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By R. Roufail

"Energy consumption in stirred mills has been studied, in the last couple of decades, on a macro scale. Effective operation and meeting particle size required for downstream operations used to be the main objectives behind energy utilization of stirred mills. In this paper, three energy terms are defined to assist in understanding the breakage mechanism for various types of minerals versus mill operation. The types of minerals studied had diverse physical and mechanical properties that are summarized as specific gravity, hardness and crystal structure. The minerals utilized in this study were quartz and galena. The effect of quartz and galena mix has been addressed as well as Lead-Zinc ore sample from SAG mill discharge. The energy input to the mill is function of the agitator speed, therefore three agitator speeds were evaluated, 1000, 1500 and 2000 RPM, respectively. The energy terms studied are specific energy (kWhr/ton). Effective energy is the ratio between net energy and total energy consumed by the mill. Last type of energy is the specific breakage energy, which is the net energy consumed by the mill per one-micron breakage. Results showed that specific energy and specific breakage rate are functions of mineral type, while effective energy is only function of mill input power (agitator speed).INTRODUCTIONGrinding is the largest energy consuming component of a mineral processing operation and typically consumes about 50% of the total energy used at a mining operation (Botin, 2009). Over the last two decades, stirred mills have been extensively utilized in mineral processing operations due to increased mineralogical complexity of ore bodies. Stirred mills grind particles to less than 10 µm by applying a high power intensity. The technology has been the focus of several research studies to investigate mill energy and grinding mechanisms. Becker, et. al. (2001) studied the relationship between different types of energy including input energy, specific energy, volume/mass specific energies, to stress intensity and final product particle size. Other studies such as by Kwade (1999), Kwade and Schwedes (2002), Blecher et al (1996), Partyka and Yan (2007), Stender et al (2004), focused on mill design and/or stress intensity distribution. Peukert (2004) studied the effect of mechanical properties of the grinding media and ground material on the comminution process."

Jan 1, 2016

By David C. Uhrin

Two improved methods have been developed to transfer microfilmed mine maps to suitable base maps showing surface features. The methods provide for (1) positioning and orienting maps; (2) merging adjacent maps; and (3) plotting maps at a common scale. One method produces an overlay mosaic of mine maps using an Integrated camera-processor. This photographic method shows the details of mine workings and is most useful for specific limited-area projects. In the second method, outlines of mine maps are digitized, manipulated, and plotted as overlays using a computer. This computer method can plot mine outlines and spatially index large numbers of microfilmed maps. Microfilmed mine maps used in this Bureau of Mines study are on file in the Mine Map Repository of the Eastern Field Operations Center. The base maps are U.S. Geological Survey 7.5-minute topographic maps. The demonstration area is located in the New Kensington East and West quadrangles, Pennsylvania.

Jan 1, 1977

By Magnus Evertsson, Haijie Li, Erik Hulthen, Mats Lindqvist

"The static and dynamic models for autogenous (AG) and semi-autogenous (SAG) mills have been studied for decades. Though the effects of mixing soft and hard ores in a mill and their interactions are not widely investigated. To develop a general numerical model for AG/SAG mills, a dynamic model has been introduced, and its capability to simulate multi component ore breakage has been examined and compared with previous publications. The simulation results show that the dynamic model can cover a range of milling conditions and is able to simulate complex scenarios with soft and hard ores. The dynamic model discussed here could provide substantial potential for the controlling and optimization of the comminution circuits. INTRODUCTION In the last decades, efforts have been devoted to studying the comminution circuit due to their high energy consumption. The energy directly spent in minerals comminution was about 2% globally in the year 2000 (Maurice et al, 2003). As one important part of the comminution process, AG/SAG mills are widely used for primary grinding in minerals processing. AG/SAG mill models include static and dynamic models (Kojovic et al, 2012; Yu et al, 2014; Yu et al, 2017; Liu and Spencer, 2004; Salazar et al, 2009). Many static models have been well validated over the past decades, but they are all based on steady state assumptions. Even though plants experience a steady-state condition under certain circumstances, it can be inaccurate to simulate the system by static models under all circumstances (Asbjörnsson et al, 2013). The advantages of a dynamic model are apparent that it provides more information and insights both inside the mill and through interactions with other machines in terms of pebble crushers, conveyor belts, screens and so on. In many mines, the multi-component grinding is inevitable, and the ratio of hard and soft components in the mill strongly affects mills operation and performance. Bueno (Bueno et al, 2010; Bueno et al, 2013) studied the effects of blending hard and soft ores in AG/SAG mills and used them to update the JKSimMet toolkit which was a steady state plant simulation software. However, due to the complexity of the particle interactions such as multi-component breakage function, appearance function, in mill transportation, there has been no dynamic AG/SAG mill models developed yet for simulating multi-component."

