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By Thamyres C. Carvalho, Edemarino A. Hildebrando, Roberto F. Neves, Francisco R. Valenzuela-Diaz

Synthetic clays are an option of materials that can be modified to obtain better and specific properties when compared with natural clays. Although clays are found in nature, they have many disadvantages that limit the use of them, such as existence of impurities, and variations in composition. Therefore, the objective of this work was to obtain synthetic clay/polyester resin nanocomposites. To characterize the clay, we used X-ray Diffraction (XRD), Total Attenuated Reflection Spectroscopy in the Fourier Transform Infrared Region (ATR-FTIR) and Scanning Electron Microscope with Field Emission (FEG-SEM) methods and the nanocomposites were characterized by XRD and mechanical resistance to compression. The results show the purity of the clay and the time of synthesis is an important parameter for its crystallization process. The clay/polyester nanocomposites were obtained and showed an increase in the ductility.

Mar 1, 2018

By Alessandro Bertero, Dylan Pearson, Wesley Schmutzler, Matteo Bertoni

"The SR 83/US 331 highway is located in the Florida panhandle, where it connects the Walton County beaches to the I-10 corridor. The roadway is of vital importance to the economy of the area as well as its safety since it represents the primary hurricane evacuation route from southern Walton County. The Florida Department of Transportation (FDOT) decided to increase the number of traffic lanes from two to four and improve the geotechnical properties of the moderately deep, very loose foundation soils, that had affected the highway rideability for years. The soil mixing was selected as the method to meet the unique deep ground improvement challenges of the project. The design required that Shallow Mixing Method (SMM) be used to build a 10-foot thick platform that transferred axial load to the bottom soil layers through a series of Deep Mixing Method (DMM) columns. Upon completion over 8,300 SMM columns and 1,500 DMM columns had been installed, with no remedial work required. Also, only 1% of the almost 1,500 specimens tested did not meet the specification requirements. This paper will describe the challenges encountered and provide valuable information that may be useful for other future projects, including details not previously published.INTRODUCTIONThe counties of Walton and Okaloosa have been a very popular vacation destination for many ears. The 50-mile long coastline boasts beautiful, sugar-white beaches and waters the color of emeralds. The popularity of the area has been growing even further, over the last few years. A consequence of this phenomenon is a fast-paced increase of the traffic flow on the SR83/US331 highway, especially at the bridge that connects the Walton County beaches across Choctawhatchee Bay (Fig. 1) to the heavily traveled I-10 corridor. The highway plays a very important role for the area also as a commercial link and as the primary hurricane evacuation route from southern Walton County. The increase in traffic has produced higher travel time, when not a complete traffic paralysis, and exacerbated the issue of ground settlement where accelerated wearing of road foundation occurred due to the presence of very loose, moderately deep, soils, that had afflicted the highway for several years. The Florida Department of Transportation (FDOT) decided to put an end to these issues by increasing the number of traffic lanes from two to four and improving the geotechnical properties of the foundation soils. The Design-Build Maximum Price Request for Proposal (RFP) issued for the expansion of the Choctawhatchee Bay Bridge saw the participation of numerous D/B teams which produced various technical solutions. Among them, the FDOT selected the Skanska/Parsons Brinckerhoff (General Contractor) proposal which provided for the use of soil mixing as the ground improvement technology. The design/build team assigned Foundation & Geotechnical Engineering (Designer of Record) the ground improvement design which Treviicos South (Specialty Contractor) would execute."

Jan 1, 2017

By Stephen P. Signer, John L. Lewis

This paper presents the results of a case study conducted in a two-entry gateroad in a coal mine where excessive roof deformation and bolt loading resulted in failure of many roof supports. The instruments consisted of 16 fully grouted, strain-gaged resin bolts, load cells on both full and partially grouted cable bolts, and vertical deflection multipoint extensometers. These instruments were installed on-cycle to measure loading on bolts in an existing support pattern and to determine if cable bolts could be used to improve roof stability. Results showed significant amounts of movement within the bolted zone. In some cases, these movements were enough to load the supports past their ultimate strength. Geology appeared to be a significant factor in localized roof degradation; that is, a very weak rock layer in the immediate roof overlain by a very strong rock layer contributed to the development of shear planes. Only one instrumented bolt had a maximum strain of less than 2,000 microstrain, which was the yield point of the steel. The average maximum strain on all bolts was 20,000 microstrain. However, electrical continuity to many gages was lost and a pattern was noted that would indicate possible bolt failure. Wire mesh and concrete cans installed as secondary support performed very effectively.

