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By R. W. Van Dolah

The feasibility of formulating cap-sensitive slurry explosives for use in underground mines with potentially flammable gas atmospheres was examined. Formulations containing aluminum metal as sensitizer and sodium chloride to reduce incendivity were prepared; some were cap-sensitive and had adequate air-gap. Flaked aluminum metal rather than the atomized type proved to be the more effective sensitizing agent of the formulations tested for incendivity in the large gallery of the Bureau of Mines, some were found to be suitably nonincendive.

Jan 1, 1968

Written contribution by J.F. Curtist The paper is an interesting exercise in the application of mathematics to a theoretical situation presumed to oc¬cur underground. However, some of the assumptions on which the calculations are based are unlikely to occur in any actual mining situation. Assumptions made in the paper Objections to these assumptions are noted seriatim. (1) `it is assumed that any loading-rate effect will be small and can be ignored' (p. 3). A loading rate of the order of 50 kN-12 per cent of the maximum load-is customary to prevent the props being dislodged by the blast. (2) `it is unlikely that all the props will be installed with their full stroke available, but for the purpose of this analysis, it is assumed that this is the case' (p. 3). A more reasonable assumption would be that, with the most careful selection of prop length and the most rigid control of stope width, the available stroke length would on average be reduced by the order of 70 mm on installation-20 per cent of full stroke. (3) `each support unit supports a block of 3,3 m2 bound¬ed by vertical fractures with zero cohesion that are parallel and at right-angles to the stope face respec¬tively' (p. 5). Joughin and Jager have shown this to be an unwar¬ranted assumption in respect of the positioning, the direction, and the dip of the fractures present in a stope in rockburst conditions. If, as assumed, there was `zero cohesion' between such blocks, the removal of a hydraulic prop in row 3 supporting such a block would ensure that it fell out before a profile prop could be installed in the same position. (4) `the height of each of these blocks is 3,0 m, the volume of each block is 9,9M3, the mass of each block is 27 225 kg' (p. 5). The concept of individual props being affected by dis¬crete blocks of known and uniform dimensions of relatively low ground velocities (less than or equal to 2,16 m/s) acting in line with the axis of the prop is one that lends itself to neat mathematical calcula¬tions. It does not, however, bear much similarity to the actual conditions that are exposed underground in excavations where rockbursts occur. Ortlepp and co-workers concluded that `the impulse of the shockwave can cause the displacement of the

Jan 1, 1991

"Pressure leaching is an option for copper recovery from chalcopyrite. Leaching takes place at high temperatures and pressures in the presence of an oxidizing agent. This work shows how the performance of pressure leaching circuits may be improved by optimizing the configuration of autoclaves and the heat removal method. The objective was achieved by creating an autoclave model that combines mass balances, energy balances, and population balances. A base case circuit consisting of a single autoclave was chosen, and this base case was compared with options for increasing capacity by adding more autoclaves to the circuit. These capacity increase options include circuits in which the additional autoclave is added in parallel, in series, and in series with thickening between the two autoclaves. The copper extraction, productivity, and cooling requirements for these options are compared. The series circuit with interstage thickening has the highest extraction and productivity; however, the cooling duty in the first autoclave is high. In addition to comparing circuit options, three options for heat removal were investigated: cooling coils, quench water, and flash recycling. The flash recycle option results in the highest copper extraction, and the quench water option the lowest copper extraction. IntroductionBackgroundCopper sulphide ores and concentrates containing chalcopyrite are typically hard to leach under atmospheric conditions. Smelting of these ores may also be a challenge, due to the inability of smelting processes to handle low-grade ores, as well as impurities such as arsenic and antimony. Alternative hydrometallurgical routes to treating chalcopyrite are therefore required. One option is pressure leaching, which is the focus of this work.In the pressure leaching process, sulphide ores and concentrates are leached in autoclaves at temperatures of 200 to 220°C and a pressure of about 3000 kPa (Schlesinger et al., 2011). An oxidizing agent, usually oxygen, is required to oxidize sulphide ions to sulphate ions. The oxidation of sulphur to sulphate is exothermic; consequently, a method of heat removal is necessary in order to maintain the temperature in the autoclave."

