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By Henry M. Howe

COLUMBIA UNIVERSITY The Equilibrium Position of A 1.—Some of the most important data on this subject are collected in Table I. Definition of Ae 1.—-Just as we call A 1 of rising temperature Ac 1, and that of falling temperature Ar 1, so we may give the symbol Ae 1 to the equilibrium position of A 1. Preliminary Assumptions.—In deciding what weight to assign the various data, and indeed what data are to count, three assumptions should be made. These are : 1. The corollary from the phase rule, that the temperature of Ae 1 is constant and independent of the carbon content, though, of course, it may be changed by the presence of other elements. 2. That because neither in heating nor in cooling can the transformatioil begin before the temperature reaches Ae 1, though it may be delayed by lag till after the temperature has passed beyond Ae 1, therefore Ae 1 should be at or below the observed beginning of Ac 1 and at or above the observed beginning of Ar 1, and, a fortiori, it should be at or below the observed maximum of Ac 1, and at or above the observed maximum of Ar 1. It may be necessary to take these maxima into consideration in view of the experimental difficulty of detecting these beginnings. 3. Because of the extraordinary degree of lag in the immediate neighborhood of Ae 1, as proved by Brayshaw, little weight should be attached even to the most conclusive evidence that the transformation has not occurred on reaching, or even staying at, a given temperature, because that failure to occur may always be due to lag. Evidence that the transformation has occurred, or has even begun, at a given temperature deserves incomparably greater weight. In other words, the temperature may pass beyond Ae 1 without inducing the ' transformation, but the transformation cannot be induced except by

Jan 1, 1914

By Adrian Moore, Alan Richards

"It has been common practice to set blast vibration limits for structures using an “observational”approach whereby limits are set at a level based on observations of damage, or the lack ofdamage, combined with a tendency to further reduce the permitted level due to uncertainty. Suchan observational approach was used in the USBM RI 8507 to produce the frequency dependent‘Safe Levels of Blasting Vibration for Houses’ which has become a universal Standard for overthirty years."

Jan 1, 2013

By Fu Ping-Hao, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton’s Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By Melvin P. Silverman

The literature on methane-oxidizing bacteria is reviewed in regard to (1) the growth and isolation of cultures by special techniques; (2) the distribution of these organisms in nature and descriptions of individual species; (3) the physiology of methane-oxidizing bacteria as influenced by temperature, light, pH, aerobiosis versus anaerobiosis, and carbon and nitrogen sources; and (4) the biochemistry of methane oxidation revealed by studies with intact cells and subcellular systems. Present practical applications of methane-oxidizing bacteria are limited to prospecting for natural gas and petroleum deposits. Desirable areas for future research are discussed as well as some possible applications such as (1) the removal and/or early detection of methane gas in coal mines by intact culls or enzyme preparations; (2) the generation of electrical energy by microbial fuel cells using methane as fuel; (3) the growth of methane-oxidizing bacteria on methane fur their food value; (4) the purification of hydrocarbon gas mixtures using methane-oxidizing or other alkane-oxidizing bacteria; and (5) the synthesis of methane from mixtures of H2 and CO or H2 and CO2 by methane-forming bacteria.

Jan 1, 1964

By R. Carson Dalzell

The use of nuclear fission for chemical process heat offers the special advantage of high temperature, limited only by materials of construction. The process heat may be supplied economically at elevated pressures, since no compression of combustion air is required. For the initial effort in developing a high-temperature reactor, the indirect cycle, using helium as the heat-transfer medium, was chosen. The major problems are the design of high-temperature fuel elements, construction of an exchanger to transfer heat to process streams in the range of 2,500° F., and development of compressors capable of recycling helium at 1,000° F. and above. A conceptual design of a nuclear reactor to furnish process heat for coal gasification has been made. Spherical fuel elements utilizing a graphite structure, impregnated with uranium carbide fuel, were chosen, as spheres offer the possibility of easier loading and unloading of the reactor. Calculations of pressure drop and gas-pumping power for the system are included.

