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By Ibrahim Yusufoglu, Ahmet Orkun Kalpakli, Cem Kahruman, Sedat Ilhan

"The effects of oxalic acid concentration, temperature, stirring rate and particle size on the dissolution rate of synthetically prepared calcium molybdate were investigated. Dissolution of calcium molybdate in oxalic acid solutions takes place as a series - parallel type reaction. In the first reaction step, which proceeds according to the ""Langmuir - Hinshelwood Mechanism"", calcium aqua oxalato molybdate is formed as a complex chelate intermediate product. In the second reaction step, molybdic acid is formed during the slow hydrolysis of calcium aqua oxalato molybdate, and it reacts rapidly with oxalic acid to form the polymeric hydrogen oxalate dimolybdate chelate as an end product. Activation energies were calculated as 41.4 and 49.9 kJ mol-1 for the first and zero order reactions. The fractional conversion versus time relationship can be given by the following equation.IntroductionMolybdenum is used widely in electric-electronic, metal working, aerospace and aeronautic, nuclear, glass and petrochemical industries because of its high melting temperature and resistance against chemical effects. However, the largest molybdenum consumers are the iron-steel and super alloy industries where molybdenum is used as an alloying element. Industrially important molybdenum minerals are limited to molybdenite (M0S2), powellite (CaMo04) and wulfenite (PbMo04), which are considered as primary molybdenum resources. Secondary molybdenum resources are spent catalysts and scrap [1-4].Molybdenum has been produced by pyrometallurgical processes in the past. Since it is possible to process low grade molybdenum ores and industrial wastes by hydrometallurgical processes, which are more environmentally friendly than pyrometallurgical processes, the importance of the use of hydrometallurgical processes has increased in the molybdenum production industry."

Jan 1, 2012

By K. L. Morton, R. .. J. Connelly, P. C. Bouw

Uncertainties in the forecasting of the volume of groundwater likely to enter underground workings present difficulties for mine management in planning and costing the water-related activities of mining. This paper describes a technique that was developed to assess future inflows into a gold mine in the Orange Free State. The approach employed was based on the interactive operation of two separate computer models: a regional-flow model and an inflow model. As a first stage, a regional finite-element model of groundwater flow was set up and calibrated. Predictive runs were made to establish the influence of mining on the water levels from base-line conditions. This step was necessary since observations of the regional water levels were sparse. The predicted water levels were transferred to the inflow model, and the future flowrates were calculated. Both models were calibrated by trial and error until a satisfactory match was obtained between historical records and the values predicted by modeling. In this way, an improved monitoring system to record regional water levels and pressure heads within a mine was established. By the use of information, the initial model predictions can be refined as mining progresses. The models used are based on a non-linear relationship between the area mined and the inflows. A phased behaviour in the rates of inflow increase was noted. In conclusion, the modeling approach can provide mine management with guidelines for dewatering requirements. The confidence levels depend upon the records that have been collected during the mine's history.

Jan 1, 1988

By Thomas L. Craig

The Wellman-Lord SO2 Recovery Process is operating commercially at one location in this country and at two locations in Japan. Tail gases from a sulfuric acid plant, from an oil fired steam generator and from a sulfur recovery unit are the respective applications. 1) At the Olin Corporation's Paulsboro, New Jersey, stack gas from a spent acid regenerative sulfuric acid plant-45000 SCFM - is treated in the W-L unit to reduce sulfur dioxide concentrations from 4500 ppm to less than 500 ppm. 2) At the Japan Synthetic Rubber plant in Chiba Prefecture, stack gas from an oil-fired steam generating plant - 120,000 SUM - is reduced from 2100 ppm S02 to less than 200 ppm. 3) At the Toa Nenryo Kogyo refinery in Kanagawa Prefecture, tail gas from a sulfur recovery (Claus) unit - 41,000 SUM - with, an inlet SO2 concentration of up to 13000 ppm is reduced to less than 200 ppm. The three installations are operating successfully and are capable of reducing S02 emissions to levels significantly below the concentration guaranteed. With the one exception of a higher than guaranteed chemical make up requirement at Paulsboro, utility and chemical requirements will be less than design.

