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By G. Martino, F. Silva, Emmanuel Marchal

The definition of the chemical specification at multiple steps of the steelmaking process is very common in the industry. Among all elements and compounds, the Sulphur content has a special control over several stages, from the coal blend to the final products. Coke, iron and steelmaking specialists usually agree on a static specification for each intermediate product according to their local operation capacity and production cost. However, local decisions have major impacts on the whole production chain and many global factors should be considered in order to make the best decision. In this study, we will exemplify focusing on Sulphur content concepts and techniques that could be applied to many decisions in an integrated carbon steel plant. The variation of coal and coke prices, the desulphurization cost and time, the processes operating points, the hot metal rate at converters, prices and demands of low and ultra-low Sulphur steel grades are some of the integrated factors that are usually disregarded during the specification process. Mathematical modeling presents itself as a proper option into dealing with all the complexity that emerges from integrating all these processes' trade-offs and decisions. This study presents the results of a mathematical model that encompasses economic, thermal, chemical, and mass balances, physical quality of materials and productivity constraints of all processes of a hypothetical integrated carbon steel plant. It optimizes the iron and steelmaking process on a global and unique objective, dynamically defining targets for product quality to achieve the lowest steel production cost. This study details multiple market-plant scenarios in order to compare economic and operating results of a static vs dynamic specification practice.

Oct 1, 2019

By J. T. Lapsley, I. I. Cornet, A. E. Flanigan, R. Hultgren, J. E. Dorn

With the greatly expanding use of magnesium during the war, it appeared necessary to the War Metallurgy Committee that procedures of heat treating common magnesium casting alloys be investigated systematically. Accordingly, the National Defense Research Committee of the Office of Scientific Research and Development placed a research contract with the University of California, supervised by the War Metallurgy Committee. Research on the solution heat treatment and aging of magnesium alloy AZg2, (formerly ASTM No. 17; also known as Dowmetal C or AM26o) which was done under "Restricted" Project NRC-2I, in 1942-1943, and reported in detail in a final report to the OSRD on September 3, 1943, is the basis of this paper, which has been released for publication by the OSRD. American experience with magnesium alloys prior to World War II was limited, although some of these alloys had been in commercial use since 1909. Requirements of the aircraft industry for light alloys made it imperative to understand and utilize the advantageous strength-weight properties of magnesium castings. Magnesium casting alloys are commonly solution heat- treated to increase their ultimate tensile strength and ductility; this treatment may be followed by an age hardening at elevated temperatures, which raises the tensile yield strength but diminishes the ductility. In the present investigation, AZp was studied to determine the effects on properties of various solution heat treatment and aging schedules. The principles of heat treatment of magnesium alloys are the same as for other non-ferrous alloys. The alloy studied, AZp, has a nominal composition of 9 pct aluminum, 2 pct zinc, and minor constituents. Fig I shows, by the projection of isothermal sections on the concentration plane, the solubility surface1 of the ternary magnesium-rich solid solutions as determined by X ray 'analysis. From this figure it may be seen that above approximately 375°C (707OF), AZp alloy is a single phase alloy at equilibrium; below this temperature the equilibrium condition is a two phase alloy. The beta constituent which precipitates from the solid solution exerts a hardening effect. Because the zinc concentration is only 2 pct, ancl because of its solubility relations, AZqz resembles a binary alloy of magnesium with aluminum. The solubility curve1 of Fig 2 shows how rapidly the solubility of the beta phase decreases with decreasing temperatures. Unlike many aluminum alloys, magnesium alloys do not age harden at room temperatures; precipitation hardening of AZ² alloy is performed at about 177°C (350°F). At this temperature about 3 pct aluminum

