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By P. Hatefi, O. Rahmani, M. Noor-Mohammadi, A. Tohry

"Depressants play an important role in the selective separation of impurities from iron minerals by direct or inverse flotation. In this paper, sodium co-silicate (SCS) with chemical formula of Na4SiCO6, as a depressant with pH modifier features, has been synthesized and used for phosphorus bearing iron ore in anionic reverse flotation. In this process, phosphorus is floated while the iron oxides are depressed, using fatty acids as collector in an alkaline medium. Batch and pilot flotation tests were carried out to investigate the influence of SCS on the separation selectivity of phosphorus from iron oxides. Also the depression mechanism of SCS on hematite surface was investigated by microflotation tests and FTIR spectroscopy measurements. The flotation results indicated that without using a pH modifier, the pH of pulp could reach up to 10, when SCS was used as depressant. In this condition, a better depression performance was observed compared to sodium silicate (SS). Using the SCS, phosphorus and total iron content in iron concentrate was 0.046% and 66.29%, respectively, compared to SS where these values were 0.06% and 65.75%, respectively. As a result the weight recovery of iron concentrate was increase by around 4%, compare to SS. It was also found that 238 g/t of SCS could be used instead of 3 types of reagents collectively, including 32 g/t of NaOH, 151 g/t of Na2CO3 and 400 g/t of SS gel.INTRODUCTIONThe phosphorous presents in iron ore minerals is mainly in the form apatite mineral. The apatite is separated from iron ore minerals by magnetic and flotation methods (Ma, 2012). The reverse anionic flotation of iron is one of the most common method for removing phosphorus from iron concentrate (Araujo et al., 2005).Usually apatite minerals are readily floated using anionic collectors such as fatty acids (Ma, 2012). In this conditions the iron minerals are depressed and by modifying the pH in alkaline conditions, selective separation of phosphorus from iron concentrate can be achieved. Depressants including; sodium silicate (SS), starch, dextrin, guar gum and humic acids play an important role in the reverse flotation of iron ore (Kar et al., 2013; Ma, 2012; Turrer and Peres, 2010; Araujo et al., 2005). Studies have shown that SS has a better effect on iron recovery and phosphorous reduction, compared with other depressants (Tohry and Dehghani, 2016; Qi et al., 1992, Dho and Iwasaki, 1990). In most flotation processes, modifiers are used to adjust the pH. To achieve alkaline conditions, mainly pH modifiers such as carbon dioxide and sodium carbonate are used."

Jan 1, 2018

By B. Elevli

This paper deals with the selection of alternative accesses to a podiform chromite orebody in Turkey. The most important alternatives studied in a related project have been stated as a new vertical shaft and a ramp system. The comparison of these alternatives have been carried out on the basis of total investment costs, ore transport unit cost and net present value (NPV) of overall project for various depth. The results show that up to the depth of 700 m, the total investment cost and NPV favours the ramp access while unit ore transport cost make the shaft access preferable.

Jan 1, 2002

By Han Jie

The results of full scale plate load tests on stone columns on soft clay in coastal areas are presented in this paper. Four load tests were made, two of which were performed on the ground treated with stone columns, one on an isolated stone column and the last one on the untreated ground. For a given stress range, the settlement of the rigid plate, the stress concentration factor, and the excess pore water pressure were measured. It is found that the distribution of vertical stress beneath the rigid plate supported by the composite ground of stone columns is very different in shape from the one by the untreated ground, that the stress concentration factor has a relation with the stress level and time, that the stone columns increase the bearing capacity up to by 2 times, and that the ground stabilized by stone columns is of great advantage to keep the foundation stable.

