Search Documents

Equilibrium calculational software programs can be effectively utilized to illustrate the importance of activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation to students studying hydrometallurgy. The calculational program STABCAL will be demonstrated. illustrative examples for the creation of diagrams such as EH-pH, activity or concentration-pH and activity or concentration-EH will be presented to demonstrate the fundamentals of real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Applications will include treatment of Acid Mine Drainage (Berkeley Pitlake water and sediments), mass balance potential/pH diagrams, leaching and selective separation of metals from electroplating sludge, metal adsorption at femhydrite surfaces, and flowsheet development for treating mercury sulfide K106 sludge.

Jan 1, 2002

By R. A. Winters

At the operations level, productivity is a principle key to profitability. If you are competing with other mines that are paying roughly the same wage rate and the same prices for capital, materials, and energy, the only way your profit can be greater is by producing more output per unit of input. Mines with higher productivity have higher profit margins. Higher profit margins lead to greater operating cash flow, and cash flow is what distinguishes a dog from a cash cow. The turnaround in U.S. metals during the 1980s was in large part due to incredible improvements in productivity. According to statistics compiled by Kaufmann, 1991, labor productivity, measured as tonnes of primary production/manhour, increased 64% in steel, 94% in copper, 75% in lead, 143% in zinc, 132% in molybdenum, and 75% in gold. These improvements were hard won. However, with most modernization programs now complete, measuring and monitoring productivity becomes even more important as producers strive to maintain the gains they have achieved.

Jan 1, 1993

By N. Syna

The selection and preparation of activated carbon suitable for specific application can often involve exhaustive adsorbent preparation and testing. This work examined an emerging technique based on modelling the correlation of observed adsorption capacity to the carbon characteristics as a means of decoupling the roles of carbon textural and surface chemical properties. The insights to these specific roles are then used in tailor-making adsorbents and in establishing the optimal carbon properties for specific application. In this study, a series of activated carbons prepared from bagasse by physical and chemical techniques and commercially available carbons were used in developing the models. These carbons were tested for the adsorption of thiourea-gold (I) chloride complexes. Thiourea is an important alternative gold lixiviant with the potential to address current ecological and safety concerns in the extraction of gold. A four-component model, which correlated the adsorption gold capacity to carbon textural and surface chemical properties, was proposed. The model fit was assessed using multi-linear regression and a partial F-test. This was followed by goodness of fit test achieved through r2, adjusted?r2 and mean square error (MSE) values. The results suggest the adsorption of the gold-thiourea complex is strongly influenced by the internal surface area and pH of the carbon. Tailor-made activated carbon from bagasse showed adsorption gold capacities of up to 198 mgAu/g adsorbent, demonstrating the potential of bagasse as a precursor for gold adsorbents and of this empirical modelling approach in developing adsorbents for metal recovery.

Jan 1, 2014

By W. Clark Ashby

Productivity is a fascinating concept. Like motherhood or apple pie, we know it as a good thing. Just what it means is not so clear. To a coal miner we assume it means tons of coal hauled from the mine. To the company president it means profit after capital, labor, and other costs have also been reckoned. To the government economist it means output in a balance of payments. What does it mean to the biologist, and can reclamation really be productive? In this paper we discuss productivity from a biological viewpoint, give some yield data for various types of reclamation plantings, and discuss how our demand for or acceptance of differing kinds of productivity is tied up in bigger questions of land use, environmental stability, and resource allocation.

