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By J. C. DeSantis

Thin, highly reflective rhodium films with metal compositions greater than 98% (elemental -weight percentage) have been deposited by chemical vapor deposition using Rh(allyl)3 (ally1 = q3-C3H5) in the presence of a hydrogen plasma. Uniform, crystalline films that adhere well to several types of substrates result from depositions at temperatures as low as 150°C. Depositions using H2 (no plasma), or an argon plasma yields material that is amorphous, contains a significant amount (>14%) of residual carbon, and has a dramatically slower growth rate. The composition of these materials does not vary significantly from that of the materials obtained from the in vacuo thermal deposition with Rh(allyl)3.

Jan 1, 1992

By Rebecca Boakye, Zohreh Kazemi Motlagh, Virginia T. McLemore

The most significant uranium (U) deposits in New Mexico are sandstone-hosted deposits in the Morrison Formation (Westwater Canyon Member), where >169,500 short tons of U3O8 were produced from 1950 to 2002. In addition, >9076 pounds of vanadium (V, a critical mineral) and some molybdenum (Mo) were produced from these deposits. These and other U deposits (limestone-hosted, U-veins) in New Mexico also contain critical minerals. Critical minerals are mineral resources that are essential to our economy and whose supply may be disrupted; many critical minerals are 100% imported into the U.S. Some sandstonehosted, limestone-hosted, and U-vein deposits are elevated in heavy rare earth elements. One sandstone-hosted sample contained 0.3 ppm Re (critical mineral), 659 ppm Se and 408 ppm Mo. The arsenide five-element vein deposits in the Black Hawk district are mineralogically and texturally complex, low- to moderate-temperature, hydrothermal, structurally-controlled, Ag-Co-Ni-Bi-As bearing carbonate vein systems with local minor elements. Mineralized samples from Black Hawk contain up to 9970 ppm Ag, 8540 ppm As, 5690 ppm Co, 72,400 ppm Ni, 57 ppm Bi, 165 ppm Sb, and 32,600 ppm U.

Feb 22, 2026

By Courtney A. Young

Cyanide is a critically important chemical to the mining and metallurgical industry. It has a strong affinity for metals making it favorable as an agent for metal finishing and treatment as well as a lixiviant for metal leaching, particularly gold. These technologies are environmentally sound but, because cyanide is very toxic, safeguards are required to prevent accidental spills and treat effluents before being discharged. Various methods of cyanide remediation by separation and destruction for cyanide management purposes are therefore reviewed. The methods have been broadly categorized as physical, -adsorption. complexation and oxidation methods including photolysis and other advanced-oxidation processes. Reaction mechanisms for these methods are presented throughout this paper, Finally, the methods are compared in regards to their effectiveness in treating various cyanide species: free cyanide, thiocyanate, weak-acid dissociables, and strong-acid dissociables.

Jan 1, 1998

By S. G. Dixit

Alunite (KAl3(SO4)2(OH)6] is one of the important nonbauxitic resources for aluminum in U.S.A. The major gangue material associated with a unite ore body is quartz. Experimental results indicate that oleic acid flotation of alunite is quite effective in upgrading the ore. The flotation chemistry of the alunite/oleate system has been investigated using various techniques such as: hallimond tube flotation response, measurement of adsorption density using I4C labeled oleated, electrokinetic measurements, infrared spectral studies, contact angle measurements and thermochemical measurements using an isothermal microcalorimeter. Alunite has been found to float readily with oleate in the pH range 4-10.5 and its flotation response is enhanced at higher temperatures. The PZC of alunite has been determined to be at pH 7.2 ± 0.15 which agrees with what would be predicted from solution chemistry and from the flotation response with physically adsorbed collectors. Infrared spectra show a specific peak in the range 1585-1600 cm-1 which has been attributed to the formation of an aluminum oleate surface species. Both adsorption density measurements and infrared spectra indicate that during adsorption multilayers are formed. The heat of adsorption of oleate on alunite has been found to be endothermic and of the order of 4-6 KJ/ mole.

