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Standard petrographic profiles for many Permian seams from New South Wales and Queensland have been drawn up. The standard profiles of seams of the same age and from one or more coalfields were used to compile an idealized or type seam sequence for those coals in which more than half the seam profiles were similar to one another. A marked similarity existed between at least 7 of the 10 type seam sequences formed. The configurations of the vitrite-plus-clarite contents of the plies of 95 per cent of the seams could be formed from different arrangements of 3 basic sequences: (i) a two-ply sequence with a lower vitrite-rich and an upper vitrite-poor ply; (ii) a two-ply sequence with a lower vitrite-poor and an upper vitrite-rich ply; and (iii) a four-ply sequence of 3 plies with vitrite-plus- clarite decreasing upwards, terminating in a vitrite- rich ply. The third basic sequence was very similar to a succession described for some British Carboniferous coals. Eighty per cent of the Australian Permian coal seams studied began with the first (i) basic type of sequence and are interpreted as originating in peat- forming areas which became progressively drier. More than half the seams were formed in an area with a stable depositional surface level which was subject to oscillations of small amplitude.. Many (30%) were formed in an area with a steadily rising depositional surface level.

Jan 1, 1969

By N Esmaeili, M Saghaeian, L Hosseini, V Sheikhzadeh, R Hejazi

Ore roasting has long been used for beneficiation and assay upgrading of different ores. In this process, which is mainly used for sulfide ores, the ore is heated to a high temperature. More specifically, it is a metallurgical process involving gas-solid reactions at elevated temperatures. Some types of Iron ore are weak in magnetic properties. Hematite, goethite and limonite are classified in this group. Unlike magnetite, which shows strong magnetic susceptibility, these ores are hard to beneficiate through magnetic separation route. Many researches have focused on gravity separation and flotation routes for upgrading these ores and these methods have also been utilised in the industry. One of the methods to whose industrial application less attention has been paid is magnetising roasting in which the non-magnetic iron ore is transformed to magnetite which is further beneficiated through magnetic separation. In this study, magnetising roasting tests have been performed on one goethite sample in order to check the feasibility of using this method for this specific ore in industrial scale. It is worth mentioning that high intensity magnetic separation have been performed on this sample before but the achieved results were not promising. Results have revealed that through magnetising roasting magnetite content of the ore could be increased from 1.7 per cent up to about 25 per cent. FeO content of the feed sample was increased from 1.03 per cent up to around 9.25 per cent. Also optimum size distribution for achieving the best results in magnetising roasting for this sample has been determined through this study. The best results were achieved when the ore size was 0–10 mm. The effect of coal ratio, time and temperature on the process have also be studied. A coal ratio of 5 per cent, time of 30 min and a temperature of 850°C were determined to be the optimum conditions. Finally, the technical feasibility of utilising magnetising roasting for this specific ore has been confirmed.

Aug 24, 2022

By A. F. Spinks, S. P. Nicholls

"The Lower Orebody at Chingola Division of Nchanga Consolidated Copper Mines, Limited, is a stratified orebody that is mined by a continuous caving system. The accurate determination of the developed and semi-developed ore reserves has always been difficult. The new system proposed in 1971 is designed to update and, as new informa¬tion becomes available, to account for the depletion of, the reserves.There are three main inputs to the system. These are borehole data, survey data and extractions data. The borehole data are input to a geological borehole master file system, which holds every recorded detail of a borehole in an easily extractable form. These data can be extracted for ore reserve calculations or for contour mapping of orebodies and rock types. The grades for use in the ore reserve calculations are extracted from the relevant boreholes.The survey data are information on the position of the blocks and drifts, taken from plans, and information on the scraper drift and trough drive positions taken from sections. The information is extracted from the plans and sections using a D Mac pencil follower. The ore reserve is calculated from the survey data and the borehole data.Data on extractions are taken from scraper operators' logs, tramming records, skips hoisted records and accepted mill tonnages and grades. Using these data, the mill tonnages are reconciled back to the drifts, to deplete the current ore reserves.As new workings are brought into operation and further evaluation holes are drilled, the relevant data are input and the new developed ore reserve is calculated."

