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By J. M. Uys, T. B. King

The solubility of water in silicate melts of various compositions was measured. The basicity of the silicate did not appreciably affect the water solu-bulity at low-base content (acid compositions). Near the orthosilicate composition the solubility increased with basicity for silicates in which the cation displayed a weak ion-oxygen attraction and apparently decreased for those in which the cation showed a strong ion-oxygen attraction; metasilicates of the former class dissolved more water than those of the latter. Temperature had little effect on water solubility. The experimental results are interpreted on the basis of two modes of solution, the contribution of one decreasing, and that of the other increas -ing, with increased melt basicity. In the former, solution occurs through interaction with doubly-bonded oxygen atoms and in the latter, through interaction with singly-bonded oxygen atoms, or, in very basic melts, through reaction with free oxygen ions. THE hydrogen content of a steel melt is in a large measure determined by water dissolved in the slag. In some glasses water may be a major cause of "seeds". Water vapor in the furnace atmosphere is the primary source in both instances. A knowledge of the mechanism of water solution in silicate melts should help in assessment of practical methods for its control in steelmaking and glass refining. Walsh et a1.l measured the water content, expressed as hydrogen, of 40 pct lime-20 pct alumina-40 pct silica and 62 pct manganese oxide-38 pct silica melts as a function of the steam partial pressure, in equilibrium with the melt. Tomlinson 2 and, also, Russell3 investigated this relationship for a molten 30 pct soda-70 pct silica glass. In all three investigations, the solubility of water was found to be proportional to the square root of the partial pressure of steam. Moulson and Roberts 4 confirmed this relationship for a silica glass. On the basis of the square root relationship, Tomlinson2 and Russell3 interpreted the solution reaction as "network-breaking", similar to that expected on the addition of metal oxides to silica. Walsh et al.' postulated two possible modes of solution, one the mechanism suggested by Tomlinson and Russell and the other the reaction of the water molecule with an oxygen ion to form hydroxyl ions. These two modes of solution suggest opposite effects of melt basicity on water solubility. However, little appears to be known about the effect of melt basicity on water solubility. Walsh et a1.l found, in the lime-silica system, that the water content increased slightly with increased basicity. As these authors pointed out, this does not appear to be in accord with their further observation that slags containing little or no silica dissolve very little water. Kurkjian and Russell5 measured the effect of basicity on water solubility in alkali silicates in the composition range 15 to 45 mole pct alkali oxide. They found a minimum in the water content at about 25 mole pct alkali. This was interpreted on the basis of two concurrent solution reacZions; one in which solubility was proportional to the activity of doubly-bonded oxygen and, in the other, proportional to the activity of singly-bonded oxygen. The present work was aimed at establishing the effect of basicity on water solubility in silicate melts over as wide a range of compositions as practical. APPARATUS AND EXPERIMENTAL PROCEDURE The silicate melt was equilibrated with a "carrier-gas" of accurately known water content, quenched, and analyzed for water by a vacuum fusion technique. Some pertinent details of the equilibration procedure, analysis technique, preparation, and handling of the silicates are given below. Gas-Silicate Equilibration. The apparatus used to equilibrate the melt with the gas mixture was similar to that used by Walsh et al.' but with some important modifications.6 Purification trains were provided for nitrogen and hydrogen; whenever air or oxygen was used as carrier gas the nitrogen purifiCation train was used with the copper furnace at room temperature. Gas flow rates were measured with capillary flow meters; bleeders filled with a mixture of dibromo and tribromo ethyl benzene (density about 2 g per cc) were used for convenience in controlling flow rates.

Jan 1, 1963

By K. K. Kelley

This report contains heat-content values for hexagonal crystalline germanium dioxide between 298.15° and 1,350° K., and for germanium dioxide glass between 298.15° and 1,800° K. experimentally determined by the Federal Bureau of Mines. No similar data for these substances are to be found in the literature. The heat-content and corresponding entropy-increment data are presented both in tabular form and by equations. Free energy of formation values are estimated for germanium dioxide glass at 298.15° and 1,800° K.

