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By R. R. Angel

Drilling rate is a parameter that should be considered in determining the volume requirements for air and gas drilling. The use of past methods which ignore the effects of the solids content upon the pressure and velocity of the annulus flow stream can result in undercalculation of the required volurne by as much as 50 per cent. A vertical-flow equation is presented for determining volume requirements. This equation includes the effect of the solids that are transported up the annulus in the flow stream by incorporating the drilling rate as one of the parameters. The effect of down-hole temperature on required circulation rates is also ana-lvzed. A simple approximate method of determining volume requirements is presented. This method is more accurate than the methods used in the past. Hole cleaning difficulties are analyzed for a recent air drilling job where past methods indicated that - excess air was being used. Sample curves of calculated boitom-hole pressures are presented for air and gas drilling in several hole sizes. INTRODUCTION In certain areas the use of air or natural gas as a circulating medium for drilling oil and gas wells is becoming a common practice. Large increases in penetration rate and bit life are achieved through the use of these media in preference to mud or water. Drilling rates as high as 90 ft/hr have been obtained in shales. The importance of maintaining adequate circulation rate is generally recognized; however, much disagreement exists among drilling operators as to what constitutes "adequate" circulation rate. In quarry drilling, where annular velocities can be accurately determined, an annular velocity of 3,000 ft/min of standard air is required for best results in rocks having approximately the same density as those commonly penetrated in drilling oil or gas wells'. Although this standard air velocity has proven satisfactory for quarry drilling, some oil and gas well drilling operators believe that an equivalent annular velocity of more than 4,000 ft/min is required; others believe that as little as 2,000 ft/min . is sufficient. Much of this disagreement results from determining the required circulation rates with methods which fail to incorporate the drilled solids in an equation which is applicable to vertical flow. Hughes Tool Co. Bulletins No. 23' and 23-A3 present data for determining circulation rates based on the Weymouth formula. These data do not include the drilling rate as a parameter and, therefore, neglect the effect of the solids being transported up the annulus. In spite of this apparent defect and the fact that the Weymouth formula is not applicable to vertical flow, the Hughes data have well served the drilling industry in many areas and are important and timely contributions to the science of air and gas drilling. The Hughes data purposely omit a correction for increasing down-hole temperature. At slow drilling rates this effectively compensates for the use of a formula which is not valid for vertical flow; however, volumes determined by the Hughes method are not sufficient to support rapid drilling rates at moderate and great depths. For example, Phillips Petroleum Co.'s Cauthorn "D" No. l in the Vinegarone field for Val Verde County, Tex., was air drilled from 1,500 to 9,300 ft using a compressor delivering 1,400 cu ft/min. The 8 3/4-in hole was drilled with 5-in. drill pipe, and drilling rates as high as 90 ft/hr were obtained between 7,000 and 9,300 ft. No water or caving hole was encountered. At 7,728 ft it was necessary to wash-out 60 ft of cuttings to reach bottom after a trip to change bits. At 8,130 ft a twist-off occurred and the drill col-lars were stuck in drill cuttings. These difficulties indicate that the 1,400 cu ft/min of air was not sufficient to keep the hole clean. Hughes data indicates that 1,180 cu ft/min is sufficient to produce an annular ve-

