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By H. A. Doerner

Tellurium is a silver white solid with metallic luster, the e17atal.line torm being ver., brittle aud e.g,s!ly powdered. It has a specific gravity of 6,27, melta at 45a0c. and boils at red het, giving off a. golden 1ellow vapor when air 11 excludei. When heated in air, telluri'UiD burns with a bl\te name tinged with green, and evolves wh1 te vapors ot tellurium dioxide. An amorphous form of tel­lurium, obtained by red.uction and precipi ta.tion from so).ution, haa II specific gr1.vity ot 6,015, and when heated ia cho.nged to the cry:.,talline variety. Telluri,a 11 insoluble in water, c&rbon diaiJ.phido, or h;rd.rochl oric acids, but it 11 41a-1olved bJ nitric or concen t1·ated. sulphi.U·ic acid. It 1..oea not tamiah in moiet ah•• 11 ree11tant to alkaline solutions, e,;:ctpt concentrated KOB, but it 11 cliaaolvecl by tuaed. &lkl 1••. I ts 11.to!!lic weight h..'l.a been the "J.Ubject ot mch controverq, bu\ t.he value 137 .5 :.a bl!ten generally accepted, Tho chflmietr:, of tellurium ia eim1lar to that ot IUlphur. It tonne throo xid.ee TeO, To02, and Te0 , al10 tellur14ea, t•llurite,, and. tellur1.t11, A number of halide compoWld.1, a 3iulph1de, and. a .ulpbat.e are known.

Aug 1, 1922

Before presenting this address I desire to express my appreciation of the honour which has been conferred on me by my election as iPresident of The Australasian Institute of Mining and Metallurgy. At this stage it might not be out of place to recall that Broken Hill was the birthplace of The Australasian Institute of Mining and Metallurgy, originally formed as the Australasian Institute of Mining Engineers in 1893.In selecting for my address the topic of "The Broken Hill Mining Industry and its Contribution to the Economy of Australia" I realise it is impossible to cover fully every aspect of the nation's economy which owes all or part of its origin to the Broken Hill field. Nevertheless, I feel that some attempt should be made to give credit to the Broken Hill mining industry for its part in the progress which Australia has made over the past seventy years.. If we care to reflect for a moment it soon becomes apparent that, not only is the Broken Hill mining industry an important producer of base metals for domestic and overseas consumption, but its profits have provided the means whereby many of Australia's leading secondary industries have been established or built up. Examples which come to mind are the founding of the iron and steel industry by the Broken Hill Proprietary Company; the establishment of plants at Port Pirie in South Australia, and at Risdon in Tasmania, for the production of metallic lead and zinc; and also at Port Kembla for the smelting of copper ores. From profits derived from operations at Broken Hill, capital has also been provided to assist other new essential...

Jan 1, 1956

By H. Suharyono

The results of an experimental study of polymer-induced flocculation of clay suspensions in continuous, stirred-tank reactors are presented. The effects of polymer dosage, mixing time and mixing intensity are shown to be generally similar to those observed for equivalent batch systems, but flocculation appears to be generally less effective in the continuous process. Settling rates are lower and supernatant turbidities are higher for the continuous system. It is postulated that non-equilibrium effects due to simultaneous polymer adsorption and floc growth can be exploited so as to enhance flocculation in batch systems. The nature of the continuous process, however, offers less opportunity for taking advantage of such effects. Conditions in a continuous flocculation system inherently lead to a closer approach to equilibrium.

Jan 1, 1994

By O. A. Ojo, D. L. Chen, N. Zhou, J. Q. Zhang, A. K. Khan

Dual phase (DP) steels are designed to consist of hard martensite dispersed in a relatively soft ferrite matrix, which offers a favorable combination of high strength with good deformability. Fiber laser welding (FLW) is becoming increasingly important for joining advanced materials due to its flexibility and deep penetration. In this study, the microstructure of a dual phase steel, DP980, welded by FLW technique was carefully analysed. Gleeble thermo-mechanical simulation coupled with analytical transmission electron microscopy (TEM) revealed that the FLW process produced significant microstructural changes in a narrow heat affected zone (HAZ) and fusion zone (FZ), which can result in dramatic changes in mechanical properties. This is reflected in the micro-hardness profile obtained across the welded material. The salient phase transitions induced by the FLW, including the formation of new martensite grains in the upper-critical HAZ and FZ, are discussed.