Jan 1, 1961

By M. S. Klima, A. P. Pinkerton

Solid-bowl (decanter) centrifuges are used extensively to dewater slurries in a wide range of industries. However, the application of decanters as classification devices is not as common. In this study, the performance of a continuous, pilot-scale, solid-bowl centrifuge was evaluated when classifying an ultrafine coal slurry containing nearly 60% material less than 10µm. The current study examined the effects of operating conditions on centrifuge performance. The test conditions included centrifuge bowl and scroll speeds, volumetric feed rates, solids concentration, and pond depth. Centrifuge performance was evaluated using partition curves, along with product yields and solids concentrations.

Jan 1, 2000

By Jean Cayouette

"In 1995, Louvicourt Mine started one of the first paste backfill operations in Canada. From 500,000 tonnes in 1995, the annual paste backfill tonnage produced reached 800,000 tonnes in 1999. The maximum throughput of the surface plant (including binders) is 3,50Ot/d with a final density of 75 to 76% solids which gives a slump of 15 to 17cm. Following the start-up of the paste backfill plant, the backfill strength performance levels were well below the pilot plant’s predictions. The introduction of ferrous slag, laboratory tests on various binder ratios with or without additives, and the desliming of the tailings enabled us to optimize the mix and operation costs. Primary and secondary stopes are filled respectively with a paste containing 4.5% and 2% binders consisting of a mixture of 20% cement and 80% ferrous slag. In certain stopes, the binder ratio may vary from 2 to 7%, but always in a ratio of 80/20. Six years after start-up, or 4.5mt of paste backfill later, this paper discusses the present operation and the major changes that have occurred over the years to optimize both the operation and the paste fill quality.INTRODUCTIONLouvicourt Mine is operated by Aur Resources Inc. which owns 30% of the shares. Its partners are Novicourt Inc. (45%, subsidiary of Noranda Inc.) and Teck Corporation (25%). The mine is located in the north-west part of Quebec, about 600 km north of Montreal and about 25 km east of Val d’Or. The mine commenced commercial production in July 1994."

Jan 1, 2002

The need for legislative reform of health and safety legislation has been recognised in New Zealand for about a decade. Previous legislation did not cover all work places, many areas were excluded from coverage, and there were at least 14 different acts and dozens of sets of regulations dealing with various aspects of health and safety.

Jan 1, 1993

By J. F. Archibald

A research effort has been undertaken, under Workplace Safety and Insurance Board of Ontario (WSIB) sponsorship, to characterize the support capabilities of conventional and innovative spray-on lining materials for mitigating dynamic failure effects created by simulated rockbursts. Conventional spray support media, such as shotcrete and fibrecrete linings, and a variety of new spray-on lining materials [thin, spray-on liners (TSLs)], typically polymer-type thin coatings, were subjected to simulated rockburst influence. For baseline comparison, conventional rockbolt and bolt-and-mesh support products were also evaluated. Observation of lining performance was undertaken through completion of field-scale support and rock detonation trials. Controlled blasting tests were conducted at the Queen’s University Explosives Laboratory to examine the effectiveness of the variety of surface coating agents for modifying dynamic rock spalling processes. All tests were performed upon largely undisturbed and homogeneous rock materials in highly repeatable fashion. All blasts were observed seismically and photographically to provide detailed information concerning rock motion, surface fracturing, ejected fragment motion and support liner survivability characteristics. These material comparison trials were performed to assess the relative effectiveness of a wide range of currently available area support techniques for suppressing hazards associated with dynamic rock ejection. The results of this study validate that thin, spray-on linings may be equally as effective, and often better, than conventional support materials at mitigating rockburst or like damage in highly stressed mine environments.