Jan 1, 1980

By T Higuchi, T Yamamoto, K Takehara

Iron ore fines are used as raw materials for sintered ore for blast furnaces in the world. Since the production and quality of sintered ore have a great influence on the stable operation of a blast furnace, many technologies were developed for controlling the heat profile in the sintering machine, which largely affect the sintered ore properties. In particular, the influence of oxygen in the suction gas, which plays an important role in combustion, was investigated over the years. It is known that increasing the oxygen ratio by about 30 per cent not only significantly improves the combustion rate, but it also increases the strength and yield of sintered ore. However, the details of the mechanism for improving these qualities are unknown. In this study, we investigated the influence of oxygen enrichment at higher ratios (O2: 21–40 per cent) and tried to understand the sintering behaviour enhanced by oxygen. The effect of oxygen enrichment on sintered ore quality and the heat profile were evaluated by sintering tests using a quartz glass pot. From the results, sintered ore yield had a maximum value for O2 = 30 per cent, but strength was increased for O2 = 40 per cent. From heat pattern analysis, it is clear that the high temperature holding time also reached a maximum at O2 = 30 per cent. Furthermore, we found that with increased oxygen ratio, the combustion speed (flame front speed) was increased, but the area of combustion was enlarged. It is considered that there could be a maximum oxygen ratio value for the yield from the balance of these positive and negative effects on high temperature holding time. To clarify the reason for strength improvement, thermodynamic calculations were performed and it was found that melting behaviour could be improved by changing the oxygen ratio.

Sep 18, 2023

By C. S. Witherell

THE first feature that strikes one when considering the use of air enriched with oxygen in pyrochemical processes is the conservation of Enriched Air FIG. 1.-TEMPERATURES THEORETICALLY OBTAINABLE BY BURNING PURE AMOR¬PHOUS CARBON IN AN ATMOSPHERE COMPOSED OF AIR ENRICHED WITH OXYGEN, PRODUCING GAS CONTAINING CO. heat due to the partial elimination of the inert heat-carrier nitrogen, as set forth in the report of the committee. The second feature, which

Jan 11, 1924

By I. Jauhari, F. Stober, D. Fowler, B. O. Wasmund, T. Miraza, C. Nichols, A. Taofik Hidyat, K. Said

The existing PT Aneka Tambang (Antam) ferronickel smelter located at Pomalaa, Indonesia consists of two RKEF lines with reduction furnaces nominally rated at 17 MW and 18 MW, respectively. The low power densities and heat fluxes allowed both furnaces to operate with falling water film shell cooling systems. The furnace campaigns comprised a 5-yearly cold shut -down for metal taphole area rebuild and a 10-yearlysidewall and hearth perimeter repair. Towards the end of these campaigns the furnaces would typically be operated at below nominal power due to excessive sidewall temperatures. In January 2001 Hatch performed a smelter study which proposed options which indicated the possibility of a single furnace operation for the smelter, elimination of lime addition and transition to shielded-arc operation with associated efficiency and throughput gains. This paper discusses the process of uprating the second?line furnace capability from 18 MW to 32MW following the decision by Antam to implement the recommendations proposed by Hatch. It will cover the development of scaled-up furnace design basis by Hatch and Antam with the enabling application of Hatch cooling and binding technology. To optimise the capital cost and maximise Indonesian supply content and post installation support, the scope was carefully and clearly divided between Hatch and Antam. The challenges, set backs and valuable learning experiences gained during the implementation of the retrofit include; ?The support and re-use of existing roof system and challenges presented in re-use of existing crucible support steel. ?Training and technical assistance for Antam operators to perform refractory and copper cooler installation and maintenance of crucible integrity technologies. ?Hearth integrity during start-up and development of an initial charge and start-up procedure to achieve planned thermal expansion of the hearth prior to bath formation ?Implementation of a sidewall hold-down system within the refractory sidewall due to space constraints ?Existing furnace foundation reinforcement to overcome lateral forces on furnace piers during crucible support steel expansion ?Conversion of an open-loop gravity feed cooling water system to a closed loop pressurised system with integrated emergency gravity feed and backup system ?Existing water treatment system and pumping system improvement and modification to meet copper cooling system requirements ?Integration of the new instrumentation control system designed by Hatch to increase performance of the furnace monitoring system and operation ?Uprate transformer capacity from 25 MVA to 40 MVA to meet with requirement of Shielded- Arc Furnace Operation.