Jan 1, 2014

By Stefano Pirrello

"Sydney’s booming real estate market has pushed property developers to invest in historically “no-go” areas, which were previously too expensive to develop. These areas are usually near rivers where the sites are underlain by deep alluvial and estuarine sediments. In these ground conditions conventional bored pile techniques are often not competitive. Contiguous Flight Auger (CFA) and Drilled Displacement Piles (DD) techniques are on the other hand suitable for these ground conditions. This paper deals with the design and construction challenges encountered with these piling techniques for a series of high-rise towers in Sydney’s West. The advantages of DD over CFA piles such as reduced overall spoil with substantial cost savings and achievable rock sockets in medium strength bedrock are discussed. Design validation through interpretation of real-time data from the piling rigs’ on-board computer data, and low and high strain pile dynamic testing (PDA) is discussed. Testing data is presented as CAPWAP (Case Pile Wave Analysis Program) analyses for different concrete grades.INTRODUCTIONThe booming real estate market in Sydney has pushed property developers in investing in historically “no-go” areas, which were previously too expensive to develop. These areas are usually near rivers where the sites are underlain by deep alluvial and estuarine sediments. In these ground conditions conventional bored pile techniques are often not competitive. Contiguous Flight Auger (CFA) and Drilled Displacement (DD) Pile techniques are on the other hand suitable for these ground conditions and were utilised using concrete injection methods. This paper deals with the design and construction challenges encountered with these piling techniques for a series of high-rise towers in Sydney’s West.GEOLOGY & GEOTECHNICAL CHARACTERIZATION OF THE SITEThe Sydney 1:100 000 Geological Series Sheet shows that the site is underlain by man-placed filling and alluvial/estuarine sediment. The sediment comprises silty to peaty sand, silt and clay. Shell layers are also expected to be present within the soil profile. The Prospect/Parramatta River 1:2500 Acid Sulphate Soil Risk Map shows the site as ‘Disturbed Terrain’ in which soil investigations are required to assess acid sulphate soil potential. Several Cone Penetration Tests and Boreholes were carried out during the geotechnical investigation. All boreholes were extended to bedrock and NMLC-sized diamond core drilling was used to obtain 50mm continuous core of the rock, enabling unconfined compression strength testing to be carried out on selected samples. A summary of the ground conditions encountered on this site and inferred from the CPTs can be described as follows:"

Jan 1, 1900

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By Eugene Stephenson

CRITICAL analyses of the work expended in producing oil by the utilization of gas energy have appeared in the publications of Shaw,1 Pierce and Lewis,2 and Herold,3 authors who have ably discussed the factors which must be taken into consideration in comparing energy consumed per barrel in various wells which are flowed by means of gas-lift. However, two distinct phases of oil production are concerned with the ratio of gas energy consumed to oil produced. One of these phases is the gas-lift, which utilizes the differential gas pressures for the purpose of flowing oil, whether these pressures be natural reservoir pressures or be induced by artificial compression of gas or air. The other phase has to do with prorating oil production in pools which are operated either as units, or are subject to such restrictions as those imposed at Oklahoma City by the Corporation Commission, or, by similar controlling groups in other fields. An abundance of literature is available relative to the problems of flowing wells by gas-lift, but the first suggestion that the energy of the gas within the oil and gas pool might serve as a basis for proration, appeared in the timely article by McWilliams.4 Much of the. dissatisfaction with proration in certain fields is because some operators feel that besides the hazard to the wells which accompanies the test, the method of allocating production on the basis of the "potential" gage is inequitable and gives some operators a distinct advantage over others.5 The most severe penalty may be exacted from the most progressive operators or those who attempt to produce their oil with a minimum quantity of reservoir gas. If :no difficulties ever

Jan 1, 1931

By Lloyd M. English

Accurate knowledge of the gas content of coal seams has always been important, according to the work of W. P. Diamond and J. R. Levine, 1981, but is becoming increasingly important for several reasons: Excessive gas emissions in the mine can create explosion hazards. Depletion of shallower coal reserves is forcing underground operations to greater depths where coal gas content is often greater. Natural gas prices and the need for new energy sources make naturally occurring coal gas a potential resource of economic interest. Information on coal gas content will impact mine designs, mine ventilation system specifications, and the effectiveness of methane control procedures used. Accurate resource assessment is needed for projecting and designing potential gas utilization enterprises. The emphasis upon methane hazards in mining operations, and upon potential methane utilization, has led us to improve upon the procedures used to determine coalbed methane levels.