Jan 1, 1971

By A. G. McGregor

DURING the past 5 years, five new copper-smelting plants have been built and put into operation in the State of Arizona. The monthly copper output from these plants averages from 5,000,000 to 18,000,000 lb. Previously, there never was as much activity in copper-smelting plant construction in the same length of time in all the rest of the world. Naturally, in this amount of work, some new problems were met and new features in plant design and. equipment developed. Some of these features are described in this paper. CONCENTRATE HAULING, UNLOADING AND SAMPLING SYSTEM (a) Concentrate Car The International Smelting Co. has provided at its plant at Miami specially designed cars for hauling the concentrates from the mills of the Inspiration Copper Co. and the Miami Copper Co.. The car has a bottom that is readily made tight to hold flotation concentrates and is quickly and cheaply unloaded. Figs. 1, 2 and 3 show views and details of the car. The main feature of this car is the slot in the bottom throughout its length, which is closed by means of short planks that overlap like ship-lap as shown by Fig. 1. At one end of the car an iron gate operated by a screw and hand wheel is provided, which clamps or presses the planks together, making the bottom tight. A removable tapered plug rests vertically over this gate when the loading of the concentrates at the mill commences.

Jan 8, 1916

By Glenn Lyle

CEMI Introduction ? Introduction of the CAF VOD Project ? Who are our partners ? What were the Outcomes What is next

May 1, 2011

By Mizuta T, Sakurai M

The Pine Creek Inlier produced 12 440 kg of gold in the period from the first gold discovery in the 1860s to the early-1900s. During the 1930s renewed large-scale prospecting took place and gave a foothold for today's gold mining operations. The rise of the gold price and improved mining methods in the 1970s and 1980s made possible low cost, bulk low grade mining operations. Various gold deposits including vein, network and stratiform types occur in the Pine Creek Inlier (Nicholson and Eupene, 1990). The Tom's Gully deposit is located 100 km south-east of Darwin in the Northern Territory. It is hosted in the early Proterozoic Wildman Siltstone and lies north-east of 1800 my old Mt Bundey Pluton (Figure 1). Around the Mt Bundey Pluton, there are several prospective base and precious metal deposits such as Quest 29. The Tom's Gully gold deposit was discovered in 1986 and yielded a total of 3070 kg of gold from ore averaging 9.35 g/t gold between 1987 and 1990 when the mining operation was terminated.

Jan 1, 1994

By J. T. McLendon

As part of its research project in developing improved refractory materials for metallurgical applications, the Federal Bureau of Mines obtained hot modulus of rupture data at 1,500°,1,550°, and 1,600° C on samples of 13 refractory periclase materials produced from seawater, lake brines, and natural magnesite. The periclase samples also were characterized to establish chemical and mineralogical composition and microstructure. The results indicated that a high MgO content does not necessarily assure good hot strength and that an optimum and varying CaO-Si02 ratio exists for each individual periclase sample.

Jan 1, 1979

By Jaroslav Vicek, Alois Adamus

In the Czech Republic nitrogen was first used for the fight against the mine fire in 1949 (Hajek,1969). In the years 1949¬1996 the consumption of nitrogen in the Ostrava-Karvina Coal Basin /OKB/ reached more than 220 mil. m-3. The main source of nitrogen in the OKB is a central pipeline now. Gas nitrogen is used for the prevention of spontaneous combustion in gobs of longwall faces. The nitrogen infusion technology (Froger,1985), often called "franca technology", has been applied in the Czech coal mines since 1982. The aspects of the nitrogen infusion technol¬ogy can be theoretically solved by the calculation of mixing two gas streams in the filtration space. Longwall faces are parts of the ventilation network of the coal mine. The intake airflow of the longwall face is divided into the airflow passing through the face and a part of air losses passing through the gob. Air leakages through the gob and nitrogen in¬jected into the gob mix there. There is the main problem to solve air leakages in the gob. Usually, the principles of the gob aerody¬namics were used by many authors (Glusberg,1988;Voracek, 1994; Sulkowski,1993; Michailov, 1995; Dziurzynski, 1995; Kolarczyk, 1995; Saghafi, 1995; Sedlaty, 1993) that are applied to our case as well.

Jan 1, 1997

By JOHN HOMER, KATHLEEN STABRYLA, JACOB L. CARR, JONATHAN K. HRICA, JENNICA L. BELLANCA

Given the recent focus on powered haulage incidents within the U.S. mining sector, an appraisal of collision avoidance/warning systems (CXSs) through the lens of the research literature is timely. This paper aims to evaluate the maturity of CXS technology through the application of a technology readiness assessment (TRA) to research literature identified by systematic search methods. Results indicate that much of the evidence for CXS performance is at lower levels of maturity: that is, components and prototypes tested in a laboratory and in relevant environments. Less evidence exists for CXS performance at higher levels of maturity — that is, systems evaluated within operational environments — despite the existence of commercial products in the marketplace. This lack of evidence at higher maturity levels within the scientific literature highlights the need for more peer-reviewed research to evaluate CXS technologies. Additionally, results of the review reveal that most of the literature relevant to CXS technologies is focused on vehicle-to-vehicle interactions, which contrasts with haul truck fatal accident statistics that indicate most are due to vehicle-to-environment interactions, such as traveling through a berm. Lastly, the relatively small number and segmented nature of relevant studies suggest there is a need for more incremental research that would better facilitate the improvement of CXS technologies. This progression could be achieved through continued long-term interest and support for CXS technology research.