Jan 1, 2016

By Valentín Pamo Caytano

La electrorefinación en un electrolito de CuSO4 - H2SO4 es usado universalmente para producir cobre de alta pureza a partir de los ánodos impuros. Aunque una parte de las impurezas se disuelve durante la electrorrefinación y se concentra en el electrolito, otros elementos son insolubles y se acumulan como lodos anódicos en las celdas de refinación. Las impurezas deben ser removidas del cobre para cumplir las especificaciones del mercado sobre la ductibilidad y conductividad y para recuperar los sub-productos valiosos como el oro y la plata. En ese sentido, el presente trabajo describe los equipos y procesos que permiten la recuperación del oro refinado en la planta de metales preciosos de la Refinaría de cobre de Ilo.

Sep 12, 2011

Laboratory scale flotation tests were done on mineral hematite and aspecular hematite ore using oleic acid and sodium oleate as collectors. The mineral hematite floated strongly in the neutral pH region, with an increased pH range of flotation at higher oleate additions. Concentrates with sufficient hematite grade to meet the paint pigment specification were produced using oleic acid and sodium oleate as hematite collectors on the specular hematite ore. Hematite recoveries of 70 per cent at 60 per cent Fe grade were obtained using stagewise roughing. The interaction between hematite and oleate was confirmed as chemisorption but the exact mechanism could not be determined, as two independent phenomena can be used to explain the fact that the pH of maximum grade increased with increasing oleate addition.

Jan 1, 1999

By Michael S. Wieland

This report investigates whether it is tractable and thereupon reasonable to remove the booster influences when ranking the toxic fumes of non-cap-sensitive mining explosives. The hazard potential is represented by relative fume toxicity RFT, the resultant influence computed from a formulated rule with a restricted set (tally) of fume components and multiplying constants. The RFT result is compared to the rule criterion that represents the worst case tolerable toxicity stipulated by regulations or otherwise. The typical nonstoichiometric booster composition can render notable unwanted influence on the RFT ranking results. Historically, the remedy was to shoot the booster separately and reduce the trial concentrations by the relevant subtractions. Unreal negative concentration results were noted on rare occasions, revealing the faulty nature of the reduction procedure. With thermodynamic reaction chemistry codes TDRC, on the other hand, the booster ingredients can be retained in or removed from the reactant tabulation, yielding reduction factors taken as the concentration ratios for the two circumstances. The underlying presumption regarding reduction factors is that the ratios of component concentrations with and without the booster ingredients when resolved theoretically ought to equal those rendered experimentally, when tractable. Upon rearranging the presumed relationship, the unadjusted fume concentrations divided by theoretical reduction factors yield the wanted readjusted fume concentrations, thereby removing the booster influence without generating unreal negative concentrations. The work principle from thermodynamics restricted by the constraint of zero-net interaction loss is utilized in conjunction with the TDRC to resolve the wanted (Z-state) fume spectrum. This circumvents the recognized difficulty with traditional hydrodynamic detonation theory that is related to the nonideal reaction characteristics of typical mining explosives. The tacit characteristic of the Z-state resolved from the non-trajectory work principle is that it can not be remedied or tampered with, unlike the traditional trajectory techniques where the reaction products can be readjusted by changing formula representations, nullifying specific reactions or otherwise manipulating the thermodynamic trajectory process. Though the work principle theory is an unfinished formulation, the Z-state results prove worthy enough for rendering trends and comparisons and reaching otherwise useful conclusions. Further refinements should yield more reliable fume spectra and indicate explosive composition readjustments that would reduce toxic effects within underground mines and the wider world environment.

By E. H. Ahrens

This paper deals with the daily work of operating geologists and should be of interest to recent graduates. Working with development and production is quite different from exploration and many of the required skills and techniques must be learned on the job. Try to obtain your first position at a mine where good geological work is being done because it is important that you establish a solid foundation by learning valid techniques. Many do not! Those who desire to work in exploration are well advised to spend the initial two or three years at an operating mine where they will deal daily with an orebody during development and mining. Attempt to understand the controls of ore deposition and be interested in all phases of the operation. Learn something about factors which can adversely affect profitability and you will be a better explorationist.

Jan 1, 1983

By W. J. Grose

The Embankment Place office development over the platforms of Charing Cross Railway Station in London has presented many interesting and unusual problems to the engineers involved with the project. The main structure is supported on widely-spaced columns which penetrate the station platforms and underlying vaults, calling for high capacity foundations built in severely restricted spaces. Hand-dug underreamed piles were chosen. Whilst a conventional design approach was taken to size the piles, a detailed appraisal of ground movements was made to explore the effects of the new building loads on the existing foundations, not only beyond the site perimeter but also those amongst the new foundations. Before construction of the pile proper could take place, it was necessary to sink a caisson through the upper unstable and water-bearing soils. This being identified as a high-risk item, a full-scale trial was carried out prior to embarking on the main works. The twenty-one hand-dug piles were 2.5m diameter, over 30m deep and belled out to between 4.5m and 6.6m.