Jan 1, 1991

By C. H. Mahoney, P. E. LeGrand, A. L. Tarr

MAGNESIUM, it is now generally realized, differs in some important aspects from most other structural metals, not excepting even its close neighbors, the aluminum-base alloys. This is particularly true with respect to the effects of elevated temperatures on the two light metals when in the molten state. Aluminum, on the one hand, should not be raised above its melting point any higher than is absolutely necessary if one is to avoid danger of gas absorption and a tendency toward grain growth in the resultant casting.1 Magnesium alloys, in sharp contrast, actually benefit by being heated to temperatures considerably above their melting point. It is a commonly accepted practice to establish the desired fine grain in the industrial magnesium alloys of the aluminum-bearing group by raising the temperature of the melt after the refining treatment to some 25e C (482°F.) above the melting range. To recall briefly the typical practice for magnesium alloys, the molten metal is refined by fluxing at about 730° C. (1350 F.), and after the melt has been covered with a suitable flux, the temperature is raised to between 870°C. (1600°F.) and 930°C. (I700°F.). It is then cooled as quickly as possible to the casting temperature. This superheating, as it is called, results in a fine-grained cast metal structure which has superior mechanical properties, enhanced amenability to solution heat-treatment, and better machinability than cast metal that has not been superheated. The minimum temperature of superheating varies to some extent with the composition of the alloys to be treated and usually increases with the percentage of magnesium in alloys containing the same constituent metals.2 It should be noted that the grain-refining effect of superheating is markedly apparent only in connection with the alloys containing aluminum as an alloying constituent-the binary alloy containing r.5 per cent manganese, for example, is not refined in grain to any noticeable extent by a superheating effort. While the phenomenon of superheating is well known in the magnesium industry, the mechanism of the process has remained a mystery. During the superheating cycle something occurs that forces a fine grain upon the solidifying metal. The process has been controlled in an empirical manner, and occasionally, especially on large-scale melts, and for no apparent cause, no grain refinement is obtained from a superheating treatment. Only a few papers of importance have been published on the subject. Of these, one of the most helpful is the paper by Achenbach, Nipper and Piwowarski,3 which gives considerable data concerning the effect of superheating on various properties such as fluidity, shrinkage and hot crack formation, as well as grain size, and a discussion without any definite conclusions on the theoretical aspects of superheating. A short article by Murphy, Wells and

Jan 1, 1945

By Howard Scott, Henry S. Rawdon

The method of demonstrating the structure existing in a metal or alloy at high temperatures, by etching a polished sample after it has been heated to the desired temperature, is quite familiar to metallog-raphists. The usual procedure1 2 is to heat the specimen, previously polished for microscopic examination, to the desired temperature, in a neutral atmosphere (hydrogen or nitrogen), then admit the etching gas (chlorine, hydrochloric acid or similar gas) for a few seconds, and finally, after flushing out the etching gas with the neutral one, cool the specimen in the neutral atmosphere. The pattern produced by etching at a definite temperature is usually taken as a record of the microstructure prevailing at that temperature. It has frequently been pointed out that changes in composition of the surface metal occur during the preliminary heating in the neutral atmosphere, so that the appearance produced by the etching at high temperature may not exactly represent the condition of the interior of the specimen. To overcome this uncertainty, the heating has sometimes been done in vacuo,3 the etching gas being admitted when the desired temperature was reached, then pumped out and the specimen cooled in vacuo. The studies of Rosenhain, Humfrey, and other workers 4, 5, 6, 7, 8 dem-

Jan 1, 1922

By Howard Scott, Henry S. Rawdon

The method of demonstrating the structure existing in a metal or alloy at high temperatures, by etching a polished sample after it has been heated to the desired temperature, is quite familiar to metallog-raphists. The usual procedure1 2 is to heat the specimen, previously polished for microscopic examination, to the desired temperature, in a neutral atmosphere (hydrogen or nitrogen), then admit the etching gas (chlorine, hydrochloric acid or similar gas) for a few seconds, and finally, after flushing out the etching gas with the neutral one, cool the specimen in the neutral atmosphere. The pattern produced by etching at a definite temperature is usually taken as a record of the microstructure prevailing at that temperature. It has frequently been pointed out that changes in composition of the surface metal occur during the preliminary heating in the neutral atmosphere, so that the appearance produced by the etching at high temperature may not exactly represent the condition of the interior of the specimen. To overcome this uncertainty, the heating has sometimes been done in vacuo,3 the etching gas being admitted when the desired temperature was reached, then pumped out and the specimen cooled in vacuo. The studies of Rosenhain, Humfrey, and other workers 4, 5, 6, 7, 8 dem-