Mar 1, 2023

Mr. Tays (communication to the Secretary): Mr. Wynne's criticism of my paper* brings forward a few points which are really important, and might properly have been considered in the original paper. By calling attention to them he has rendered me a service. It is quite true, as Mr. Wynne says, that, in the tests reported by me, the Bryan mill was always working at a relative disadvantage, and my comparison of the work of this mill with that of the stamp-battery should be interpreted, therefore, so much the more favorably to the mill. Of course, wire screens can be used to advantage on the Bryan mill, if they are not of smaller size than 30-mesh; but

Jan 1, 1902

By Hakan Gürsoy, Kemal Bilir, Bahri Öteyaka, Ali Uçar, Oktay Sahbaz

"Jet diffuser flotation column (JDFC) is a flotation device resembles Jameson flotation cell (JFC) in terms of operational principles, but it has significant difference structural points of view. This difference is an essential change in the downcomer to provide an increase of performance of the cell for the coarse particles. By using the hydrodynamic and fluid mechanics principles (Sahbaz et al., 2013) downcomer was changed as a diffuser, therefore turbulence at the end of the downcomer was reduced to provide better aggregate stability and homogeneous dissipation of the bubbles in the separation tank. According to experimental results carried out in pilot scale JDFC, not only higher flotation performance comparing with Jameson cell was obtained specifically for coarse talc particles in a certain condition, but also quiescent froth layer was acquired. In these tests, vertical pipe of JDFC having inlet diameter of 6 cm and outlet diameter of 11.5 cm was used with separation tank having the diameter of 39 cm. By using the data, pilot scale JDFC having 410 cm vertical pipe integrated with separation tank was produced and flotation tests were carried out by using the naturally hydrophobic mineral (talc). Finally, the talc recovery obtained as 94% by the use of JDFC, while Jameson cell has the recovery of 77% for the particle size of 250 µm."

Jan 1, 2014

By Dr. -Ing. Rainer Alles

Introduction Belt conveyors usually run in a straight line. The correct alignment is a major criterion for reliable functioning and optimum running properties. Any misalignment of the conveyor, especially mistracking of the belt, can have many negative effects. As a consequence of this, damage can occur on the belt and conveyor, some material can he thrown off at the edges and serious running problems can arise. In the worst case the belt can come off its supporting structure so that operations are brought to a halt. The absolutely straight alignment of a belt conveyor is actually impossible so that on closer observation every belt conveyor contains more or less sharp curves. Whereas on non-movable conveyors the deviations from the straight can he kept within the range of practical measuring accuracy by careful installation, movable conveyors in surface mining or belt systems in difficult terrain often contain curves that are easy to see with the naked eye. Below ground, too, alignment cannot always achieved to a desirable extent or is changed by geological faults over the years. Despite these unwanted curves, most belt conveyors perform their function reliably. In view of the belt tension, the belt tends to take the easiest path. This in general is the shortest distance between the pulleys on which the belt is tensioned and bent. This means for example that for a curve radius of 10,000 m over a flight of 100 m the greatest deviation from the ideal line is as much as 12 cm. And a figure of this magnitude cannot normally he accepted. In such cases, use is made of guide devices to properly train the belt if it doesn't center itself anyway. If it's possible to control the belt position over such unwanted curves. it can also he expected that the belt tends to follow the desired curved path within certain limits. I'd now like to cite a few examples to illustrate the ways and means of guiding a belt conveyor in curves. Cost-effectiveness The advantages of belt conveyors, in particular for longer conveying distances and mass flows have been known and undisputed for some time. However, there are often obstacles standing in the way of the concept of straight routing. If a belt conveyor is to bypass elevations or existing buildings or to follow the seam of underground deposits or a predetermined path, then substantially tighter radii and longer curves are desirable or necessary.