Jan 1, 1989

By Lawrence B. Cochrane, Olivier Tavchandjian, J. Michael Anderson, Christopher R. Davis

"Abstract - Resource modelling is a complex process involving different specialists with relevant experience using a multi-disciplinary approach and the best available technology and reviews by independent auditors. The reliability of the final resource estimate is highly dependent on the quality control exercised at each stage of the process. At each step in the resource modelling process it is necessary to define the specific objectives, the methodology proposed to achieve those objectives and to establish a set of checks and validation tools to assess the effectiveness of the proposed methodology. Designation of responsibility and authority for meeting these objectives must also be clearly identified. External audits must also be incorporated to review and validate the implementation of new procedures.Resource modelling is the basis for any economic appraisal of a mining project and includes a number of steps from data acquisition and validation to resource reporting, classification, and risk analysis."

Jan 1, 2001

By B. L. Averbach, E. E. Underwood

The vapor pressure of zinc in equilibrium with solid ß AgZn alloys has been measured by the dew-point method. The thermodynamic activities of silver, and the molar heats of formation have been calculated. Similar measurements have been made for the ternary alloys formed by adding gold to AgZn. An apparent particle size effect has been observed for AgZn filings. The vapor pressure of zinc over filings is 15 to 20 pct higher than over the solid alloys. STATISTICAL methods have been used to inter pret the thermodynamic activities of the components of a solid solution in terms of average equilibrium atomic configurations. In some cases, the atomic arrangements can be measured by X-ray methods, and the results are usually expressed in terms of short range order parameters. Only in the cases of Cu³Au and AgAu have there been sufficient X-ray and thermodynamic data to verify the assumed correlation between the X-ray and the thermodynamic measurements. In Cu³Au the agreement is good; negative deviations from Raoult's law are observed and the number of Cu-Au nearest neighbor pairs predicted on the basis of the thermodynamic treatments agrees quite well with the number of such pairs observed by the X-ray methods. The ß brass alloys present a different set of conditions. The ordering is so rapid in these alloys that the disordered state cannot be retained on quenching. In contrast, the disordered state in CuAu is easily retained on quenching. On heating, the ordered ß brass loses its long range order continuously as the critical temperature is approached; in Cuau the order decreases slightly on heating and then drops discontinuously to zero at the critical temperature. These differences indicate that the short range order configurations in ß brass systems may be of a different character than in Cudu systems. However, X-ray measurements of local order cannot be made in the Cu-Zn alloys because of the similarity in scattering factors. The alloy AgZn is isomorphous with CuZn, however, and recent experiments have indicated that there is a good possibility of observing short range order in this system. Another complication arises in the case of ß AgZn. The disordered body-centered cubic structure exists above 280°C. On quenching from above this temperature an ordered structure of the cesium-chloride type is formed. On slow cooling, however, a complex hexagonal structure, the 3 phase, is produced; and if an ordered quenched alloy is reheated the phase begins to form above 80°C. It is thus difficult to study local order by X-ray methods in single crystals of AgZn since the C phase formed on heating does not necessarily return to a single crystal of the original orientation. This problem has been met, however, by adding a few percent of gold to the AgZn. The gold suppresses the formation of the c

Jan 1, 1952

By Yuchun Wang

In principle, supported liquid membranes could be an exceedingly elegant separation process. However they tend to fail by displacement and emulsification of the organic solution in the pores, which allows mixing of the feed and strip solutions. We have stabilized supported liquid membranes comprising moctylamine in nylon and PVDF supports by covering the pores with semi-permeable polyamide films, using an in-situ polymerization technique. Scanning electron microscopy demonstrates that the polyamide films are sensitive to production conditions and the nature of the support. The transport properties of stabilized supported liquid membranes for Cr(VI) are compared with those of unstabilized membranes.

