Search Documents

By A. V. Tarasov

The high efficiency of autoclave processes is attributed to the fact that they are suitable for processing of refractory raw materials, have low capital costs and high productivity, ensure integrated utilization of the feed materials, produce innovative saleable products, completely eliminate any air emissions, provide low-waste or waste-less technology, as well as mechanization and automation of production processes. In the immediate future, it might be expected that autoclave processes will find use on commercial scale for production of heavy non-ferrous metals in combination with other processes (hydrometallurgical, upgrading, sorption and solvent extraction, electrolytic, etc.) to ensure: -Integrated processing of refractory ores and concentrates (pyrrhotite, zinc, copper-zinc, lead-zinc, nickel-cobalt, copper, pyrite); -Production of metallic powders of base metals as commercial products (copper, cobalt, nickel, etc.), composites on their bases, final products and saleable salts. Processing technologies incorporating autoclave processes, especially, at the stage of liberation (chemical upgrading) of minerals, are characterized generally by high overall recoveries of valuable constituents significantly exceeding recoveries common for conventional pyrometallurgical processes (for some elements by several tens of percent). An example is processing of low-grade refractory pyrrhotite concentrates using autoclave liberation of feed material under pressure of a new reagent, i.e., sulfur dioxide. The use of sulfur dioxide ensures a significant improvement in the recoveries of non-ferrous metals and platinoids to sulfide concentrate and smelting of the latter increases the capacity of the smelting units employed and minimizes the yield of discard slag and loss of metals in slag; in addition, it resolves the problem of sulfur dioxide utilization.

Jan 1, 2003

By Z. T. Bieniawski, E. H. Skinner, R. A. Cummings, F. S. Kendorski

INTRODUCTION Caving Mine Drift Support Design The support of production drifts remains a high-cost item facing the developer or operator of an underground caving mine. Support costs are incurred well in advance of ore production, and there is a strong need to minimize these pre-production commitments of capital. Due to the extensive rock loads that normally develop during the caving process, the support used in caving mines is typically quite heavy and therefore costly. The process of designing this support increasingly makes use of basic tunneling principles, but is hindered by the still-incomplete state of knowledge of rock behavior in caving mines, and high variability of geological conditions in caving orebodies. Caving mines differ from tunnels in that the deformations and rock loads induced are transient and dynamic in occurrence, and are normally large in magnitude, often well in excess of rock mass strength. As opposed to tunnels, caving mine layouts are more intricate, and the methods and effects of construction ordinarily are not as closely monitored. Safety factors in mining tend to be lower and rock masses tend to he weaker. These aspects prevent strict application of tunnel design technology to caving mine drift support, with the result that mine drift supports are commonly designed chiefly on the basis of experience at other mines. Mining procedures at caving mines are evolved in response to site-specific requirements, to the extent that there are really as many caving methods as there are caving mines.

Jan 1, 1983

By K Gordon

A methodology for assessment and remediation of acid mine drainage (AMD) developed at the Sullivan Mine in the West Coast Region has been applied to the closed Blackball Mine, Blackball, West Coast Region. AMD from the Blackball Mine has low pH, high acidity, and elevated levels of iron, aluminium, manganese, nickel, zinc and arsenic. The AMD flows at a variable rate (36 - 101 L/s) into adjacent Ford Creek, causing an increase in acidity and trace element concentrations in the creek. To test the effectiveness of treatment with a simple limestone-based treatment system, a column leaching experiment was conducted over a nine day period. The results show effective removal of acidity, reduction in the concentrations of iron, aluminium, manganese and zinc, and production of alkalinity. To determine if this treatment method reduces the toxicity of the AMD to aquatic invertebrates, a 96 hour ecotoxicity experiment was conducted. The results show a significant decrease in mortality in the treated AMD compared to untreated. The column experiment, in conjunction with the ecotoxicity work, suggest that a passive treatment system consisting of a limestone leaching bed and an open limestone channel may be sufficient to treat the AMD from the Blackball Mine. Further work, such as large-scale treatment trials, is recommended.

