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By C Chen, W J. Bruckard, F R. A Jorge

The base metal industry mines and processes hundreds of million tonnes of ore per annum to produce saleable products and large tonnages of waste by-products such as tailings. These ores usually contain less than 1 wt per cent of toxic elements (As, Sb, Bi, Cd, Se, Te, Hg, etc), which are subsequently treated with the other components in the ore during the production of concentrate through to saleable metal products. The deportments of minor elements across the various unit operations of a process flow sheet do not normally receive the attention that the major elements receive. However, these minor elements can have a major influence on the quality of the products as well as an economic and environmental impact. Therefore, a high degree of control over their deportments is a key step in reducing their dispersion in the biosphere. Ongoing work at CSIRO has been examining minor element deportments across unit processes used for smelting and refining and the options for early removal of minor elements, as well as methods for safe disposal of some toxic elements. This paper provides an overview of the R&D activities undertaken at CSIRO to develop tools and methodologies for improved management of minor elements during the processing of sulfide ores.

Jan 1, 2006

One of the main bottlenecks in the carbon-in pulp process for the recovery qf gold is the elution procedure, which typically requires the heading of caustic cyanide eluants to high temperatures for 16 to 24 hours. The present work demonstrates that sodium sulphide solution as an alternative eluant can effect complete elution in about 4 hours at ambient temperatures. Elution efficiencies of around 100 per cent were obtained in 4 hours with a single pass of eluant containing 0,2 M Na2S and 0,4 NaOH about 10 bed-volumes of eluant The initial rate was slow over the first hour of elution, probably because the activated carbon catalysed the oxidation of sulphide to polysulphide. Elution efficiencies of around 100 per cent were also obtained in less than 4 hours during the batch elution of carbon at liquid-to-solid ratio of about 100. Lower liquid to solid ratio resulted in the re-adsorption of gold, probably owing to the oxidation of sulphide to polysulphide, with the resultant formation of gold complexes that were eluted less readily. Improved rates of elution were obtained at higher sulphide concentrations and pH values greater than about 13. Higher temperatures increased the initial elution rate, but lowered the overall extraction efficiency, probably because of the deposition of elemental gold on the carbon. Variation of the ionic strength by the addition of NaCl had no defect on the elution, which confirms that the elution mechanism in the case of sulphide is different from that when cyanide or I1)1droxide is used as the eluant. It is proposed that the elution of gold by sulphide solutions proceeds by means of an initial step that involves the reaction of polysulphide ions with the adsorbed aurocyanide speeds, forming AuCN on the carbon and thiocyanate in solution. This step is followed by the formation of poorly adsorbed complexes with sulphide ions, such as [AUS3-2]-The presence of polysulphides, whether generated in situ by the catalytic oxidation effect of activated carbon or by the addition of elemental sulphur, reduces the elution rate and efficiency dramatically. This is probably due to the formation of complexes such as AUS-3 and AUS-2 , which have a high adsorption affinity.

Jan 1, 1994

By Che Xin, Liu Tianlong, Bi Hongyun, Chen Lijia

"High-cycle fatigue experiments were conducted at 800°C in laboratory air for three ferrite stainless steels including 15CrNbTi, 15CrMoNbTi and 18CrNbTi, where the stress ratio of 0.l was adopted. The experimental results show that at 800°C, the fatigue limit of the 15CrMoNbTi steel is the highest, the fatigue limit of the 15CrNbTi steel is slightly lower than that of the 15CrMoNbTi steel, and the fatigue limit of the 18CrNbTi steel is the lowest. At the same maximum stress, the 15CrMoNbTi steel has longer fatigue lives than the 15CrNbTi steel in the low stress area, while the 18CrNbTi steel has the shortest fatigue life. In addition, the observations on the fracture surfaces of fatigue specimens reveal that the fatigue cracks initiate transgranularly at the free surface of the specimens and propagate in a transgranular mode.IntroductionIn modem automotive industry, the manufacturers have paid great efforts to clean exhaust gas and to improve fuel economy. It is thought an effective way to increase the temperature of combustion chamber in automotive engine. And thus, the manifold closed to the engine in automotive exhaust system can suffer high temperature up to approximately 1000°C. Because of their relatively low thermal expansion coefficient, high yield strength at elevated temperature and good fatigue resistance, ferrite stainless steels, especially added with alloying elements such as Mo, Nb and Ti, are increasingly used for automotive exhaust systems [1-3]. In fact, exhaust manifold operated under high frequency vibration and exposed to high temperature exhausting gas also requires good fatigue resistance at elevated temperature. Some studies on the high temperature fatigue characteristics of stainless steel have been documented. It has beeen found that the fatigue limit of four ferrite stainless steels including 409L, 436L, 429EM and 444 (18Cr- 2Mo) reduces significantly with increasing temperature [4, 5]. In the research concerning the effect of a-phase embrittlement on fatigue behavior in a high-chromium ferrite stainless steel, it is noted that the precipitation of brittle a-phase will reduce the crack initiation and growth resistances and result in a decrease in fatigue limit [6]. In this investigation, the high-cycle fatigue behavior of three ferrite stainless steels including 18CrNbTi, 15CrNbTi and 15CrMoNbTi at 800°C have been studied to address the mechanical aspect of high-cycle fatigue behavior for ferrite stainless steels and to provide the theoretical reference for the safe design of automotive exhaust system."