Jan 1, 2018

By Ulrich Schwarz-Schampera

Submarine hydrothermal vents and associated mineralization on the Tonga arc have been identified in the summit calderas of two shallow-water volcanoes. The highest temperature vents (up to 270°C) occur at water depths between 430 and 540 meters below sea level (mbsl) near the summit of one volcano at 24°S (volcano 19). Clusters of large barite, anhydrite, and sulfide chimneys on the summit cone are vigorously discharging clear hydrothermal fluids with temperatures on the seawater boiling curve. There is abundant evidence of phase separation and associated gold and base metal precipitates. Pyrite, marcasite, wurtzite-sphalerite, tennantite, and chalcopyrite line the interiors of the highest temperature vents. Acid-sulfate alteration of basalts and basaltic andesites is evidenced by intense silicification and the presence of abundant alunite. One volcano at 21°S (volcano 1) has a chain of explosion craters on the flank of a neovolcanic scoria cone and associated massive pyrite, barite and native sulfur deposits at a water depth of 210 mbsl. Intergrowths of pyrite and enargite are associated with intensely argillic altered basaltic andesites. The reported alteration and Au-enriched mineralization styles of these vent fields are similar to other shallow water hydrothermal systems at island arc volcanoes and contribute to the diversity of seafloor hydrothermal activity in the western Pacific region.

Jan 1, 2010

By Scott A. Anderson, Benjamin S. Rivers, Derrick D. Dasenbrock, Silas Nichols

Unknown geotechnical conditions are a major source of risk. Unexplored places vastly outnumber the sampled and tested ones, and widely spaced boreholes with intermittent tests and samples are the norm. Sometimes site-specific planning and thought goes into locating these special, tested places, such as basing them on the geologic understanding or anticipated key locations for the structure; more often they are simply evenly distributed. We demonstrate a holographic model that allows viewers to see real data in real space, scaled or not, and to visualize where measurements are taken, what those values are indicating, and where there exists more unknown and more risk. The holographic model shows in an intuitive way, values from Standard Penetration and Cone Penetration tests, and surface geophysics. The mixed reality of this future is that a wide audience – owners, designers, project managers, contractors, and stakeholders interact together in a real space where they see and talk to each other, while at the same time are individually looking all around below or above ground, like a gopher, in a virtual one. Risk in the future will be better managed through more thoughtfully designed investigations and better communication of 3D data in a world of augmented reality. INTRODUCTION This paper explores the use of augmented reality to convey understanding of the subsurface conditions of a bridge site. This is in contrast with the current state of practice where this information is contained in a geotechnical report, and the ideas are also applicable to other structures, earthworks, and excavations. “Augmented reality” describes a situation where a 3D holographic model is displayed for users in such a way that the users experience both the model and the real environment of their setting- such as at a desk, in a meeting room, or in an open space at a project site (Figure 1). The 3D holographic model is used to directly visualize underground features, to see through the earth to the actual locations where explorations are made, samples are obtained, or measurements are taken, design values are assigned, or construction is planned. An immersive model provides the following three powerful functions for users:

Jan 1, 2019

By K. Wangerud, B. S. Caruso

A water balance model with deterministic and stochastic components was developed and used for the Gilt Edge Mine Superfund Site, South Dakota, to evaluate risks of contaminated runoff discharging to surface waters based on assumed water treatment plant (WTP) rates for different remedial alternatives. The objectives of the modeling were to use a stochastic approach for analysis of precipitation based on historic records, and for probabilistic estimation of annual and monthly runoff from primary disturbed/mining activity areas that currently requires, or will need, treatment at the WTP, water storage and changes in a major pit, and risk of contaminated water bypass of the WTP to a downstream drainage. Subareas/source areas generating contaminated runoff requiring treatment were delineated. A simple water balance model was used based on precipitation inputs and evapotranspiration and groundwater losses. Annual and monthly precipitation records for Lead, South Dakota were used to estimate precipitation at the mine site. A lognormal distribution was estimated for monthly precipitation. The stochastic software package/Excel add-in “@Risk” was used to generate random monthly precipitation values using a Monte Carlo method based on the distributions. The average annual and monthly distribution of pan and lake evaporation, and groundwater losses were also estimated for the site. Stochastic outputs from the model for the end of each month and year included contaminated runoff requiring treatment, water storage in mine pits and the risk of WTP bypass given different assumed WTP rates. The probability of the time required to dewater the pits was also modeled.

Jan 1, 2002

By Leonard Obert

This report describes an inexpensive triaxial equipment for testing 2-1 / 8- , 4- , and 5-5 / 8 - inch - diameter rock cylinders subjected to loading conditions comparable to those encountered in underground mining . Only minimal specimen preparation is required . The maximum axial load that can be applied is 250,000 lb , which corresponds to an axial stress of 70,000 psi for the 2-1 /8- inch- diameter specimen . The maximum radial pressure that can be applied is the same for each specimen diameter ; namely , 10,000 psi . The mechanical parts in this equipment are relatively easy to machine and fabricate . The cost of all parts , including the 250,000- lb hydraulic press but not including labor costs , was approximately $ 1,000 .

Jan 1, 1963

By W. W. Smeltzer

The linear formation rates of wustite films have been determined over the temperature range 590° to 1030°C using a vacuum microbalance technique. These rates are dependent directly on the partial pressure of carbon dioxide, Activation energies for film and scale formation in carbon dioxide and oxygen atmospheres are equivalent to either the dissociation energies of carbon dioxide and oxygen, or the activation energy for the diffusion of cation vacancies in wustite. Of the metals, iron is the most widely used basic constituent of durable alloys despite its intrinsic property of converting at a relatively rapid rate to the oxides from which it is derived. This property has accounted partially for many investigations on the oxidation of iron at low and high temperatures. Interpretation of the results have been complicated by formation of multilayers containing the various oxide phases. To aid in elucidation of the oxidation kinetics, measurements have been carried out in this investigation on the growth of the wustite surface layer. There are several studies directly related to the objective of this investigation. The growth of multilayer scales has been demonstrated to be diffusion controlled in oxygen at atmospheric pressure over the temperature range 450" to 1200°C by Davies, Simnad, and Birchenall.' To gain an insight into the diffusion mechanism, Himmel, Mehl, and ~irchenall' determined the self-diffusion coefficients of iron in wustite, magnetite, and hematite. These results were used to evaluate the oxidation rates of iron and its oxides, taking as a basis the theoretical parabolic rate equation developed by Wagner., The evaluations were compared to experimental data and were shown to provide essential confirmation of this theory. Fischbeck, Neundeubel, and salzer4 have demonstrated that the oxidation of iron in carbon dioxide and other atmospheres at high temperature obeys a linear relationship. Because the Arrhenius temperature coefficients of the reaction rate constants changed at the A, point they concluded that the passage of iron into the oxide controlled the reaction. This viewpoint has been accepted by Benard and ~albot' to explain the occurrence of linear rates in oxygen before the onset of diffusion-controlled parabolic oxidation. This basic premise of a rate-controlling reaction at the iron/oxide interface has been questioned recently by Hauffe and Pfeiffer.' Since the formation of wustite may follow a linear or parabolic relationship depending on the pressure of the gaseous re-actant, they propose that linear oxidation is determined by a chemisorption reaction while parabolic oxidation is controlled by diffusion. As confirmation of this viewpoint, Hauffe and pfeiffer6 and Pfeiffer and ~aubmeyer' have established that the linear scaling constants of wustite formation at 1000°C in carbon-dioxide or low-pressure oxygen atmospheres