Jan 1, 1959

By E. T. White, Dean Ilievski

"Mathematical modelling of the precipitation process requires that the kinetics of crystal growth, nucleation and agglomeration be known. This paper reviews the current state of knowledge on these precipitation sub-processes (ie. growth, nucleation and agglomeration) and describes a number of experimental techniques for estimating their kinetics. The experimental methods used to generate the precipitation data and the data analysis techniques used to extract the kinetics information from the data are discussed separately. There is no universal ""best"" technique for determining the kinetics. However, studies on multi-crystal systems are more reliable for modelling purposes than are single crystal studies. The selection of a technique will depend on which sub-processes are present. A problem with all kinetics studies is that there is generally a large uncertainty in the estimated kinetic parameters. This stems from the scatter in the experimental data being further propagated by the mathematical techniques used to extract the kinetic parameters.IntroductionCrystallisation operations, including precipitation, are widely used in a number of hydrometallurgical processes to recover a desired component or to remove an undesired impurity. The goals of industrial precipitation processes are to maximise the recovery while maintaining product quality (generally product crystal size distribution, purity and morphology and product handling properties). Knowledge of the precipitation mechanisms and kinetics is invaluable for designing new precipitators or for improving existing units. The mechanistic and kinetic information is generally incorporated into mathematical precipitator models, which are then used for process design and optimisation."

Jan 1, 1996

By ABBOT A. HANKS

WHEN gold was discovered in California, and San Francisco grew almost over night from a handful of people to many thousands, one of the first difficulties experienced was the lack of money. Gold dust in considerable quantities was rushed into the city from the various mining camps but there was no money. Purchases were paid for by weighing out dust in hand scales. We can appreciate' the difficulty of paying for a drink or buying a postage stamp under these conditions. All this gold was in the form of dust from placer workings and the first metallurgists were the assayers' who melted and refined this gold, casting it into bars which were weighed, assayed, stamped with fineness; value, and the name of the assayer. Many .of these plants were of considerable size, handling shipments that were accumulated by banks and express companies throughout the "Diggings" and sent to San Francisco to be shipped by water to the eastern states. Several

Jan 1, 1931

By Ronney Rodrigues Silva, Renata Mendonca, Gabi Knesel, Cathrine Monyake

Locus Mining is working side-by-side with a prestigious iron ore company to evaluate the addition of Locus ESG-friendly green flotation reagents with the primary goal of improving recovery and grade. In this paper, we will focus on the cationic reverse flotation application. The most “established industry” reagents for cationic reverse flotation are amine as the collector, starch as the depressant, and in some cases frothers are also used (among them MIBC, pine oil, others). Here, we evaluate the synergies of different classes of eco-friendly biosurfactants and industry-standard reagents during the cationic reverse flotation method. Exploratory research was done first with an analog sample under different pHs, eight different biosurfactants with starch and no-starch, and a customized DOE was used to perform 145 microflotation tests. The results show Separation Efficiency from 20% (baseline) to 50% (biosurfactant), and Selectivity from 3.27 (baseline) to 5.67 (biosurfactant). Optimized result conditions were then applied to the iron ore samples received from our client to perform flotation tests on a Denver Lab cell. Similar results were obtained by improving Separation Efficiency and Selectivity, which corroborate with the previous work.

Feb 1, 2025

By J. E. Shearer

The state of Arizona produced 253,276.2 metric tons (279,000 st) of crude gypsum during 1986. This represents approximately 1.7% of the total U.S. production. Four mines provided Arizona's gypsum, three of these mines are in the San Pedro Valley. The uses of the gypsum produced in Arizona are for manufacture of cement, agricultural uses, and wallboard manufacture. The gypsum is used as a retarder in the manufacture of Portland cement. The use in agriculture is treatment of alkali soils to allow water penetration. Other deposits in the San Pedro Valley have production potential, providing there is sufficient market for additional wallboard. The author completed an evaluation of one property earlier this year.

Jan 1, 1988

By Kailash Narayan

Atlantic Richfield Company began operating a commercial uranium solution mining project in April, 1975 in Live Oak County, 10 miles southwest of the town of George West (Figure 1). The operation is designed to produce 250,000 pounds of U303 per year and is jointly owned by Atlantic Richfield Company, Dalco and U. S. Steel. The proprietary process employed in this operation consists of injecting an alkaline leaching solution into the ore-bearing formation through a pattern of injection wells. The uranium-bearing solution is then removed through producing wells using submersible pumps in central production wells. The produced solution is pumped through a pipeline to the plant area where the uranium is extracted. The barren solution is refurbished and returned to the pattern area for reinjection. The injection field and plant site are located in the drainage of Spring Creek, a small intermittent stream tributary to the Nueces River. Land use in the area is primarily agricultural -- cattle ranching and farming -- but several producing gas fields are present in the areas as well.