Jan 1, 1922

By J. D. Hadden

The Bureau of Mines conducted drilling studies in the Pocahontas No. 3, the Pittsburgh, and a western coalbed to establish the gas migration characteristics for each. Gas pressures in the Pittsburgh coalbed were about 260 lb/in2 and in excess of 550 lb/in2 in the Pocahontas No. 3. Caving in drill holes prevented pressure measurements in the western coalbed. The Pittsburgh coalbed contained intersecting "clay veins" which formed gas pressure cells. Although these geological features hamper mining, they can be used to control the flow of methane into a mine working. Methane control techniques are proposed for the Pittsburgh and Pocahontas No. 3 coalbeds.

Jan 1, 1969

By D. A. Robbins

The application of remote sensing for environmental measurements is already being utilized. Aircraft mounted imaging spectroscopy has been utilized to evaluate areas of historical mining operations as well as active mine sites. To the extent that remote sensing can provide more sensitive, cost effective, and timely monitoring potential, the technology is of interest to the industry. Questions remain about the application and validation of the data and the availability of the technology in the private sector. This presentation will discuss some of the potential uses, benefits, and concerns related to remote sensing and efforts to monitor the technology's development.

Jan 1, 1999

A field trial of the prompt neutron-gamma SIROLOG technique was undertaken by the CSIRO - Division of Geomechanics at Callide Coalfields during July 1989. The trial investigated whether the sonde could reliably be used for the determination of Ash and Iron Oxide (Fe2O3) in coal seams, which had a highly variable iron content. Ten boreholes were logged, being water filled of a nominal diameter of 120 mm. The logging probe employed a 1.6 ¦g 252Cf neutron source and a 51 x 51 mm BGO detector. The source to detector distance was 15 cm. The results from one exploration borehole at the Dunn Creek Mine are discussed in the paper. The rms deviations for ash and iron determination between the neutron-capture predictions of the geophysical logs and the laboratory - chemical assays were 1.9 per cent Ash and 0.88 per cent Fe respectively. Using existing empirical equations which relate iron oxide concentration in coal ash to Initial Deformation Temperature (reducing conditions) at Callide, it may be possible to indirectly determine ash fusion properties as least as accurately, on a more detailed ply-by-ply basis, and more cost competitively than current laboratory techniques allow.

Jan 1, 1991

By B E. De Gee, N Viviers, A Naidoo

In 2013 the Mopani Copper Mine Mufulira plant in Zambia embarked on a project that was aimed at improving concentrator recoveries. The project commenced with the automation of the milling and flotation circuits. This involved the installation of new instrumentation, namely measurement devices and actuators, and the connection of these to new programmable logic controllers (PLCs).The infrastructure changes were followed by the implementation of basic proportional-integral-derivative (PID) controllers on the PLCs. Supervisory control and data acquisition (SCADA) interfaces were also implemented to allow for switching between controller modes, inputting of setpoint variables and to provide a visual display for process monitoring. The final phase of the project involved the installation and commissioning of advanced process control (APC) solutions on the milling and flotation circuits. This work was carried out by Mintek over 21 on-site days. The APC solutions included the MillStar and FloatStar suites of advanced controllers.The MillStar control suite focused on stabilising the mill feed and mill discharge on the two primary mills as well as the flotation circuit feed. Mintek’s CyLas instruments, which provide a measurement of the hydrocyclone underflow angle, were also installed. The measurements were incorporated into the discharge stabilisation control on both milling circuits. The FloatStar level stabiliser controller provided flotation cell pulp level control on fourteen cells, including two columns.Performance tests showed that the Mintek APC system stabilised the mill feed and mill discharge while ensuring the process remained within operational constraints. The MillStar control system utilised the CyLas instrument to prevent roping on the hydrocyclone underflow. This was not always achieved under normal operation. Additionally, the flotation section was stabilised as a result of improved level control by the FloatStar control system.Performance comparisons showed that the Mintek control system improved the operation of the milling and flotation circuits resulting in a greater copper recovery.CITATION:Naidoo, A, De Gee, B E and Viviers, N, 2014. Implementation of an advanced milling and flotation control system at Mopani Mufulira copper mine, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 363–368 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By J. D. Grozier, W. W. Mullins, H. W. Paxton