Jan 1, 1958

By P. Tukkaraja, K. Katzenstein

"Block caving is one of the most economical and efficient underground mining methods and has gained popularity around the world especially for extracting low grade and massive ore bodies. However, during the extraction of ore from the draw bells, gases trapped inside the cave could emit into the working areas; hence, ventilation plays a key role in operating block cave mines successfully where gas emission is a concern. To design an effective ventilation system for a block caving mine, given the dynamic nature of the caving process, it is necessary to develop airflow characteristic curves (P-Q) for a given cave. This study uses a 1:100 scale physical model with an exhaust fan system, and a Computational Fluid Dynamics model of a block cave to investigate the airflow behavior through the cave filled with broken rock material. From this study, it was observed that the cave airflow resistance increases with the decrease in cave porosity and the particle size.INTRODUCTIONThe block cave mining method is gaining popularity owing to its low cost and high productivity. This study considered a case where this bulk mining method is used for the extraction of an orebody that contains uranium mineralization. During the extraction of broken ore from the draw bells, radioactive gases trapped in the cave zone could be released into the production drifts and could create unsafe working conditions in the mine. Mine ventilation systems play an important role in regulating the migration of radon in working areas. One of the strategies to control radon migration in a block cave mine is to exert negative pressure on the cave zone by using an exhaust fan above the cave zone. In order to select an appropriate exhaust fan system, it is necessary to study the airflow resistance of the cave zone (Loring & Nelson, 2006).Extraction of broken ore via drawpoints creates a void volume inside the cave called the air gap. Air gaps with larger heights can lead to air blasts in a block cave mine should the cave collapse. Besides that, the air gap can also lead to decrease in ventilation system efficiency due to recirculation of air flow and associated shock losses. Air gap height can also have a profound effect on the variation of cave airflow resistance (Erogul et al., 2015, 2017). The knowledge of cave airflow resistance is also important for predicting the intensity of an air blast. Cave airflow resistance is a function of cave properties such as broken rock size, air gap, and porosity inside the cave zone (Baysal et al., 2017). Initially, a scaled experimental model with a forcing system was developed to investigate the airflow behavior through the cave, however, this model couldn’t provide an observable change in the airflow resistance when the cave properties were changed (cave porosity, and airgap) This was attributed to the difficulties associated with forcing system in terms of achieving lower porosity values with the available material (lightweight shipping boxes) for simulating broken rock inside the cave zones, and controlling air leakage from the model (Ajitha et al., 2018)."

Jan 1, 2019

By George A. Packard

The experiments here described were made under my supervision while temporarily acting as head of the Department of Metallurgy at the Missouri School of Mines, at Rolla. The work was done by Messrs. W. E. Brown, W. C. Richards, and F. L. L. Wilson, and the description of the results forms a portion of a thesis presented for the degree of Bachelor of Science. These results are submitted because I have seen no description of the application of pot-roasting to the treatment of a copper-concentrate. This work followed that already described in the discussion of the Lime-Roasting of a Galena-Concentrate,' and was similarly occasioned by the lack of a furnace of the reverberatory type in which the copper-concentrates could be smelted. The material for the tests was a mixture of three lots available. The first consisted of 8-mm. ,jig-concentrates and the second of 0.5-mm. table-concentrates, from the San Juan district, Colo. Both contained pyrite, chalcopyrite, and galena. The third was a lot of copper-ore, found in the laboratory, which had been crushed through 8-mm. screen, and had at some previous time, before the laboratory roasting-furnace was torn down, received a partial roasting. The analyses of these ores are given in Table I. In order to determine the applicability of pot-roasting as to each lot of ore, and the effect of varying proportions of lime, six preliminary tests were made in a " size N " Battersea crucible, 9 in. high by 6 in. in diameter at top, with a 5/8-in. hole bored through the bottom. The crucible was set in the upturned elbow of a 2-in. pipe, the joint being luted with clay; and air was obtained from a receiver supplied by a compressor. The

Jan 1, 1908

By S. S. Ryu, J. C. Kim, H. Lee, Y. D. Kim, I. H. Moon

"Recently, W-Cu alloy becomes one of the very important candidate materials for heat sink and packaging in the field of microelectronics due to its good thermal properties. The metal injection molding of W-Cu powder can satisfy the requirement for mass production of complex shaped parts in microelectronic devices. In the present study, the application of MIM process to the nanostructured W-Cu powder prepared by mechanical alloying was investigated. The multi-component binder system of 45PW+ l 5BW+ 30PE+ I OSA was proven to be suitable one for the MIM of the W-Cu composite powders by adopting the debinding cycles of multi-stage in N2 and H2 atmospheres. Other process conditions for the MIM of the nanostructured W-Cu composite powder were also studied. The MIM debinding part of W-30wt.%Cu was sintered to the relative density of more than 96% by sintering at 1200 °C for !hour in H2 atmosphere. Such an improvement of sinterability was attributed to the intrinsic homogenous and fine mixing state of W-Cu phases in nanostructured W-Cu composite powders, and also partly to the effect of the activated sintering by the presence of impurity introduced during the extensive milling.IntroductionW-Cu alloys have been widely used for heavy duty electrical contacts and arcing resistance electrode(1-2). Recently there has been a growing interest in this W-Cu alloy because of its superior thermal managing properties and its high micro wave absorption capacity(3). Such W-Cu alloy parts are conventionally fabricated either by the Cu infiltration sintering technique or by hot pressing of W-Cu powder mixtures. However, these conventional PM techniques are hardly applicable for mass production of small size parts with a complicated shape such as the parts required for microelectronic devices. The metal injection molding(MIM) technique is potentially applicable for the mass production of small and complicatedly shaped parts compared with other PIM forming techniques."