Jan 1, 2004

By John E. Pahlman

The Bureau of Mines has conducted research on a dual leaching method that offers the potential for the economic recovery of the silver, as well as of the manganese, contained in some domestic manganiferous silver deposits. The method consists of an initial leach of manganese with aqueous sulfur dioxide (S02) followed first by a neutralization rinse, and then by a second leach with cyanide solution for the extraction of silver. Refractory silver in these ores was either (1) intimately associated with the manganese, (2) chemically resistant to cyanide leaching, or (3) rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization. Less than 10 pct of the silver was extracted when minus 2.5-plus 1.3-cm ore pieces were leached directly with cyanide. However, extractions of 25 to 82 pct of the silver and 65 to 96 pet of the manganese were attained in laboratory column-leach tests using the dual leaching method on equivalent-sized ore pieces from seven domestic deposits.

Jan 1, 1987

By E. T. Turkdogan, P. Grieveson

Molten silver is equilibrated with silicon nitride at 1400°C in nitrogen + hydrogen gas mixtures, and from the solubility data the activity coefficient of silicon is found to be 1.76 at silicon concentrations below 1 pct. Using this value, and that available from the silicon cmbide solubility measurements, together with those derived from the phase equilibrium diagvam, the activities of silver and silicon are estimated for the entire composition range. The main feature of the activity data is that there is a pronounced positive deviation from ideality. The activity of silver in molten silver containing up to 5 pct Si was determined by Schadel, Derge, and Birchenall1 by measuring the vapor pressure of pure silver and of the alloy over a temperature range of 850º to 1050°C. They deduced from their results that there is a positive deviation from Raoult's law and that the activity coefficient of silver increases with decreasing temperature. However, as pointed out by Kubaschewski and Catterall,2 their activity coefficients are much too high, giving silver activities greater than unity. At a later date McCabe and Birchenal13 showed that the previous vapor pressure data on silver4 were high by a factor of about 1.3; presumably a similar error must have occurred with the vapor pressure measurements on the Ag-Si alloys. The activities of silicon and silver calculated by tager' from the phase diagram and by Gibbs-Duhem integration, respectively, show a positive deviation from Raoult's law for silicon activity and positive and negative deviations for the silver activity. According to these computations, at infinite dilution of silicon ygi = 1.12 at 1420°C. d'Entremont and chipman6 measured the solubility of silicon carbide in molten silver at unit carbon activity; the equilibrium silicon content is found to be Nsi = 0.017 ± 0.002 atom fraction for 1420°C. Using the data of Grieveson and Alcock7 for the free energy of formation of silicon carbide from pure silicon and graphite, the activity of silicon for unit activity of carbon and of silicon carbide is asi = 0.0308 at 1420°c; therefore for the above solubility data on silver, YSi = 1.81, which is somewhat higher than that given by Hager. Use is often made of silver alloys in the measurements of activities of solutes in metals where silver has a very low solubility; in fact, Ag-Si and Ag-A1 alloys have been used in the past for such purposes. In an attempt to gain more thermodynamic data on molten Ag-Si alloys, measurements have been made in the present study on the solubility of silicon nitride in molten silver; the results on these solubilities are given in this paper together with a detailed discussion of activities of silver and silicon. SOLUBILITY OF SILICON NITRIDE The standard free energy of formation of silicon nitride is known with a reasonably high degree of accuracy. According to the measurements made by Hincke and Brantle8 and by Pehlke and Elliott,' the following are the free energy data for the standard states of solid Si3N4, liquid silicon, and Nz at 1 atm pressure:

Jan 1, 1963

By Jack E. Thompson

Thank you Tom and JM for that nice introduction. The remarks I am about to make rely on a large way on comments made by Barrick's Chief Counsel, Patrick Garver, to an internal meeting of Barrick's senior staff. I plagiarized so much from his notes that I thought that I should provide attribution. I did get his consent to borrow so freely. What I have done is take his general comments and used my conversations with CEO's and other participants in the industry to enhance the message with concrete examples that underscore the points I wish to make. What you are about to hear is my personal view – I am not speaking as a representative of any company. With that introduction, now would be a good time to give you the main theme of my talk: The SEC should change its rule making to a more public cooperative approach. If that were to happen the SEC would avoid some of the harm it has been doing to the companies in this sector and the very shareholders it seeks to protect.