Jan 1, 2013

The face of project evaluation is changing continuously, making it ever more critical to get a clear understanding upfront of the objectives, decision-making processes and criteria of the project proponents. Requirements are usually significantly different for emerging æjuniorsÆ compared with long established major mining houses and companies in developing countries compared with western companies. Requirements are also different for different types of evaluations, such as due diligence studies compared with feasibility studies of æownedÆ projects and there are often key misunderstandings around the use of the term æbankableÆ. Further, it has become increasingly important with increasingly remote and lower quality resources to understand risk relativities such as infrastructure compared with the core processing facilities. This has also driven the need for more trade-off studies to determine the best balance between critical issues, such as optimisation of the interface between mine and processing plant, capital versus operating cost and automation versus labour. In every project evaluation, it is also critical to consider emerging trends and changing requirements and standards such as sustainability and community interface. Finally, the inescapable drive to reduce time to market has driven changes such as increased use of more standardised designs and innovative approaches to the transition from project development to execution. This paper begins with a brief review of the different objectives and risks of each project development stage to establish a framework for subsequent discussion of the different requirements of different types of companies in different locations, different types of evaluations and different types of projects and project components. This is followed by a review of changing requirements and standards and some innovative developments in sustainability and community interface are presented. Finally, the paper outlines a number of developments in the area of operational readiness planning that focus on minimising the time to achieve maximum return on investment.

Jan 1, 2009

By M. Cambridge

The extractive industries are currently, and will continue to be, major contributors to the world economy, particularly in the developing world where economic growth is dependent upon a sound supply of primary materials. However, tailings dam and other mine failures have been very much a feature of recent anti-mining publicity, particularly in Europe, and thus instrumental in inhibiting new mine developments. Although, superficially, the record of dangerous incidents might support the anti-mining position, closer inspection suggests otherwise. This paper reviews the failures which have occurred over the last 50 years and demonstrates that, though poor practice is an ongoing problem for the industry, the record is one of improvement in both design and practice. Examples are provided of significant events which have led to dramatic advances in design and operation. The paper assesses the improvements made in technology and practice, and concludes that historic events must continue to form the underlying basis for design and operation of future mining projects.

Jan 1, 2005

By Jonguk Kim

Hydrothermal sulfides were recovered from the16°50?S triple junction area in the North Fiji Basin, at a water depth of ca. 1900 m. The chimney samples can be divided into three groups according to their major metal contents: 1) type 1 (Fe-Cu-rich), 2) type 2 (Fe-Cu-rich with minor Zn), and 3) type 3 (Zn-rich) chimneys. Type 1 chimneys are mainly composed of chalcopyrite and pyrite, and are enriched in elements commonly precipitated under high temperature conditions (> 300°C), such as Cu, Co, Mo, and Se. Type 3 chimneys consist dominantly of sphalerite and marcasite with traces of pyrite and chalcopyrite, and are enriched in elements commonly associated with low temperature (150 to 250°C), such as Zn, Cd, Pb, As, and Ga. Type 2 chimneys show mineralogy similar to that of type 1 chimneys but their metal contents range between type 1 and type 3 samples. Trace element compositions of basaltic rocks indicate that magma generation in the triple junction area was influenced by two different sources: N-MORB and E-MORB. Sulfur and lead isotope patterns of the hydrothermal chimneys show distinct differences between the type 1 and type 3 chimneys. For example, type 1 sulfides are depleted in 34S and have lower Pb isotope ratios compared to type 2 and 3 chimneys. The d34S values (0.4 to 5.6?) of chimney sulfides are typical range of sulfur isotope composition of sediment free mid-ocean ridge hydrothermal system. Type 2 and 3 sulfides show slightly higher d34S values than type 1 sulfides, which can be explained by subsurface boiling of hydrothermal fluids followed by mixing of saline solutions with ambient seawater. Lead isotope compositions of the chimneys indicate that the Pb in type 1 and type 3 chimneys originates from hydrothermal leaching of N-MORB and E-MORB volcanic rocks, respectively. Considering that both these chimneys are located in the same area, our model suggests that type 1 chimneys formed by hydrothermal circulation controlled by an intrusion of N-MORB magma; the fluids were not influenced by boiling during the formation of type 1 chimneys. In contrast, type 3 chimneys are younger and were formed by hydrothermal circulation closely related to E-MORB magma intrusion at shallower depth. The necessary conditions for phase separation of the hydrothermal fluids that formed the type 3 chimneys might result from changed P-T conditions in a shallower high-temperature reaction zone beneath the hydrothermal venting site. Under these conditions the fluid may cross the two-phase boundary for seawater, ensuring subcritical phase separation. The mineralogical and geochemical properties of these chimneys suggest that type 1 and type 3 chimneys were probably black smoker and white smoker, respectively. Type 2 chimneys might be product of low-temperature replacement of type 1 chimneys, which is related to formation of type 3 chimneys.