Jan 1, 1998

By P. Lenegan, R. Masethe, R. I. L. Ferreira

Underground mining in high rock-stress environments can induce unanticipated dynamic rockmass deformation, posing a serious risk to the workforce. Data collected by seismic networks are imperative for the design-as-you-mine process. Often an inappropriate assessment of the seismic hazard is done when unnecessary data are included in analytical techniques, particularly short-term time frames. Depending on the methodology or application of data analysis and interpretation, some of the information may not be relevant and even detract from the objective. By using the spatial event clusters associated with active workplaces to define the shape and size of the polygons for data selection for subsequent analysis, a problematic subjective component can be eliminated. The mining of tabular reefs in South Africa, be they gold- or platinum group metals, is very extensive, and underground workplaces are often widespread. Production stoppages are very costly, especially for marginal mines, so there is just cause not to evacuate an entire operation’s workforce following the occurrence of a large mining-induced seismic event. A rationale based on the damaging peak particle velocities (PPV) of the past seismicity can exclude the unaffected underground personnel and allow a quick orderly withdrawal where required. Micro-deformation may precede rockbursting, which can occur on-shift close to the workface. A mine-wide array of geophones suitable for the accurate location and analysis of seismicity may not be able to detect these higher-frequency emissions. Inexpensive but fit-for-purpose accelerometers, providing real-time, continuous measurement of acoustic rockmass deformation near the workplace, integrated through underground and surface communications networks, are shown to record ‘rock-talk’, clearly distinguishable from the instrument background noise, which can be in the order of hours leading up to an imminent damaging seismic event.

Jan 12, 2025

By W. J. Fene

It is often desired to obtain samples of air in places where collection by ordinary methods is not feasible, as in shafts amore means of descent or ascent are not provided, in sewer manholes, in gas or water wells, in empty oil tanks, and in sealed areas in mines. Heretofore, when such sampling was required, it was necessary to utilize the aspirating method, which was not always satisfactory; and to obtain samples of air in deep shafts, it was necessary to use long sections of rubber tubing, which was not always available. DESCRIPTION OF NEW DEVICE A new method or "device" employs a common snap-type mousetrap to break the neck of a vacuum tube at the place where it is desired to collect the sample (see fig. 1). A mousetrap is mounted on one end of a block of wood 11-3/4 by 3 by 3/4 inches in such camper that a lead weight attached to the trigger hall spring the trap when the device is given a sharp jerk. A vacuum tube is placed on the other end of the block and held in place by a strong rubber band. A strip of corrugated rubber is placed on each side of the grooved block to prevent the tube from clipping when the sample is taken. An adjustable shoulder, provided with a rubber cap, is pieced se that the neck of the vacuum tube will rest on it. The shoulder is made adjustable to accommodate various sizes of tubas and to keep the neck of the tube from breaking tee far back from the point. A metal handle is fastened to one end of the block, with a hole in the end through which the brass wire used for lowering the device is tied. The device is enclosed by a strong wire-gauge covering, hinged on one side and so arranged that it can be locked shut on the other side. This covering prevent: breaking of the tube while it is being lowered or raised in a shaft or other place. Brass wire of not less than 22 gage should be used for lowering the device. A detailed drawing of the device is shown in figure 2.

Jan 1, 1940

By David T. Farber

"Stabilization of an existing cellular tower foundation system without dismantling the tower or compromising the existing foundation system was accomplished by installation of a jet grouted pile system. The tower was originally designed to be placed on a steep hillside and to be supported by a mat foundation founded on existing bedrock. The as-built conditions of the tower foundation system showed it to be constructed on a combination of loose fill of varying thickness and native stiff silts and gravel material. To avoid the potential of differential settlement, a jet grouted pile foundation system was installed to the top of bedrock. The jet grouted pile system was rapidly installed over a two-day period so as to not delay operational permitting of the tower.INTRODUCTIONA tri-legged lattice cellular communication tower was constructed on the side of a steep hill located in a mature hard wood forest. Access to the site as well as available work area was limited to small track type drill rigs and equipment. The original tower design required the tower to be supported by a mat foundation bearing directly on bedrock. Based on a review of the foundation construction and results of a subsurface investigation, it was discovered that the foundation was built directly over a loose fill material that varied in thickness from 0 to 4.27 meters (0 to 14-ft). Because of the uncompacted nature and varying thickness of the loose fill materials, the tower would be susceptible to differential settlement which, could lead to tower instability.The objectives of this project included the following:• stabilize the mat foundation against differential settlement without removing the existing tower structure or foundation system• rapidly complete stabilization activities to allow operational permitting of the towerSOIL CONDITIONSThe subsurface soil conditions that the tower mat foundation rested on were evaluated by installing three borings in a row from the inward slope portion of the mat foundation (B-1) to the outward slope portion of the mat foundation (B-3). Figure 1 illustrates the subsurface soil stratigraphy. The three borings encountered the following subsurface conditions:"