The morphology of the nucleation and growth of austenite into high-purity iron in NH3-H2, gas mixtzires has been studied. The growth rate of an austenitic rim (planar interface) from scratched surfaces of- polycrystalline iron specimens was determined as a function of temperature and percent NH3 and found to he in reasonahle agreement with growth-rate calculations based on a model which assumes the diffusion of nitrogen to he the rate-controlling step. Under certain conditions, austenite pew as platelets; growth rates of these along the surface of single crystals were found to he dependent on surface preparation, orientation, THE development of microstructures can conveniently be thought of in terms of nucleation and growth. The complex topic of nucleation in solid-solid transformations will not be discussed at length, although a few qualitative experiments were performed. Growth is determined by the mobility of the various possible interfaces under the available driving forces in a particular situation. In homophase transformations, it has been clearly demonstrated that the mobility is very sensitive to small amounts of impurities, to the kind of impurity, and to the orientation relations across the boundary.' A degree of quantitative knowledge has temperature and percent NH3. On electropolished surfaces with a (110) pole, the maximum growth rate of platelets was determined and found to be in agreement within a factor of 2 to 3 with theoretical calculations of the edgewise growth rate of a platelet. The calculations are based on a model which assumes that the diffusion of nitrogen in the ferrite in front of the moving curved attstenitic interface at the tip of the platelet is the rate-controlling step. The growth direction on the surface of the single crystal and resztlting habit plane of the platelets were determined and found not to he unique but to vary systematically with the pole of the surface. been obtained. In the case of heterophase transformations, which are significantly more complicated to treat, a comparison of theoretical and experimental studies often shows rather poor agreement.'-' The main purpose of the experiments discussed below was to obtain additional quantitative data on crystallographic effects on boundary mobility in a system which was otherwise as simple as possible, viz. the growth of iron-nitrogen austenite into fer-rite. In the course of the experiments, it became necessary to re-examine the theory for the growth of Widmanstatten plates, especially the influence of anisotropic interfacial free energy. Some other minor experiments in the Fe-N system were performed, and are described briefly. EXPERIMENTAL METHODS A) Material Preparation. The floating zone purified iron used for this investigation was supplied by Battelle Memorial Institute. The nominal composi-

Jan 1, 1965

Every step on the path from the mine to the smelter invites a comparison between material inputs on one side and outputs plus accumulation on the other. Or put simply, between what you think you have produced with what you find you have at hand. The discrepancy between these sets of comparisons is the error. Following that error in a systematic and objective manner is a way to improve the mineÆs measurement systems, that in turn leads to more accurate accounting for ores, metals and concentrates. Because the control of production is so tightly coupled with the accounting of materials, any lasting improvements in materials accounting will benefit the predictions of materials movements and quality. This translates to more reliable planning and scheduling in stockpile management, logistics, shipping and marketing. The statistical tools described are direct adaptations from the long-standing methods used to maintain the quality of manufactured product in the discrete parts industries. Their use in the process industries, of which mining is one, requires some care owing to the continuous nature of ore extraction and its variable properties. The tools can be used for problem diagnostics and as early warning systems. In common practice many professional staff, in attempting to get a perfect reconciliation between expected and observed results, try to explain away the error or bury it completely. The methodology advocated here requires a different mindset because the error must be given pre-eminence for lasting improvement to be realised.