By Walter Larsh

The Ruth orebody, so far developed, is roughly oval in plan, major and minor axes about 1600 ft. (487 m.) and 1200 ft. (365 m.) respectively, average thickness about 120 ft. (36 m.), and with a general dip of about 15° to the northwest. According to the generally accepted theory, the ore is a secondary enrichment of the porphyry due to leaching in situ by meteoric waters. Copper occurs as chalcocite, chalcocite coating pyrite, and a little chalcopyrite. The leached zone, or capping, covering the ore varies in thickness from 110 to 540 ft. (33 to 164 m.), average about 410 ft. (124 m.). The ore is blue gray in color, and the capping, light yellow to brown. Ore was first discovered in quantity in the workings from the Ruth shaft, now caved. Further development work was done by churn drills, and the outline of the orebody, as stated above, determined in this manner. Drilling is still being carried on. The porphyry area is entirely surrounded by sedimentaries, lime-stones and shales; and, in so far as the underground workings have shown, the porphyry' itself, the sedimentaries near the contact, and the country underlying the ore (igneous or sedimentary) is very soft, heavy, and in places swelling ground. All openings have to be carefully and stoutly timbered, and, after once driven, they have to be constantly eased off and repaired. The mine is at present served by two shafts, the Star Pointer, the main working shaft; a vertical, and the Ingersoll, an incline used for waste and material. The two shafts are about 2600 ft. (792 m.) apart, connected on the 500 level; a connection is now being driven on the 600 level. (Dec., 1917. This connection is now completed.) The 300 level, which is finished, and the 400 level which is nearly completed, are accessible only from the Ingersoll and connections with the 500 level.

Jan 1, 1918

A large lab apparatus was designed using a scale-down methodology based on the design legacy of the current FLSmidth commercial forced air flotation machines. This new apparatus, along with a new test methodology, was used to evaluate new rapid prototype concepts. The apparatus was designed to monitor bubble size, power, pumping capacity, Jg, velocity profiles, froth character, and tip speed. The methodology developed follows a sequence that goes from hydrodynamic tests and solids suspension tests to a flotation kinetic test. This methodology has been demonstrated to be a good tool to determine the effect of machine design changes on flotation.

Jan 1, 2012

By J. E. Urosek

Decisions made during a response to a mine fire or an explosion greatly affect the final outcome. The safety of miners should be the primary concern with accounting for all of the miners the first issue for resolution. If miners have not safely evacuated from the mine, the last known location of the miners at the time of the event and anticipated travel routes are primary exploration areas. After the mine is evacuated, there are many very important decisions that must be made quickly and often under great stress. It is critical that the mine operator establish an orderly method to direct the mine emergency response. Designation of a Command Center, staffed with personnel charged with developing plans, is a common method of establishing control. Scheduling of key mine managers will be critical, since decisions must be made 24 hours a day and people working for extended periods with little or no sleep do not always make clear or cognizant decisions. Internal communications, passing information on to subsequent shifts, and external communications with families and media must be accurate and timely. Assembling resources for responding to the mine emergency is critical for an effective response, and pre-planning can pave the way to a successful recovery. Sampling mine gasses and accurately determining the composition of gas mixtures is a common tool used to develop response plans in all fires and explosions. It is essential that preparations for emergency situations are made well in advance of a disaster. Effective communications are essential for mine management to successfully respond to a mine emergency. This paper discusses some considerations which need to be addressed in directing a response to a mine fire or explosion.