Jan 1, 2005

By V. J. Lynch, A. L. Peyton

"INTRODUCTION AND SUMMARYThe Brewer mine, near Jefferson, Chesterfield County, S.C., was originally operated as a gold mines as late as 1890 this mine was reported to have been one of the large gold producers in the southeast,Occurrence of topaz on the Brewer property was not reported until 1935, when it was discovered by Pardee and Parks. 3/ of the Federal Geological Survey while they were investigating gold deposits in the Piedmont province.During the 1940's the Chemical Engineering Branch of the Tennessee Valley Authority and the Electrotecbnical Laboratory of the Bureau of Mines at Norris, Tenn., investigated topaz from the Brewer mine to determine the possibilities of its use as mullite and for the production of calcium fluoride.From July 1950 through. April 1951 the Bureau of Mines conducted a diamond-drilling project at the Brewer mine to determine the grade and extent of the topaz deposits. Ten diamond-drill holes, totaling 2,344 feet, were completed, and 231 analyses of core samples were made during the course of the project.This report presents factual data relating only to the diamond-drilling project, The placer deposits on the Brewer property were previously investigated by the Federal Geological Survey 4/."

Aug 1, 1953

By E S. Souza, H Delboni Jr, M F. Calixto

This paper aims at presenting the results of laboratory, pilot plant and simulation studies for the design of the grinding circuit for the beneficiation of compact itabirites from the Conceitpo mine. Two alternatives were investigated, both utilising the current crushing circuit up to tertiary crushing. Under alternative #1, quaternary crushing was considered to produce the feed of the ball mill; under alternative #2, high pressure grinding rolls were selected to prepare the ball mill circuit feed. Pilot scale studies pointed towards the use of high pressure grinding rolls (HPGR). The circuit design was based on a throughput of 720 t/h, representing a nominal solids flow rate of 600 t/h, considering a design factor of 1.2, and P80 of 95 ¦m.

Jan 1, 2007

By Tadashi Nishida

Subsidence due to mining caused various kinds of damage to the surface structures, and actually great deal of mining damage becomes the severe social problem at some time in many coal fields, but the most of mining damage was restored at present. Recently, the effect of old coal working on the deformation of newly constructed structures has become into question, because it was obliged to plan many engineering structures in old mining areas for the shortage of adequate construction sites and the difficulty of getting location. That is, building, dams, bridges for railroads and highway, power plants, tunnels, storage tanks and so, have to be built on the ground which has old coal working.

Jan 1, 1982

By M. Y. Wong

Electronic detonators have been used on a trial basis for over a decade, and found more recent application in production blasting as well. The relative merits of these detonators and their applicability are outlined through examples from actual blasting operations. They offer unprecedented flexibility in the design of mass blasts and in control of vibration and blast-induced damage. However, the drive towards replacing the pyrotechnic detonators by electronic ones in general could prove to be counter productive without a re-examination of prevailing blasting practices. In fact, such an approach tends to blur the tremendous potential of the electronic detonators in redefining many standard blast designs and practices.

Jan 1, 2004

By C. O. Browner

Dados los altos costos que implican la explotación de una mina a tajo abierto, se ha previsto excavar los taludes de las minas lo más erguidos posible. En este sentido, el objetivo del texto describe los métodos actuales para evaluar la estabilidad de los taludes en roca. Para ello, se revisa la influencia de las estructuras rocosas, el agua subterránea y la voladura sobre la estabilidad de los taludes de los tajos. Asimismo, se consideran las condiciones de roca intemperizadas, las lluvias y los temblores presentados en algunas áreas del Perú. Producto de esta revisión, se analizará los problemas típicos de estabilidad para diversos proyectos mineros.