Jan 1, 2002

By Kenneth N. Han, Peter Mam-soo Kim

The extraction behavior of gold in ammoniacal solutions in the presence of bromine as an oxidant has been studied. The effect of concentration of ammonia, bromine, and pH of the solution on the rate of dissolution of gold was investigated. The dissolution behavior has been analyzed using electrochemical method, and its results were compared with direct leaching tests using gold powder. The overall dissolution of gold in ammoniacal solution containing bromine was found be affected significantly by pH of the solution and the concentration of bromine. The rate expression found in this study has the following form.

Jan 1, 2005

By Chu E. Ho

This paper describes a case history involving the use of the Equivalent Driving Energy concept for evaluating timber piles that failed to achieve the termination criterion traditionally based on final driving resistance and minimum pile depth. It was assumed that a pile would be acceptable if the overall energy delivered during pile driving was at least equal to that of an ideal pile that achieved the design pile capacity established during an initial load test. The equivalent driving energy was determined by integrating the cumulative driving resistance profile over the embedded length of the pile within the founding soil strata. The required equivalent driving energy was calibrated using representative restrike PDA capacities of production piles as piling progressed. This approach enabled piles that failed to meet the original acceptance criterion to be re-evaluated, resulting in a significant reduction in the number of rejected piles that would otherwise have to be replaced.

By Gaston Gingras

"IntroductionL'entretien de l'equipement minier dans les mines à ciel ouvert est une activité qui est aussi vieille que I'existence des mines et qui a progressé au cours des années pour suivre l'évolution des techniques d'exploitation. Lors de la mise en usage de s premières pelles à la va peur, celles-ci étaient généralement entretenues par I ‘équipe de quatre hommes qui était responsable de son opération. Pour les travaux plus compliqués ils utilisaient les services de machinistes qui eux savaient comment réparer Ie moteur à vapeur et couler des coussinets de ""babbit"". Les premières pelles diesel étaient entretenues de la même façon mais pour les réparations au moteur, on devait recourir au représentant du manufacturier qui était Ie seul à avoir les compétences nécessaires.Ce n'est vraiment qu ‘après la deuxième guerre mondiale que I ‘usage de l'équipement mobile s'est répandu dans les mines à ciel ouvert pour débuter les extractions selon les méthodes que I'on connaît aujourd'hui.L'entretien de l'équipement minier de façon organisée à débute avec I ‘usage de ces machines dans nos mines. Ces machines étaient un peu primitives, petites et pas très dispendieuses a I'achat. Même si la disponibilité était basse, elles fournissaient quand même un rendement qui en ces temps était acceptable. L’organisation de I ‘entretien de cet équipèrent était assez primitif et n'occupait qu'une place secondaire aux yeux de la direction de la mine."