Jan 1, 1998

By Paul M. Vercruijsse

Deep sea mining operations by nature are performed (or planned) in challenging environments. Another typifying characteristic of deep sea mining operations is the relatively high investment cost. This combination challenges engineers to design configurations able to mine the desired production rate in an efficient way. As design choices made for individual systems impact other parts of the system, it is vital to follow an integral approach to establish the one optimal overall system. Dredging and especially dredge mining learns that the excavation system, the slurry transportation system and the processing plant cannot be considered as individual sub-systems. These systems in any ?traditional dredge mining? operation interrelate to such extend that they must be developed towards an integral solution. The nominal production, peak production and variability of these figures must match for all subsystems in the overall mining system to optimize the mining efficiency. We call this the ?game of capacities?.

Jan 1, 2011

By Thais Cristina Lemes dos Santos

Neste trabalho será apresentado estudo sobre nanotubos de dióxido de titânio (TiO2) sintetizados pela técnica de anodização com variação do potencial entre 10 V e 50 V durante tempo fixo de 1 h. Além disso, para obter a estrutura cristalina deseja as amostras passaram por um tratamento térmico que foi realizado a 400 °C por 3 h a uma taxa de aquecimento de 10 °C/min. As amostras foram caracterizadas pelas técnicas de microscopia eletrônica de varredura com emissão de campo (MEVFEG), difração de raios X (DRX), espectrofotometria no ultravioleta visível (UV-VÍS) e de espectroscopia de impedância eletroquímica (EIE). Observou-se que o potencial de anodização exerce influência obre a morfologia dos nanotubos e sobre a absorção de luz e, consequentemente, sobre o desempenho fotoeletroquímico das amostras. O melhor desempenho foi obtido a partir da amostra anodizada a 30 V, este resultado está relacionado com a sua ótima absorção de luz e a sua baixa resistência ao transporte de carga interfacial obtido por EIE.

Aug 17, 2017

By R. Hedin, M. Dunn

The Pennsylvania Department of Environmental Protection (US EPA 319 program) provided funding to aid a public-private effort in the installation of an environmentally-friendly system to treat abandoned mine drainage at Jennings Environmental Education Center (Pennsylvania Department of Conservation and Natural Resources). Through this cooperative effort among state and federal agencies, mining, excavation, and environmental companies, college and home school students, Girl Scouts, and volunteers, a successful multi-component passive system, readily accessible for upgrades and public education/research activities, was built. 90 people were directly involved in construction of this award-winning system and about 1000 people annually benefit from the educational opportunities.

Jan 1, 2002

By M. Fofana

The use of a laboratory-scale magnetic fluid-based separator for coal separations was examined. A Frantz laboratory magnetic separator was modified by fabricating new pole pieces of the appropriate geometry to provide the proper magnetic field gradients. Two separation chambers, which were constructed out of Plexiglas, were designed to fit between the pole pieces. A commercially available, water-based, ferro-magnetic fluid was used as the separating medium. The separating density was changed by varying the intensity of the electromagnet. Both batch and continuous separations were made using 0.59x0.50 and 0.18x0.15 mm coal. The results are compared to those obtained using organic liquids.

Jan 1, 1996

By H. H. Murray

The largest reserves of palygorskite in the world are located in Anhui and Jiangsu Provinces in East Central China. The deposits are Middle Miocene in age and range from 3 to 6 m in thickness. The deposits are the alteration product of basaltic volcanic ash. The Chinese Geological Survey estimates the palygorskite reserves are in excess of 200 million tons. The elongate particle shape results in unique colloidal properties. Large quantities are exported to Japan, Taiwan, Southeast Asia, New Zealand, Australia, and West and Gulf Coasts of the United States. The markets include agricultural carriers, paint, joint tape compounds, animal feed binders, catalyst support, drilling muds, and suspending agents for chemicals, pharmaceuticals, and medicines. The viscosity is high and the quartz content is generally 5% or less.

Jan 1, 2009

By E. L. Frueh

AMAX Base Metals Research & Development, Inc. has developed a process for treating copper-nickel mattes to produce copper cathodes and a pure nickel sulfate solution. In this process, the input matte is preleached in a copper sulfate electrolyte bleed solution so as to dissolve nickel from the matte and cement copper from solution. The preleach leaves a substantially pure nickel sulfate solution. The residue from the preleach is roasted to less than about one percent sulfur. A portion of the calcine is leached with sulfuric acid to make a copper sulfate solution for input to the tank house. The residue from this leach and the remaining calcine are smelted to form a bimetallic (copper/nickel.) anode. The anodes are electrolytically refined and copper is preferentially deposited on the cathode while the nickel reports to the electrolyte, A bleed stream is taken from the electrolyte and used in the preleaching of the input matte. This process produces high purity metal streams while consuming less energy and smaller amounts of reagents as compared with other matte processes.