Jan 1, 2005

By AIME AIME

OVER-ALL operations of the oil industry, as measured by production of crude oil and consumption of products, are almost exactly of the same magnitude as a year ago. Does this mean that the great oil industry has been undisturbed by the war? Has this industry, so vital to the prosecution of the war and to the maintenance of our way of life, been unaffected in its operations? No indeed - changes within the industry are great. It has been called upon to revamp its trans¬portation methods so as to move about one fourth of the total amount of crude and refined products by railroad tank car instead of by ocean-going tankers. Its fundamental internal economy, based on maximum gasoline yield from a barrel of crude, has been relegated to memories of the past. Rationing of oil products, which has been forced upon us in face of an abundant supply, is not only disagreeable medicine but is in itself completely disruptive to the marketing end of the-business.-

Jan 1, 1942

By K. H. Boss

In modern iron pelletizing plants fuel consumption has been optimized to such an extent that only minor savings can be expected in the future. Inspite of this fact, different process parameters were studied with a mathematical model and firing tests. The influence on fuel consumption and productivity was established. Furthermore, the adoption of simplified firing patterns was investigated, in particular for coal firing. In view of high costs of oil and natural gas, only substitution of these fuels by coal can substantially reduce production costs. In existing plants partial replacement of oil and gas can be achieved by addition of coal to the iron ore feed and by firing the pellets with pulverized coal. Two systems have been developed for the Lurgi- Dravo travelling grate process which enables coal to completely replace oil or gas. This paper describes in the first part the potentials for fuel savings available in the Lurgi-Dravo process. In the second part, different techniques for the use of coal as fuel in iron or pelletizing plants and in particular the recently developed Lurgi Multistage Coal Injection and Combustion Process (LMC) are discussed. Combined with the LMC process, a wide variety of iron ores and coals - also with high ash contents - can be used in the Lurgi-Dravo travelling grate process.

Jan 1, 1983

By M. A. Trevits, A. Ozment

"According to the Office of Surface Mining Reclamation and Enforcement Abandoned Mine Land Inventory System, in 2013 there were 98 underground mine fires burning in 9 states. This is considered by experts to be an underestimate for the actual number of fires nationwide. Abandoned mine fires, if left uncontrolled can burn for years and in fact, one of the most well-known mine fires in the US, the mine fire in Centralia, PA, which began in 1962 has been burning for over 55 years. In Centralia, the mine fire won the battle, despite suppression and control efforts, as most of the residents were bought out by the State of Pennsylvania and moved away. However, the world record for the longest-burning coal fire, which may have been started around 6,000 years ago in New South Wales, Australia is still smoldering. Suppressing a coal mine fire requires cooling the hot zones and removing any source of oxygen. If the workings are shallow, the fire zones can be unearthed and the burning rock mass can be quenched on the surface. If the workings are too deep to excavate, then the fire must be fought remotely through boreholes using a variety of agents including water, gas-enhanced foam and grout. Access to surface areas for drilling can be problematic due to topographic and property constraints. When this occurs, large areas of burning may go unaddressed or simply left to burn. Fire Solutions, Inc. has been investigating the use of gas-enhanced foam in concert with directional drilling technology. Gas-enhanced foam has the advantage of using less water and adds inert nitrogen gas to displace oxygen to infiltrate and suppress a fire. Directional drilling has the capability to steer a borehole to a specific place underground. Directional drilling has many advantages over conventional drilling technology as it can provide the least disruption to the ground surface, minimize surface preparation and reclamation costs, multiple sites can be accessed underground from a single site and thus treated simultaneously and it offers increased efficiency because it is not constrained by difficult terrain. This paper discusses the combined use of these two technologies and it is hoped that with the use of these two technologies the efficiency and capability to address mine fires will be significantly improved. INTRODUCTION According to the Office of Surface Mining Reclamation and Enforcement, Abandoned Mine Land Inventory System, in 2013 there were 98 underground mine fires in 9 states. This is considered to be an underestimate for the actual number of fires nationwide. Many mine fires are started by people burning trash where the coal seam or an abandoned coal mine is close to the surface. Other fire ignition sources include lightning and forest fires. Once ignited, a coal mine fire can easily spread into the remaining coal pillars and mine entries. Once established, the fire creates its own ventilation system supporting further combustion by drawing air down into the workings through unsealed mine shafts, fractures and surface subsidence depressions. As the coal left in the workings from the past mining operations burns, the mine void can collapse, causing subsidence and creating dangerous voids, damaging damage overlying surface structures and roadways. The products of combustion include smoke and noxious fumes such as carbon monoxide gas. These products are released to the atmosphere through fractures that develop within the ground surface, killing vegetation and creating serious health hazards [1]."