Jan 1, 2007

By C. Hakan Gür

Optimization and control of the microstructure is important for improving the properties of steel components. Development of non-destructive techniques for microstructure characterization is a critical task. Magnetic Barkhausen Noise (MBN) technique is a promising and challenging non-destructive technique fo automated evaluation of microstructures in steel components in a fast and reliable manner. This paper presents the results of MBN measurements for microstructure characterization of the quenched and tempered steels.

Mar 1, 2017

By E O. Foster

When roasting started at Giant Yellowknife Mines in 1949, it became apparent that, to prevent air and water pollution in the surrounding district, it would be necessary to collect the arsenic that was contained in the exit gases of the roaster. The arsenic collection problem was finally solved by the installation of both electrostatic and baghouse collectors. It was realized that a considerable quantity of gold-bearing dust was leaving the roaster with the exit gases. When the collection problem was solved, it was possible to measure this loss. The loss proved to be considerable and it became evident that a substantial quantity of gold could be recovered. Research programs on dust treatment began in 1958, and by May, 1960, the treatment process which is currently being followed was started in the plant. At present, the two electrostatic preci11itators, Operated at temperatures above 600°F, collect the gold-bearing dust.

Jan 1, 1963

By Ritayan Chatterjee, P. K. Mukhopadhyay, Surajit Biswas, Dinabandhu Ghosh, Sandeep Agarwal

An Indian magnetite ore from the Nagaland region was characterized by powder X-ray diffraction, spectroscopies (ultraviolet-visible and Raman), high temperature magnetization and thermal analysis. A Rietveld refinement of the diffraction data revealed that the principal phase present in the sample is magnetite with partial substitution of Fe with Mg (mainly) and Cr, leading to the chemical formula of MgCr0.2Fe1.8O4. The UV-visible spectra of the sample in MeCN solution showed three distinct peaks. The lower region bands are due to metal-oxygen charge transitions and the other band is for d-d transition of iron. Raman spectral study at room temperature gave four characteristics bands of magnetite. The sample underwent a magnetic transition at high temperature and the thermomagnetization curve shows hysteresis during cooling cycle which indicates the possibility of first order structural transition at high temperature. The thermal property of the concentrate was studied by differential scanning calorimetric technique.

Mar 1, 2018

By S. de Vries, B. Wasmund, J. Metric, N. Voerrnann, S. Kasinger

Gulf Chemical & Metallurgical Corporation (GCMC) operates a circular DC electric smelting furnace to treat nickel and cobalt bearing residues at its plant in Freeport, Texas. The furnace, originally built by others, has experienced problems including runouts through the hearth and the lower sidewall. Hatch has designed several improvements to the furnace to alleviate these problems. The single anode at the centre of the hearth was replaced with a patented system of twelve air-cooled copper anodes evenly spaced around the furnace lower sidewall. The DC power supply comprises two transformers and two rectifiers operating in parallel. The water-cooling system on the bottom and lower sidewall shell plates was replaced with an air-cooling system using copper cooling fins. The existing row of water-cooled copper coolers in the metal bath zone was re-designed for greater heat removal capacity and better element joint sealing, and a new row of water-cooled copper coolers was added to cool both the alumina bath and freeboard zones. The existing water-cooled metal and alumina tapblocks were also re-designed for more robust cooling. A binding system was added to provide refractory compression that reduces the risk of liquid leaks. Finally, the furnace tilting frame was relocated to the top of the furnace where it is less likely to be damaged.

Jan 1, 2000

By D. R. East

Recent experiences within certain sectors of the international mining industry suggest an underestimation of the environmental risk associated with the design of mine waste management facilities. These experiences show that the technical and managerial challenge of responsible mine waste management is not always fully appreciated. Unfortunately, the image of the mining industry's environmental performance is negatively impacted by a relatively few number of failures. This negative view overrides the many positive contributions made by the majority of mining companies. The fact that these failures continue to occur to this day in both developed and developing countries is indeed remarkable, and indicates a degree of risk-taking approaching unacceptable levels. The design requirements for tailing storage facilities are, in many cases, more demanding than those of conventional water dams, because seepage of fluids which contain dissolved metals may pose a greater threat than the mere loss of water.