Jan 1, 2009

By Richard A. Dick

This Bureau of Mines report describes the evolution of modern-day blasting agent and slurry products and the state of the art of the usage of these products as it exists today. The steadily increasing consumption of blasting agents and slurries at the expense of cartridged high-explosive usage is related. Although safety is not covered in depth, reference is made to pertinent safety literature available. Product formulations, detonation reactions, and detonation products are discussed. Product terminology is defined and the significant differences between the relatively insensitive modern-day dry blasting agents and slurries and cap-sensitive high explosives are described. Blasting agent and slurry properties are discussed, as well as methods of determining and describing these properties, and specific types of products are also discussed with reference to their ingredients,-properties, and field applications. Increasing consumption of slurries, particularly in small-diameter boreholes, and the development of more cap-sensitive varieties of slurries are forecast although dry blasting agents should continue to dominate the market. The consumption of cartridged high explosives will level off or gradually decrease.

Jan 1, 1972

By J. Drew

Oregon Resources Corporation (ORC), an industrial minerals mining company, is currently engaged in the development of a new process design that will allow the unique paleo-beach placer deposits of southwestern Oregon to be mined efficiently and economically, creating an additional domestic source for chromite, garnet, and zircon. Engineering design has been guided by the variable geology and mineralogy of the paleo-beach placer deposits as well as the need for a dry tailing scheme that resolves a lack of water resources at the placer locations and at the same time eliminates the need for slurry settling ponds, typical of paleo-beach placer operations in North America. Metallurgical study of the placer material was grouped into four distinct samples based on marine terrace deposition, geological facies, and mineralogy. Because the metallurgical samples represented the extremes likely to be encountered in all future Oregon paleo-beach placer ores, the process design is highly dynamic and will successfully adjust to meet the production needs. Water availability at the mining area is seasonal and will not support a typical placer operation?s water requirement needs for heavy mineral concentration. For this reason, ORC has developed a plan to construct the ore processing facilities near Coos Bay, where a municipal source of water is available. Raw ore will be transported from the mining sites approximately twenty miles one way to the processing facility with return loads hauling tailings back to the active pit. The need to haul dry tailings, return dry material to the pit for reclamation, and limit the amount of water being purchased from the municipality has driven the design of a unique water reclamation system. BACKGROUND Location and Access Economic concentrations of ?black sand? or heavy mineral (minerals with specific gravity greater than 2.85) have been recognized and studied in marine placers from Coos Bay to the mouth of the Rogue River, a distance of approximately 75 miles along the southern Oregon coast (Hornor, 1918; Griggs, 1945)(Figure 1). ORC will begin mining existing reserves approximately 20 miles south of Coos Bay in a region known locally as Seven Devils. Ore will be trucked north to the processing site near Coos Bay via use of existing county and state roads, including U.S. 101. The available facilities at the processing site include highway, rail, municipal water and electricity, natural gas, and a deep water port. At the time of this writing, the rail line had been abandoned, but was being pursued by the International Port of Coos Bay. It is anticipated that this will be serviceable at some time in the future. History The southern Oregon marine placers have garnered the interests of miners since 1852, when present day beaches were exploited for gold. The beach deposits were small and irregular in nature and were easily washed away by the major storms the coast endures during the winter months (Hornor, 1918). [ ] In the 1920?s, deposits at the beach were followed upstream to their paleo-beach terrace origins (Pardee, 1934). These terrace placers were mined, but with little success, as the cost of mining and processing was greater than at the present day beach deposits. The greatest effort to understand and delineate the paleo-beach terrace placers came during World War II. As the need for a domestic source of steel hardening chromite was evident, the heavy mineral bearing placers of southwestern Oregon provided just that. The U.S. Geological Survey, under guidance from the Oregon Department of Geology and Mineral Industries, began exploration drilling of the paleo-beach terraces in 1940 (Griggs, 1945). This work was part of the investigation of strategic mineral deposits and would ultimately supply much needed chromite for the war efforts. The first mining efforts began in 1943 by the Humphreys Gold Corporation and the Krome Corporation (Griggs, 1945). Black sand

Jan 1, 2009

By Nobuaki Sato

The electrical conductivity, k, of pure and sodium doped sulfur melts was measured with and without ultrasonic waves at temperatures ranging from 140 to 340'C by the two probe method using an ultra high resistance meter. The k value of the pure sulfur melt with irradiation jumped at around 170°C by an order of 102 after which it mouutuniocally increased from 10-5 to10-4 A' 1 cm-1 with an increase of the temperature. The addition of the sodium metal to the sulfur melt was found to cause a larger jumping in the K value. The k value increased with the increase of Na proportion in the melt. For a 10mol% Na doped sulfur melt it was as high as max ~30 A 1cm -1 above 180 C under the irradiation of of ultrasconics.