Jan 1, 1976

By H. Shang

The materials science and metallurgical engineering communities have expended enonnous resources in developing high fidelity process models. Exploiting these Models for Predictive Optimization (MPO) and Control (MPC) is a new frontier in Materials Process Engineering that will lead to exceptional process perfonnance. This paper will begin with a short survey of the development of high quality process models available in the literature and a discussion of how these could be used to improve process operation. A summary of the current "state-of-the-art" in process automation technologies and the traditional framework in which these technologies are deployed will be presented. An illustration of the use of MPO in process design and operations will be presented for the continuous casting of steel. In addition, a simple run-out table simulation will be used to demonstrate the power of the MPC technique.

Jan 1, 2003

By Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

At the present time of depletion of reserves of high grade rare earth deposits, it has become necessary to involve low grade raw materials in the production. Among the rare-earth deposits in Kazakhstan, the most advanced one is Kundybai. The mineralogical composition of ore is represented by the minerals: a-quartz SiO2, kaolinite Al2(Si2O5)(OH)4, muscovite KAl2(AlSi3)O10(OH, F)2, albite Na(AlSi3O8), rutile TiO2, and hematite Fe2O3. It contains: 59.1–68.5% SiO2, 19.1–28.4% Al2O3, 7.2–10.3% Fe2O3, 0.51–0.84% TiO2, 0.10–2.32% CaO, 0.39–2.10% MgO, and some other elements. Rare earths are located in the clay part (kaolinite, goethite) in the ion-adsorbing form, and they are represented by the main ore mineral churchite - YPO4·2H2O. In the ore the amount of rare-earth elements (total REEs) varies from 210 to 600 ppm. Elements of the cerium group predominate (La, Nd, Ce, Sm, Pr) and the yttrium group is represented by Y, Gd and Dy. Extremely thin intergrowth and accumulation of REEs in clay minerals cause difficulties in their recovery using flotation and gravitation beneficiating methods. The purpose of this work is the development of an extraction method for the main mineral components of ore with transfer of the total REEs into the solution with high extractive efficiency. Results of the experimental work into high-temperature processing (hereinafter referred to as sulphatization) of ore by sulphuric acid with subsequent dual-mode water leaching of the sulphate product (sinter) are presented in this manuscript. The influence on the ore sulphatization process of some physical and chemical parameters: liquid-to-solid (L/S) ratio (0.36–0.86 cm3/g), temperature (100 – 500°?), concentration of sulphuric acid (3.0–18.62 mol/L) and duration (0.5–2.5 h) was studied. Optimal technological parameters of the process were determined to be: L/S ratio 0.36–0.46 cm3/g; temperature 500°?; concentration of H2SO4 9.0 mol/L; soaking time 1.5 h. Under these conditions it is possible to obtain extractions of ~ 85% REE, as well as 58% aluminium and 10% iron. XRD and IR-spectroscopy analyses were used to determine the material constitution of sulphated cakes obtained under optimal conditions. It was found that the primary minerals are quartz and muscovite; however different sodium aluminium silicates and albite minerals are present as well. In the future, it is proposed that the leach residue cakes are processed into precipitated silica (“white soot”).

Jan 1, 2016

By E. T. White, Dean Ilievski

"The population balance is one of the basic relations for analysing particulate mineral processing operations. It is an exact relation. The principles of the population balance are reviewed and applications in the minerals industry discussed.IntroductionMathematical modelling has proved to be a very successful approach for improving the design and performance of mineral processes, particularly since the availability of computers to handle the complexity usually necessary to give a useful model.Mineral processes almost invariably involve particles, as either solid fragments, liquid drops or bubbles. Process performance usually is highly dependent on the behaviour of these particles. In modelling particle behaviour, the basic relation to be used is the population balance. This paper discusses the role of the population balance and the range of its applications in minerals processing.The Population BalanceThe population balance was developed for demographic studies, ego predicting the change in the population (numbers) of, say, school children between one census and the next. The first sustained application to the processing industries appears in the 1960s for crystallization. However it was recognised almost immediately that it had application to all particulate processing."