Jan 1, 1949

By Eugene McAuliffe

The mining press, as well as certain federal and state bulletins, refer from time to time to the relative hazards that attach to loading bituminous coal by hand when compared with the so-called "mechanical loading" process. Much of the coal coming under the head of hand-loaded coal is won in part by the use of machinery; the coal-cutting machine is in general use, the electric power drill employed to a lesser extent. Therefore it may be said that the principal difference in the process employed, mechanical loading versus hand loading, lies in the fact that some type of loading machine is employed in the mechanical loading process to lift the coal from the face of the room, place or entry, after it is mined, placing it in the pit cars for transport to the tipple. It is a common practice to compute accident records on the basis of tons mined per fatal and per nonfatal accident, disregarding the fact that it is possible to produce by the aid of coal-loading machines the same daily, monthly and annual tonnage with a much smaller force than is required where the coal is all shoveled by hand. Inasmuch as the men who are released by the substitution of machinery for hand labor must find employment elsewhere, suffering some measure of hazard in their new occupation, we are of the opinion that the true relative hazard that attaches to the processes of mechanical loading and hand loading can be determined only by using as the basis of comparison "man shifts worked" or "hours of exposure" experienced per accident. The Union Pacific Coal-Co., beginning with the year 1929, undertook to maintain a true record of man shifts worked per compensable accident, giving equal weight to fatal and nonfatal accidents. Accidents lacking sufficient severity to come under the compensable terms of the Workmen's Compensation Act were not included in the compilation, the Act providing that "no compensation, except the expense of medical attention, shall be allowed for the first seven (7) days of disability, unless the incapacity runs beyond the period of twenty-one (21) days, in which case the compensation shall run from the time of the injury." With the further thought that all accidents suffered by employees engaged in any service, in or about the place where the loading process

Jan 1, 1931

By Roberto Golchi

This article describes the method used to quantify the Environmental Impact for the mining, by drilling and blasting, of a borrow pit for a gravity-dam. The affected environment was broken down into a number of components, such as public health and safety, social relationship, air and water quality, flora and fauna. The effect of the various impacting factors from the mining activities, both directly and indirectly, was then calculated for each environmental component. To do this, each impacting factor was first given a magnitude, a number based solely on the range of scenarios possible for the impacting factor. A matrix of weighting factors was then derived to systematically quantify, and normalise, the effects of each impacting factor on each environmental component. The overall impact upon each individual environmental component was then calculated by summing the weighted magnitudes for all the impacting factors.

Jan 1, 2003

By Heinz Brandl

Box-shaped pile and diaphragm wall foundations have proved suitable for transferring heavy loads of bridges, power plants, tanks, towers or other buildings in a concentrated form into the ground. The bearing-deformation behaviour and the earthquake resistance of such "box-foundations" are superior to those of conventional pile groups. The reason lies in the reduction of lateral soil displacement and in the composite effect between concrete elements and the enclosed soil. The paper describes results of comprehensive model tests and in situ measurements, theoretical aspects and case histories.

Jan 1, 2002

By W. J. Kuit

"Complex facilities which provide for the collection, management and treatment of effluents emanating from the Sullivan mine and concentrator tailings were made operational in October 1979. Key features of the system are the use of upgraded tailings ponds for the storage of up to 800 million litres of metals-contaminated effluents, a treatment plant employing lime in a high-density sludge process and a sludge-impoundment facility designed for maximum long-term environmental safety. The completed works are capable of satisfying a difficult range of operating requirements imposed by highly variable weather conditions, drainage flows and soluble metals loadings. Final capital expenditures for the project approached $10 million and annual operating costs are about $0.8 million.This paper discusses the Kimberley effluents treatment project and the major considerations in its development. The treatment process, major plant equipment and initial operating experience are also described.IntroductionCominco Ltd. has worked the Sullivan orebody at Kimberley, B.C. since 1909 and has operated a concentrator some 5 km distant from the mine since 1923. Over the last 70 years, in excess of 120million tonnes of ore have been mined, and production continues at an average rate of 6,500 tonnes per day. It is a well-known fact that the contribution of this operation to Canada's mining industry and, in particular, Cominco's development has been significant. However, this success has not been without some undesirable side effects.Unfortunately, the Sullivan is one of only a few major Western Canadian orebodies which may be classed as ""acidic"" in nature. That is, the primary economic minerals, galena and marrnatite, are enclosed in a siliceous host rock with abundant pyrrhotite, but with little or no accompanying alkaline gangue minerals such as calcite and dolomite. The unavoidable consequence of mining such an ore is that contact with air and water generates an acid mine drainage containing various soluble metals orginally present as minerals.This problem also arises in the concentrator's tailings ponds, which, in the case of the Sullivan, are two separate impoundments of different materials. The 1,100 tonnesl day of ""iron"" tailings are primarily pyrrhotite which is surplus to the requirements of a separate operation that produces sulphuric acid as an intermediate to phosphate fertilizers. Inert gangue minerals with only a minor sulphide content are the main constituents of the 1,200 tonnes/ day of siliceous tailings. Corresponding to the relative proportion of sulphides in the solids, the decant from the iron tailings is substantially more contaminated than that from the siliceous pond."