Jan 1, 2003

By Alexandre de Freitas Gomes de Mendonça

O pick-up de nitrogênio no aço deve ser evitado nos processos de fabricação em uma Aciaria de alto desempenho. Entretanto, o pick-up de nitrogênio pode ocorrer em inúmeros pontos na Aciaria, principalmente quando o aço líquido é exposto ao ar atmosférico. Alguns locais de controle têm grande relevância no resultado do pickup, tais como: durante o vazamento do aço do convertedor para a panela, no refino secundário durante a agitação excessiva do aço e no lingotamento contínuo devido a aspiração de ar atmosférico nas conexões. Neste trabalho, o foco do controle da incorporação de nitrogênio é no lingotamento contínuo e, para efeito de estudo, tomou-se como referência um pick-up de nitrogênio de até 5 ppm. Os dados históricos mostram que menos de 64,6% das corridas encontravam-se com pick-up de nitrogênio abaixo de 5 ppm. Assim, visando reduzir esse pick-up foi proposto um ajuste no ângulo da sede da válvula longa, melhoria do projeto do gasket e capacitação da equipe de operação. Após a efetivação dessas ações de controle esse número passou para 97,7% das corridas lingotadas.

Jul 30, 2018

By Yoshiak Mizuta, Hi Keu Lee

The manuscript of this paper was not available for publication when the Proceedings went to press. Should the authors elect, they may distribute copies at the time of the Symposium

Jan 1, 1986

By Michael A. Poling

Ladies and gentlemen, I appreciate this opportunity to be with you, and to share my outlook on the future of Federal coal leasing. I'm told that you wanted the best speaker on this subject in the world. Perhaps it's a reflection of these trying financial times, but I'm glad you finally agreed to settle for the best speaker your budget would afford. I have been asked to give you some insight on the status of Federal coal leasing, and how the budget problems facing the Department will affect the coal program. So I've polished up my crystal ball, and I'll try to give you a peek at the future. Before I do that, however, let me first go back in time - to when this Administration took office in 1981. We had a coal program then, after a hiatus of ten years. But that program was untested and - for reasons well known to all of you - did not work well in practice once we began operating the program. We went back to the drawing board and redesigned the program so that it can do what it is intended to do. We've made the program more predictable. That means that when future lease sales are scheduled, those sales will be reflective and reactive to the need to lease coal. On February 26, Secretary Hodel unveiled a framework for resumption of Federal leasing program activities, ending a more than two-year suspension of regional coal sales. The new program will provide the opportunity to satisfy market demand for acquiring and developing new leases, assure the government of fair market value for its coal reserves, and provide a stable supply of coal for this country's energy needs. The new program grew out of the Department's response to recommendations of the Linowes Commission and the Office of Technology Assessment, coupled with a supplemental environmental study. The Linowes Report, issued in 1984, contained 36 recommendations and three Judgments on leasing levels, tract selection, sale procedures, appraisal methods, key statutory and related factors, and organization and management of the leasing program. Major changes in the new leasing program reflect these concerns. We have developed a definition for captive tracts and devised procedures to appraise their value to the adjacent coal or mine owner. Other steps include a coal lease appraisal guide which describes our appraisal methodology and is available to the public. Improvements have also been made in the gathering of lease assignment information to help in estimating the value of potential lease tracts. To improve market analysis, a three-tiered system will be used to ensure that steps of the lease sale decision process are undertaken in the context of coal supply and demand. Regional Coal Teams will thus have the advantage of long range, regional and tract specific market studies to help them determine whether sufficient demand is expected first to warrant the initiation of activity planning, then to set regional leasing levels, and finally to actually offer specific tracts for lease sale. Sale procedures will also be improved in many ways to encourage competition, improve the chances for receiving adequate bids, and to evaluate whether bids represent fair market value. We made additional modifications to the program in response to the OTA recommendations. Regional Coal Teams have been given a larger role in recommending key decisions concerning the amounts of coal to be studied and the actual selection and scheduling of tracts for lease sale. These recommendations will be accepted unless the Secretary can cite an overriding national interest factor, or a governor's request to modify the recommendations. Smaller, more frequent sales will be held, to better judge market conditions and prevent over- or under-leasing. Public participation guidelines have been written, to document all opportunities for the public to comment at various stages in the planning process. We also decided that resource management plans prepared after the passage of FLPMA in 1976 must be completed, in order for a new round of lease sale planning to begin. The BLM will also beef up its procedures for consulting with affected Federal agencies during the planning process, to assure that the purposes and values of those agencies are considered and factored into land use decisions. To assure consistent use of an adequate data base in coal lease decision-making, Regional Coal Teams will develop standards and guidelines for data adequacy, and document the use of these standards. These procedures will also be applied to the unsuitability criteria screening process. Thus, the new leasing system announced by Secretary Hodel: is fully responsive to recommendations made by the Linowes Commission and the Office of Technology Assessment for improving environmental planning and fair market value procedures; gives the regional coal teams a major say in determining leasing levels, and on the timing,