Jan 1, 2003

Implementation of Fine-Screening in Preparation of KGHM PM SA Sandstone-Carbonate Copper Ore for Flotation

Sep 13, 2010

By R Wolff

One critical factor in open pit mining projects is the estimation of the recoverable reserves. The reason for this is that at the valuation stage there is a lack of information about future metal prices and production costs. Consequently, the estimation of the recoverable reserves needs to be done based on a fixed break-even cut-off grade (BECG), in which fixed expected metal prices and production costs are assumed throughout the operating life of the mine (OLM). In this paper, an alternative technique for estimating the recoverable reserves of an open pit mining project is presented and explained in detail. The main characteristic of this technique is that it estimates the recoverable reserves of the project using mining costs as reference: this is done due to the fact that mining costs are easier to model than metal prices. Another important characteristic of this technique is that it uses the uncertainty of the geology of the orebody, given by simulations of the deposit, to make final strategic decisions, such as the selection of the operating life of the mine and the optimal production rate, which minimise the risk of not achieving future production targets while maximising the upside potential of future rewards. As it will be shown, the final outcome of the proposed technique is the generation of a robust open pit design, that include cutbacks and ultimate pit limits, called the marginal open pit mine design (MOPMD). One characteristic of the MOPMD is that, at each production period, it will be characterised by their respective geological uncertainty, given as probability distributions of ore, waste and metal quantities, and by marginal economical project indicators, such as cut-off grades and metal prices, among others. The details follow in the paper.

Jan 1, 2006

By D. C. Jillson

BRIDGMAN1,2 melted metals in a graphite or hard glass tube and lowered the tube through a furnace to make it cool from one end only. Because of the difficulty of eliminating all vibration of the mold, others have raised the furnace instead. Neither way seems as desirable as a setup with no motion of either the mold or the furnace. A furnace in which both the shape and the slope of the temperature gradient could be controlled and varied over a wide range and in which such a gradient could be moved from one end of the furnace to the other, freezing the specimen from one end to the other, at any desired rate, all by means of isolated external control, seemed to offer definite advantages. In addition to eliminating the possibility of vibration due to moving parts, it might also give better control over the direction and rate of heat flow. Such an apparatus was assembled and is shown schematically in fig. 1. Equipment Furnace: A clay-carborundum tube of 3 1/2 in. ID with a % in. wall thickness was used as the core. This had a main winding of No. 12 B.&S. gauge Nichrome V with some compensation for heat loss at the ends. Taps to this winding were made at points 12 in. from each end. Fig. 2 shows details of this winding and of the two end windings. Each end winding was wound over Micanite over the main winding. No. 15 B.&S. gauge Nichrome V was used for these, and again taps were supplied at two inter-mediat,e points on each. The tube was supported in an 18 in. OD black iron shell with brick insulation. The input to each of the windings was regulated by means of a variable transformer. Temperature Regulation: A chromel-alumel thermocouple located near the furnace wall in the center of the furnace was connected with a Celec-tray controller, type PIC, 300" to 900°C range, which opened and closed a shunt across an external variable resistance in the main winding circuit. An "anticipatory response" device also was incorporated to minimize the cyclic effect of the control mechanism. Eleven survey couples in a common pyrex glass protection tube were located near the furnace wall and spaced 2 in. apart. The couple leads went to a common reference junction box where they were connected to copper leads from a selector switch which, in turn, was connected to a type K potentio-meter. This arrangement permitted rapid temperature surveys. The knob on the controller dial was replaced with a threaded brass spool turned at a controlled rate by a thin iron wire one end of which was attached to a gear train and the other to a small weight heavy enough to prevent slipping of the wire on the spool. The gear train, driven by a 1-rpm Telechron motor, contained a series of different sized interchangeable gears and threaded drums permitting a range of travel speeds from 0.10 in. per hr up to a hypo-