Jan 1, 1996

By R Razanatsimba, A Galli

A mining company has entered into contractual commitments to supply certain quantities of its product to clients in each time period. Failure to fulfil its obligations would damage its reputation as a reliable supplier. The planned production would normally be sufficient unless major problems such as highwall failures, roof falls, natural disaster, or strikes that interrupt production or delays in obtaining environmental permits, occur. To overcome these difficulties, the company may be able to obtain more of the commodity: from its strategic stockpile (if there is sufficient there); by buying it on the spot market; or for some commodities such as gold and uranium, by leasing it. Two sources of uncertainty, the spot price of the commodity and the occurrence of serious incidents that interrupt production, are considered. For simplicity it is assumed that the commodity price follows a geometric Brownian motion, that productions incidents have a binomial distribution, that they are independent from one time period to another and that they do not affect prices. A branching tree structure is used to model the joint evolution of prices and production incidents. The aim of this research project was to evaluate the companyÆs options for fulfilling its contractual commitments. When evaluating these options, multi-stage stochastic programming with recourse was used to solve this problem because in addition to providing the dollar value of the project, it gives decision-makers the æroadmapÆ to reach the optimal value. That is, how much material should be bought/sold on the spot market, how much to add to/subtract from the stockpile, how much to lease and in the worst case what the shortfall would be, for each time period as a function of the current spot price and breakdown status. A case-study over a five-year period is used to illustrate the proposed procedure. In this study the production would be sufficient to cover the companyÆs contractual commitments unless production incidents occur. Focus is on evaluating the impact of the quantity initially in the stockpile on the value of the project when the commodity market is tight, that is, when only small quantities can be bought on the spot market or by leasing.

Sep 26, 2011

By D Chalmers, C C. Harb

The detection and control of gas levels in mining is a continuing challenge for the industry. Standard detectors have many problems that could be overcome with laser based spectroscopic instruments, but to date these systems have not been suitable for mining conditions. This paper reports the development of a new digital data extraction scheme to modernise traditional cavity ring down spectroscopy (CRDS). CRDS is a direct cavity enhanced laser based absorption technique, which is used to allow the identification of an unknown substance by their molecular fingerprint; this unknown substance is identified by analysing the ring downtime of the light exiting the optical cavity. Traditional CRDS has many issues when analysing substances in hostile environments, or when multiple species may be present. This presents an alternative approach, called real-time CRDS (rtCRDS) that has the potential to overcome many of these issues and produces systems that could be used in the mining industry. The system utilises newly developed widely tuning quantum cascade lasers combined with improved optical cavities and novel digital data extraction to produce spectra over a 1500 nm range in a few seconds. The ring downtime measurements produced are accurate and have high sensitivity and maximum signal to noise ratio. This paper discusses the technique, illustrating the advantages compared to traditional systems and show real-time spectra for a set of molecules of interest to the mining industry. This paper also provided an analogy between this approach and that used in digital communications systems, and shows that this scheme is ideally suited to provide a network of sensors in hostile environments.CITATION:Harb, C C and Chalmers, D, 2015. Real-time methane detection – modern digital laser spectroscopy for hostile environments, in Proceedings The Australian Mine Ventilation Conference, pp 161–166 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By R. M. Beauchamp

Base metal processing operations often treat process tailings and acid mine drainage using a high density sludge (HDS) water treatment process. Lime is used in this process, which reacts with existing sulfates to form gypsum. When a recycle stream is incorporated in the process, gypsum levels in recirculating water may build up and cause high levels of gypsum supersaturation. Precipitation of gypsum from the supersaturated process water causes many problems. It is speculated that gypsum may precipitate on sulfide minerals and silica gangues in the flotation circuit, resulting in decreased selectivity and recovery. An understanding of the determinants and nature of precipitation may provide solutions to mitigate the formation of precipitates and improve flotation performance. This study showed that both sphalerite and silica exhibited gypsum- or calcium carbonate-like behavior in the respective supersaturated solutions, indicative of a coating of calcium species on the mineral particle surfaces. The addition of copper sulfate and/or potassium xanthate had little effect on the precipitation of gypsum or calcium carbonate on the mineral particles. Sodium carbonate is encouraging as a method to minimize calcium species interactions on sphalerite/silica surfaces.