Jan 1, 1981

By Maurice Bottiau

"Abstract When addressing the performance of deep foundations, many parameters play a role, from adequate soil investigation to performance monitoring and testing. The correct understanding of pile construction, though, remains crucial. After a long period of empirical design and regulations, the last decades have been the ones of theoretical considerations and extensive codes writing. The interaction between technology and design, however, still plays a determinant role. The introduction of hydraulics and the exponential increase in available power on one hand, the miniaturization and the introduction of electronics in control and monitoring systems on the other hand have exerted a major influence on new foundation systems or the evolution and control of existing systems. It appears important to try to take execution related parameters and their control during execution more deeply into account when assessing the final result of the deep foundations and the achieved level of safety and reliability. In this contribution, we will try to analyze how systems, equipment and pile production monitoring and testing can influence the pile performance, and if/how this influence could/should be translated in adapted safety or installation factors. This analysis will run through different categories of piles: driven, augercast and displacement auger piles and bored piles. INTRODUCTIONThe global performance of a deep foundation depends on different aspects (Poulos, 2003):1. Ground investigation2. Design and analysis3. Construction4. Testing5. Performance monitoring6. Remediation and performance enhancementThis paper intends to address the importance of pile construction and the control of it on the final performance of the pile-group of piles. There has been an increasing interest for theoretical analysis over the last 20 years, followed by an increasing impact of regulation and codes. Without denying the importance of the latter, the author wants to point out how installation procedure and project specific parameters can largely influence the reliability of the deep foundation. In this context, detailed and prescriptive standards can miss their objective of intended improvement of accuracy and reliability, but even worse they can adversely impact engineering judgment. In today’s construction world, it is possible to gather installation information which can be of outmost importance for the final deep foundations performance. Therefore, the increase or decrease of installation reliability through adequate pile testing and performance monitoring should be emphasized and should be taken into account in the codes. This is the case already in most advanced codes, but in a limited and insufficiently refined way. After reviewing how codes deal with this issue today, we will show some recent examples of unexpected results due to pile installation. We will try to put these examples into a broader perspective by highlighting some reference and/or recent literature considerations. Finally we will try to summarize how pile testing and installation documentation can increase reliability and attempt to open the debate on how codes could/should allow for more engineering judgment."

Jan 1, 2014

By E. J. Kloos

The Bureau of Mines evaluated all previously approved gas masks to determine their ability to provide respiratory protection against each of the following six selected amines: ethylenediamine, diethylamine, n-butylamine, ethylamine, methylamine, and hydrazine. Minimum requirements were a 24-minute service life at a flow rate of 64 liters per minute (32 liters per minute for hydrazine) and an amine concentration of 1.0 volume-percent (0.5 volume- percent for hydrazine). The three masks meeting these requirements were the LG4, Willson Products Division, The Electric Storage Battery Co.; the GMD-SS, Mine Safety Appliances Co.; and the 084-PHOV-R, Acme Protection Equipment Co.

Jan 1, 1966

By George A. Calboreanu

In order to overcome drilling and tapping of high hardness wear resistent material in slurry pumps, most of time mild steel inserts are mounted in the mold and after pouring they become an integrated part of the casting. This process is limiting the size and design possibilities of slurry pumps and efforts were made to drill and tap the hard iron itself. The paper will present practical results obtained in drilling and tapping Cr-Mo wear resistent material with hardness in excess of 700 HBN. The life time of the slurry pump parts used in hazardous waste fuel transportation with high slurry velocity and 15% solid loading some of it being quartz, increased 2.5 to 6 times.

Jan 1, 1996

By Ali Behrad Vakylabad, Esmaeel Darezereshki, Babak Koohestani

As a by-product of the steelmaking industry rich in iron and zinc, electric arc furnace dust (EAFD) landfill disposal is restricted in many countries due to the metal lixiviation risks. Several approaches have been examined to recycle or reuse EAFD. Hydrometallurgical methods mainly include the preparation of pregnant acid leached solution (PLS) using inorganic acids followed by selective metal recovery using different methods. We herein proposed a hydrometallurgical process initiated by acid leaching and finalized by thermal treatment to produce nano-ZnO from EAFD. At the condition of this study, only 67% of zinc was leached by sulfuric acid from EAFD into PLS while 98% of surplus leached iron was removed through precipitation by sodium hydroxide. Additional purification of iron removed PLS was accomplished using di-2 ethylhexyl phosphoric acid to extract Zn+2. The addition of ammonium hydroxide to purified PLS provided (Zn(OH)2)3(ZnSO4)(H2O)5 as the final precursor for nano-ZnO that ultimately transformed to nano-ZnO (60 ± 6 nm particle size) at 850 °C. The achieved results were scrutinized through various tests and analyses including TEM, XRD, SEM, EDS, FTIR, and TGA.