Jan 1, 2004

By Stanley F. French

ELECTRICAL power and distribution for the sulphide ore plant is an addition and extension of the existing power system which has served the oxide reduction plant since its inception in 1914. The power plant is located at Tocopilla on the west coast of Chile, some 90 miles from Chuquicamata. A brief description of this plant and the existing transmission system is necessary to an understanding of the problems involved in the provision for the sulphide plant load. Originally the Tocopilla power plant consisted of four Escher Wyss turbines driving Siemens Schuckert generators, each rated 10,000 kw. At various times, units of 10,000 and 20,000 kw were added, all of which operated at 215 psi and 600°F at throttle. In order to improve the economy of the station, a Topping unit was installed in 1938 together with a high-pressure steam generator of 360,000 lb per hr capacity. This unit is rated at 11,000 kw and was designed for 750 psi, 880°F. The exhaust from this turbine passes to the low pressure station header for operation of part of the low pressure turbines. Total kw generated by the high pressure boiler, topping turbine and associated low pressure turbines totals 33,000 kw and the total station capacity is 113,000 kw. This installation proved one of the most successful of its kind, operating almost continuously. The original plant was of German design and consequently European characteristics were incorporated into the system, the frequency being 50 cycles and voltages of 500, 5000 and 100,000 were used for low, generator, and transmission voltages,

Jan 1, 1952

Over the last three decades, the mining industry has been moving towards more underground mechanized mining methods and the number of LHD vehicles utilised has increased. The growth of mechanization and automation has benefited both workers and the mining companies. However, due to the design of the LHD vehicle and the limitations of the operating environment, restrictions to operator visibility are inevitable. The inability of the equipment operator to see clearly (i.e. people, objects or hazards) around the machine has contributed to a number of accidents including fatal injuries. In order to identify vehicle design characteristics resulting in restricted and blocked sightlines, visibility assessments for existing machines are traditionally completed in the field using a light filament technique. Past researchers have used the light filament technique to collect obscuration zones around the equipment and to produce a 2D chart of this information. The 2D shadow diagrams have proved to be useful in highlighting potential equipment problems and have been performed repeatedly to show the potential of redesigning a part of the LHD for improving visibility. The light filament method involves manually collecting data and requires a level of judgment to be used. As a result the method is susceptible to errors and requires around three hours to complete. The objective of the current research is twofold; firstly to develop a rapid method for field visibility data collection using a laser scanner and secondly to compare results of repeat tests for both light filament and laser scanning methods. A MENSI GS100 laser scanner along with Pointscape and 3Dipsos software has been used to collect visibility information and process the data. The research aims to develop the laser scanner as a technique to rapidly evaluate the visibility profile of an LHD vehicle. Machine design changes can then be assessed quickly using these results.

May 1, 2004

By P. Massi

"Wholly owned by the Coniagas Mining Company, the oldest continuously listed mining company on the Toronto Stock Exchange, St. Andrew Goldfields is located on Hwy. 101 approximately 30 miles east of downtown Timmins, Ontario. Geographically situated on the Porcupine-Destor Fault, the mine and mill in Stock township is positioned in the heart of Northeastern Ontario's goldmining communities.In July 1988, a 600 ft. shaft, hoist, and compressors were already in place when construction started on a 500 T.P.D. capacity C.I.P. mill and crushing plant.By June 15, 1989 the mill was commissioned and attained the design capacity by August of that same year. Since then, changes to the circuit have increased throughput to 900 T.P.D. from two significantly different ore sources.Meeting the Ministry of the Environment's guidelines is an ongoing commitment utilizing the Inca S02 process in line between the tailings pond and secondary polishing pond.INTRODUCTIONExploration on what is now known as St Andrew Goldfields' Stock Township Mine was carried out ln the early l960 1 s by Hollinger Mines Ltd. The property was acquired by Quebec Sturgeon River Mines 1n 1973 and the main shaft was started ill 1979.When St Andrew Goldfields was incorporated 1n 1983, exploration and development commenced to identify the ore body. The company decided 1n 1987 to bring the Stock township property into production after an extensive feasibility study and testwork at Lakefield Research in Toronto. Leslie Engineering was contracted to design, engineer and procure al 1. equipment from the coarse ore bin to the tailings distribution system and backfill plant"

Jan 1, 1992

By C. A. F. Pinto

In the present work compared flotation kinetics of apatite with four different collectors was established. Sodium oleate and rice bra~ oil were used to represent conventional collectors. The new collectors included a sulfosuccinate and a sulfosuccinamate. It was observed that the collection ability of each reagent was very dependent upon the mineral size ranges. The results-were analyzed in terms of size-by-size recovery curves. Flotation rates were also very dependent on size ranges of the mineral particles. One of the new collectors displayed higher flotation rates for coarser particles than the other reagents tested. Synergetic effects were also apparent when a conventional collector was mixed to a new collector.