Jan 1, 2018

By W. P. Blacutt

A financial-economic model incorporating physical, market, and policy variables is developed for mining investment in Bolivia. Additional risk criteria emanating from political instability. new mining legislation, recent environmental regulations, and a new minerals taxation system are accounted for and are integrated into the investment decision model. Results of the model indicate that geologic and market variables have the dominant effect on the investment-worth function. Among policy variables, exchange rate and taxation policies have the most significant influence. Depreciation allowance for infrastructure development has negligible weight in the investment-worth function. The business structure of the firm considering investing in the Bolivian Polymetallic Project is found to be an instrumental factor in the investment-worth outcome. Specifically, undiversified mining companies whose operations exclude zinc production as the primary source of revenue would benefit most from adoption of this project.

Jan 1, 1993

By Steven R. Lowe

Construction of a pump station, consisting of an inlet chamber, wet well and pump chamber, required excavation to a depth of 9.7 m (32 ft) below ground surface and more than 7.6 m (25 ft) below the ground water table in a rural, but rapidly developing part of southern New Jersey. Private houses are located [ ] within a few hundred feet of the pump station that use shallow wells for water supply. The pump station design anticipated support of the entire pump station on shallow foundations bearing directly on the underlying natural soils. However, during construction, uncontrolled ground water flow caused ground loss and damage to the bearing qualities of foundation soils. As a result, remedial repairs were required including support of the pump station on drilled pile foundations and releveling of the pump chamber that had settled. This case study is an example of where a poor understanding of the significance of upward flowing ground water had a major impact on the cost of construction. Anticipated subsurface conditions The pump station layout is shown in Fig. 1 with the locations of two borings made prior to construction superimposed. One of the borings was located within the footprint of the deep wet well excavation. Generally, this is not advisable where a deep excavation is required below the ground water table. This is because there is a history of projects where ground water seepage, or pressure, has broken out into an excavation through an ungrouted borehole and compromised the integrity of foundation soils. Logs of the borings did not indicate that the borings [ ] were grouted upon completion.

Jan 1, 2011

By J. D. McLenegan

The purpose of this investigation was to prepare a market survey of the refractories industry in California and Nevada (referred to in subsequent paragraphs as the region), and to determine the degree of self-sufficiency and the potential capacity for anticipated growth. The report includes estimates of the total annual refractories consumption, the quantity of refractories imported into the region, the tonnage of raw materials required for their manufacture, and the resources of fire clay and high-alumina minerals in the region.

Jan 1, 1956

By W. A. Dunkley

During the past year and a half the Western United Corporation of Aurora , Illinois , has been distributing carburetted water ges from its Lockport , Ill . , plant , to an extensive territory , under an initial pressure ranging up to 90 lb.. per sq. in . The most distant distributing point on the system is at Harvard , Ill . , about 35 miles from the plant.. The territory supplied is approximately 85 miles long and 35 miles wide , the total mileage of rains being 1223 , or approximately 24 per cent of all the gas trains in Illinois outside the city of Chicago .

Feb 1, 1923

By Clyde L. Brown

Recent developments in portable communication equipment for use in emergency recovery work following mine fires and explosions have wade possible a convenient and dependable means of directing rescue teams working under hazardous conditions. INTRODUCTION Mine rescue and recovery operations following; fires and explosions are frequently conducted under adverse conditions that require the use of oxygen breathing apparatus by members of a 5- or 6-man team. Conventional apparatus used for this purpose for many years was equipped with an oxygen supply adequate for at least 2 hours. The design of the apparatus is such that the nose passages are closed with a clamp, and breathing is accomplished through a mouthpiece connected to the apparatus by tubes and arranged to prevent inhaling air or gases from outside sources. The use of the mouthpiece has presented difficulties in the development of telephone communication because of the wearer's inability to speak while wearing the mouthpiece. The method of conducting operations of rescue teams requires a person to direct operations at a fresh-air base as close to the rescue team as possible. At least one standby rescue team and 2 or 3 other persons assigned to various tasks are stationed at the fresh-air base. An efficient and reliable means of communication between the director of operations and the rescue team is necessary for reasonably safe and efficient work in hazardous areas.