Mar 10, 2021

By Steve Karl

"The International Tunnelling and Underground Space Association (ITA) held its 42nd General Assembly along with the 2016 World Tunnel Congress (WTC) April 22-28 in San Francisco, CA. The event was co-organized by the Underground Construction Association of SME (UCA). This was the first time the event has been held in the United States in 20 years.As cities demonstrate strong needs in tunnels and underground spaces for public transportation, subway stations, hydroelectric infrastructures and other underground infrastructure needs, the WTC 2016 provided the 2,319 attendees from around the world a unique occasion to discover the latest state-of-the art innovations in urban planning and underground construction projects in the United States and worldwide.The Congress, held in lieu of the UCA’s North American Tunneling Conference, included an exhibit that attracted 226 exhibitors in 298 booths. The exhibit had on display the latest in technical equipment and services from some of the largest and best companies in the international tunneling industry. The exhibit hall was also the place where participants were able to interact with the authors of the 168 posters and receive answers to various topics directly concerning civil engineers: innovative procurement processes, cost and risk management, contractual methods, BIM technologies and examples of innovative underground infrastructures built worldwide. And the technical program included 353 technical presentations – 185 podium and 168 posters.What is ITA?ITA-AITES is a nonprofit, nongovernmental organization that promotes greater use of underground space as a key instrument in sustainable development. Established in 1974 and based in Lausanne, Switzerland, ITA-AITES is made up thousands of professionals involved in the tunnel and underground space industry, including engineers, project owners, town planners, architects, industrial designers, companies specialized in public works and major structures, suppliers of construction site facilities and equipment, lawyers, politicians, researchers and academics, economists, financial experts and other stakeholders.ITA-AITES consists of 73 member nations and 300 affiliated members, including 15 major sponsors and 60 donors. The association is run by an executive council made up of 15 members elected by the 73 member nations, each representing a different dimension of the tunnel community."

Jun 1, 2016

By Gerd Weyand

Gontermann-Peipers GmbH (GP) Germany developed a new, high alloyed steel grade for the manufacturing of back-up rolls. The advanced GP double pour casting processes provide highest flexibility in being quite open in rolls work layer chemistry and hence microstructure with no influence on core respectively neck properties. GP took the process advantage to provide a brand new back-up roll grade with remarkably reduced roll wear while operating with textured work rolls. In the meantime several successful trials have been made with this new roll grade on different Skin Pass Mills. As a result the performance of back-up roll and thus availability of mill will be improved while specific costs for mill will drop. This quite new back-up roll grade has recently been launched. As next step increasing the field of applications is under progress.

Aug 17, 2017

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By N. Pajunen

The basic objectives of current EU waste policy are to prevent waste and promote re-use, recycling and recovery to reduce negative environmental impact (2008/98/EC). In this paper, we focus on drivers and barriers for sustainable development by decreasing amount of waste and increasing material efficiency. Main target is to understand what are the most efficient drivers for environmental friendly decision making for reasonable consumption and use of raw materials. Environmental control instruments usually mean those actions the regulatory authority uses to control and limit environmentally harmful behavior of companies. A major change in the environmental control system took place in the 1980s with the focus moving from specific environmental issues to the environment as a whole. The environmental control system i.e. the legal (administrative), economic and informative instruments focuses on prevention. Before and still, the legislation is one of the main drivers in improving material efficiency. In this paper, we focus on drivers and barriers for effective industrial material use, and mainly on drivers. The objective of this study is to analyze how the drivers are working and are there any possibilities to influence on those. Our aim is also to introduce few examples of the existing supply chains and the drivers for better environmental performance and material efficiency. These examples are also compared with ideal reference scenarios. Our main research question in this article is: ?Are the financial issues the most important driver for environmental friendly strategic decisions?? In addition, retell the story from another perspective: ?The most important barrier for environmental friendly innovations seem to be the investment cost, the high risk involved in committing capital to unproven technology.? Other drivers, like the corporate social responsibility, stakeholder pressure, and general public pressure, will also affect the final decision. This article is based on research projects and literature. Keywords: drivers, decision-making, environmental management, saving primary raw material, material efficiency, sustainable production, critical raw materials

Sep 1, 2012

By R. S. Dean

IN THE COURSE of its investigations directed toward providing strategic metals from domestic sources and toward utilizing power from Federal power projects in West, the Bureau of Mines concluded some years ago that the development of a method for producing electrolytic manganese might well be an important step towards both goals. Accordingly, laboratory investigations were undertaken in 1935. Further studied on a relatively large laboratory scale indicated that electrolytic manganese could be made from domestic ores at a cost not out of line with other nonferrous metals. On the basis of these results, the Electro Manganese Corp. Operating under U.S. Patent 2,119,560 issued to S, M, Shelton and assigned to the Secretary of the Interior for administration, undertook commercial production of electrolytic manganese at Knoxville, Tenn, This company has brought the process through the pilot-plant stage successfully, and is now regularly producing approximately one ton a day.