Jan 1, 1986

By Gualberto Carpio

El presente texto señala la metodología desarrollada en Tintaya para la identificación de posibles proyectos, los cuales están enfocados con los objetivos del negocio y del líder del área ya que comparten metas comunes de mejoramiento. Esta mejora alcanzada con Six Sigma, solo es posible con el soporte del plan estratégico de la compañía y por ende, se hace énfasis en la correlación que existe con los proyectos a desarrollar en todas las áreas. En este sentido, el plan estratégico es alineado y controlado por indicadores clave de desempeño (KPIs) de primer, segundo y tercer nivel, los cuales indirectamente norman el desarrollo de los proyectos planteando metas de costos, incremento de producción, productividad, reducción de tiempos de ciclo, etc.

Sep 19, 2006

By R. V. Lundquist

Lime-soda sinters, made and processed for recovering alumina and soda, consisted of several types of compound structures differing from the ideal dicalcium silicate and sodium aluminate. Many or these compound structures were causes for low alumina recovery and contributed to the relation or leach slurries. Presence or free lime, whether in the sinter or released by hydrolysis of sinter compounds, contributed to relation of leach slurries. Free lime tends to establish the initial viscosity assumed by a leach slurry. Previous investigations by the Bureau of Mines (1, 4)4/ and by other laboratories (5) have demonstrated the technical applicability of the lime-soda sinter process to the recovery of alumina from aluminum silicate materials. The basic concept of the process is sintering aluminum silicate materials with limestone and soda ash for the production of dicalcium silicate and sodium aluminate and then extracting the sodium aluminate by leaching the sinter in causticized liquors. Alumina is precipitated from the pregnant liquors by carbonating with carbon dioxide. Reaction in the sintering operation may be represented by the following simplified equation: A1203?SiO + 2CaCO3 + Na2C03 = 2Ca0?SiO + Na20?Al203 + 3C02

Jan 1, 1960

This is the third in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C. F. R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ The second report gave the same data for motor gasolines sold during the summer of 1936)4/ As was the case with the first cooperative gasoline survey, reports were received for some areas from only one company and in other areas from two companies that did not in all instances report on the same brands of gasoline. In still other areas reports were received from five or six companies on the same brands of gasoline. Thus, it can be seen that data on gasolines are unequal in regard, to the number of reports that were averaged in calculating the data shown in table 1. The data from the Pacific Coast were averaged by the Pacific Coast technical group before submission and are published exactly as they were submitted.

Jan 1, 1937

This is the third in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C. F. R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ The second report gave the same data for motor gasolines sold during the summer of 1936)4/ As was the case with the first cooperative gasoline survey, reports were received for some areas from only one company and in other areas from two companies that did not in all instances report on the same brands of gasoline. In still other areas reports were received from five or six companies on the same brands of gasoline. Thus, it can be seen that data on gasolines are unequal in regard, to the number of reports that were averaged in calculating the data shown in table 1. The data from the Pacific Coast were averaged by the Pacific Coast technical group before submission and are published exactly as they were submitted.

Jan 1, 1937

By D Trembath

"One of the key risks to the success of a mining operation is the accuracy of the estimates of both the economic mineral and any accompanying contaminants contained within the ore reserve. Misrepresenting the mineralogical characteristics of the ore reserve can result in considerable financial investment in an operation that is in fact uneconomic and/or carries a significant environmental risk. This in turn can result in an unplanned closure of the operation with associated financial, environmental and social legacy. One way to minimise this risk is to undertake high density resource sampling to gain a better understanding of the resource characteristics. However, such an approach is expensive, time-consuming and often impractical. The risk of not having an accurate model is typically assessed during a feasibility study utilising a Monte Carlo simulation method or some form of sensitivity analysis. Importantly, the error margins used in these types of analyses are often based on subjective or very general criteria such as ‘professional judgement’ or an ‘industry standard’. This presentation introduces a conditional simulation method for developing a range of mineralogical distribution models. Based broadly on the method outlined in Journel and Kyriakidis (2004) the proposed approach develops this work further. It combines a geostatistical analysis of the available data with automated mine design software to provide a rigorous method for assessing the confidence in the mineralogical characterisation of the ore reserve. The process is based on simulating possible mine plans based on the statistical characteristics of the available resource sample data. These plans are then assessed against high resolution resource models generated using a Sequential Gaussian Simulation method. The outcome is confidence intervals for important characteristics of the ore reserve estimate relative to the actual resource. These confidence intervals are an objective and transparent measure important for assessing closure risks and represent an improvement over common practice.CITATION:Trembath, D, 2016. A simulation approach for improving the assessment of closure risks, in Proceedings Life-of-Mine 2016 Conference , pp 36–38 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By David Beck, Eko Wibowo, Hendri Silaen, Andres Sugiyanto, Karl Llewelyn

