Search Documents

By David N/A Doucet, Colter N/A Angell, William N/A Joa, Kyle N/A Wagner, Catherine N/A Johnson, Marty N/A Langenderfer

The Kingery-Bulmash (K-B) equations are a widely accepted means of predicting air-blast parameters from surface explosive detonations. The parameters predicted from these calculations include incident and reflected pressure, time of arrival, shock front velocity, incident impulse, reflected impulse, and positive phase duration. K-B calculations are based on curve fitting of experimental data and can be used to predict air-blast parameters for explosive weights from less than 1 kg (2.2 pounds) up to 400,000 kg (440.9 US Tons), and ranges of 0.05 to 40 meters (1.9 inches to 131.2 feet). The K-B equations can also determine the parameters for multiple explosive types using scaled distances and relative equivalency to TNT. An experiment was designed to demonstrate if the measured results for incident pressure, time of arrival, shock front velocity, incident impulse, and positive phase duration equal the expected results reported for the detonation of a small quantity of explosive determined by the K-B Calculator. Three surface-detonated 300-gram (0.66 pound) hemispherical charges of Composition C-4 were observed via high-speed imaging and hydrostatic pressure monitoring. The hydrostatic pressure generated from each charge was measured via piezoelectric pressure transducers at a scaled distance of 10 from the charge epicenter, and at elevations of 0.30, 0.61, and 1.22 meters (1, 2, and 4 feet) above ground level. Variances in experimental values from the K-B predicted values were recorded for each measured blast parameter. Time of arrival, which was redundantly confirmed through high-speed imaging analysis and hydrostatic pressure monitoring, showed the highest deviation from the predicted values at more than double the K-B predicted value. This report compares the observed blast parameters from the test series with the expected blast parameters from the Kingery-Bulmash Blast Parameter Calculator. Differences between the experimental and predicted values are reconciled through analysis and discussion of testing conditions, instrumentation setup, and scaling methods.

Jan 1, 2019

Separation performance of a Floatex Density Separator (FDS) has been studied both experimentally and theoretically. Experimental results reveal that at a lower bed pressure the FDS acts like a classifier. Higher bed pressure is required to attain the concentration effect as proper development of suspension density occurs under these conditions. It is seen that the size or density alone is not able to describe the partition fully. The terminal settling velocity, which includes both the size as well as the density of the particle can be a useful descriptor of separation in a FDS. While a narrowly distributed feed offers better performance of a FDS, a wide size distribution of feed results in large scatter in the terminal settling velocity distribution and renders the separation difficult. The closely sized feed enhances the density effect in concentration. A higher teeter water flow rate also helps in carrying larger-lighter particles to the overflow by increasing the cut off terminal settling velocity as it increases the net upward force. A detailed description of separation performance in a Floatex Density Separator has also been established from theoretical considerations. Separation performance of the separator is described using a simple slip velocity model. The model has been validated com-paring the predicted FDS performance results with those experimentally measured under widely different operating conditions.

Jan 1, 2014

By M. M. K. McCrank

"PRACTICAL SAMPLING TECHNIQUESIt is important to achieve reliability when sampling heterogeneous materials where there is a difference in composition, and non random distribution of the constituent particles. Throughout the design, construction and installation of sampling systems it must be borne in mind that the sampling point must be capable of:-allowing each particle in the stream an equal opportunity to be sampled.-accepting and collecting as large a volume or mass of material as necessary to satisfy the requirements of particle counting statistics.-establishing a sampling plan so that the sample is representative of the whole to a defined standard of accuracy.Design ConsiderationsFactors that may influence the design of the sample point include:-the mass, or volume flow rate of the material being sampled-the size and shape of the material or flowing stream-the physical condition of the material being sampled (i.e. temperature, wetness, size consist, density).-the chemical composition of the material being sampled -the location of the sample point and the space available for installation, extraction, reduction where necessary, secondary sampling, and return of the sample rejects downstream.-whether the process to be sampled is in an existing plant or one yet to be designed and built.-ease of access for servicing and maintaining the equipment.-whether the sampled material must be collected continuously or intermittently.-whether an existing sampling method is likely to be adequate or whether a new technique has to be developed."