Jan 1, 1961

By John J. Sammarco

The U.S. Bureau of Labor Statistics reports that the mining industry has the highest average annual fatality rate (31.9 per 100,000 workers) among all major American industry. To address this, a major research program to reduce hazard exposure of miners with computer-assisted mining equipment was initiated by the U.S. Bureau of Mines.1 One application involves the manual process of extracting and hauling coal where operators, in the tight confines of a mine, can be struck or caught by mobile machinery. The approach to remedy this problem uses a guidance system on the haulage equipment so that it follows the machine that extracts coal. This, in essence, involves sensor-based docking of the machines. Sensors that can survive the hostile mine environment of dust, methane gas, and water, play the key role. Computer analysis of the mining machine's movements and empirical machine characterizations were conducted to establish operating requirements and spatial limitations to ensure proper loading of coal into the haulage equipment. These data served in the selection of a sensing system. Various technologies such as scanning laser systems and ultrasonic sensors have frequently been used in other applications but were found unacceptable. However, a near infrared (IR) sensor employing active targets met the requirements. The sensor has a nominal 75° conical field-of-view and a range from 0.1 to 18.0 m. For the single target mode, nominal range accuracy was 4.3% at a distance of 3.56 m. Correction algorithms were generated reducing the error to 0.6%. Airborne dust testing showed less than 0.8% accuracy (worst case) degradation at levels exceeding (by a factor of 7.5) concentrations permitted by Federal law. The sensor can track multiple active targets providing five degrees-of-freedom (DOF) measurements. Using four targets, the nominal range accuracy was 0.4% without correction algorithms. A guidance system for the haulage system to follow the mining machine does not exist commer¬cially. Such a system can reduce fatalities and injuries by current haulage mining equipment, and is a viable alternative to current haulage control.

By M. E. Holuszko

Although there is no widely accepted rigorous definition of handleability, the handling coal characteristics often referred to as handleability define whether a coal has the ability to flow unhindered through the processing and transportation systems. The handleability may be severely affected if fine coal particles tend to aggregate. In the pelletization process, the rolling action of the drum is applied to bring the individual particles into proximity with each other so that they can aggregate and form pellets. Because of apparent similarities between these two processes, the pelletization tests are carried out in parallel to the handleability tests in this project, and the pelletization results are used to explain coal handleability properties.

Jan 1, 2004

By Alana Pereira Ramos, Walman Benicio de Castro

Amorphization and martensitic transformation (Ms) characteristics of Ti–Ni-Cu alloy ribbons prepared by melt spinning were investigated by means of differential scanning calorimetry and X-ray diffraction. In these experiments particular attention has been paid to change the wheel linear velocity from 21 to 63 m/s. Then the cooling rates of ribbons were controlled. The effect of this cooling rate and alloy composition on martensitic transformation behavior is discussed.

