engine has evolved from a relatively simple mechanical engine to an electronic system with advanced air handling, fuel system, after treatment, and controls. Cummins has also continued to expand into systems beyond diesel, including natural gas. Many new components have been added to diesel engines to reduce emissions while improving fuel efficiency and reliability and, at the same time, reduce the total cost of ownership to the customer."

Jan 1, 2019

By Blamey Stevens

(San Francisco Meeting, October, 1911.) My previous paper is entitled, The Laws of Igneous Emanation Pressure. The present paper lays no claim to the exactitude and completeness of a law, since it is of a provisional nature and may be disregarded when experiments have established a basis for more exact reasoning. The general physical states in which aqueous emanations may occur are first considered. The possible physical conditions under which the mineral elements may occur in emanations are then discussed, and a classification of deposits, dependent on emanation, is proposed. A system of scientific experimental investigation is outlined, and it is shown that the physical and chemical properties of emanation may be exactly determined thereby. The investigation is urged as feasible and simple, and not necessarily requiring large and costly apparatus. It is the only step necessary to make possible the formulation of a complete set of laws of igneous emanation. Process of Emanation. In a rising column, magma ranges in temperature from 900° to 1,200°C. Exhalation must begin at some fairly great depth. What this depth may be we can only surmise, since no experimental evidence is available. Exhalation, however, continues as the magma flows upward, until at another level the occluded gases have all escaped. This depth is probably upward of 5,000 ft. (See Fig. 1.) All exhalations must come from between these two levels. As the whole emanation is the sum of the exhalations and residues, the residues must come from below the uppermost level. They will be most abundant when coming, from those parts of the intrusion which have solidified below the lower level.

Apr 1, 1912

By W. W. Stephens

As part of the Bureau of Mines program directed toward more effective utilization of the mineral resources of the United States, a number of processes for production of sponge iron have been investigated. The use of sponge iron as a raw material for production of steels and other ferrous alloys offers several possible advantages over the conventional pig-iron and scrap process, especially for utilization of the smeller, widely distributed iron-ore deposits of the western United States. Although considerable information has been made available on various processes for production of sponge iron, little information 118.6 been published heretofore on the problems and costs involved in melting the sponge iron for production of steel. The present Paper reports the results of tests conducted at the Bureau of Nines pilot plant at Redding, Calif. in which several different types of sponge iron Were used as charge material for production of steel in a 4-ton-capacity basic arc furnace.

Jan 1, 1949

By Arthur Notman

Since addressing the Institute a year ago on The Future of the Copper Industry (l), many things have happened, most of them bad. It has been a hard year for profits and prophets. It was, therefore, with consider-able perturbation that I accepted the gracious invitation of your Committee to reappear. On reviewing my remarks of a year ago, I. have wondered whether, under pressure of more important matters, the Committee had neglected to make a note of them, or whether they felt that further explanations from me were in order. In either event, I am glad that I am here and welcome the opportunity to make any contribution I can to a clearer understanding of the problems of copper to those concerned. The English-speaking nations own 80 per cent of the present world-production of the metal. Col. P. E. Barbour, Secretary of the Mining and Metallurgical Society of America, and I recently completed an estimate of the known world resources of copper. We placed the figure, in round numbers, at 100,000,000 tons of metal. Of this amount, about one-third lies in the United States, one-third in the British Empire, and one-third in South America; and all but 4 per cent of this is owned by British Empire and United States capital. Our figures do not include any estimates for Russia, Japan, or Europe, on which there are no available data. It is true, consequently, that the British Empire and the United States are the ones concerned. It seems to me to be a matter of great importance to the world at large, and of even greater importance to those nations themselves, that the known sources of supply of this metal, so essential both in peace and war, rest so strongly in their hands. I cannot believe that in the long run they will neglect their responsibilities in the wise administration of these resources.

Jan 1, 1932

By John Ross Middleton

Based upon 30 years+ experience in the Development, Implementation and Ongoing Support of Computer based Melt Shop Management Systems in about 40 plants in the UK, Europe and the USA, consideration of the overall facilities of a state of the art, comprehensive, Integrated Melt Shop System covering Melting and Secondary processes for all grades of steels and superalloys; the scope of functionality of these systems, covering Raw Materials and Consumables Procurement and Inventory Management, Laboratory Management, Melt Shop Scheduling, Furnace Charge and Additions Optimisation, Level 1.5 to Level 2.5 Materials Optimisation and Process Control Calculations, Process Data Recording, Management of Ladles, Furnace Bodies, Vessels and Moulds, Comprehensive Management Reporting and Integration with Corporate ERP Systems. The second section of the paper reviews the key ‘Success Factors’ to achieve rapid, successful implementation, comprehensive, fast response user support, continuing system improvement and maintaining ‘perfect fit’ of system to operations in an ever changing future technical, operations and business environment.