Jan 1, 1989

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel.oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which typo of plant utilizes more thou the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which crude oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining. Although no outstanding technical developments of a fuel-saving nature were made in 1934, some progress undoubtedly was recorded. Heat exchangers, an effective fuel-saving device, wore enlarged, and some refiners now take off several cuts before the crude reaches the pipe stills. The total capacity of pipe stills increased 2.5 percent in 1934, and many of the less efficient shell stills were torn out.

Jan 1, 1935

By Robert T. DeGavre

I have been asked by the Society of Mining Engineers to present a paper on Inco Limited's Indonesian nickel project as a case study in the financing of large overseas mining projects. I welcome this opportunity It is a story worth telling not only because the project itself represents a significant human achievement but also because there are certain important lessons that can be derived from our experience in financing the project. The paper will be divided into four sections: (i) a brief history of the project, (ii) a critical appraisal of the project's financing plan in terms of the goals that we sought to achieve, (iii) some comments on certain factors underlying the relative success of the financing plan, and (iv) the contributions that the engineering staffs must make to a successful financing plan. The paper will not present a technical assessment of the project since Inco Limited has been asked to submit a series of papers on this subject at the International Laterite Symposium as part of the 108th Annual Meeting of the AIME in February 1979.

Jan 1, 1978

By D. L. Moellenberg

Under various state laws enacted mostly within the last 20 years, reclamation requirements and standards for hard-rock mining operations have been established virtually everywhere in the western United States. Unlike the uniform and detailed coal mine reclamation requirements under the federal Surface Mining Control and Reclamation Act ( "SMCRA" ) and state programs mode led after SMCRA, the various state law hard-rock mine reclamation requirements are based upon a variety of objectives, and therefore are subject to varying standards from state to state. While the diversity of reclamation requirements complicates the determination of what reclamation measures will be required at any particular mine, there are valid reasons for this diversity. There are dozens of different commodities mined in the United States, and mining methods are different for each commodity. Local natural conditions such as climate, precipitation, geology, hydrology, and biology vary widely across the county. Site-specific conditions also affect mining and reclamation methods. Also, factors such as economics, land use, and environmental protection issues receive different priorities in different states and communities within those states. State reclamation requirements in general provide the flexibility to consider site-specific circumstances, allowing operators to design and engineer the best reclamation measures for each mining site. To the mine developer or manager, reclamation requirements must be translated into design, operational, and closure measures for mine planning. Each of these measures must then be assigned additional costs to be factored into the economic decisions for a particular mining operation. On a broader level, reclamation costs must be factored into decisions such as where to invest in exploration and mine development. The purpose of this paper is to provide a summary of the state non-coal mine reclamation requirements in twelve western states. This summary comparison may be useful as a starting point in considering how local reclamation requirements will impact potential mining costs.

Jan 1, 1994

By Feng-guang Li, Rui Guo, Ju Zhang

Cooling stave is one of the most important equipment of blast furnace for iron making. The heat transfer performance and service life of the cooling stave, to a large extent, determines the efficiency and economy of the iron making process. In this paper, a 3-D heat transfer model of cooling stave was founded by ANSYS based on FEM theory, and the heat transfer characteristics of cooling staves which were made of different materials (cast iron, cast steel and copper) were analyzed. Then, several suggestions on choosing material of cooling staves were given according to the calculation results and the actual working conditions of the cooling staves.

Mar 1, 2017

By C J. Carr

The Ernest Henry Mine (EHM) is owned and operated by Xstrata Copper and is located in North-West Queensland, Australia. The mine is currently undergoing a transition from an 11 Mtpa open pit mine to a large sublevel cave underground mine producing 6 Mtpa. Due to a number of factors, including geometry of the pit and crusher depth, the decision has been taken to develop a hoisting shaft rather than inclined conveyors.During the feasibility study the strip and line shaft sinking methodology was preferred over blind sinking due to scheduling opportunities and interactions with level development. Other methods of sinking considered included large-diameter raise boring, which was rejected due to concerns relating to centreline accuracy. The strip and line decision was reviewed during the tender process where better than anticipated blind sink advance rates and costs were presented. This in turn enabled the higher cost of the blind sinking method to be justified by a combination of reduced risks including schedule and ground water management. This paper discusses the pros and cons of both strip and line and blind sinking methodologies in the Ernest Henry context including sinking rates and total schedule impacts of the two methods, the key risks associated with each method, cost implications of blind sinking and safety implications of the work methods in general. The paper then concludes with the reasoning behind the decision to change to blind sinking for the EHM shaft.