Jan 1, 2015

By K. Huang

"Solvent extraction (SX) is one of the most effective techniques for the multi-metal separation. However, repetitive pre-treatment of feed-in solutions and/or multi-steps two phase equilibrating in conventional SX processes were always unavoidable due to the poor separation selectivity between those metals with similar physicochemical properties. In this paper, our recent efforts, aimed to develop a “Three Liquid Phase Extraction” (TLPE) strategy for one-step separation and selective enrichment of different metals respectively into three coexisted liquid phases, are reviewed. Various feasible “Three Liquid Phase Systems” (TLPS) are evaluated. The TLPE technique provides a potential possibility for multiphase extraction to separate multi-metals.INTRODUCTIONLiquid-liquid Solvent Extraction (SX) is one of the most effective techniques for metal separation and purification. Traditionally, extraction and separation of multiple valuable metals from the leaching solutions of complex ores, industrial wastes and byproducts have to face such difficulties that multiple target metals with similar physicochemical properties co-exist in the solutions, and therefore their mutual separation selectivities are very poor. In conventional organic-water two phase SX processes, repetitive pre-treatment of feed-in solutions including the adjustment of the solution acidity, removal of impurities and/or multi-step liquid-liquid two phase equilibration were always unavoidable (Wang and Chen, 2001). Only one of the target metals is obtained in each extraction step, therefore the whole separation processes for multi-metal separation are typically very long and costly.Liquid-liquid-liquid three phase extraction is a developing technique for separation of complex systems containing multiple target components (Tan, 2003; Shen, 2006; Yu, 2009). The technique is in fact a three-liquid-phase selectively partitioning of different target components through the control of phase-forming behaviors of extraction system to create a unique separation medium with three co-existed liquid phases. The separation selectivity of “Three-Liquid-Phase System” (TLPS) may derive from its three-layered liquid phases from up to down with different hydrophobic or hydrophilic environment, and therefore each phase has its own specific selectivity for dissolving of an individual component. In a well designed “Three-Liquid-Phase System” (TLPS), multiphase extraction and selective separation of different components respectively into three different liquid phases can be achieved by only one-step of extraction. Owing to its distinct advantages, “Three-Liquid-Phase Extraction” (TLPE) technique has found many potential applications in purification of various organic chemicals (Shen, 2007) and biological activities (Chen, 2002; Tan, 2006; Jiang, 2008), treatment of environmental wastewaters (Shen, 2006; Yu, 2009; Yu, 2010; He, 2012), extraction of valuable components in natural products (Liu, 2010) and separation of multi-metals in complex leaching solutions (Jin, 2009)."

Jan 1, 2012

By A. W. Asman

The problem of balanced design in a belt conveyor has been under constant study. Increased use of this method of transport in recent years has stimulated investigations. Conveyor belt, power transmission and other machinery should be adequate to perform the required service. All components of the belt conveyor should work as an efficient unit moving its load continuously between terminals. As part of a long term research project on belt conveyors, Hewitt-Robins established in 1954 a 2-year grant at Pennsylvania State University. Under terms of the grant, certain fundamental phenomena were to be studied. This work evolved a new concept in belt conveyor power determination based on the principle of belt tension. The Penn State contract furnished the foundation for later more detailed studies. From these most recent investigations, more specific factors were defined. In the final analysis, all of the data collected has been worthwhile in belt conveyor design. Units now operate over long distances at speeds of over 800 fpm. Long high lifts are commonplace. Where vertical or inclined shafts were the rule, belt conveyors receive first consideration. Although belt conveyors have moved forward rapidly, the future will see a tremendous gain in their use. The ideal test belt conveyor would be several thousand feet in length and have a maximum tension of at least 70,000 lb., Also, this conveyor should be horizontai and have a variable feed rate of more than one material. Data from such a field belt conveyor combined with laboratory information would permit accurate analysis. Since this type of conveyor was not available, many field locations were visited: An alternate would have been to erect a closed circuit system in the laboratory. Either method had limitations and the first was selected as having the best possibilities. Manufacturers of conveyor belting and machinery basically have been using the same horsepower formula. As more information became available from field installations, factors in the basic formula were modified. Practically all conveyors are designed today by adding together the horsepowers required to move the empty belt, move the load horizontally, and elevate the load. In selecting size of drive motor, the first two elements are relatively unimportant if the last is large. However, it is the combination of

Jan 1, 1961

By Fuming Wang, Xi Chen, Shuai Liu, Changrong Li, Dan Wu, Yaxu Zheng

The effects of B content and austenitizing temperature on hardenability and toughness of Cr–Mo alloy steel have been studied. The results show that the hardenability is deteriorated with increasing B content and austenitizing temperature. With increasing temperature, more and more B containing particles were dissolved in austenite and increase the amount of B atoms segregating at grain boundaries. Moreover, the coarsening grains reduce area of grain boundaries and also increase the amount of B atoms at unit grain boundary, excessive B atoms segregating at grain boundaries promotes precipitation of M2B, which accelerates ferrite nucleation and reduces hardenability. The main elements in M2B phase are Fe, Cr, Mo and B. The B atoms segregating at grain boundaries during austenitizing promote precipitation of M2B during tempering which deteriorate toughness significantly.