Jan 1, 1980

By G. J. Olson, K. S. Noah

A combined physical/biochemical process for the precombustion removal of 13 inorganic hazardous air pollutant (HAP) precursors, i.e., Sb, As, Be, Cd, Cr, Cl, Co, F, Pb, Hg, Mn, Ni and Se, from coal was tested. Biochemical processes for removal of HAP precursors from coal potentially offer advantages of deeper cleaning, more specificity and less coal loss. The slurry column is a second-generation process for the beneficiation o f fine (60-mesh x µm coal by a combination of physical separation of mineral matter and biooxidation of pyrite. Sixty-seven percent removal of pyrite from a 60-mesh Pittsburgh #8 coal was achieved at a 35% (w/w) slurry concentration and a five-day reactor residence time. Ninety percent of the heating value of the feed coal was recovered. Among the HAP precursors of most concern, over half of the Se, As and Hg were removed from the feed coal. From 40% to 70% of most HAP precursors were removed from the feed coal. Hg in the feed coal was reduced from 0.12 to 0.054 ,µg/g in the product coal, while waste coal contained 0.24 µg/g.

Jan 1, 2000

By Ilpo O. Auranen

Background: Mines of today are moving ever increasing tonnages of rock. The new ore bodies tend be of lower grade and located deeper in the earth?s crust. The industry?s focus to overcome this ?deeper but poorer? ore problem has traditionally been to lower the costs by increasing the scale of mining. This has resulted in an ever increasing size of mining equipment like drills, loading shovels, dump trucks. The main focus has been in reducing the cost per ton of mining. This cost focus has often resulted in increased waste rock dilution and more ore losses. From costs to value: Waste rock dilution means waste rock in the concentrator feed. It?s value in open pit mining is equal to the value of ore it replaces. In underground mining, waste rock dilution?s value is equal to the value of ore it replaces added to the costs of mining it. It is commonly accepted that waste rock dilution in open pit mining ranges between 5 and 20% and in underground mining between 5 and 40 % . In a typical large open pit mine ore value is from 20 to 60 USD per ton and mining costs are 1 to 3 USD per ton. One percentage point reduction in waste rock dilution represents savings corresponding to about 20% of total mining operation costs. The difficulty of reducing waste rock dilution comes from the complicated nature of the ores. Accurate ore waste-border detection has not been possible due to excessive costs. Core drilling combined with geochemical lab analysis is the most accurate method for locating ore waste borders. However, it is also expensive and time consuming, which is why it is often combined with somewhat lower cost methods like sampling drill cuttings from blasting drill holes or from reverse circulation drills and analyzing them in a laboratory. The main drawback with these methods, in addition high costs, lies in the sampling accuracy and in the quality control of the whole process when a large number of samples have to be handled manually. In every mine it is possible to halve waste rock dilution by using new on-line analysis technology .