Jan 1, 1993

Blasting is an essential component of most mining operations, and is used to reduce the rock mass to a workable size distribution, as well as to create stable openings and pit walls. Frequently, there is little difference between the designs of blasts to achieve these two functions, though more advanced operations have developed different designs for these very different functions. To assist in the appreciation of how blasting practices can impact on the stability of rock openings and pit excavations, this paper reviews the role of high pressure explosion gases on final block stability. It is assumed that the stability of all surface and underground excavations are, to a greater or lesser extent, controlled by the interaction between discrete rock blocks. Typically, these blocks will be defined by either natural, or excavation induced, jointing.

Jan 1, 1999

By J. D. Bateman

At Giant Yellowknife, where high grade gold-bearing orebodies are highly irregular in shape, geology has been applied extensively to the mining of ore. The classical functions of the mine geologist in the fields of exploration and mine development have been extended to guide ore extraction, ensuring "clean" mining and effectively reducing waste dilution. THE property of Giant Yellowknife Gold M.ines Ltd. is situated west of Yellowknife Bay on the north shore of Great Slave Lake, a distance of 600 air miles north of Edmonton, Alberta. The Giant claims were staked in 1935, the company was formed in 1937, and the main orebody system was disclosed by diamond drilling in 1944 following a geological study of the property by A. S. Dadson,* Consulting Geologist for the company. Production began in 1948 at the rate of 200 tons per day and, during 1950, reached a daily rate of 425 tons. During the first 3 years of operation a total of 366,000 tons was milled with an average grade of 0.79 oz of gold per ton. Work is in progress with an expansion to 700 tons per day in view. A descriptive account of the geology and gold-bearing shear zone has appeared previously.* The rock formations in the vicinity of Yellowknife Bay have been subjected to protracted pre-Cambrian tectonic deformation culminating in a series of late faults having a cumulative horizontal displacement exceeding 11 miles. The Giant property is underlain by part of an Archean sequence, several miles thick, consisting of basic volcanic flows and minor intercalated tuffs. The volcanic succession forms the west limb of a major syncline, the flows facing east, but overturned on Giant property to dip west at 65" to 75". Orebodies are confined to shear zones up to 200 ft in width, which were formed along early thrust faults. The shear zones assume fold-like attitudes, the larger of which have an amplitude of several hundred feet. The rock formations beyond the limits of the zone of shearing do not reflect the simulated folds, the axes of which are within a few degrees of the strike of the flows. The schistosity and most of the planar elements in both the shear zones and the orebodies dip west • A. S. Dadson and J. D. Bateman: Structural Geology of Camdian Ore Deposits, Can. Inst. Min. Met. Jubilee Volume (1948), PP 273-283. at angles between 65" and 75", generally corresponding to the dip of the flows. The planar elements within the shear zone system thus dip more or less constantly west whether the shear zone is flat, vertical, or expressed as east or west dipping limbs. The shear zones reflect the deformation and alteration of the basic volcanic flows into chlorite schists which, in most places, have undergone metasomatic replacement to form chlorite-sericite-carbonate schists or sericite schists. The boundaries between the shear zones and country rock, although often gradational, usually can be defined within a few feet or even inches as they are expressed by the limits of metasomatic alteration. Orebodies may occupy a small or large proportion of the shear zone and, although they generally conform to the shape of the zone, their morphology is much more complex. Ore boundaries in some instances are sharp and can be delineated with a chalk line; but more generally, a large proportion of the ore boundaries is not visually obvious and can be determined only by the perception acquired by the geological mapping of ore or study of drill cores. Ore shoots in fold-like attitudes may transect the planar elements of the shear zone at any angle; yet the schistosity within the ore shoot may be coincident with that in the enclosing shear zone. Thus it is clear that problems may arise in the delineation of mining boundaries. Ore generally consists of 20 pct or more quartz with ferruginous carbonates in sericite schist deposited in two dominant stages. The earlier stage limits of quartz with carbonate, pyrite, and very fine-grained arsenopyrite in lenses and bands. The later stage consists of quartz-carbonate lodes, in