Jan 1, 1984

By J. Stachurski

Flotation tests were carried out on 6 coal samples of different rank as well as their oxidized samples. A mixture of diesel oil and alcohols was used in these tests. Surface oxidation caused a distinct decrease of the flotation recovery with some improvement in the grade The reduction in the recovery increased with increasing the concentration of the oxidizing agent. The floatability of low rank coals was affected by oxidation to a higher degree than medium and high rank coals. The recovery size curves of oxidized samples mere similar in shape to that of non-oxidized coals.

Jan 1, 1990

By Wesley Schmutzler

The Deep Mixing Method (DMM) was employed to raise and support the LPV (Lake Pontchartrain and Vicinity) -111 Levee in New Orleans. Even using innovative technologies, the tight schedule to achieve the 100 year elevation by June 1, 2011 was a daunting endeavor. The size and scope of DMM proposed for LPV-111 was on a scale never attempted outside of Japan. Over 1.65 million cubic yards of DMM was installed. LPV-111 is adjacent to the Bayou Sauvage Wildlife Refuge, which is the largest urban National Wildlife refuge in the United States. By utilizing DMM to control settlement and improve stability of the taller levee, side slopes were steepened from the conventional 1V:4H to 1V:2.85H, thus avoiding encroachment into the Bayou Sauvage and reducing the amount of clay needed for the completed levee. The COE utilized Early Contractor Involvement (ECI) for this contract. The ECI process allowed for input from the DMM contractor, TREVIICOS South, in order to optimize equipment resources and material requirements. This paper gives an overview of the extensive DMM requirements for LPV-111 and explains the benefits of the ECI process.

By Kymberley Worrell

The Cripple Creek and Victor Gold Mine was acquired by Newmont in August 2015. The high grade flotation mill project was commissioned in February 2014. The mill to date has been throughput limited due to mechanical and design issues. In order to create the most value from a throughput limited plant a campaign to provide timely ore characterization was undertaken. A diagnostic leach methodology was developed to determine gold associations by ore type. The resulting associations were then used to characterize feed blend; gold losses and optimize gold production. The diagnostic methodology is presented along with discussion on flotation implications.

By Christoph Muller, Geoffrey Liggins, Mohan Hensman

Modern commercial blasting is as much a technical process as it is a business one. As with most processes both aspects of blasting are driven by and generate new data. The time-critical nature of commercial blasting in mining and construction projects, dictate the timely exchange of information so as not to impede production or commerce. Up-to-date information about the blast to be undertaken can help suppliers: meet customers’ expectations to address challenging ground conditions; react to a market where quickly changing orders occur regularly; and address as-drilled blast patterns as opposed to baseline plans. “Real-time” data exchange into and out of the blasting process supports the whole-of-mine data management that the industry is migrating to.

Jan 1, 2010

By F. P. Hassani, H. B. Poorooshasb

"A kinematically admissible velocity field is applied to study the arching phenomenon in a cohesionless granular backfill placed between two rough vertical inflexible walls. The study is different from the previous works which are almost entirely based on statically admissible stress fields. It is shown that the development of arches is strongly influenced by the previous loading history of the backfill which controls the nature of the constitutive laws that govern the mode of stress deformation of the backfill. This preliminary study employs simple models in order to show the potential use of such an approach in evaluating and understanding mine backfill behaviour in the underground excavation. The pressure exerted on the floor supporting the backfill is also studied in some detail.INTRODUCTIONAlthough the importance of the design of mine backfill has been discussed extensively by a number of authors, i.e. Hassani et al. (1985), such theories have not as yet been incorporated in design criteria for underground mine backfilling operation . One factor that such theories must incorporate is the so-called arching action .The phenomenon of arching has been the subject of study by many researchers in the field of civil engineering and mining engineering. Among these scholars the works of Terzaghi (1943), Krynine (1945), Lusher and Hoeg (1964) and Handy (1985) are noteworthy. All these authors use a statically admissible stress field as a starting point to develop their theories. The approach taken by the authors of the present paper is completely different because they employ a kinematicallyadmissible velocity field. It is their belief that the arching phenomenon is closely linked to the interlocking of grains as manifested by the degree of dilatation of the granular mass when subjected to a shearing process.This paper is written in the following sequence. To define the interlocking quantitatively it is necessary to state the constitutive law governing the stress deformation characateristics of the granular mass. This is done in the next section as the law proposed by Poorooshasb and Pietruszazck (1985, 1986) is stated and simplified to suit the present analysis. Next the mode of formation of an arch in a simple system consisting of a mass of backfill sandwiched between two vertical rough walls of infinite extent is examined. The velocity field obtained from the above example is used to obtain solutions to two more complicated situations. The first situation assumes that the backfill is supported, in addition to the vertical rough walls, by a Winkler foundation at its base. The second situation assumes that the Winkler foundation has been replaced by a horizontal beam of uniform section and simply supported at its extremities. The findings of the study are summarized and their practical implications discussed in the concluding remarks."