Oct 1, 2009

By ?. S. Potokin

"In general the electric pulse treatment is composed from two processes – electric pulse grinding and electric explosive (electric discharging) activation. The electric pulse grinding with the effect of selective destruction refers to a major slag fraction, more that 2-5 mm, when a one can see a physical prerequisites for electrical breakdown of the slag particles. The electric pulse treatment of slag is considered as an additional operation in the technological scheme extraction of non-ferrous metals from copper smelting slags in addition with mechanical grinding, flotation enrichment and acid leaching. Studies of the reprocessability of pelletized slag have shown the possibility of higher extracting non-ferrous metals via flotation after electric pulse disintegration (EPD) treatment. By using EPD of slag pellets, it is possible to increase the non-ferrous metal yield to concentrate by 18-24%.INTRODUCTION The use of the explosive effect of the plasma discharge channel at electrical breakdown of a solid at a pulsed high voltage is the physical basis of the electric pulse method of destruction of geomaterials (Vorobiev et al., 1971; Andres, 1995; Semkin et al., 1995). The flowing of a pulsed current in the discharge channel is accompanied by a sharp increasing of plasma’s temperature and pressure, leading to a supersonic expanding of the discharge channel, the formation in the solid of intensive mechanical tension field, spreading of cracks, and eventually, to the destruction of the solid. Fragmentation and grinding of ore and mineral aggregates by electric pulse method due to a number of specific physical mechanisms of power load and crack formation, belonging only to this method, is different by high selectivity of destruction. This ensures better liberation of grains of individual minerals and their better preservation from destruction and less formation of a slurry output. These features creates the prerequisites for a more complete extraction of a useful mineral in the concentrate during ore dressing, to improve the quality of concentrate. In contradistinction to mechanical methods, electric pulse technology does not contaminate the product with instrumental metal, material of lining and grinding bodies. The possibility simply and in a wide range to change the dynamic load character allows to regulate the granulometric composition of the product of grinding, to obtain a narrower class of product size than is possible with mechanical grinding. The product of electric pulse grinding is characterized by less roundness and large specific surface area of grains due to the trait, that a new surface is formed in the process of splitting during the expanding of cracks. The degradation product has increased sorption and reactivity in chemical reactions. Liberation of the mineral inclusions particle better corresponds to their initial natural state in the rock and this is the great importance for the study of mineral raw materials."

Jan 1, 2018

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

Mining has traditionally been seen as a relatively risky business. Exploration is expensive and the failure rate is high, while start-up costs commonly run to many hundreds of million dollars. To justify the risk and expense, the returns from successful projects must also be high. Accurate estimation of mineral resources and reserves is fundamental to the processes of optimising returns and managing risk in mining developments. Systematic development from initial exploration through a series of development stages enables expenditure and risk to be balanced. As a consequence, large scale modern mine are more akin to manufacturing businesses. This paper examines the life history of a mineral reserve estimate from the perspective of a large mining company against a background of modern estimation and reporting requirements. It will also touch on what constitutes, in the author's opinion, `best' practice in reserve estimation, and how this concept can be spread more widely. [Abstract to be re-written and reduced to 100 words]

Jan 1, 2003

By Richard A. Allwes

This Bureau of Mines report presents a procedure for the design of an arch canopy for use in rehabilitating a high-roof-fall area. Only dy-namic line loading of an unbackfilled arch canopy at its crown is considered, and the procedure does not account for an asymmetrical loading condition. The evaluation of whether an arch canopy is suitable for a particular installation depends on many variables, including in-mine conditions and the engineering properties of the structure. However, a general evaluation can be based on a comparison of the arch's maximum crown deflection and a prescribed allowable crown deflection. The design procedure is based on the concept that when an arch canopy is sub-jected to impact loading at its crown and deflects from its unloaded state to maximum crown deflection, the structure absorbs strain energy, both elastic and plastic. As a result, this strain energy can be calculated from a static load-displacement diagram for the structure. The significance of this design procedure is that it gives mine personnel an analytical tool to select an arch canopy to meet the dimensional and functional requirements of a mine entry and a prescribed allowable crown deflection.