Mar 1, 2018

Well designed and maintained haul roads are the key to minimising truck haulage on-road hazards and costs, as well as increasing productivity. However, practically designing and managing a haul road for optimal performance is often diff cult to achieve. Poorly designed and built roads exhibit high rolling resistance - a one per cent increase in road rolling resistance can typically reduce speed on ramp by as much as ten per cent - and on the f at by up to 26 per cent. In the current economic climates, investment and operating decisions come under scrutiny. In the long run, this scrutiny returns improved efficiencies and leaner, healthier operations. The focus of this evolving evaluation process should and will certainly fall on haulage operations - simply by virtue of their contribution to overall cost of operations - often in excess of 50 per cent of total costs for deep open-pit mines. Whilst the end result - improved efficiency and reduced cost per ton hauled - is not in itself problematic, it is the route, or process followed to achieve these savings that needs to be carefully managed. We can be guided on this journey by our understanding of how a road is designed, and, critically, the interplay between a good design and safe, cost efficient haulage.This paper brief y summarises the evolution of mine haul road design, from the seminal USBM work of Kaufman and Ault in 1977, through to current geometric, structural, functional and maintenance management design components. These augmented design and management guidelines have been developed over the past decade, both in response to the requirements of mine operators for more safe and efficient haulage systems, and the truck manufacturers' requirements for a more predictable and controlled operating environment. These developments have been paralleled by the need to minimise haulage hazards, both from a health and safety perspective. Generally, both objectives have been achieved, but with some specific areas of design and operation still presenting ongoing potential health and safety hazards.The paper then summarises current design guidelines for these safety-critical issues, both from a road-design 'best-practice' and road management perspectives. Implementation of the approach is seen as a basis for reducing the potential of an under-designed mine road to lead to health and safety defects and secondly as a means of giving haul road safety and performance issues greater prominence in the minds of the road-user, operator, mine planner and designer alike.

Dec 6, 2010

By R Bertuzzi

Permanent rock bolts in civil engineering are taken as having to serve their design purpose for at least 50 years. In many projects the design life is specified as greater than 100 years. A review of recent Australian tunnelling projects shows that substantial differences exist in the level of corrosion protection provided for permanent steel shafted rock bolts. This paper reviews the current state of practice and sets out what the authors consider to be appropriate requirements for corrosion protection.

Jan 1, 1999

By Yi Luo, Jian Yang

Subsurface strata movements and deformations associated with longwall mining operations in underground coal mines could cause various disturbances to subsurface mine structures, ground water bodies, and coalbed methane reservoirs. In order to assess those disturbances correctly and to design effective and efficient mitigation measures, it is necessary to develop an accurate prediction model for subsurface strata movements and deformations. Decades of research have demonstrated that variations of stratification and lithology in the overburden have significant influence on the subsurface strata movements and deformations during ground subsidence process. The key strata theory states that the thick and hard key strata serve as the backbone of the overburden and control the movements of the thin and soft weak strata located above them. From an engineering standpoint, the overburden strata are subdivided into several individual groups by the key strata with each group consisting of a key layer at the bottom and weak layers overlying it. A new subsurface subsidence prediction model considering the key strata effects on subsurface strata movements and deformations has been proposed. In this method, elastic modulus, specific weight, tensile strength, and uniaxial compressive strength (UCS) of each layer are used to identify the key layers and to determine the needed subsurface subsidence parameters. The influence function method, proven to be accurate and versatile for surface subsidence prediction, was employed to predict the subsidence on each of the overburden layers from mining horizon progressively upward to ground surface with the assumption that the predicted subsidence on a given layer serves as the subsidence source for the layer immediately above. The enhanced subsurface subsidence prediction model has been demonstrated with an actual case to show its applicability and improvement.