Jan 1, 1988

By George A. Brown

Flexoid tubing for ventilation and some of the reasons for its use in re-opening old workings at the Union Pacific Coal Company's mines at Cumberland, Wyoming. , These mines are located on a branch line off the Oregon Short Line Railroad, about sixteen miles south of Kemmerer. The seam averages from 16 feet to 20 feet thick and is split about six feet from the bottom with from six inches to four inches of fire, clay; and is covered by a heavy sandstone roof about 45 feet thick and a fire clay floor about 15 feet thick. Pitch of seam 21 degrees. These mines were opened up with 5 openings on the pitch to the west, with main slope, north and south manways and north and south aircourses on 50-foot centers with parallel entries driven north and south at right angles to the slope and rooms turned on 50-foot centers up the pitch ; entries being 350 feet apart and chutes used in the rooms. Several years ago there was a heavy, squeeze came on these mines which necessitated shutting down all of No. I Mine below the third entry, the slope being down to 12 entry; also shutting the lower end of No. 2 Mine down from the twelfth entry to fifteenth entry and from the third entry down to the tenth entry, so as not to work too much territory at the one time. These mines are very gassy and were subject to heavy bumps during the squeeze ; also at the present time. In reopening these slopes, aircourses and entries for the recovery of the pillars, ventilation was quite a problem, as the squeeze had caused them to be practically tight; also the rooms for about 50 feet from the entry and the face of the rooms for about fifty feet. These rooms in the open space being either filled with Methane or depleted air. It was found in opening up these entries that in driving back entries parallel with the top entries for ventilation. which had to be skipped along the barrier pillar left from the face of the rooms of the entry below, that we had more bumps or bounces which made it a dangerous proposition to nine, as it will be noted as stated that the entries, room necks and face of rooms were more or less squeezed tight, showing that all the weight was centered on these points and the more they were disturbed the more it relieved the overlying pressure and something had to give; hence the bumps or bounces which have filled slopes, aircourses, entries and rooms with coal from the ribs and face, for hundreds of feet, throwing cars off the track, both loads and empties, and throwing track up to the roof and discharging timbers. We found it necessary to abandon driving back entries and have used Flexoid tubing with small blower fans to open up these slopes, aircourses and entries which has proved a success. We have carried air for distances that would have been impossible with brattice cloth or with

Jan 1, 1921

R. L. Bullock (St. Joseph Lead Co., Bonne Terre, Mo.)— The progressive approach of The International Salt Co. as described by Mr. Ryon is certainly commendable as is his paper. St. Joseph Lead Co. has been shooting AN/FO in 13/8 to 1 1/4-in. holes for several months now (as of October 1960) on a trial basis. The results thus far obtained are excellent, but conclusive evidence at this date is premature. One point that he gave should interest even the most ardent skeptic. That is, they are getting a detonation of the 1 1/4-in. ANDO charges in 2 1/4-in. holes. In light of its low sensitivity and critical diameter, this would appear to be one of the worse conditions that one could expect in which to get proper detonation of AN/FO. It has been shown* that partial confinement sometimes decreases sensitivity of a column of explosive because the air space above the explosive becomes highly compressed and in turn compresses the explosive prior to passage of the detonation front. Apparently, this does not happen in their shooting and the poor explosive coupling caused by the 2 1/4-in. holes yields a minimum of overbreak and is an ideal condition for their back.

Jan 1, 1961

By T. M. Barczak

Longwall tailgates in coal mines are often subject to severe mining induced loading and deformation. Innovative tailgate supports have been developed over the years to provide safe and economical access and a ventilation pathway at the tailgate. The support capacity and yield capabilities of the supports need to be matched to the loading imposed by the surrounding rock mass. The ground response curve can be used to represent the rock mass response to mining and its effect on support systems. The FLAC finite difference code was used to supplement field results by simulating a longwall tailgate and the associated ground response. The ground response curve is developed by modeling tailgate excavations with different internal support pressures and recording the resulting convergence. Ground response curves are developed for two typical longwalls operating in the Pittsburgh seam with weak and strong immediate roof. An additional model is presented in which the effect of weak overburden strata is simulated. The ground response is shown to be significantly affected by the strength of the immediate roof as well as the main roof. The importance of yield capacity of standing support is demonstrated. Gob height and compaction are found to affect the amount of convergence in the tailgate. The potential exists to develop site specific tailgate design curves by combining model results with field observations.