Jan 1, 1952

By Thomas C. Wilder

Jan 1, 1965

By C. S. Smith, Chih-Chung Wang

D. Turnbull—In the opinion of the writer the most interesting result described in this paper is that the distribution of tin with respect to solidification temperature has several fairly well-defined maxima. It appears that each peak may be associated with a catalytic impurity of some rather specific composition. Recently we have obtained some additional evidence in favor of this viewpoint in experiments on the supercooling of lead droplets coated with different surface films. The distribution of lead droplets, ostensibly coated with lead sulphate, with respect to solidification temperature exhibited two distinct and reproducible maxima, one at 20" supercooling and the other at 47". On the other hand, when the droplets were ostensibly coated with halide films, no solidification was perceptible until the aggregate was supercooled more than 55". Upon further cooling a single well-defined peak centering at 60" supercooling was observed. Since the particle size distribution was the same in these two sets of experiments it appears that the most reasonable interpretation of the results is that the sulphate surface film or its reaction products with lead are much more effective in catalyzing the nucleation of lead crystals than are lead halide films. C. S. Smith (authors' reply)—Dr. Turnbull's experiments with lead drops coated with various surface films are most interesting. However, before drawing conclusions from the cooling curves described in the paper as to the existence of a few nucleus types effective at a few different temperatures, one must consider the state of subdivision of the liquid metal. In the A1-Sn alloy used, the tin was not in uniform droplets but tended to collect in three distinct shapes—in long interconnecting prisms along grain edges, in somewhat elongated interdendritic branching pools. and in isolated droplets. A single nucleus will solidify only the metal in contact with it, and the heat evolved will be proportional to the connected volume. A uniform distribution of nuclei of random effectiveness in such an alloy will cause peaks on the specific heat curve on cooling, which correspond to the volume distribution of tin and tell nothing about the nucleus type. In any real alloy both effects will be combined, and it seems impossible at present to distinguish between them. M. B. Bever—The thesis of this interesting paper is supported by a combination of positive and negative evidence. The authors have shown that under certain conditions a liquid phase may undercool, if it is dispersed in a thoroughly discontinuous manner throughout a solid matrix. They also found that undercooling

Jan 1, 1951

By T. W. Beck

Drilling into coal mine roof strata to install roof bolts has the potential to release substantial quantities of respirable dust. Due to the proximity of drill holes to the breathing zone of roof bolting personnel, dusts escaping the holes and avoiding capture by the dust collection system pose a potential respiratory health risk. Controls are available to complement the typical dry vacuum collection system and minimize harmful exposures during the initial phase of drilling. This paper examines the use of a bit sleeve in combination with a dust hog-type bit to improve dust extraction during the critical initial phase of drilling. A twisted-body drill bit is also evaluated to determine the quantity of dust liberated by comparison to the dust hog-type bit. Based on these laboratory tests, the bit sleeve may reduce dust emissions by one-half during the initial phase of drilling before the drill bit is fully enclosed by the drill hole. Because collaring is responsible for the largest dust liberations, overall dust emissions can also be substantially reduced. The use of a twisted-body bit has minimal improvement on dust capture compared to the commonly used dust hog-type bit.

Feb 27, 2013

By Dever Ashmead

ANTHRACITE was first mined in the Wyoming Valley and sold as an article of commerce in 1808. As some preparation has always been necessary to make it ready to burn, the preparation of anthracite must date back over a hundred years. Two vital factors have determined to a large extent the degree and method of anthracite preparation. These are, first, the character of the beds worked and the methods by which they were mined and, second, the equipment used and practices followed in the burning of the coal. It is not the intention here to go deeply into these phases of preparation as a paper of no mean length could be prepared on the history of either. Rather, the intention here is to point out the main considerations and to show the influence they have exerted on the preparation of anthracite. MINING METHODS AND THEIR RELATION TO PREPARATION In the beginning f the nineteenth century, the coal beds were virgin with the possible exception of some outcroppings that had been worked, to a slight extent, by the Indians. It is known that the American aborigines had a knowledge of the use of this fuel, because when the Wyoming Valley was purchased from them, in 1754, they mentioned the fact that, by selling the land, they would lose their coal.

Jan 9, 1921

By A Unlutepe

The Bosphorus Rail Tunnel Project, located in Istanbul, Turkey, aims to provide a Euro-Asian rail link, via an immersed tube tunnel crossing the Bosphorus Strait, along which will run all commuter, freight and intercity passenger trains of Turkish State Railways (TCDD), as well as the future extension to the European rail network. The total length of upgrading and new railway construction will be approximately 76 km. The main structures include the immersed tube tunnel; mechanised shield tunnels; new Austrian tunnelling method (NATM) tunnels; cut-and-cover, at-grade and retained-cut/fill structures; and some service structures. This paper discusses Phase 1 implementation of the project, one of the major transportation infrastructure projects in the world today, whose varied structures present stimulating engineering and construction challenges.

Jan 1, 2008

By A N. Gupta, C Joginadham, P Shiva Shankar

Cast boosters made with pentaerythritol tetranitrate(PETN) and trinitro toluene(TNT) give high velocities of detonation and are sensitive to initiation even under high pressures. However, the manufacture of the same involves heating of TNT to its melting temperature and mixing of dry PETN in it.

Jan 1, 1996