Mar 21, 2011

By Ernest D. Mast

Noranda's Altonorte custom smelter, located in the 2nd region of Chile, 20 kilometres southeast of the city of Antofagasta, started operations in 1993. Presently, 1150 tonnes per day of new feed are smelted with an 85% sulphur capture. An oxy-fuel reverberatory furnace produces a 48%-55% copper matte that is treated in 13 ft. x 36 ft. (3..96m x 10.97m) Peirce-Smith converters (two hot and one blowing). Up to thirty percent of the new concentrate is smelted via dry concentrate injection into the converters. This paper reviews the development of the concentrate drying and injection system, and oxygen enrichment at Altonorte from start-up in 1995 to the present time. The relationship between oxygen enrichment and concentrate injection is reviewed from a theoretical and practical standpoint. Concentrate injection has improved the smelter's productivity and added flexibility to the operations. Due to the relatively high matte grades and the subsequent short converting times, maintaining consistent operations was difficult at times and the smelter has gone through a learning curve. Plant operating results and experiences are presented on the impact of concentrate injection in relation to: feed treatment, blowing times, revert generation, slag quality and refractory wear.

Jan 1, 1999

By P. M. Solozhenkin

On the territory Sakha (Yakutia) are located largest in Russian Federation reserves of antimony ores, Sarylakhsk and Sentochansk deposits, amaunt 10% of world stocks of antimony. A processing gold antimony ores Sarylakhsk deposit is carried out on gravitation-flotation circuit to receive gold gravitation concentrate and gold-antimony flotation concentrate with the contents of antimony over 60%. The gold-bearing concentrate is treated on place hydrometallurgicaly to a high-standard product, accepted by gold bank cash department. At the ore dressing plant reached the highest recovery in world in a concentrate of antimony 90%~91.6%, and gold 85.7%~86.0% as a result of scientific research works. Studied the mechanism of interaction cations of metals Pb2+, Cu2+, Cd2+, Hg2+, Ag+ with a surface antimonite presented on the basis of modern physical-chemical methods: nuclear quadrupol resonance, x-ray electron spectroscopy, electron spin resonance. The industrial tests of sodium dimethyldithiocarbate were carried out which confirmed high recovery of Sb and As. The leaching Sb2S3 by bacteria Desulfovibro desulfuricans and transformation antimonite in antimony trioxide by Tiobacillus Ferrooxidans improved following cyanidation . The extraction of antimony in a solution 96.0%~98.0% under optimal conditions. The common total extraction in the appropriate commodity products for gold reached 98%, for Sb 96.5%. At a combination of bioprocessing and cyanidation 85.5% of extraction Au was achieved. The new solvents for antimonite were found. Now by the Close Joint-Stock Co ?Sarylach-Antimony? industrial plant is constructed for processing Au-Sb concentrates to receive antimony trioxide and gold from various antimony deposits of Sakha (Yakutia).

Jan 1, 2014

By K. A. Mackinnon

The choice of fan type (axial flow, centrifugal or mixed flow) most suited for a mine ventilation application depends on a number of technical and economic factors. For each project, the relative importance of these factors will vary. It is worthwhile to carry out an assessment on a case by case basis. The paper, by discussing a number of technical and economic factors and their interactions, will provide the ventilation official a methodology to easily and methodically undertake such an assessment.