By P. M. Robinson, M. B. Bever

THE heats of formation at 273°K of the compounds InBi, In2Bi, and TIBi2 have been determined by metal solution calorimetry with bismuth as solvent. The published information on the thermody-namic properties of these compounds is limited. The structure of the compound InBi (mp, 383°K) is tetragonal of the PbO (B10) type.1 The compounds In2Bi (mp, 362°K) and TIBi2 (mp of highest-melting composition, 486°K) are now believed to have structures of the NizIn (B8) type273 and not the A1B2 (C32) structures reported earlier.4, 5 The compounds In2Bi and TIBi2 have limited homogeneity ranges at room temperature, while the compound InBi has no detectable homogeneity range.' Samples of the compounds were prepared from 99.99 pet Bi (Mallinckrodt Chemical Works), 99.999 pet in (American Smelting and Refining Co.), and 99.99 pet Tl (Amend Drug and Chemical Co.) by melting the components in sealed, evacuated Vycor tubes. The compounds InBi and in2Bi were of the stoichiometric compositions. The compound TIBi2 contained 40 pet T1; this composition was chosen because at room temperature the alloy of stoichiometric composition does not lie within the homogeneity range.' The melts were held approximately 50°C above the liquidus for 8 hr and then quenched into iced brine. The samples were homogenized for 48 hr at temperatures 20°C below the temperature of complete solidification. Metallographic examination of sections taken from the center and the ends of the ingots did not reveal second phases or segregation . The heats of formation were determined as the difference in the heat effects on solution of a compound and of a mechanical mixture of its components added from the reference temperature of 273°K to liquid bismuth at 623°K. The details of the calori-metric procedure and method of calculation have been described elsewhere? The calorimeter was calibrated by adding bismuth at 273°K to the bismuth bath at 623°K. The calculated values of the heats of formation of the compounds, listed in Table I, are based on a value of 4.96 keal per g-atom for the difference between the heat contents of bismuth at 273" and 623oK7 No published values are available for the heats of formation of the compounds InBi and In2Bi. Hultgren et a1.7 have calculated a value of -0.50 i 0.10 keal per g-atom for the heat of formation at 423°K of the compound TIBi2 containing 40 at. pet T1 from heat-content measurements in the range from 398" to 700°K and the heats of formation of the liquid alloy. The difference between this value and the value of -0.66 * 0.01 keal per g-atom at 273°K is too large to be attributed to a difference between the heat capacities of the compound and the components over the temperature range 273o to 423oK7 However, the direct determination of the heat of formation by a calorimetric method should give a more accurate value. The heats of formation at 273°K of the compounds InBi and In2Bi lie on a straight line when plotted as a function of composition, Fig. 1. The compound In2Bi, therefore, appears to be barely stable with respect to its neighboring phases. In order for the free energy vs composition curve to be concave towards the composition axis, the entropy change on formation of In2Bi must be more positive than that on formation of InBi. As the compounds are ordered,2, 3, 8 there is no configurational entropy change on formation. The difference between the entropy changes on formation of the two compounds, therefore, is probably associated with the vibrational entropies. In view of the low heats of formation, the changes in vibrational entropy, due to changes in bond strength on formation of the two compounds, are likely to be small. Owing to the volume contractions on formation of the two compounds,5 the vibrational entropies probably decrease slightly but the decrease of the vibrational entropy of InBi is expected to be larger than that of In2Bi.

Jan 1, 1965

An active list of permissible explosives was published in July, 1931, as part of United States Bureau of Mines Report of Investigations 313, under the title of "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1931." Changes in that list were authorized in August, September, October, November, and December, 1931, and. January and March, 1932, as published in Reports of Investigations 3l40, 3147, 3l50, 3155, 3158, 3161, and 3163, respectively. By these changes the following explosives were added to the active permissible list: [Austin Red Diamond No. 1, L. F. Gel-Coalite W. L. F. Austin Red-Diamond No. 5, L., F. Gen-Gel No. 2. Black Diamond Nu-Gel No. 1 Genite C-1 Burton 1, L. F. Liberty No. 4 Burton 2, L. F. Liberty No. 5 Burton 10, L. F. Peerless D Burton 12, L. F. Permigel 1, L. F. Burton F, L. F.]

Jan 1, 1932