PT Freeport Indonesia’s Deep Mill Level Zone mine is one of the deepest block cave mines in the world and is in mountainous terrain in West Papua, Indonesia. The mineralization is hosted in a skarn deposit in a structural setting that is complex at the footprint, mine and regional scale. Large seismic events and significant episodes of rapid rock mass deformation are potentially critical geotechnical risks during this ramp-up stage of mining. Understanding the interaction between stress, strain, rock mass strength and geological structures is essential to minimize the hazard and engineer control measures to help ensure the safety of the employees while achieving production targets. This paper discusses how the seismicity and excavation damage have been shaped by the interactions between the mine and geological features, and how this affects strategic mining decisions. Additionally, the paper presents a summary of the mitigation measures used for mining the DMLZ in the safest and most productive way. These include improvements to geotechnical characterization of rock mass and structure, dynamic ground support designs, production scheduling for desirable cave propagation and a seismic monitoring system with re-entry protocols.

Apr 26, 2022

Simplify the spraying of sealants onto coal mine roofs. Approach A nonclogging system in which dry-fed sealant is mixed with water down-stream of the spray nozzle, has been developed and tested. How It Works The two-channel nozzle of this spray discharges two separate flows, a mixture of air and dry sealant from a central cylinder, and an encircling spray of water from a concentrically mounted water ring (a ring-shaped manifold). Downstream of the nozzle, the water mixes with the air and sealant to form a wet sealant spray that adheres to mine surfaces with very little rebound. (See photograph.) Extensively modified commercial spray machines are used to feed the sealant to the spray nozzle smoothly, without raising dust. Plugging of the nozzle is practically eliminated by two self-cleaning design features of the nozzle. These are the air gap and the tapered bore of the cylinder, (See drawing.)

Jan 1, 1979

By G. K. Ruhlandt, C. W. Kim

"A 3-D Finite Element Method program called ""SOLCAST"" has been developed to simulate the casting solidification process. Using the temperature recovery method to evaluate the latent heat of fusion and applying a new combination of the time integration scheme, SOLCAST reduces the computational time significantly compared to an existing commercial FEM program, and produces accurate results comparable to experimental casting results. Prediction of casting shrinkage porosity for A390 aluminum alloy will also be discussed. To make this FEM program useful for foundry engineers, this program was connected to a commercial pre- and post-processor.IntroductionBecause of recently increased competition, foundrymen must produce high quality castings more economically. Therefore, casting solidification analysis prior to casting production is an attractive way to reduce costs and development time.Although the actual casting solidification process is a very complicated phenomena, foundrymen could predict where shrinkage defects would occur based on a transient conduction heat transfer analysis that includes the liberation of latent heat. A numerical analysis is generally required to solve the heat diffusion equation with the latent heat diffusion term, because casting shapes are very complicated and pure materials are rarely used.Different numerical methods have been applied to the casting solidification analysis 1. Among them, a finite difference method 2 and a finite element method (FEM)3 are most commonly used.Each simulation method has one or more basic difficulties which are different for each method. These difficulties are:(1) Modeling casting shapes on a computer.(2) Time consuming computation.(3) Uncertain material properties."