Jan 1, 1991

By Ruth McKeown, Gilson de F. N. Gitirana, Murray Fredlund, HaiHua Lu

The current design standards for the use of anchors in slopes is based on two-dimensional (2D) limit equilibrium analyses. Anchors are considered as discrete loads and the 2D anchor, factored based on the spacing distance, corresponds to extending anchors indefinitely in the third dimension. A three-dimensional (3D) analysis offers a more realistic representation of the problem, including the true discrete nature of the anchor point loads. This paper explores the typical differences between analyzing anchors in 2D and 3D, using four typical conceptual models. Slopes with constant cross sections were shown to be adequately represented by the traditional 2D approach. The maximum difference between 2D and 3D models was 21% and becomes negligible for lower anchor spacing values, as expected. A slope with an external load was analyzed to evaluate critical slip surfaces with lower aspect ratios. Slip surfaces with lower aspect ratios presented higher edge effects that contributed to the stability of the slope. The results indicate that optimum design requires the 3D evaluation of field conditions inducing low aspect ratios, such as concave and convex surfaces, weak layers, and external loads. INTRODUCTION Slopes may be stabilized using a variety of solutions, including anchors. When performing an analysis, geotechnical engineers often follow the traditional two-dimensional (2D), Limit Equilibrium Method (LEM). It is important to understand the consequences and limitations of the assumptions on which the 2D LEM is based. There are numerous studies on anchors that show the importance of considering the actual three-dimensional field conditions. Desai et al. (1986) proposed a three-dimensional procedure based on the Finite Element Method and considering elastoplastic behavior and interface elements, to account for stress and displacement distributions, the relative motion between the anchors and the soil mass, and nonlinear soil behavior. Several important stabilization mechanisms were explained. The role of grout injection was evaluated in terms of the produced normal stresses along the anchor-soil bounding surface. The approach was shown to reproduce adequately experimental tests on a sand, proving realistic stress distributions around the anchor. Nonlinear soil behavior influenced to a large extend relative interface motions. Michalowski (1989) applied an upper-bound limit analysis in 3D to slope stability analyses. Anchors were not specifically considered in this study, but the consideration of locally loaded conditions shed light on important modeling aspects. The manner how the slide mechanism becomes three- dimensional as the slope is locally loaded was demonstrated. This emphasizes the fact that anchors should produce field conditions that require 3D analysis approaches.

Jan 1, 2019

By Esperidiana A. B. Moura, Célio H. Wataya, Roberta A. Lima, Rene R. Oliveira

Biodegradable starch/copolyesters/silica nanocomposite films were prepared by melt extrusion, using a twin screw extruder machine and blown extrusion process. The influence of the silica nanoparticle addition on mechanical and thermal properties of nanocomposite films was investigated by tensile tests; X-rays diffraction (XRD), differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM) analysis and the correlation between properties was discussed. The results showed that incorporation of 2 % (wt %) of SiO2 nanoparticle in the blend matrix of PBAT/Starch, resulted in a gain of mechanical properties of blend.

Jan 1, 2015

By James M. Henderson, John B. Pfeiffer

The recently completed liquid sulfur dioxide plant at American Smelting and Refining Co.'s Tacoma copper smelter in Washington last April is one step by the firm to meet ambient air quality standards in the vicinities of its three US copper smelters. At a capital cost of $18.5 million, the liquid SO2 plant will work together with an existing sulfuric acid plant to treat all gases generated by the copper converters. Designed to handle up to 45,000 cfm of converter gas utilizing the Dimethylaniline (DMA) process, this plant is expected to recover about 51% of the total smelter input.