Jan 1, 1957

By E. M. SEELEY, F. S. LOTT

Expansion in total capacity of the natural-gasoline industry.to produce light products continued in 1944 and 1945. The average rate of gain, however, was reduced to about 6 percent annually from over 9 percent in the preceding 4-year period. New facilities at cycle plants again accounted for most of the increase in productive capacity. Between January 1, 1944, and January 1, 1946, the number of cycle plants increased from 32 to 37 and their total capacity from 3,278 thousand gallons daily to 4,848 thousand (48 percent). Capacity of all other plants in the industry increased in the same period from 12,735 thousand gallons daily to 13,080 thousand, or only 3 percent. The capacity of the average plant increased to 28,600 gallons a day from 24,400 gallons on January 1, 1944, continuing the established trend. The average capacity of cycle plants increased to 131,000 gallons a day from 102,400 gallons, and the average capacity of all other natural-gasoline plants increased to 22,200 gallons a day from 20,400 gallons. Although the number of plants increased in only three States in the 2-year period (Texas, Okla- homa, and Arkansas), the total capacity of plants increased in eight States. A further decline of 29 reduced the total number of plants to 626 on January 1, 1946. Compared with 10 years earlier, gasoline plants were more numerous in only 4 States: Texas (48 more), New Mexico (7 more), Arkansas (2 more), and Louisiana (1 more). The largest declines, in order, were in Oklahoma, Illinois, Pennsylvania, West Virginia, and California. The number of plants with fractionating equipment for separating the liquefied gases from heavier fractions was 202 on January 1, 1946 and 182 2 years earlier. The principal changes in number and capacity of shut-down plants were an increase in Texas and a decrease in California. Shut-down natural-gaso- line plants are usually among the smallest units in their vicinity.

Apr 1, 1947

By F. W. Tregarthen

"This paper gives a brief description of the methods used to form and implement the present planned maintenance program. The system is designed to assist plant personnel in their task of controlling a large work-force and maintaining the many and varied types of equipment used in a mining and concentrator operation. The types of reports and methods used in scheduling and work-loading are described. General built-in flexibility is derived from computer assistance to the Central Planning Group."

Jan 1, 1971

By Harold H. Fukubayashi

The effect of various zinc electrowinning solution impurities on the surface morphology of deposited zinc was investigated. Impurities studied included Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, Pb02, PbSO4, and HC1. Also, the effect of animal glue, gum arabic, and Na2SiO3 additives on the deposited zinc surface structure was studied. Results were compared with deposits from a pure electrolyte consisting of H2SO4 and Zn+2, 200 and 65 gpl, respectively. Zinc was deposited on a Al cathode, 99.9 pct pure, using Pt anodes. Time, temperature, current density, and impurity concentrations were con¬troller The bulk of the tests were conducted at 40° C and 75 A/ft2 (82 mA/cm2). A scanning electron microscope (SEM) was used to examine the surface morphology. X ray diffraction techniques were used to determine crystal orientation and nondispersive X-ray spectrometer analyses were employed in an attempt to locate impurity concentrations on the zinc deposit when pitting or re-solution occurred. The impurities were categorized by their effect on current efficiency, morphology, and apparent mechanism of H2 evolution from the cathode.

Jan 1, 1974

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By John Demol

Monazite, a rare earth and thorium phosphate mineral, is one of the major minerals processed for extraction of rare earths. Industry practice for treating monazite concentrates is to use either a sulfuric acid bake or caustic conversion route. In the sulfuric acid bake, monazite concentrate is mixed with concentrated sulfuric acid and roasted. The rare earth phosphate mineral is converted to rare earth sulfate which dissolves in a subsequent water leach. As the bake temperature increases above 300 °C, thorium becomes less soluble. Although acid baking is practised in industry, the bake reactions are not well understood. A combination of chemical analysis, XRD and SEM-EDS was used to identify reaction processes occurring during sulfuric acid baking of a 93 wt% monazite concentrate between 200 °C and 800 °C. The effects of these reactions on the leachability of the rare earths, thorium and phosphate were also examined.