Nov 20, 1972

By L. C. George

The Bureau of Mines measured the vapor pressures of selected mixtures in the binary systems CdCl2 ?SnCl2, CdCl2 -ZnC12, PbCl2 ?SnCl2, and PbCl2 -ZnCl2 by the static pressure method. These data were evaluated by the second-law (sigma-plot) method. Equations expressing the vapor pressures and the heats and free energies of vaporization as functions of temperature are given.

Jan 1, 1969

By Judith A. Eisele

The possibility of improving the volatilization of gold through the formation of a metal-gold chloride vapor complex was investigated. Gold-silica mixtures, containing ferrous and nonferrous minerals and salts as additives, were treated in a laboratory tube furnace with a flow of chlorine gas at various temperatures. The addition of pyrite (FeS2) to a charge of gold-silica increased the volatility of the gold from 3, 20, and 62 percent of the total gold to 62, 93, and 100 percent at 200°, 300°, and 400° C, respectively. Chemical analyses of the condensate indicated the volatile species to be FeAuCl6.

Jan 1, 1971

By Ted M. Noskiewicz, James A. Ramsay

INTRODUCTION During the various stages of an underground project from inception through design and construction, probably the single factor of most interest and concern is the nature of the ground. The ground conditions more than any other item govern costs and feasibility; and although the methods available for assessing the ground have become increasingly reliable during the past thirty years, it is still very difficult in many cases to predict the behaviour of soil and rock during and after excavation. To help in this ground evaluation process, we have frequently supplemented the boring program with one or more large diameter inspection holes; and during the past eighteen years, seventeen of these holes have been constructed on tunnel projects which we have designed. There are references in the literature to similar inspection holes (1); however, as far as we are aware, no detailed description of them has been published. The behaviour of soil or rock during and after excavation and the effect of ground water on tunneling operations are of vital interest to tunnel designers and contractors. A comprehensive geotechnical investigation is therefore among the early and most important tasks carried out on a tunnel project and the backbone of every geotechnical investigation is the boring program. A series of borings, typically 50 to 100 mm (21 to 4 in) diameter, are drilled from which soil samples or rock core are recovered and the ground water observed.

Jan 1, 1979

By J. H. Jones

The original term of grant No. 1115174 was September 1980 through December 1983. An extended progress report, covering this time period, was forwarded to the Bureau of Hines in January 1984. The principal investigators were given a no-cost extension of their grant to cover the period January through December 1984. The report which follows covers this latter time period only.

Jan 1, 1985

In early-1989, subsidence due to voids at the top of previously filled stopes and stopes awaiting filling,began to threaten the 15 level fill conveyor horizon. This together with the need to maintain production targets meant that a method was required to significantly increase fill placement.Alternative methods of placing dry fill underground were investigated. One option was to drill 200 mm boreholes from surface directly into stopes 600 - 800 metres underground. A drilling program was successfully undertaken, and resulted in the placement of more than 800 000 tonnes of dry aggregate fill via four boreholes.This paper details the drilling program undertaken and discusses the difficulties encountered, the fill placement system and the project costs.

Jan 1, 1992

By R. T. White

The usual figures quoted for water usage in South African gold mines are 1 ton of water used per ton of rock broken, which represents a consumption of 4000 litres of water every second. Owing to the limited sources under ground water, the high cost of surface-water supplies, and the environmental problems of effluent disposal, water IS recycled continuously for underground use. This paper reviews the various types of water treatment and why water needs to be treated. The uses of lime and some flocculants are considered, since much of the mine service water requires only simple neutralization and clarification. Where mining depths necessitate the installation of underground refrigeration plant, more stringent water requirements must be met, and where plant performance is to be maintained, the prevention of system scaling and corrosion is necessary. The families of chemicals added to provide such protection are outlined, together with a description of the mechanisms of control.

Jan 1, 1985

By J. M. Carr

The history, geological setting and local geology of the Magnum vein system, 100 miles west of Fort Nelson in northeastern British Columbia, are described. The system comprises a number of quartz-ankerite veins, mineralized with chalcopyrite and lesser pyrite, occurring in a steep northeastly zone of deformation and subsequent dike intrusion within otherwise little-deformed Precambrian sedimentary rocks. In April of 1970, Churchill Copper Corporation began producing copper concentrates in a 750-tpd mill fed from the Magnum mine.