Jan 1, 1999

By Zhucheng Huang, Ronghai ZHONG, Liangming Wen, Tao Jiang

The reduction roasting-magnetic separation and its strengthening of high silicon coal-containing mini-pellets by sodium additives were researched. The results show that the carbon gasification reaction and reduction of fine hematite in high silicon coal-containing mini-pellets with 3% sodium additives were enhanced. Comparing with no sodium additives, the gasification rate of carbon with 3% sodium additives reacting with CO2 for 40 minutes at 950 and the metallization rate of reduced pellets with 3% sodium additives after roasting for 35 minutes at 960 increased from 35.15% and 58.72% to 86.98% and 86.15%, respectively. The analysis of SEM equipped with EDS demonstrates that the inner pore of reduced pellets with 3% sodium additives was more developed and the iron grains size significantly enlarged, meanwhile, the iron grade of concentrate increased from 60.45% to 80.23% and the iron recovery rate decreased from 84.67% to 80.78% after grinding-magnetic separation.

Jan 1, 2016

By C. F. Gleeson

"Geochemical stream-sediment reconnaissance can be a useful exploration tool from the point of view of rapidly and cheaply evaluating the mineral potential of an area. This is particularly true of rugged and mountainous areas such as are found in Gaspé. For the past two years, SOQUEM has been carrying out such surveys over favorable geological regions in the Appalachians of northern New Brunswick and Gaspe. To date, about 4,000 square miles of terrain has been systematically covered by reconnaissance geochemistry. Jeeps have been used as a means of transportation in the easily accessible areas and a helicopter equipped with a winch has been used to lower crews into the more difficult-to-reach regions. Such surveys have been successful in finding metallic mineralization which otherwise might not have been detected.Electronic computation of analytical information has been used to construct regional metal maps, rolling mean maps and residual metal maps. These maps have helped in evaluating anomalies, in relating the regional geo-chemistry to the regional geology and in comparing the distribution patterns of metals. To date, some 30,000 stream-sediment samples have been collected from the Gaspe region and analyzed for Cu, Pb, Zn and Mn. These analyses are being subjected to computer analysis."

Jan 1, 1969

By N L. Turner, K Ehrig, V Liebezeit, D J. Robinson, L L. Kuhar, N Francis

Conventional industry tests used to determine leach recoveries are often fully monitored and may be time-consuming and expensive. Such tests may be limiting in geometallurgical applications where large numbers of samples are required to be processed for characterisation of an ore deposit. BHP Billiton currently use a fully instrumented leach test for characterisation of Olympic Dam uranium-rich samples. Researchers at the Commonwealth Scientific Research and Industrial Organisation (CSIRO) were approached to develop an alternative to these full-scale leach tests that could allow for the ranking of samples in terms of their leachability. The novel geometallurgical test was required to use samples of small mass and be affordable and rapid.Three leach test protocols were pursued in developing the small-scale tests. Kinetic leach tests were performed using mild conditions at higher pH, low temperature and low oxidation reduction potential, moderate conditions at intermediate pH, temperature and oxidation reduction potential and aggressive conditions at lower pH, higher temperature and higher reduction potential.This paper presents results from 44 leach tests on 11 samples with varying uranium mineralogy. The developed small-scale tests correlate well with data from the more costly conventional industry laboratory tests, indicating the possibility of using this alternative test as a geometallurgical leach proxy. Simple regression analysis confirmed the importance of pH, reduction potential and temperature on uranium extraction. Experimental data were fitted to published leach models to predict uranium leach extraction for a range of operating conditions.The ultimate aim of the test work is to combine a limited number of large-scale calibration tests, a large number of small-scale geometallurgical tests and leach models for geometallurgical sample characterisation and evaluation of a wide range of scenarios or processing options.CITATION:Turner, N L, Kuhar, L L, Francis, N, Liebezeit, V, Ehrig, K and Robinson, D J, 2013. Development and testing of a small-scale uranium leach for geometallurgical applications, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 345-350 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By Arthur A. Cole