Jul 29, 2018

By Felipe Henríquez, Daniel Silva

"Traditionally, the implementation of an automated advanced process controller in any mineral processing complex is a challenge, mainly due to the quality of resources and technologies required, the uniqueness of each control solution and the uncertainty of the engineering hours needed to complete the task. Thus, the use of advanced and proven control technology becomes a key factor when deploying the control strategy. However, success would still not be possible without the presence of common sense, process knowledge and fundamental process data. Minera Los Pelambres, taking advantage of such factors and its accumulated process experience, implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control for secondary grinding and regrinding stages at its copper concentrator plant. In both cases, the control objectives are: being capable of processing a variable feed from the upstream process while at the same time avoiding to become a process bottle neck and yet, maintaining an adequate product quality (in terms of size distribution) to the process downstream. Additionally, for the case of the vertical regrinding mill (vertimill), the control system should also be capable of keeping an adequate circulation load and making an efficient use of the available grinding power. In either case, extending hidrocyclones availability while maintaining their performance is a must, since both factors are required for process and maintenance purposes. Thus, the process control problem becomes one with a multi-variable type of process with multiple control objectives to satisfy simultaneously. In trying to solve it, many mineral processing operations have implemented basic or conventional control or even better yet, expert systems. Minera Los Pelambres believes that better and faster results can be achieved using a combination of MPC and advanced control. Such strategy was successfully implemented, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Their control philosophy, implementation process, main results and their key performance indicators are discussed here."

Jan 1, 2014

By R. V. Lundquist

Aeration in water slurries and controlled drying of manganous hydroxide produced from dithionate leaching of Artillery Peak manganese ores from Arizona were investigated by the Bureau of Mines at its Electrometallurgical Experiment Station, Boulder City, Nev., to determine whether a simple process could be developed for converting this product into a battery-grade manganese dioxide. The properties of manganese dioxide prepared by the thermal decomposition of manganous nitrate were investigated also. Manganese dioxide suitable for use in batteries was not obtained from the dithionate leach product, but some of the factors controlling its oxidation were isolated. Aging of manganous hydroxide was of major importance in retarding its oxidation by aeration. Sodium hydroxide and sodium silicate promoted oxidation by drying. Optimum quantities were about 0.85 mol of sodium hydroxide and 0.2 mol of sodium silicate per mol of manganese, and drying temperatures of 200° C. produced yields of manganese dioxide up to 90 percent of the manganese present. Higher temperatures and concentrations of reagents carried oxidation of manganese beyond its tetravalent state.

Jan 1, 1957

By J. Szekely, Robert G. Lee

Calculations are presented for the prediction of the combined radiative-convective heat loss from molten steel held in a ladle, covered by initially molten slag. A mathematical formulation is given and numerical solutions are presented of the resultant partial differential equation. It is shown that a slag layer of about 2 to 3 in. thick would prevent any significant heat loss from the top metal surface for Periods of up to 1 hr. For thinner slag layers (or in the absence of the protective slag) appreciable heat losses would occur; plots given in the paper allow the quantitative evaluation of the fall in the metal temperature due to this heat loss. The ironmaking-steel processing operation involves several intermediate steps where the molten metal is held or transfered in ladles. The quantitative assessment of the heat losses occurring under these conditions is of considerable importance in process design considerations since the temperature of the metal may have to meet rigid specifications in any given part of the processing sequence. While the metal is held in a ladle, heat is lost by two mechanisms: i) by conduction into the ladle walls; ii) by radiation and convection from the top surface. Calculations relating to the conductive heat loss, are readily made and information may be found in the literature both on data pertaining to metallurgical situations and on the techniques that are available for performing additional computations.'-3 The evaluation of the combined convective-radiative heat loss is less straightforward, especially when there exists a protective slag layer covering the metal. In this latter case, as the top slag surface loses heat partial solidification may occur and the latent heat thus given up by the slag may represent an effective barrier to the heat loss from the metal. A semiquantitative assessment of the role played by the slag in preventing heat loss from the metal has been made in a previous paper,4 where it was shown that a slag layer 6 in. thick would act as a near-perfect insulator for periods of up to 2 hr. However, this first paper reported on an essentially preliminary investigation that considered only one slag layer thickness; furthermore, the boundary conditions used for the calculations were somewhat restrictive since no allowance was made for changes in the metal temperature. The purpose of this second paper is to extend the scope of the preliminary investigation previously reported by: i) considering several slag layer thicknesses; ii) allowing for variations in the metal temperature; and finally iii) by performing calculations on the net loss from the metal rather than from the slag surface. FORMULATION Consider a slag phase extending from y = 0 to y = L1, covering a metal phase that occupies the region extending from y = Ll to y = L, as illustrated in Fig. 1. Denote the slag and metal temperatures by TS and Tm and assume that initially both slag and metal are molten, having a uniform temperature Ti. At time = zero the surface represented by the y = 0 plane (top slag surface) is brought into contact with cold air, the temperature of which is given as T Thus for time > zero, heat will be transfered from the slag to the air by natural convection and thermal radiation; as a result of this heat loss the slag temperature will fall and after some time a solid phase is formed and a solidification boundary (more realistically described as a zone) will move progressively from y = 0 toward y = L1. Once the region of temperature gradients, moving ahead of the solidification zone, reach the slag-metal interface (y = L1) there will be a net transfer of heat from the metal through the slag to the cold air, across the y = 0 plane. In the formulation of moving boundary problems, involving phase changes that require computer solution, it is convenient to represent both phases by a single equation, making allowance for the latent heat of solidification by assigning an appropriate temperature dependence to the specific heat content. Thus the energy equation for the whole of the slag may be written as follows:

Jan 1, 1969

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006