Jan 1, 1941

By B. P. Watson, D. P. Roberts, R. A. Lamos

The Upper Group 2 (UG2) chromitite reef is a shallow-dipping stratiform tabular orebody in the South African Bushveld Complex, which strikes for hundreds of kilometres. Mining is extensive, with depths ranging from close-to-surface to 2 500 m. Pillars are widely used to support the open stopes and bords. Little work has been done in the past to determine the strength of pillars on the UG2 Reef and design was done using formulae developed for other hard-rock mines. This has led to oversized pillars with consequent sterilization of ore. In this paper we describe a back-analysis of stable and failed UG2 pillars on the Bushveld platinum mines, and provides a strength formula for UG2 pillars. The formula may be used cautiously on all Bushveld platinum mines with similar geotechnical, geometrical, and geomechanical conditions to the pillars in the database.

Aug 1, 2021

By Jianhua Xin, Min Chen, Cuihuan Huang, Shan Yu, Xiaoao Li, Nan Wang, Guanghao Chen

Copper enrichment behavior in continuously cast slab induced by scale formation after continuous cooling in H2O vapor atmosphere and consecutively in air has been experimentally investigated by combining with SEM-EDS analysis, for the purpose to examine the effects of initial slab surface temperature and contents of copper and nickel. For Slab 1 with copper content of 0.1 percent, no visible copper enrichment is found at scale-substrate interface irrespective of the various scale microstructures formed at different initial slab surface temperatures. For Slab 2 with higher contents of copper and nickel, copper-rich phase accumulates and stays at scalesubstrate interface under the condition of lower initial slab surface temperature; while Cu-rich phase in the porous scale formed at higher initial slab surface temperature is noted with simultaneous Ni-enrichment appearing in front of the steel-scale interface. Both a porous scale and high nickel content work together to provide pores for copper-rich phase migration away from interface and occlude within the scale layer.

Jan 1, 2016

By M. Kellner

Due to continuously growing resource demands and increasing requirements for sustainability, safety and environmental protection on the other hand, the mining industry is being subjected to these additional requirements. Over the past few decades progress has been made in all topics. In 1987, the United Nations published the following in the Brundtland Report: ?development that meets the needs of the present without compromising the ability of future generations to meet their own needs.?[5] The term ?Blue Mining? means to work sustainably, economically, ecologically, and efficiently while also improving ergonomics, for example by increasing automation. An example of how mining can actively be involved in energy management will be shown. Initial evaluations of underground cavitites were done for purpose of energy storage. The planning and construction of underground pump storage plants both in active and inactive mining operations was also investigated.

Aug 1, 2013

By N. Parnian

"Carryover of caustic soda (NaOH) in the steam path caused catastrophic failure of superheater 304H stainless steel tubes in a steam generator and led to an unexpected shutdown after just five months of continuous service of petrochemical following the start of production. The cause of the failure was studied, with a focus on the formation of sigma phase in the weld joint and effect of caustic embrittlement on stress corrosion cracking (SCC). The cracks were examined at the seam weld, heat affected zone (HAZ), and Ubend areas. Hardness was measured for the base metal, HAZ, and weld metal, and microstructures were examined using optical microscopy and scanning electron microscopy (SEM). Crack initiation is attributed to gouging on the precipitated carbide at the HAZ and also the formation of sigma phase in the weld metal, as shown by energy dispersive X-ray (EDX) analysis. In addition, cracking was propagated by caustic embrittlement because of residual stresses and hammering. Finally, the characteristic feature of fracture was illustrated by SEM fractography, and consists mostly of intergranular SCC and some quasicleavage transgranular. INTRODUCTIONThree key factors are needed for the initiation and propagation of intergranular stress corrosion cracking (IGSCC): a susceptible material, a corrosive environment, and sufficient stress. Although austenitic stainless steels are susceptible to sensitization and IGSCC, they are widely used in boiler and superheater tubes because of their high corrosion resistance, high oxidation resistance, acceptable mechanical characteristics at elevated temperatures, and low cost.Sodium hydroxide is injected to neutralize acidic constituents in the steam path, but caustic can concentrate in boiler tubes and attack the surface metal (known as gouging) even traces of caustic in the steam can deposit on surfaces and cause local concentrations of several percent (ASM handbook, 1992). Not only sensitized grains but also sigma phase formed in the weld metal can initiate caustic cracking. In this research, the cause of the failure of 304H stainless steel superheater tubes in a methanol petrochemical plant in Iran was studied with a focus on the effects of caustic embrittlement on IGSCC."