Jan 1, 1951

By R. R. Judd, H. W. Paxton

The rate of dissolution of cementite was studied in three low-carbon materials: a zone-refined Fe-C alloy, an Fe-0.5pct Mn-C alloy, and a commercial low-carbon steel. The materials were spheroidized, ad then held isothermally at temperatures above the Al. The isothermal anneal was interrupted periodically by a water quench and the specimens were analyzed by quantitative metallography for the amount of aus-tenite formed during the anneal. The results of this study were compared with an analytical model for the process, which assumes that carbon diffusion in aus-tenite is the rate-controlling step for the cementite dissolution process. The correlation between the model and the experimental data is excellent for the zone-refined Fe-C alloys; however, the Fe-0.5 pct Mn-C alloys and the commercial steel deviate from the calculated model. This deviation is thought to be a result of manganese segregation between the carbide and the matrix. The rate of nucleation of austenite at carbide interfaces was reduced by the manganese addition and enhanced by the presence of ferrite-ferrite grain boundaries. PREVIOUS investigations of the nucleation and growth of austenite from ferrite-carbide aggregates are not entirely satisfying for at least one of several reasons. The most prevalent of these is a lack of quantitative data. Engineering studies have been run on many steels with little control over important parameters such as composition and initial aggregate structure. The data obtained are valid only for material with identical chemistry and thermal history. A more informative approach to the problem of aus-tenitization would be to determine the mechanism that controls the rate of solution of carbide in austenite and how it is modified by alloying elements. This information could then be used to calculate an austeniti-zation rate for any material, provided its composition and structure are known. The object of the present work is to establish the rate-controlling step for cementite dissolution in Fe-C austenite and to investigate the modification of this rate by small manganese additions. The composition and structure of the material used were carefully controlled and all measurements were designed to allow a quantitative analysis of the kinetic process that controls the austenitization rate. A MODEL FOR DISSOLUTION OF CEMENTITE Cementite dissolution has been analyzed mathematically by a model that approximates the material used in the experiments. This model postulates a regular ar-array of identical cementite spheroids with 4 C( diam, embedded in a grain boundary- free ferrite matrix. The analysis provides a detailed description of the dissolution of one carbide spheroid and a generalization of the solution by summation over all the carbides in the material. The carbides may be isolated by defining identical, space-filling cells of ferrite around them. If the cell dimensions are greater than the diameter of the austenite sphere resulting from complete dissolution of the carbide, and no interaction (through diffusion in ferrite) takes place between cells during the dissolution process, the model need concern only one cell, since the solution in each cell is identical. In the experimental material, the dimensions of the cell, the carbide, and the final austenite sphere are approximately 24, 4, and 8 p, respectively; use of the single cell is therefore justified. The experimental observations are made on the austenite nodules that form around each carbide during the dissolution process. The model concerns the growth of these austenite nodules. The attendant shrinking of the carbide can be obtained from the same analysis by an extension of the calculations. Several a priori assumptions are necessary to make the analysis of the growth problem tractable. They are: 1) carbon diffusion through the austenite nodule is the rate-controlling process; 2) local equilibrium exists at all interfaces, 3) the austenite nucleus that forms on each carbide instantaneously envelops the carbide; 4) during the austenite growth process, the diffusion flux of carbon in ferrite is insignificant; 5) a quasi-steady state exists in the austenite concentration field; that is, at any instant during the dissolution process, the austenite carbon concentration gradient closely approximates that for a steady-state solution; and 6) the effects of capillarity on the dissolution rate of the carbides can be neglected. Referring to Fig. 1, a mass balance at the y-a interface for an infinitesimal boundary movement gives: Where rb is the outer radius of the austenite shell, C1 and C are carbon concentrations at the interface in austenite and ferrite, respectively, see Fig. 2, is the diffusion coefficient of carbon in austenite for the concentration of carbon at the interface, and t is time. The fifth assumption permits the austenite carbon concentration to be approximated by the Laplace solution for the spherical case. Therefore, where C(Y) is the carbon concentration at r, and A and B are constants. Local interfacial equilibrium fixes the boundary conditions for the diffusion problem. They are:

Jan 1, 1969

By C. G. Dunn, W. W. Martin

Various X ray diffraction techniques have been developed for determining orientations of crystals. Transmission and back-reflection Laue methods1,2,3 in particular have been found to be very useful. In many applications, however, a need still exists for a simplification of the details of analysis so that orientations can be determined more rapidly, and operators with little or no training in crystallography can be easily instructed in the necessary procedures. Filling this need in part is a system of analysis that has been in use for several years in the Metals Section of the Laboratory, General Electric Co., Pittsfield, Mass. This method is an extension of the one of Majima and Togino,4 which uses fifty-five indexed standard transmission Lauemams to cover the entire range of crystal orientations. Greater rapidity in determining the orientation of a crystal is achieved by using a slightly larger set of standard Lauegrams and by systematizing the steps followed. This system of analysis in its present form constitutes the subject matter of the present paper. Although the method uses transmission X ray Laue patterns, many of the operations are applicable to the analysis of back-reflection Lauegrams. Very briefly the method is based on the fact that Bragg and azimuthal angles for two or more identified Laue diffraction spots completely determine the orientation of a crystal, and standard Laue photographs of the Majima and Togino type provide a ready means for identifying Laue spots. After a preliminary analysis, which consists of identifying the pattern in terms of one of the standard patterns, a correctly marked Lauegram is selected to carry out the final analysis. From measured Bragg and azimuthal angles, the normals (poles) of the reflecting planes for the selected Laue spots are located on a stereographic projection and the orient.at.ion of the crystal determined (in terms of the positions of cube poles for example) by a few additional operations on a \I1ulff net. The actual procedure followed will be illustrated in detail after a brief treatment or X ray problems connected with orientation determinations and a discussion of useful principles and techniques. X Ray and Plotting Problems RELATIVE ADVANTAGES OF BACK-REFLECTION AND TRANSMISSION LAUE DIFFRACTION METHODS In the back-reflection Laue method it is easy to make a direct measurement of the tilt of a zone of Laue spots. Specimen thickness also is generally no problem. In the case of thin specimens, however, the time of exposure is less for the transmission Laue method. For example, with silicon ferrite this advantage holds up to a thickness of 0.6 mm if tungsten radiation at 40 kv peak voltage is used. Furthermore, the transmission photograph represents the entire thickness of the crystal whereas the back-reflection picture represents only a surface layer (a thickness of less than 0.05 mm for silicon ferrite), the deeper layers supplying a negligible amount to the diffraction pattern. If a crystal is distorted, the transmission Laue pattern gives more information particularly with regard to the orientation of the crystal and the overall amount of spread in orientation. Finally a 3 1/4 X 4 in. film suffices for transmission photograms; a 4 X 5 in. or 5 X 7 in. film with a central hole is needed for back-reflection patterns Not only is the manipulation of film easier because of the size of film, but

Jan 1, 1950

This technical note describes a problem with WANG82, a ventilation network analysis programme. The problem was highlighted by Renison Ltd when using the programme on large, complex networks. Under certain circumstances the programme produced incorrect results or failed to converge to a solution.

Jan 1, 1986

By Alton Gabriel

During the fall of 1940, J. R. Thoenen of the Mining Division, Bureau of Mines, accompanied by the senior author, surveyed the more important domestic alunite deposits. Although the study was designed primarily as an economic survey, samples from a number of the deposits were collected to investigate the beneficiation of the lower-grade material.

Jan 1, 1942

By Alton Gabriel

During the fall of 1940, J. R. Thoenen of the Mining Division, Bureau of Mines, accompanied by the senior author, surveyed the more important domestic alunite deposits. Although the study was designed primarily as an economic survey, samples from a number of the deposits were collected to investigate the beneficiation of the lower-grade material.