Although the metal silver has been known and prized from very ancient times, it is in the New World that the greatest silver camps have been found. This is shown in the following comparison: [] For the last few years, the World's annual production of silver has averaged about 240 million ounces troy. Of this total, the North American Continent contributes approximately three quarters, Mexico leading with 38 per cent, followed by the United States with 27 per cent, and Canada with nearly 9 per cent.[] Of the largest silver producers in Canada, the Sullivan takes first place. Although primarily famous as a lead and zinc mine, it produced, in 1926, more than 4.5 million ounces of silver. The Premier mine, in northern British Columbia, produced more than 3 million ounces. In Ontario, the largest producers in 1926 were the Nipissing mine, .with 1.9 million ounces, and the Keeley mine, with 1. 7 million ounces. The Mining Corporation produced 1.1 million ounces from mines in the Cobalt district proper, and an equal amount in South Lorrain; while from the Castle-Trethewey mine, in Gowganda, there was an output of slightly less than one million ounces.

Jan 1, 1927

By Manuel Gomez

This report presents prediction equations for 12 variables that are indicative of metallurgical coal quality. The variables include six for coke strength and six for carbonization product yields. All variables were predicted for coking coals having volatile matter contents from 16.3 to 42.1 percent, dry basis. The prediction equations, developed by mathematical-statistical techniques, were based on information from the proximate and ultimate analyses, the size consist, and the petrographic composition of bituminous coals carbonized in BM-AGA retorts at 800°, 900°, and 1,000° C. The equations were evaluated for validity with independent data derived from the 900° C carbonization of 33 binary blends of various coals and 22 binary blends of Pocahontas No. 3 low-volatile bituminous coal with 11 high-volatile bituminous coals. Results show that metallurgical coal quality can be predicted ahead of mining because data used to derive the prediction equations can be obtained at the time of exploration. Capability to forecast coal quality is useful in mine planning and should provide basic information for optimization of blending and crushing techniques and thus lead to the production of uniform coke.

Jan 1, 1970

By R. S. Shepard

The closing remarks of a paper which I presented at the annual AIME meeting at Dallas, Texas during February of 1963; contained a forecast of increased activity in trackless underground ore mining which finalized that presentation. At that time, HAD I been peering through my brightest rose colored glasses, I could not have foreseen the unprecedented rapidity of acceleration of underground ore mining methods which has since ensued. From Death Valley, California diagonally to St. Johns, New Foundland; from Australia to Africa to Sweden to France and Germany; from South America to Southern Mexico to Northern Saskatchewan and Northern Manitoba the expansion of trackless underground ore mining methods has probably progressed at a faster rate than any other revolutionary' change in the history of underground ore mining.

Jan 1, 1967

By J. J. Geraghty

U.S. Bureau of Mines researchers investigated the development of an innovative transport system for underground coal mining. A one-half commercial-scale bench model was constructed. Novel magnetic levitation (mag-lev) technology was developed. Frictionless and contact-free transport of a prototype materials container and payload has been demonstrated.

Jan 1, 2010

By A. Patti, S. Reutzel, D. M. Herlach, L. Ratke, I. Egry

Cu-Co shows a metastable miscibility gap in the region of the undercooled melt. Undercooling of the melt below the binodal leads to separation of the melt into a Co-rich LI-phase and a Curich L2-phase. Experimentally, undercooling into the metastable miscibility gap is realised by means of electromagnetic levitation (EML), processing in drop tube (DT) and by melt flux embedding. As undercooling is large in these experiments, the velocity of the solidification front is high and the microstructure is frozen in instantaneously. Samples have been undercooled and solidified in the TEMPUS-facility (container less electromagnetic processing under weightlessness) during parabolic flight under reduced gravity conditions. Microstructures of solidified samples have been analysed and compared to those processed under gravitational conditions. The influence of convection on phase growth is much lower in reduced gravity. The microstructure shows spherical droplets of the minority phase, statistically dispersed in the majority phase.

Jan 1, 2004