Jan 1, 2012

By V. F. Kozyrev, L. B. Tsymbulov, L. Sh. Tsemekhman, A. N. Golov

Gipronickel Institute, JS has developed a new process and equipment for melting copper raw material in a two-zone Vaniukov furnace resulting in the production of white matte and low-grade slag in terms of copper content. Tests on processing copper nickelcontaining ore from Norilsk (Cu - 17 %), Ni - 3 %) were conducted in Vaniukov pilot furnace (total area 11.4m2) of Severonickel Combine. The amount of the processed material was about 11 thousand tons. Principal results of pilot testing are presented.

Jan 1, 2007

By L. A. Thompson, A. J. Linington

"Copper–cobalt extraction is a reagent-intensive process resulting in acid consumption greatly contributing towards production costs, which in the current market conditions curtail profitability. Nanofiltration (NF) membranes have become an attractive approach in the mining and minerals industry for product concentration and reagent recovery based on the ability of the membrane to separate monovalent ions from divalent ions. NF membranes can selectively separate acids from metals and salts allowing acid to be recycled as well as the concentration and purification of product streams. Membrane technology in the field of copper–cobalt processing focusses on the concentration of Cu2+ and Co2+ in the pregnant leach solution, recovery of acid from waste streams to neutralization, recovery of valuable metals from waste ponds and process water recovery. This paper aims to provide insight into the potential applications of NF membranes in copper–cobalt processing circuits as well as a brief overview of the effects of process conditions on membrane performance and process development. INTRODUCTION The copper–cobalt industry commonly uses inorganic acids, such as sulfuric acid, in large quantities for primary leaching of copper–cobalt oxide ores and releaching during product purification (Stuurman et al., 2014). This results in numerous acidic intermediate streams containing high metal concentrations and acidic waste streams with low metal concentrations. Acid consumption typically accounts for 10–15% of the operating costs of mines in the Democratic Republic of Congo (DRC) and Zambia (Acid Plant Database, 2015). Due to remote mine locations, poorly maintained roads and cross-border conflict, the cost of sulphuric acid can range between USD 300 and 400 per ton. The pivotal role of acid in the copper–cobalt extraction process has driven many mines to build sulphuric acid plants on site to ensure a reliable acid supply, however elemental sulphur still needs to be imported which faces similar logistical challenges and contributes towards operating costs."

Jan 1, 2015

By V. Feldman, I. Holl, J. Zampini

"The Renard Mine, 100% owned by Stornoway Diamonds, is located approximately 250 km north of the Cree community of Mistissini and 350 km north of Chibougamau in the James Bay region of north-central Québec. The project benefits from a large and growing resource, good mining conditions, strong social acceptance, a modest environmental footprint, and the development of direct-to-mine road infrastructure. Construction began on July 10, 2014; following the completion of a 946 million CAD project financing transaction. Now completed, the mine is the first diamond mine in Québec, and one of only six in Canada, employing approximately 500 people. First ore was delivered to the plant approximately 5 months ahead of schedule on July 15, 2016. Commercial production was declared on January 1, 2017. In general, the project ramp up has been characteristic of a type 1 McNulty curve. One of the challenges during production ramp-up was a redesign of processed kimberlite dewatering (replacing the dewatering centrifuge with two stages of hydrocyclones and a dewatering screen). A processing opportunity captured by Stornoway was the design and installation of an ore sorting facility which rejected free waste rock from the valuable host rock; kimberlite. Through tackling both challenges and opportunities, Stornoway has realised and is now exceeding their original design tonnage.PROJECT DESCRIPTION Stornoway Diamond Corporation (Stornoway) was established in 2003 resulting from to a plan of arrangement between Northern Empire Minerals Ltd. and Stornoway Ventures. In 2011, Stornoway acquired 100% interest of the Renard Mine. The construction of the Renard Mine began in 2014 and achieved full production in 2017 [1, 2]."

Jan 1, 2019