Aug 1, 2013

By Joe Roby

Rolling disc cutters are the business end of hard-rock and mixed-face tunnel boring machines (TBMs). Since their first successful employment on a TBM more than 50 years ago, disc cutter technology has constantly evolved, allowing modern TBMs to excavate very hard and abrasive rock efficiently. Disc cutters have also been employed successfully on earth pressure balance (EPB) and slurry machines, cutting rock under water and ground pressure. The range of materials excavated by machines today is broader, excavation rates are higher and cutter costs are lower than ever before, proving the value of investment in cutter development. Disc cutters are used on a range of tunneling equipment, from pipe jacked slurry micro-TBMs less than 1 m (3.3 ft) in diameter to 15 m (49 ft) in diameter, hard-rock boring TBMs. The geological conditions under which they are employed range from sands and gravels, with several bar of water pressure, to extremely hard, massive rock with UCS up to 420 MPa. Regardless of the type of machine or geology, one thing remains constant: changing worn out cutters is costly. When cutters must be changed in the middle of a tunnel, the contractor incurs the cost of downtime as well as the cost of refurbishing or replacing the cutters. In the case of catastrophic cutter failures, the project can be stopped completely for long periods, and the costs mount up rapidly while tunnel production is at a stand still. Catastrophic cutter failures include the occasion when hard-rock disc cutters are failed in groups (called a ?wipeout? phenomenon) and the operator fails to stop the machine, which results in severe damage to the cutterhead. The cause of this can be either an undetected failed cutter propagating damage to surrounding cutters or operator error in steering. Regardless of the cause, the resulting damage can take days or even weeks to repair. When cutters fail prematurely on EPB or slurry machines in certain geological conditions, it is impossible to evacuate the chamber and, therefore, impossible to get [ ] into the chamber to change the cutters. The solution is frequently an unplanned intervention shaft that must be sunk at great cost. The importance of being able to predict cutter life accurately, and in all geological conditions, cannot be overemphasized. For these reasons, cutters have been developed for specific machine types and sizes, as well as for specific geological operating conditions. Different size cutters are required for different size machines. For example, while 483- and 508-mm (19- and 20-in.) cutters are used on large diameter TBMs, it is impossible to employ cutters so large on a small micro-TBM. Also, the cutter must be designed for the specific geological conditions under which it will be operating. The disc cutter rings required to bore extremely hard rock are the most expensive of cutter rings. However, they provide little advantage in weaker rock formations where less expensive rings will do the job as well. It is important to choose the correct cutter for the machine and the geological conditions in order to get the best balance of cost and risk.

Jan 1, 2009

By R. Bhaskar

The results of an experimental study on the dispersion and deposition characteristics of fine coal dust in mine airways are presented. Experiments were conducted at various flow velocities using bituminous and semi-anthracite-coal dust which had a large proportion of dust in the respirable size range. Cross sectional variations in the concentration of dust at various points in the airway were also measured. Instruments used in the experiments included gravimetric samplers and impactors. Concentration measurements were made both for the respirable and total airborne dust. The experimental design, sampling procedures and results are discussed. The study is aimed at providing a better understanding of the temporal and spatial behavior of dust particles in underground mine airways.

Jan 1, 1986

By M. M. Jones

Natural brines are potential domestic resources of minerals. The brines of Searles Lake, CA, for example, contain an estimated one-fourth of our current reserve of tungsten. A key to Bureau of Mines research to recover this critical mineral is the ability to quantitatively measure concentrations of particular constituents in the large number of brine samples and process solutions produced under a multiplicity of test conditions. This paper describes procedures used to determine arsenic, boron, phosphorus, silicon, and tungsten in these solutions by simultaneous inductively coupled plasma spectrometry. A variable in-ternal standard method was used to compensate for tungsten interference on the other analytes in tungsten concentrates, and matching standards were used to determine tungsten in raw brine. Other solutions were analyzed using normal techniques. Analytes were determined down to 1 mg/L with an average precision of 2.5 pet relative standard deviation. Accuracy, estimated using synthetic solutions and by comparison with values obtained by other methods, averaged about 2.5 pet. The methods were rapid, required little sample preparation, and provided the needed sensitivity.