Jan 1, 1983

By Arthur F. Taggart

PROGRESS in a technical art is of several kinds. It springs .from many diverse sources. It comprises invention, mechanical improvement, operating advance, analytical study, education. Invention is, by definition, a relatively great, essentially individual step, taken quickly. Operating advance is the slow, cumulated march of practice; in contrast, it moves at the pace of the tortoise, but over, the years its effects rival and, in some cases, surpass those of invention. Mechanical improvement- is a usual concomitant of the reduction of invention. to operating practice; thereafter it is a primary tool of operating advance. Analytical study is the process of mental digestion of the fruits of invention and practice. Its purpose is to render these into a form assimilable by the art as a whole, and by the perennial crop of would be practitioners. Education, disseminating the results of such study, consolidates and maintains the positions gained. Thus, slowly at first, but continuously accelerating, the tide of progress grows- to flood. Such growth, in mathematical parlance, is expressible in the general form y = mxn, where x is time, n is some positive number greater than one, m is another positive number, and y is the state of the action at instant x. When n is 2, the readers will recognize the graph of the equation as one branch of the familiar square parabola, whose property it is to become parallel to the y-axis; i.e., to move at an infinite rate, in that never-never

Jan 1, 1947

By Z. Gxowa, L. H. Chown, U. Curle, G. Govender

This work evaluates the deformation behaviour, at warm working temperatures, of green particle-reinforced aluminium composites produced by powder blending in a high-energy ball mill. The work focuses on metal matrix composites (MMCs) based on the 2124-Al alloy, reinforced with 10 or 15 vol.% SiC and metal matrix nanocomposites (MMNCs) based on the 2124-Al alloy, reinforced with 5 or 10 vol.% Al2O3. Three batches for each powder were blended and powder properties such as particle size distribution (PSD) and shape were consistent after blending. It was observed that a more uniform distribution of the reinforcement phase in the aluminium alloy matrix was achieved in 2124-Al/Al2O3 than in 2124- Al/SiC composites. The powders (unreinforced 2124-Al and blended) were initially over-aged at 350°C for 2 hours to reverse any natural ageing that may have occurred prior to use. The over-ageing was incorporated to improve compressibility of the powders with the aim of achieving green compacts with higher integrity. Uniaxial compression tests performed at ambient temperature on a Gleeble® 3500 thermomechanical simulator were unsuccessful as the green compacts fragmented. Engineering stress-strain curves showed that green compacts of unreinforced 2124-Al, 10%SiC MMC and 5%Al2O3 MMNC deformed in a similar manner at ambient temperature and had the same compressive fracture stress of approximately 170 MPa. When the deformation temperature was increased from ambient to warm working temperatures (170–280°C) it was observed that electrical resistance heating (the heating mode of the Gleeble®) of unreinforced Al alloy, MMC and MMNC green compacts did not occur. This was attributed to the high electrical conductivity of aluminium, which resulted in poor heat generation due to the low electrical resistance in the samples. It was presumed that the small sample size (d=8 mm, h=12 mm) also caused rapid heat loss. After further experimentation, the green compacts were heated successfully by insulating the samples to retain heat. It was found that at 280°C, increasing the soaking time from 6 to 20 minutes decreased flow stress and improved plastic flow in the 2124-Al/10%SiC green compact.

Jan 1, 2016

By K. Awuah-Offei

An aggregate plant may have difficulty balancing product stockpile inventories if hot mix asphalt (HMA) design engineers do not account for aggregate inventory during mix design. Yet HMA design engineers do not, often, take this into consideration during asphalt mix design. This is due to the lack of tools that enable the lab technician or engineer to optimize the mix for good performance while helping the aggregate plant manage its stockpile inventory levels and reducing the aggregate cost. This work presents a linear programming model of the asphalt mix design problem that helps aggregate plants manage their inventory levels while meeting HMA customer demands. The algorithm is implemented in MATLAB as an Asphalt Mix Design Optimization (AMIDO) program. The program is successfully validated with real-life data. The results show that AMIDO can be used to successfully produce any mix design while reducing the cost of aggregates by using the cheapest stockpile materials. The application of AMIDO will increase aggregate plant profitability when serving HMA customers and could potentially be modified for concrete aggregate customers too.

Jan 1, 2009