Jan 25, 2021

By Clarence O. Babcock

Model pillars of limestone, marble, sandstone, and granite with length-to-diameter (L/D) ratios of 3, 2, 1, 0.5, and 0.25 (0.286 for granite) were tested to failure in axial compression to determine to what extent an increase in end constraint increased compressive strength. Adjustable steel rings, mechanically tightened about the ends of test specimens to create a radial prestress of 3,000 or 5,000 psi prior to the application of axial load, increased end constraint more than was possible in previous tests using solid steel rings. (Solid rings, epoxy-bonded to the ends of dogbone specimens, increased compressive strength compared with that of straight specimens without ring constraint.) During the loading cycle, additional end constraint was produced by lateral expansion of the specimens against the rings. The effect of the end constraint was to increase the compressive strength 55 to 58 percent for the shorter pillars of dogbone shape compared with the compressive strength of straight pillars with the same L/D ratios without ring constraint. Most pillars with L/D ratios of less than 2 were made stronger by end constraint. Pillars with an L/D ratio of 3 did not benefit significantly from end constraint. When the results from compression testing of straight specimens of rock in the laboratory are used to design mine pillars in situ, the pillars will be larger than necessary if the horizontal compressive stress is several thousand pounds per square inch greater than that resulting from the weight of the overlying rock alone. The L/D ratio can be increased by a factor of 1.76 for ratios in the range 0.25 to 3 and still provide the same compressive strength. The safety factor applied with straight specimen test results should also be acceptable for use with constrained pillar test results.

Jan 1, 1969

By Bernard J. Scheiner, R. J. Wesely, Cy E. Jordan, A. D. Zunkel, Gary M. Wilemon

The U.S. Bureau of Mines has investigated leaching of off-grade western United States phosphate deposits using sulfuric acid (H2SO4) in the presence of methanol. A combination of ore grinding followed by sulfuric acid in methanol leaching extracted over 80 pct of the phosphate. This leaching technique significantly limited the dissolution of iron, aluminum, and magnesium impurities and produced a phosphoric acid that was well within the desired limits for these impurities. The dissolution rate of phosphate rock in the sulfuric acid methanol system was significantly slower than the conventional aqueous sulfuric acid dissolution. Initially dissolution of the phosphate particle was controlled by the amount of surface area available to the sulfuric acid reactant. After about an hour of leaching, phosphate dissolution was slowed almost to a stop, limited by the rate of ion diffusion through the calcium sulfate barrier layer surrounding the unreacted phosphate particle. Consequently, the ore was ground below 38-pm to increase the particle surface area available and improve the overall dissolution kinetics and extraction. In addition, the sulfuric acid was slowly metered into the reactor to prevent any excess heat from the mixing of acid with the methanol from simulating the formation of methyl sulfates. The formation of methyl sulfate ultimately lowered the overall phosphate extraction by exhausting the supply of available sulfate ions for the dissolution reaction. Subsequent evaporation of the methanol from the product acid decomposed the methyl sulfates leaving undesirable sulfate ions in the product acid. Slow acid addition to the reactor provided high phosphate extraction and limited the amount of sulfate in the final product acid.

Jan 1, 1993

By Stefan Mewes

Europe’s second-largest seaport has installed a new combi wall consisting of pipe piles, sheet piles and inclined shaft grouted piles to support it. The new Liebherr piling rig with swinging leader was used to drive shaft grouted piles into a very dense soil layer of sand with glauconite. The 60 m Liebherr swinging leader was suspended at an inclination of 45° via a suspension frame and suspension ropes from the crawler crane. This inclined installation of shaft grouted piles via freely hanging swinging leader, as used for this project, is unique in Belgium. Moreover, the pile length of 43 m is a novelty for this type of pile. Shaft grouted piles consist of a steel profile with a separate box-like pile shoe with an open top. A thin grout is injected via an injection pipe during driving and emerges just above the pile shoe. As the pile is driven further down, so compressing the ground, the space above the pile foot is immediately filled with grout under pressure. This piling system is ideally suited for the transfer of high tensile loadings. It is a method to increase geotechnical load-bearing capacity and to reduce negative skin friction during pile driving.

Sep 1, 2022