Jan 1, 1987

By Brent Blanchard

The use of explosives to safely fell structures can be traced back over 300 years. Since then, dozens of chemists, inventors, blasters and demolition experts worldwide have played prominent roles in the evolution of what has become the modern-day explosive demolition industry. In America, one of the earliest applications of explosive demolition occurred in response to the great fires of San Francisco, where homes and businesses were blasted with gunpowder in a desperate attempt to create firewalls. Later in the 19th century, inventions such as nitroglycerine, dynamite and blasting caps made structural blasting a safe, efficient alternative to conventional demolition methods. The 20th century brought the first experiments in shaped charge technology, and this, combined with developments in portable seismology and non-electric delay systems, allowed an ever-expanding variety of structures to be explosively felled by demolition experts throughout the country. The 1950s and .60s brought a new wave of commercial structural-blasting entrepreneurs (several of whom are still active today), and their efforts towards improving adjacent-structure protection and public relations beget the felling of large commercial buildings in dense urban environments. By the late 1980s, publicity-driven motives were gaining greater influence in the decision to .implode. various structures, and the transformation of blasting operations into promotional spectator events played a role in several injuries and fatalities. Since that time, however, a renewed sense of responsibility practiced by most blasting firms and project officials has resulted in the safe, successful completion of hundreds of recent endeavors. In sum, what appears today as an efficient, economical - and visually spectacular - way to demolish structures has its roots in developments of the past several centuries

Jan 1, 2002

By Robert H. Poppe

The Regional Copper-Nickel Study examined the potential impacts of copper-nickel sulfide mining, concentrating and smelting operations in northeastern Minnesota and gathered extensive monitoring data on the ecological characteristics of the region's aquatic and terrestrial biota. Because of the many development options possible, the diversity of the region's ecology, and the uncertainty of future environmental regulatory requirements, the Study did not attempt to measure the magnitude of environmental impacts on specific biological communities from a specific development proposal. The Study provides a broad base of environmental resource and impact information that hopefully will assist mining developers and environmental regulators when assessing specific proposals in the future. The following discussion is not a description of what will happen if copper-nickel development occurs in northeastern Minnesota but an exploration of why certain potential aspects of such development should be carefully considered and adequately understood before unnecessary or irreversible decisions are made.

Jan 1, 1980

By J M. F Clout

The low-grade clay-rich -1.0 mm fraction of fine iron ores have often proved difficult to upgrade and capital intensive to process when using traditional wet beneficiation technology including single or two stage hydrocyclone desliming, wet high intensity magnetic separation (WHIMS), spirals and final dewatering using fine screens. Very fine (<0.010 mm) clay-rich slimes simply follow the water split to the hydrocyclone underflow where it often impedes the subsequent processing performance of any downstream spirals and can result in troublesome direct dewatering of hydrocyclone underflow. The -1.0 mm fraction in goethitic iron ores is typically considered as waste. A new two-stage wet gravity separation flow sheet, referred to as the ædesandÆ process, has been designed to overcome these issues for the upgrading of low-grade clay-rich goethitic or hematite-quartz fine iron ores. The desand process is designed to treat the -1.0 mm range from -8.0 mm natural fines, to recover a -1.0 +0.038 mm higher-grade fraction by rejecting to tailings any low-grade clay-rich ultrafines and low density sand-size fine chert/quartz gangue and shale.The desand process consists of wet screens with a nominal 0.7-1.0 mm cut point which direct the undersize to hydrocyclones. The hydrocyclone underflow is then fed to upcurrent classifiers where the classifier middlings is sent to spirals and classifier and spirals concentrates are then dewatered using vacuum belt filters or fine screens. The three product upcurrent classifier is employed to further deslime the hydrocyclone underflow, producing firstly a coarse final concentrate, and then a deslimed middlings for feeding to spirals as well as a 0.100 mm clay and fine quartz or banded iron formation (BIF) sand in final overflow for feeding to the residue thickener. The upcurrent classifier middlings provides the spirals with a significantly cleaner feed material than traditional methods, with the end result that the spirals do not silt up with slimes and therefore can continue to run at their optimum. The upcurrent classifier and spirals form a complimentary pair, with the upcurrent classifier better able to send coarser, acceptable grade particles to concentrate and fine slimes to tailings whilst allowing the spiral to better reject coarser, subgrade low specific gravity particles. Test results for the Mayoko-Moussondji iron project, Republic of Congo, using upcurrent classifier-Wilfley Table (simulating spirals) gave acceptable mass recovery from run-of-mine (ROM) and Fe recovery from hydrocyclone underflow for HEMCOL (6.2 per cent mass recovery from ROM/43.1 per cent Fe recovery) and HEMBIF2 (5.1 per cent mass recovery from ROM/22.3 per cent Fe recovery) mineralisation types. The desand process also enables improved dewatering of -1.0 +0.038 mm product from a clay-rich plant feed.A number of new wet plants in the Pilbara use the desand flow sheet including FMGÆs Cloudbreak and their two Christmas Creek plants. Many potential new applications are being explored, with new iron ore plants in India as well as those being proposed for West Africa. Operational experience has highlighted the importance of providing clean process water to the upcurrent classifiers as well as ongoing design improvements including increased wear life, reduced maintenance and enabling a more steady feed rate to spirals.CITATION:Clout, J M F, 2013. Beneficiation of fine iron ores using the desand process, in Proceedings Iron Ore 2013 , pp 337-348 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By R. K. Wharton, G. H. Pickering