Jan 11, 1974

By D. Kozelj

Introduction The porphyry copper deposit “Borska Reka” is the biggest undeveloped deposit in the Timok Magmatic Complex (TMC). Total reserve calculated manually is 611 Mt (cut-off grade 0.3% Cu) of 0.62% Cu, 0.21 g/t Au and 1.81 g/t Ag and 869 Mt of 0.58% Cu, 0.14 g/t Au and 1.11 g/t Ag using software. But since several deep drill holes are suspended in high grade (0.7% Cu) porphyry, total reserves could exceed 1Gt. The massive sulfide is also detected in the central (12 m at 4% Cu) and the bottom of porphyry style. Deposit was discovered during geologic exploration of deeper part of the Bor copper and gold deposit, i.e. area of high sulfidation with dominant massive sulfides. During exploitation of massive sulfide, constant explorations were carried out aimed at the expansion of reserve and discovery of new ore bodies. In that way, porphyry copper mineralization was discovered without knowing in the beginning that it was different mineralization type in regard to the ones that had been already identified and exploited. Vertical extension of porphyry is 0 m up to -1000 m sea level and not contoured along plunge. In the very beginning (1976), the exploration was focused on the shallow part of porphyry. That is because block caving method of massive underground mining was not developed at that time. Up to 1999, most of activity was related to underground exploration up to level -395 m. Geographic position The Bor deposit is located close to the industrial and University town Bor, which has over 50,000 inhabitants (census made in the year 2002). Apart from the Bor Mines, industrial complex of Mining & Smelting Basin Bor (RTB) comprises also a copper smelter (installed capacity up to 160,000 tons of blister copper) and tank house, copper wire factory, copper tube factory etc. Currently, RTB Bor is under privatization process that is going to be completed by the end of 2006. Up to date, over 20 companies have bought tender documentation.

Jan 1, 2007

By Walter G. Brusey

This paper describes a comprehensive pile test program conducted at John F. Kennedy International Airport (JFKIA) to evaluate pile types and design capacities ranging from 890 to 4450 KN (100 to 500 tons). Driven cased piles and drilled shafts, both standard construction and post-grouted after installation, were tested with platform loads extending to 8900 KN (1,000 tons). Alternate load test procedures were developed, extensive structural integrity testing and dynamic load tests were performed on selected shafts. A brief update is provided covering the application of results of the test program to pile selection for support of major structures incorporated in the on going redevelopment of JFKIA.

Jan 1, 2000

By Rojas M. Raúl

Durante el proceso de explotación de la mina Cerro de Pasco y dada la cercanía de la ciudad misma, esta se ha visto afectada por los problemas de vibración del terreno. En este sentido, el objeto del texto es determinar un control de las vibraciones a través de la voladura en el tajo Mc Cune de dicho yacimiento y así evitar daños a las construcciones civiles y labores de explotación subterránea.

Nov 8, 1984

By Zhucheng Huang, Ronghai ZHONG, Tao Jiang, Jun ZOU

The method of reduction roasting and magnetic separation of low-grade, micro- fine disseminated refractory iron ore following granulation with coal produced unexpected success. Pellets of iron ore with diameter between 3 and 8mm were granulated with coal, bentonite and water. The raw pellets and reduction products were analyzed by scanning electron microscopy and x-ray diffraction. Results show uniformly distributed coal powders inside the pellets improved the kinetics of the reduction process and accelerated the reduction rate. Reduction time was higher at temperatures below 890℃, which resulted in the formation of substantial amounts of fayalite. When temperature was increased, micro- fine hematite was then quickly reduced to iron metal and the amount of fayalite decreased sharply. When pellets were reduced at 950℃ for 25min, reduction products with 56.73% metallization rate were obtained. After grinding and magnetic separation, a concentrate with 72.18% Fetot was obtained.