Jan 1, 1985

By Georgene Renner, Chee Theng, William Gleason

"In February 2018, drawn in part by the states’ proud mining heritage, SME took its Annual Conference & Expo to Minneapolis, MN for the first time. More than 5,000 people and 554 exhibitors converged on the Minneapolis Convention Center for three days of networking, exhibiting and technical sessions.The state’s mining legacy, one that continues today, is fueled in large part by its vast iron ore resources in the northern part of the state. The historical significance of the mines in the Mesabi Range, otherwise known as the Iron Range north of Lake Superior, cannot be understated. “Mining is a way of life here,” said U.S. Congressman Rick Nolan of Minnesota’s 8th Congressional District. A native of the Iron Range, the three-term U.S. congressman was one of the featured speakers of the opening keynote session. “We like to think we contribute enormously to the well-being of this country and the world. We were the source of the iron ore and steel that helped win two world wars. And we like to think that we are part of the progress that has taken place in the United States ever since.” Nolan kicked off the keynote sessionthat focused on innovation and its part in the mining industry. The session included Rene Aquilar, vice president of corporate affairs and sustainability, Antofagasta Minerals Group; Bob Anderson, vice president for research and development, 3M; Rolf Weberg, executive director, Natural Resources Research Institute, University of Minnesota-Duluth and Christopher Beck, executive vice president and president, Nalco Water. The panel session looked at U.S. and global minerals production, and the importance of the United States to maintain a major role in the minerals industry, both as a producer and as a technology leader. The panel also touched on the global mining industry and the issues that impact mining around the world. Sustainability, the use of water in mining and earning a social license to operate were among the topics discussed by the panel.Speaking of the importance of mining, Nolan conceded that talking about the benefits of mining to the crowded auditorium at the SME conference might be akin to a preacher speaking to the choir, but, following the adage that all politics are local, he continued to illustrate his point by emphasizing the importance of mining to the Great Lakes.“A study by Homeland Security concluded that 13 percent of the nation’s GDP comes out of Lake Superior through the locks at Sault Ste. Marie and most of that is iron ore,” said Nolan. “That study found that, if those locks fail, it would create a national depression. It would put millions of people out of work. That ore and those minerals supply the steel mills, the auto industry, the heavy industrials. They are the heart of our economy. The study concluded that if the states that make up the Great Lakes were a nation, it would be the fourth largest economy in the world.”"

Jan 5, 2018

By G. R. Hopkins

The average quantity of heat needed to refine a barrel of crude oil in 1934 was 638,000 B.t.u., or about as much heat energy as contained in 5 gallons of fuel oil. Although the total heat utilized in 1934 was slightly above 1933, crude runs to stills increased 4 percent, hence the average requirement per barrel declined from 660,000 B.t.u. in 1933 to 638,000 B.t.u. in 1934 (see fig. 1). The average for 1934 constitutes a new record for firing efficiency, being just under the previous low of 1929. Heat consumption at refineries depends on many factors, of which the trends in yields of gasoline and lubricating oils are probably most important. The yield of gasoline is indicative of activity at cracking plants, which type of plant utilizes more than the average amount of heat per gallon of product. The yield of lubricating oils is indicative of the extent to which credo oil is refined; that is, it takes considerably more heat to refine a barrel of crude through lubricating oils than it does to separate only gasoline and kerosene. The yield of gasoline decreased from 43.7 percent in 1933 to 43.4 percent in 1934; on the other hand, the yield of gas oil and fuel oil increased. Although the yield of lubricating oils increased slightly in 1934 the theoretical increase in fuel requirements probably was offset by technical improvements, such as solvent refining.

Jan 1, 1935

By R. M. Lamya

A considerable part of gold encapsulated in some refractory sulphides can be dissolved during sulphide matrix decomposition in non-complexing aqueous media. This has been concluded from laboratory results of gold extraction from pyritic and arsenopyritic concentrate containing 172.8ppm Au, into 10% hydrochloric, sulphuric and nitric acids. The degree of sulphides decomposition in the non-oxidative acids limits the gold extraction from this specific concentrate to about 10%. In the case of nitric acid, the gold dissolution follows the rapid decomposition of sulphides, reaching 32 to 42% of extraction at almost total decomposition of the sulphidic minerals. Accumulation of gold in this acidic and non-complexing solution to several ppm was not affected by the soluble products of the sulphides decomposition. An attempt to explain this gold behaviour is undertaken and some practical implications are discussed. In the investigated concentrate the "soluble gold" is mostly associated with arsenopyrite. This is consistent with the latest findings of other authors that gold disseminated in arsenopyrite can occur as cation Au3+. In a comparative test the gold extraction into highly concentrated chloride solution, in the same oxidative conditions, amounted to 92.34%.