The paper reviews the explosives products that have been certified by the different Explosives Notified Bodies for sale in European Union countries. The development of harmonised standards for explosives is also discussed as are recent developments relating to certification and a possible forthcoming Directive on pyrotechnic articles.Copyright

Jan 1, 2004

By J. Kemeny, J. Lyons-Baral

"Point cloud technology is now an indispensable tool in geological and geotechnical data collection, interpretation and analysis. Open pit and underground mines of all sizes are regularly collecting point cloud data as Laser Scanning (LiDAR) and Photogrammetry surveying devices have finally become affordable and the workflows fast and efficient. Past challenges of large data processing and manipulation are gone with recent technological advancements in computer hardware and software. These innovations reduce file sizes, ease rendering requirements and allow for the implementation of real-time 3D viewers and surface meshing tools. With its ability to remotely (safely), rapidly and accurately extract large quantities of georeferenced and 3D-oriented data, point cloud technology provides numerous applications to the geomechanical field. The list of uses is continuously growing, so this paper specifically focuses on digital outcrop modeling and digital terrain engineering. INTRODUCTION Point Clouds The high-resolution and increasing availability of point cloud technology is rapidly improving open pit and underground mines’ investigation, interpretation and characterization of site geology and rock mass properties (Kemeny et al., 2015; Lyons-Baral, 2012). LiDAR and photogrammetry are common remote sensing methods employed to measure the coordinates of surfaces in three dimensions (3D), providing the X, Y and Z locations, and typically the reflective intensity and/or the visible three-band color of each point (Figure 1). LiDAR uses either a time-of-flight or phase-shift measurement of a laser beam reflected off targeted surfaces and received back into the device. Photogrammetry generates point clouds by merging multiple overlapping photographs and uses stereographic plotting to define the locations of object points in 3-D space. These methods can be deployed from airplanes, unpiloted aerial systems (UAS or drones), tripods, land vehicles, and even in a mobile backpack shown in Figure 2. RADAR, Total Station-Prism and other remote sensing systems also offer very precise “point clouds”, but this paper does not address these due to their higher cost and lower versatility and mobility. Technology In the past few years point cloud acquisition device prices have dropped significantly, devices have become lighter, smaller and easier to operate, and processing and utilizing the data has also become faster and easier. Device size improvements include mobile backpacks (Figure 2) and handheld mobile LiDAR (CISRO, 2014), allowing mobile scanning in tight spaces both above and below ground or inside and outside of man-made structures. Airborne data acquisition options have expanded dramatically with the spread of UAS technology as seen in Figure 3 (Hexagon Geosystems, 2015). Once UAS usage regulations are sorted out, these versatile machines will be everywhere, offering high resolution coordinate scans, imagery and other remote sensing. While backpacks and handhelds allow access to tight quarters, UAS permit rapid data capture from narrow to broad areas with multiple perspectives reducing data “shadows.”"