Jan 1, 2015

Throughout the industrial world, Ilmenite, Rutile, Monazite and Zircon mineral sands play a KEY role in numerous industrial processes. Australia's ilmenites, rutiles, and synthetic rutiles are of vast importance in the world of titaniferous ores, and Australia has been the world leader in the field, and continues to adapt to new demands with alacrity. These materials enter a world titanium dioxide market that will exceed three million tonnes in 1990 at an expected growth rate of 2.3%. Many experts place current use in excess of 2.5 million tonnes of contained Ti02. Here we have a slide that illustrates projected growth rates in consumption, in SCM's view.

Jan 1, 1986

By O A. Aladejebi, S Mitra, T Singh, D O’Dea, S, T Honey

Granulation of the iron ore blend and the additives is the foremost step in the agglomeration of iron ore fines to achieve a permeable bed during sintering, which is crucial for sinter productivity. This study investigated the granulation of four types of blends to determine the impact of granulation on bed permeability. The blends were granulated in a rotating drum at various moisture contents and their JPU permeability was measured at each moisture content in a permeability pot (diameter 95 mm and height 500 mm) at various flow rates. Several independent experiments were carried out to investigate the changes in permeability when mixtures of different particle size range (-1 mm and +1 mm) were introduced into a packed bed with a larger particle size range (-6.3 mm to +4.0 mm). The results revealed that the addition of particles in the -1 mm size range had a more pronounced negative impact on permeability compared to particles in the +1 mm size range. This can be attributed to the relatively higher energy losses (mainly inertial) associated with the presence of -1 mm particles in the mixture. The findings were used to quantify the granulation process based on the -1 mm particle size fraction in the granulated mix and their utilisation (denoted by UI-1 mm). For achieving optimal permeability in a specific blend, it was found that a UI-1 mm (utility index of -1 mm particle size) ranging from 0.82 to 0.92 was required. However, exceeding a UI-1 mm value of 0.95 resulted in weaker granules prone to deformation and led to decreased bed permeability. The study also showed that the UI-1 mm was highly dependent on the water addition per kg of -1 mm in dry feed and suggested adding ~80 to 110 mL of water per kg of -1 mm in dry feed to attain the best possible permeability. Additionally, the research proposed a mechanism involving the melting of granules at high temperatures and highlighted the influence of -1 mm particles on bed permeability during the sintering process.

Sep 18, 2023

By P. A. Mascaró, N. Chacon, A. A. Cecchi

"This document shows the development of a system called the “On-line charge level determination in SAG mills” (abbreviated as Jc). The Jc variable has certainly been difficult to measure due to the relevant number of factors and variables that affect the grinding phenomena inside semi autogenous (SAG) mills. To assess the feasibility stage of the proposed system, it was necessary to carry out two tests in different sized SAG mills, 38´ × 22´ and 36´ × 15´, respectively. In each test, the system was configured with a battery of sensors of the following types: (1) strain gauge, (2) accelerometer, and (3) gyroscope. The first step involved for charge level determinations was to determine kidney foot and shoulder by means of a study of the energy-impacts on shell structures. The second step consisted of correlating the measured grinding operational variables with the actual charge levels obtained from SAG mill crash stops. This system development is extremely useful and relevant for providing approximations about mass balances inside SAG mills. It will be a suitable tool for explaining “tonnes per hour” variations and determining optimal points under various operating conditions.INTRODUCTIONThere has been a growing necessity for technologies capable of obtaining “on-line data” of the main comminution variables in order to increase throughput. Computer systems have taken an important role in providing important solutions by means of processing on-line device signals (commonly referred to as monitoring). In semi autogenous (SAG) milling, there are many examples of monitoring devices that allow the operational staff to obtain detailed information both mechanically and electronically inside a grinding circuit. In this context, a new technology has been developed to obtain “Jc total charge (%) online” in two different SAG mills called Vibro-Energy® System.As part of the analysis performed by JKsimMet® the Jb/Jc was estimated because it has an important impact on SAG mill throughput. Different scenarios were simulated and contrasted at various theoretical Jb/Jc values in a baseline circuit (Figure 1)."

Jan 1, 2016