Jan 1, 2006

By C. Musingwini

Traditionally, mineral reserves management at most underground mines in Zimbabwe focus on maintaining large mineral reserves so that the time between development and production is as long as possible. Historical data at Shabanie mine, a Zimbabwean sub-level caving underground mining operation, confirms this practice. However, the high cost of underground development means that the luxury of large buffer mineral reserves cannot be justified. Furthermore significant increases in the costs of production, exacerbated by the current unfavourable economic climate, make the wisdom of extending development workings well ahead of use questionable. Poor ground conditions at Shabanie mine, mean that some development ends have to be re-mined two or three times due to partial or complete closure between the time they are mined and the time they are utilized. In order to reduce the inordinately high support costs associated with closure of development ends a new ?just-in-time? (JIT) approach that provides development ends as and when they are needed, has been adopted. Accordingly a model to determine an appropriate ?just-in-time? rate of development has been created. The JIT development model indicated that the mine could reduce development rates from 330 m/month in 2001, to 160 m/month in 2002 and achieve savings of about 50% on annual support costs, but still assure customers of a long-term product supply. The mine accepted the model in November 2001 and began implementing it in 2002. Results of the implementation will be reviewed in 2003.

Jan 1, 2003

By Alan E. Gallie

FOR many years the Witwatersrand has been the leading gold mining r camp in the world and, to a Canadian mining student, could not fail to be of overwhelming interest. The vast scale upon which the operations are conducted, the enormous production accomplished, and the perfection of the operative technique, have all so forcibly impressed themselves on his memory that it is difficult to select any one feature as more outstanding than another. For the purposes of this paper, however, the author has selected the very first feature of mine operation with which he came in contact, namely, shaft sinking, as it reflects, quite as well as any other, the spirit of mining in South Africa. Early mining in Johannesburg was by open cuts or trenches, dug along the outcrops of the reefs. The ore was thrown from bench to bench to the surface. As the depth increased, rock was hoisted by bullocks. In 1887, the first shafts were sunk and true underground work began. At the same time, boreholes were put down to test the continuity of the reefs at depth. The first was at the Village Main reef. It cut the South reef at 517 feet and the Main reef leader at 581 feet. The Main reef leader assayed eleven penny-weights. Subsequent boreholes proved the reefs down to thousands of feet. Many companies secured deep-level claims as a direct result of the information obtained from the early holes. These companies then held land on which there was no readily available ore. In order to get to their pay rock, vertical shafts through the upper strata were necessary. Shareholders were impatient, and shafts had to be sunk as speedily as possible. The old methods of shaft sinking were investigated, new methods developed, and soon all records were being broken. In the last thirty-five years, the record has been slowly advanced, and last summer it was again broken to stand at 430 feet in a 31-day month. During the period from 1915 to 1935 inclusive, in the Witwatersrand district, 96 miles of shafts were sunk. Today, with the advance in the price of gold and the increase in the mining area, there are over twenty-five major shaft-sinking operations being carried on.

Jan 1, 1937

By J. Mácsik, J. Lindblom, C. Maurice, Susanne Nigéus

Using non-hazardous industrial residues in mine waste remediation is beneficial not only for the mining industry where substantial amounts of the waste generated have potential to produce acid rock drainage and pollute the environment, but also the providing industry, minimizing the waste landfilled. In this study green liquor dregs (GLD), residue from 15 different paper mills were characterized to valorize it as a potential product as a cover material. In another part of the study, one of the GLDs and a local till were characterized to determine the optimal mixture of GLD amended till to be used in a field application at the closed Näsliden Mine in northern Sweden. The study concluded 10% GLD-amended till to be the optimal recipe and was successfully applied at the Näsliden mine waste dump. However, the great variability in the characteristics of GLD creates challenges if it is to be valorized as a product.

Dec 7, 2023

By Saeed Karimifard, Saman Nouranian, Shahram Tafazoli, Bahram Sameti, Frank Chu, Caitlin McKinnon, Tetiana Konstantynivska, Glen Turner

We propose a particle size analysis solution for haul trucks that does not impact current operational workflows. Using artificial intelligence (AI) and 3D imaging technology, our solution reliably localizes and identifies haul trucks as they drive by, then accurately calculates the particle size distribution of the visible material in each truck load. In this paper, we identify the challenges of designing and implementing the proposed solution and explain the strategies we employ to overcome these. We also discuss a method for boulder detection that leverages the existing deep learning architecture to significantly reduce crusher downtime caused by oversized rocks

Feb 1, 2020