Jan 1, 2016

By Edgard Atencia, Cristian Cerrón

Los análisis y resultados del siguiente trabajo están orientados al desarrollo de los factores claves que impactan al incremento de producción de la mina subterránea SMEB, teniendo como objetivo el incremento del flujo económico en cada proceso de la mina subterránea (throughput).

Sep 29, 2023

By Gary Eck, Kevin Tallent

Over the past decades, the science of energetic materials has advanced dramatically in both the fields of military munitions, as well as industrial explosives. Out of necessity, test methods to measure the explosive performance properties of these materials were developed. As would be expected, these test methods have evolved and become more sophisticated with the recent advancements in electronics and computerized technologies.

Jan 1, 1998

By H. R. Ogden

The notch sensitivity of titanium alloys is affected by impurity content, microstructure, and heat treatment. Using notch tensile properties to evaluate notch sensitivity, three commercial titanium-base alloys were investigated over the temperature range of -320o to 390°F. The alloys studied were Ti-5Al-2.5Sn, Ti-6Al-4V, and Ti-2Fe-2Cr-2Mo. Six interstitial levels were studied for each alloy in four mi-crostmctural conditions. The ff- 0 alloys were studied in both the annealed and heat-treated condition. All tests were conducted using 1/4-in. diam round tensile samples. The notched samples had a 50 pct notch with a notch sharpness (a/r) of 53, corresponding to Kt 6.3. Notch sensitivity was increased by increased interstitial content, low temperature, and acicular-type microstructures. The heat-treated, high-interstitial content - 13 alloys were more notch sensitive than the same alloys in the annealed condition. In addition, minima in the notch tensile-temperature curves were observed at temperatures near 32°F. These minima became more pronounced with increasing interstitial content. 1 HE increaseduse of titanium alloys in high strength applications at subzero temperatures requires that a better under standing of the low-temperature behavior of the alloys be obtained. At low temperatures, metals generally exhibit increased strength with lowered ductility and tohness. Notch sensitivity and the factors which influence it become more important as the strength level is increased and the temperature is decreased. Some of the factor s which affect notch sensitivity in ti- tanium alloys are composition, interstitial content, microstructure, and heat-treatment condition. In this paper, the results of a study of these variables on the notch sensitivity of three titanium alloys at temperatures from —320o to 390o are reported. The notch geometry selected for this program was chosen to provide a severe test of notch sensitivity. The ability of the metal to flow without initiating fracture under these severe conditions is reflected in the notch-strength values. Since notch strength is, in part, determined by the constraint exerted by the combined tensile stresses, the behavior of notch specimens reflects the properties of the material under combined stresses. For example, a material with a high notch-unnotch strength ratio may be expected to withstand the biaxial stresses encountered in a pressure vessel better than a material with a low ratio of notch-unnotch strengths. This implies that maximum strength alone is not a sufficient criterion for applications of this type. It further may be concluded that the various conditions that promote poor notch behavior also will affect adversely the performance of materials under combined stresses. In the alloys studied, these included low temperatures, high interstitial levels, and hasformed microstructures. EXPERIMENTAL PROCEDURES Three alloys, Ti-5Al-2.5Sn, Ti-6Al-4V, and Ti-2Fe-2Cr-2Mo, were purchased from commercial producers as 2-in.-dam rod stock. Oxygen and nitrogen were added to these alloys by remelting to obtain a variety of interstitial contents as shown in Table I. In order to Compensate for the much more potent strengthening effect of nitrogen compared with oxygen, an oxygen equivalent content is used to describe the total oxygen plus nitrogen contents studied. It has been suggested previously1 thatnitro-gen is approximately twice as effective in strengthening as oxygen, and carbon, to the extent it is in so-

Jan 1, 1962