Jan 1, 1986

Discussion of the paper of DR. L. EDELEANU, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin No. 93, September, 1914, pp. 2313 to 2332. F. W. BUSHONG,* Pittsburgh, Pa.-This process of extraction is particularly advantageous in the case of Roumanian oil, on account of its high aromatic content. I have prepared a paper, which will appear probably next month in the Journal of Industrial and Engineering Chemistry, describing a series of two-degree fractions of oil from the Nowata field in Oklahoma. I have made extractions with liquid sulphur dioxide in accordance with Dr. Edeleanu's method, and found that the Oklahoma oils, for instance the kerosene fractions, are purified in this way, although the quantity taken out does not at all compare with that taken out of the Roumanian oil. I have made careful analyses of separate fractions, before and after extraction, and they show a very distinct fractional separation-. I like the distinction, brought out by Dr. Day in previous discussions, in regard to oils, rather than oil, and his beautiful illustration of fractionation. Just as fuller's earth, and other clays, will enable us to obtain lower-boiling fractional portions of the oils, and eventually retain a residuum which is hard to get rid of, or to remove, so there is an advantage to be gained by the use of a reagent which begins at the other end by taking out these last constituents first, namely, ozone. I have also analyzed the ozonides and they are derivatives of hydrocarbons very much poorer. in hydrogen than we have heretofore supposed. Similar results have been obtained with Roumanian, Russian, and Italian petroleums. Furthermore, I have prepared ozonides from a fraction of Oklahoma oils, both before and after ex-' traction with liquid sulphur dioxide, and found that the ozonide obtained from the extract is the same as that precipitated out of the original oils. In other words, the residual substance, which the fuller's earth retains, is the one first thrown down by the use of ozone, but it may also be extracted by liquid sulphur dioxide- and be thus separated in apparently unaltered condition. The analysis of this extract corresponds to the formula C15H20, which is surprising, since it is lower in hydrogen content than we have been in the habit of considering among the constituents of our oils. The extract was probably contaminated with other hydro-carbons, but I think it is unquestionable that we must look for hydro-carbons in petroleum which correspond to a formula at least -as low in hydrogen as C15H2o, and possibly even as low as C15H16.

Jan 4, 1915

By K. A. Jackson

An analysis of the conditiom fm the dendrite-eutec-tic transition is presented which takes into account a temperature gradient. The composition and temperature in the liquid ahead of a eutectic interface growing at a particular velocity are used to determine whether dendrites can grow faster than the eutectic interface in the liquid which exists ahead of it. If the dendrites grow faster, then a mixed structure with dendrites growing ahead of the eutectic interface is expected. If the dendrites do not grow faster, then only eutectic will be present. The analysis is presented for Sn-Pb system, for which sufficient experimental data to make the analysis are available. The transition from eutectic to dendrites-plus-eutectic derived by this analysis is in good agreement with the recent experimental observations of Mollard and Flemings on Sn-Pb alloys. In alloys which grow with a lamellar eutectic structure, the lamellar structure can be grown over some range of compositions close to the eutectic composition. When the composition is too far from the eutectic composition, dendrites of one or another of the primary phases grow ahead of the eutectic interface, producing a microstructure consisting of "primary phase" interspersed with a lamellar eutectic. Hunt and Jackson' have recently predicted the range of compositions over which the eutectic phase should grow in Sn-Pb alloys, and the composition-growth rate dependence of the transition from eutectic to dendrites-plus-eutectic. This prediction was based on work on organic eutectics. The model on which the prediction was based assumed that there was no temperature gradient in the system, a condition approximately satisfied in the study of organic eutectics2-5 but not in the growth of metallic alloys. Mollard and Flemings6,7 have recently reported experimental results for Sn-Pb alloys in which they have located the transition from eutectic to eutectic-plus-dendritic growth. The experiments were performed using large temperature gradients (65 to 515 deg per cm), so that the assumption of zero gradient on which the predictions of Hunt and Jackson' were based does not apply. It is not surprising therefore that the predictions' were not born out by the experiments.7 In the present work, a modification of the model used by Hunt and Jackson is presented which takes into account the temperature gradient. The modified form of the theory predicts the transition from eutectic to eutectic-plus-dendritic growth in terms of the composition, growth rate, and temperature gradient. Good agreement with the experimental data of Mollard and Flemings7 is obtained. THE HUNT-JACKSON MODEL The model used by Hunt and Jackson' to predict the transition from eutectic to eutectic-plus-dendritic growth was based on the assumption that dendrites grow ahead of a eutectic interface only if they grow faster than the eutectic interface. Analytic expressions for the growth rate of dendrites and the eutectic in Sn-Pb alloys were obtained by fitting experimental data with equations whose form was indicated by theory.

Jan 1, 1969

The Honourable Neil Pickard has been in Parliament for something like sixteen years. He was Minister for Education in 1976, served as Shadow Minister in a number of portfolio areas while his party was in opposition, and since their return to power in 1988, he has been the Minister for Minerals and Energy. Ladies and gentlemen, I ask you to welcome the Minister, the Honourable Neil Pickard.

Jan 1, 1989