Jan 1, 1995

By L. Kaufman

A range of processing conditions and compositions have been evaluated in order to optimize the properties of TiB2-(Ni,Cu) composites for application as a non-sparking tool material for use in coal mining operations. Fifty billets containing from 70 to 9S weight percent titanium diboride were hot pressed at 3000 psi between 2400°F and 2650°F. Samples which were cut from these billets were used to measure hardness, bend strength and impact strength so that composition/processing optimization could be effected. Eight compositions selected on this basis were evaluated by incendivity tests in order to choose the best composition. The best results were obtained for an 85 w/o TiB2-12 w/o Cu-3 w/o Ni composite hot pressed at 2650°F and 3000 psi. This material appears to be the best choice for fabrication of coal cutter bits to be evaluated in field tests.

Jan 1, 1973

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke's law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section's susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By A. W. Sommer, H. H. Kellogg

It is shown that SO3-O2 mixtures react with sphalerite at an appreciable rate ill the temperature range of 361° to 527°C to fornz ZnSO4. The rate of reaction follows a parabolle lax. Oxygen, or O2-SO2 mixtures, have a negligible effect on sphalcrite in the same temperatuee range. PRACTICAL roasting of sphalerite is usually performed at 800°C or higher. The calcine is composed of zinc oxide unless the roaster atmosphere contains relatively large amounts of SO2 and the temperature is held to 800oC or lower, in which case zinc sul-fate may also form. Ong, Wadsworth, and assell' have made a careful kinetic study of sphalerite oxidation under these "normal conditions" and have concluded that the rate of the reaction is controlled by the decomposition of an activated complex adsorbed on the sphalerite surface. They found the rate of oxidation to be small at 700°C. Extrapolation of their data to 400°C would indicate an almost negligible rate at this temperature. In our work sphalerite was reacted with air, mixtures of SO2, O2, and N2, and mixtures of SO3, O2, and N2 in the temperature range 361o to 527OC. Negligible rates of oxidation were found, except for the gas mixtures containing SOs. With this latter gas, the oxidation of finely divided sphalerite was fairly rapid and zinc sulfate was the product. Based on the limited evidence available, the rate of sphalerite oxidation by SO3 is postulated to be controlled by gaseous diffusion through pores or cracks in the zinc-sulfate coating. This evidence for the direct reaction of sphalerite and SO, at low temperature may prove of importance to the understanding of zinc-sulfate formation in the dust-collecting equipment usually associated with zinc roasters. The roaster gas carries off fine dust, much of which may be unreacted sphalerite. The temperature in dust-collecting equipment drops from the roaster temperature (about 800°C) through the range of temperature we studied, to ambient temperature. Such dusts are known to contain far larger amounts of zinc sulfate than the primary calcine. It has been assumed in the past that this sulfate is formed by reaction of ZnO dust with SO3 (or SO, plus 0,) in the partly cooled gases. Our work shows that an alternative possibility exists—the direct reaction of SO3 with ZnS dust. EXPERIMENTAL Reaction rates for sphalerite at 350° to 600°C are relatively small so that it was necessary to use finely divided material with a relatively large surface area in order to obtain measureable amounts of reaction. In the preliminary experiments, pure mineral sphalerite, ground to pass a 325-mesh sieve, and chemically precipitated ZnS (in the form of an impalpable powder) were used. In the quantitative rate experiments the ground mineral sphalerite was processed in an Infrasizer to obtain a product with particle size between 9 and 18 µ. The analysis of this material was 66.7 pct Zn, 0.09 pct Fe, and 32.7 pct S (theoretical sphalerite is 67.1 pct Zn, 32.9 pct S). The sized powder was carefully mixed and divided into l-g samples. The apparatus used for the quantitative rate measurements is shown in Fig. 1. For the preliminary experiments the following change was made: The external catalyst furnace (B, C)* was not used. *Letters refer to Fig._______1 .___- Rather, when catalysis of the SO2 + O2 reaction was desired, the glass beads in basket M were replaced by vanadium-oxide pellets. Procedure—A l-g sample of ZnS was placed on a shallow stainless-steel tray, I, and spread evenly to a depth of about 1mm. The tray was placed in the reaction assembly and the assembly inserted in the cold furnace. The furnace tube was flushed with dry argon and then heated to the desired reaction temperature. The temperature was controlled to ±0.5oC. Gas mixtures (O2 + N2 or O2 + SO2) were prepared from tank gases by means of a mixing device identical to that employed by Darken and Gurry.2 The total flow rate of gas was 205 ml per min to point A of Fig. 1. The accuracy of the individual and

Jan 1, 1960