Jan 1, 1989

By Veena Sahajwalla

The cupola furnace is a coke-fueled shaft furnace used as a primary melting unit in iron foundries. Control of chemical composition of the iron tapped from the cupola is a key factor in productivity and quality control. In an effort to develop a control model for the cupola, a fundamental approach based on physical and chemical principles has been taken to describe the melting process. The behavior of oxidation of the solid charge in the stack of the cupola has been studied. Sulfidation of the charge materials by sulfur-bearing components released to the furnace gases from the coke has been described. Carburization of metal droplets of iron and of steel in separate molten streams has been characterized. Finally, reactions with alloying elements in the hearth (well) of the furnace have been defined. These reactions have been described in a computer-implemented model developed to predict the composition of the iron tapped from the cupola. The model has utilized the thermodynamics and kinetics of the oxidation, sulfidation, and carburization reactions, including temperature and physical aspects, in the various zones of the melting unit. The model predictions have been compared favorably with operating results.

Jan 1, 1992

By G. McIsaac

"This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone’s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place.Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. “Whatif” scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan."

Jan 1, 2005

By L. W. McKeehan

The occurrence of twins in large ferrite crystals, made by a new process, was reported in a recent note.' This paper describes a typical case of such twinning and suggests, on the basis of the observed facts, why smooth slip-planes are rarely observed in this metal. Method of Preparation The material in which the crystals here dealt with were grown was made from 1/8in. Armco iron welding rod containing C, 0.04; S, 0.037; P, 0.003; Si, 0.008, and Mn, 0.02 per cent. This rod was cold drawn into wire about 1 mm. dia. A piece of this wire was supported vertically and was locally heated in hydrogen at atmospheric pressure to about 1400" C. by an alternating current (60 cycles per sec.) of about 35 amp., passed through it between a pair of traveling contacts about 8 cm. apart. The rate of travel for the case in hand was 12 cm. per hr. After some 30 cm. of the length of the wire had been heated and cooled in this manner the whole wire was immersed for a few seconds in dilute nitric acid, not restrained by alcohol. Etching was continued until, as nearly as could be judged by eye, the original smooth cylindrical surface of the wire was no longer capable of specular reflection. Measurements The wire in the etched state was next mounted in a goniometer of special form which allowed the measurement of the spherical coordinates of the normals to any plane surfaces left by the etching. These coordinates were most conveniently a polar distance, 8, from one direction of the wire axis, and an azimuth or longitude, ?, from an arbitrary prime meridian. The region to be described more particularly is shown at a low magnification in Fig. 1, which gives two different views, differently illuminated to show the spatial relationship of a crystal occupying most of the part shown and of an inclusion, or rather a series of three inclusions suspected of being twins based on the principal crystal.

By Joseph L. Uraco, Harry C. Verakis

The use of explosives in underground coal mines presents a potential risk for serious injuries and death to miners. Widespread disasters have occurred from the explosion of methane and/or coal dust initiated by blasting with explosives. Many of these disasters took place in the early 1900's when the use of black powder for blasting was prevalent. Historically, the investigations in the U.S.A. to develop and test safer explosives for blasting coal began in 1908 when a testing station was established in Pittsburgh, Pennsylvania. Since that time, great strides have been taken in the development of safer explosives. The use of safer explosives has significantly reduced blasting accidents in coal mines. Enactment of legislation, such as the Federal Coal Mine Health and Safety Act of 1969 and enforcement of regulations has also improved blasting safety. More recently, MSHA began a major revision of its regulations for blasting in coal mines. In 1988, MSHA published final rules for the approval and use of permissible explosives in coal mines. The approval requirements for explosives address testing and evaluation. The requirements include tests for sheathed explosives which represent a new technology. The use regulations provide increased safety protection for miners by including standards to address identified hazards. Major aspects of these standards, such as qualifications for blasters, multiple-shot blasting and the use of sheathed explosives are discussed.