Jan 1, 1942

By J. R. Thoenen

[Since the publication of the preliminary report on this subject in July, 1927, (The Wire Saw in Slate Quarrying, Preliminary Report, Serial No. 2820, by Oliver Bowles) the wire saw has been in constant daily operation at the quarry of the Colonial Slate Company. Luring this time between twenty end thirty successful cuts have been made varying in length from forty-five to ninety-two feet and in depth from six to ten feet. No accurate time records have been kept on these cuts but they have totaled over 12,000 sq. ft. of area and required 19,000 lineal fact During these cuts the average speed of cutting has risen from the 12.8 sq. ft. per hour obtained in the original recorded tests to between 15 and 20 sq. ft. per hour, with the present rate running very close to 20 sq. ft. per hour at this quarry.]

Jan 1, 1928

By Konstantinos Modis

According to recently established theoretical analysis and under certain conditions, a critical sampling density can be determined for an earth-related space-distributed natural variable. Sampling above this critical limit adds little to the mapping results. The objective of this paper is the application of the above theory to the Sesklo clay quarry in Greece, where Heracles General Cement Company had conducted a sampling campaign to estimate its reserves. The structural analysis of Al2O3 values generated a variogram model, from which the critical sampling density was identified. This critical number was by far lower than the existing sampling density. Clay reserves were then estimated using geostatistics and inverse distance squares in different data schemes with variable densities. The results of the comparisons between the various models revealed that, when the sampling density was greater than its critical value, geostatistics and deterministic interpolation gave similar estimations, which is also in agreement to the theory. The optimal sampling grid finally proposed here, will result to significant cost savings in the next drilling program which is now in plan by the company.

Oct 1, 2009

By C. F. Lucks, W. D. Wood, H. W. Deem

Electrical ad thermal-conductivity measurements have been made on titanium and 6 titanium alloys. The following expression was derived for calculating thermal conductivity from electrical conductivity: K = 0.626 s T x 10-8 + 0.00497 where K = thermal conductivity, cal sec-1 cm-2 cm0C-1 s = electrical conductivity, ohm-]cm-1 T = temperature, deg Kelvin This expression gives calculated thermal conductivities that are not in error by more than 10 pct from the experimental values for A-55 titanium and the 6 alloys measured; namely, A-110AT, C-110M, C-130AM, Ti-6A1-4V, Ti-140A, and Ti-155A, which are representative of the presently available commercial a and a-ß titanium alloys. THERMAL conduction in a gas, liquid, or amorphous solid is accomplished by energy diffusion from molecule to molecule, a relatively slow process. For this reason, such materials have a low thermal conductivity. When a material is crystalline, there is in addition a heat transfer by a vibratory motion of the crystal lattice. It is the contribution of this lattice conduction that makes a crystal a much better conductor than a gas, liquid, or amorphous solid. Lattice conduction, however, does not account for the relatively enormous thermal conductivity of a metal. This is explained by the freedom of movement of valence electrons. These valence electrons drift in a metal in a direction toward a drop in electrical potential and, to a lesser degree, in the direction of a temperature drop in the metal. Since both the electrical and thermal conductivities of a metal depend upon the presence of free electrons, there should be some relatively simple relation between the two. Wiedemann and Franz in 1653 first discovered an approximate empirical relation between the electrical and thermal conductivities of metals at the same temperature. This ratio varies appreciably with temperature, and Lorenz later showed that by adding a temperature factor to the Wiedemann-Franz ratio the value of K/(s T) is constant, where K is the thermal conductivity, a the electrical conductivity, and T the absolute temperature. This Lorenz constant shows a greater variation for alloys than it does for pure metals, the ratio increasing slightly as the proportion of alloying elements increases. It has been found that a closer correlation between electrical conductivity and thermal conductivity can be obtained by means of an equation of the form K - A s T + B [1] where A and B are constants. In this equation the term AsT is the contribution of electronic conduction and B is the contribution of lattice conduction to the total thermal conductivity. EXPERIMENTAL MEASUREMENTS Electrical-resistivity and thermal-conductivity measurements on titanium and 6 titanium alloys serve as the basis for determining an equation of the K = AsT + B type for titanium alloys. Specimens—Table I shows nominal compositions of the 7 metals on which electrical and thermal conductivities were measured. The electrical and thermal-conductivity specimens for each alloy were taken from stock of the same heat and usually from adjacent sections of the same bar. All of the metals measured were in a mill-annealed condition. Methods—Electrical-resistivity measurements

Jan 1, 1959