Jan 1, 1971

By H. H. Hughes, J. G. Dunn, P. G. Fernandez, H. G. Linge

Dissolved Arsenic (As) is stabilised primarily as As(III) and As(V) and enters ground water streams from sources such as the increasing metallurgical processing of As - containing ores [1]. As(III) is more toxic than As(V) and is less effectively removed from solution by oxide precipitation. Even for dilute As(III) solutions, skin contact or ingestion can cause dermatitis or cancer and there are stringent effluent control standards in place for As containing effluent from mining operations [2]. Chemtronics (Perth, Australia) has manufactured a compact digital voltamme­ter, based on anodic stripping voltammetry (ASV) and suitable for use in the laboratory or field. In this paper we demonstrate the utility of this equipment for measuring As(III) concentration with a detection limit of ca. 10 ppb.

Jan 1, 1995

By J. W. Lacey, F. H. Brinkman, J. E. Faris

This paper presents an analysis of the high-pressure, gas-driven LPG-slug process, based on fluid flow tests in areal models. Two types of tests were made. One series was made in low-pressure models which permitted observation of fluid movement. Three completely misci-ble analog fluids were used. A second series of tests was made in high-pressure models using methane, propane and a light refined oil saturated with methane at room temperature and 1,550 psig. Under the test conditions of room temperature and a pressure level of 1,550 psig, the phase diagram for the fluids used is similar to those for many of the field systems where the process is considered for use. A method for using these laboratory data to calculate field performance of the process is outlined. As a result of this work, it is concluded that small banks of LPG (5 per cent HV or less) are not effective in increasing oil recovery in horizontal reservoirs. Znstead, where small banks are used, the driving gas quickly penetrates the LPG bank because of fingering and channeling; and from this point on, the process behaves essentially as an immiscible gas-injection project. The validity of this conclusion was substantiated by: (1) laboratory studies of the effect of rate, model size and mobility ratio on miscible displacement in areal models; and (2) calculation of field recovery, which compared closely with actual field recovery. INTRODUCTION Field applications and pilot tests of the gas-driven, LPG-bank, oil-recovery process are on the increase. Most of these tests are employing small banks (2% to 5 per cent hydrocarbon volume) of LPG, which is miscible with both the driving gas and the oil in place, in an effort to attain an effective yet economical miscible displacement of oil by gas. The expectation of miscible displacement with small banks is based on the concepts that: (1) lengths of solvent-oil mixed zones, measured during miscible displacements in long slim cores, are representative of those that will occur in the field; and (2) areal sweep efficiencies5 measured in electrolytic model studies are applicable to miscible displacement in reservoirs. Our experimental evidence indicates that the mixed-zone lengths and sweep efficiencies mentioned are not applicable to miscible displacement in reservoirs. In this paper we present an evaluation of the gas-driven, LPG-bank oil-recovery process based on fluid flow experiments in areal models. These results are used to predict the performance of a field pilot test of this process, and the results are compared with the actual test results. THE EFFECTIVENESS OF LPG BANKS The effectiveness of LPG banks of various sizes in accomplishing miscible displacement of oil by gas was determined by displacement tests in a model representing one-quarter of a confined five-spot pattern. The model, 12 X 12 X 1/4 in. in size, was packed uniformly with glass beads. It was operated at a pressure of 1,550 psig and at room temperature; the fluids used were methane, propane and refined oil saturated with methane at 1,550 psig. The saturated oil had a viscosity of 1.2 cp at room temperature. The results of these tests are shown in Fig. 1, where recovery is plotted as a function of the volume of fluid injected for: (1) an immiscible-gas drive with an oil-to-gas viscosity ratio of 85; (2) three sizes of LPG banks; and (3) two completely miscible displacements with mobility ratios of 85:1 and 10:1. (The miscible displacement data plotted are the averages of several tests.) The results show that a 2½ per cent bank of LPG does not increase oil recovery over that obtained by immiscible-gas drive. The 7 and 17 per cent banks are, respectively, about 30 and 50 per cent effective (with reference to the M = 85 miscible-displacement curve) in increasing oil recovery at the point where 2½ hydrocarbon volumes (HV) of fluid have been injected. The percentage effectiveness of the banks at a given volume of fluid injected is defined as Recovery by Bank — Recovery by Gas Drive Recovery by Miscible Recovery by Flooding Gas Drive We conclude from these results that banks of LPG smaller than about 5 per cent HV in an individual stratum will cause from little to no increase in oil recovery. This finding was substantiated by work in low-pressure models, which permitted visual observation of fluid movements. In these tests, three completely miscible fluids having the same viscosity ratios as those used in