Jan 1, 1992

By A. L. Titchener, M. B. Bever

FROM their investigation of the martensitic transformation in Cu-Zn alloys, Greninger and Mooradian' concluded that there was no critical temperature at which martensite formation began in this system. Recent unpublished work by Gen-evray With two compositions of brass revealed the existence of a critical temperature, which is a function of composition and stress. In the work reported here the temperature range of the martensitic reaction was studied as a function of composition in high purity Cu-Zn alloys. The specimens were about 4 in. long with a diameter of 1/16 in.; their compositions are given in Table I. They were heated under vacuum for 5 min at 5" to 10°C below the temperature of incipient melting, and quenched into brine at about — 10°C. Specimens of alloys C, D, E and F were obtained with little or no precipitated a phase. Many attempts yielded only three usable specimens of alloy B, and even these contained appreciable amounts of a. All efforts failed to preserve metastable p in alloy A (containing 38.02 pct Zn and 0.002 pct each of Pb and Fe). The transformation was studied by measuring the electrical resistance during continuous cooling and heating of each specimen at similar rates. The cooling media were alcohol with dry ice from room temperature to — 78°C and a bath of petroleum ether and methyl cyclohexane (75:25), cooled by liquid nitrogen, from —78" to about —150°C. Readings were also taken at —195 °C in liquid nitrogen. Fig. 1 illustrates a typical experiment. The relative resistance is obtained by assuming the known

Jan 1, 1955

By J. Diaz

"Antioquia region, in Colombia, is considered one of the areas with the highest mercury contamination in the world due to its use in gold recovery through artisanal mining, emissions to the environment between 100 and 150 tonnes of mercury are estimated by year. Therefore it became necessary to develop a project in which it was proposed aim to empower traditional artisanal mining community, or in different areas, such as gold mining in the region of Antioquia, in the implementation of safe mining practices and environmentally sustainable, from the introduction of clean technologies, in order to prevent or mitigate the impacts generated by traditional mining on the environment and the communities involved. In order to achieve this training to traditional mining community developed and technical visits to artisanal mining were performed in order to optimize operating processes and promote safe mining practices. In the project more than 1400 artisanal miners were trained.INTRODUCTION In the developing world, a combined 30 million individuals extract more than 30 different minerals using rudimentary techniques. Gold is the preferred mineral extracted by artisanal operators due to its high unit value and its market price, which has increased almost sevenfold over the last decade (Veiga et al, 2014). The artisanal gold mining sector in Colombia has 200,000 miners officially producing 30 tonnes Au/a. In the Northeast of the Department of Antioquia, there are 17 mining towns and between 15,000 and 30,000 artisanal gold miners (M. Veiga, 2010) (Upme, 2014). This production, however, has caused environmental problems, including high levels of river siltation and mercury pollution (Veiga et al, 2014) (UPME, 2007) (Cordy et al., 2013). The mercury contamination in Colombia by artisanal gold mining has been recognized by a number of researchers and local authorities for over a decade estimated that the annual mercury emissions from artisanal gold miners in Colombia in 2007 were between 50 and 100 tonnes, however given recent gold value increases and gold rush activity, current mercury emissions are likely much higher. Colombia is likely the world's 3rd largest source of mercury emissions from AGM after China (240 to 650 tonnes of Hg/a) and Indonesia (130 to 160 tonnes of Hg/a) (Telmer and Veiga, 2008) and is the world's highest per capita mercury polluter (M. Veiga, 2010)."

Jan 1, 2016

By C. Stollberg

The recovery of valuable materials from electronic waste is of growing importance for the re-source management not only in the industrialized nations. Being a significant step in an innovative automated process for recycling of metals and plastics from used electric and electronic equipment, the results of the work introduced below, prove the applicability of microbial leaching of metals from printed circuit boards (PCBs) at industrial scale. Within the first project step, which started in March 2005, experiments in shaking flasks with a mixed culture of chemolitotrophic bacteria (mainly Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans) were carried out to study the solubilization of non-ferrous metals present in the electronic waste. It was found that the best results were achieved by means of a two-stage process in which leaching of these metals was carried out by acidified ferric sulphate solutions generated as a result of the prior bacterial oxidation of ferrous ions to the ferric state. Special reactor systems for bacterial generation of such solutions and for the subsequent leaching of non-ferrous metals from the waste were developed, constructed and tested under laboratory and pilot scale conditions. The optimum technological parameters such as concentration of iron ions, pH-value, temperature and presence of nutrients were established for both reactor systems. Parameters such as particle size, pulp density and flow rate of the suspensions being leached were established for the leaching process carried out under continuous-flow conditions. The complex flow sheet reflects a highly efficient technology on the basis of metal recovery, environmental effect and economical acceptance. The process was successfully implemented into an industrial demonstration unit.

Jan 1, 2014