Jan 1, 2014

By Vsevolod Krivobok

IT is generally recognized that "low temperatures" have a definite effect on the properties of metals and alloys. Furthermore, it is also generally understood that the effect is decidedly adverse. The possibility that the same low-temperature treatment might be employed for the purpose of improving certain properties of the .alloys has received less attention until recently, and the experimental and theoretical knowledge consequently is meager. The effect of low temperatures may be studied in two ways: by studying such properties as tensile strength, hardness, impact resistance, etc., at low temperature, and by studying the properties of alloys at room temperature after these alloys have been subjected to a low-temperature treatment. Even in the latter case, certain properties will differ materially from the same properties obtained on identical material but without cold treatment. In other words, subjecting alloys to cold treatment results in an irreversible change in mechanical properties. Changes of this character are usually indications of the appearance of a new phase or phases, and would be likely to occur in alloys which, either by virtue of their composition or by heat treatment, are retained at room temperature in a metastable condition. Consequently, studies of the effect of low temperatures logically should be conducted from the physicochemical point of view, since the results of such studies not only would furnish metallurgists with interesting theoretical data but would clearly indicate the classes of alloys that would hold promise of improvement, and, possibly, of new applications. As the present investigation deals with chromium and chromium-nickel alloys of iron of the stainless variety, it has been thought desirable to present the data concerning low-temperature properties of these alloys, available from the most recent and most comprehensive work of H: S. Russell.' A summary, of these data is given in Table 1. The data are confined to a limited number of alloys of the type dealt with in the present

Jan 1, 1931

By R. L. Wilcox, M. L. Fuller

Most commercial alloys undergo changes in phase composition after casting. This is a natural result of the fact that the alloys are not in a state of phase equilibrium as cast and phase changes will therefore take place, with more or less rapidity, in an attempt to attain equilibrium. The practical aspect of aging in zinc-Alloy die castings concerns the changes in physical properties and in dimensions that may accompany aging phase changes. Harmful alterations have been reduced to a minimum and zinc-alloy die castings are being produced today that are so stable with respect to dimensions and physical properties that they are entirely suitable for most practical purposes1. In the first paper2 of this series, and in this paper, aging phase changes of zinc-alloy die castings have been investigated and the possible influence of these changes on dimensional changes of the castings has been evaluated and compared with the dimensional changes actually experienced. The change of dimensions has been selected for practical comparison in these papers because the effect of phase changes on the dimensions of a casting is directly calculable from X-ray crystal-analysis data of the phase structure. The die-casting alloys considered contain, in addition to zinc, 4 per cent of aluminum, about 0.03 per cent magnesium, and from 0 to 3 per cent of copper. It was shown in the former paper that the eutectoidal decomposition of the beta aluminum-zinc phase, while intrinsically capable of causing a considerable shrinkage, can have very little effect on the observed shrinkage of die castings because it takes place within a few days of aging, whereas the observed shrinkage continues for five weeks. It was therefore concluded that the other existing phase change, namely, the segregation of secondary phase from the zinc-base solid solution, must account for the major portion of the shrinkage.

Jan 1, 1936

By Graham J

The successful processing of arsenopyritic ores is difficult and will be facilitated by a better understanding of the mineralogy of gold within arsenopyrite and the type of arsenopyrite in which gold is taken up. Solid solution gold in arsenopyrite is now well documented, and is a significant cause of refractory behaviour in gold processing. Investigations of the crystal structure and stoichiometry of arsenopyrite by X-ray diffraction, electron microprobe analysis and convergent beam electron microscopy have been carried out in order to understand how the gold is incorporated into the structure. Variations in stoichiometry, particularly the As:S ratio, of arsenopyrite leads to variations in structural parameters. These variations result in slight changes in thermal behaviour. The distribution of invisible gold in an arsenopyrite grain is generally non-uniform and synthesised samples contain up to 2 wt per cent gold. A transmission electron microscopy (TEM) technique called ALCHEMI is being used to identify the substitution site. The process of gold agglomeration together with evidence of an ordered breakdown of arsenopyrite to pyrrhotite has been documented with the use of TEM. An arsenopyrite grain containing invisible gold was heated with an electron beam resulting in recrystallisation of arsenopyrite to pyrrhotite with arsenic being expelled. The gold is mostly insoluble in the pyrrhotite lattice and therefore exsolves out and combines with other gold atoms to form droplets at the boundary of the pyrrhotite.

Jan 1, 1992

By D. L. Albright, G. A. Colligan

An investigation has been conducted to determine the nature of the crystallographic substructure of nickel and a 1.0 wt pct Ag-Ni alloy which had been undercooled 105°C prior to solidification. A rotating back-reflection X-ray technique and modified Weissmann diffractometer were used to orient single-crystal sections from these poly-crystalline ingots and to determine the substruc-tural features of these single crystals, The sub-grain size in the pure nickel ingot is 0.5 mm diam while the silver-doped nickel subgrain size is only 0.1 mm diam. The misorientation between adjacent subgrains is approximately 1 deg of arc in both ingots, and the spread of orientation of sub-grains about the mean orientation of the crystal is 5 deg of arc in both ingots. The addition of silver results in a stable impurity substructure which is preserved during isothermal solidification and subsequent cooling to room temperature. In the absence of silver the initial impurity substructure is destroyed by dislocation interactions which produce a secondary substructure which grows to a size five times larger than the initial substructure. THE process of undercooling a metal entails cooling of the molten sample below the equilibrium freezing point without the occurrence of solidification, i.e., by exercising proper constraint over the experimental variables contributing to nucleation in the melt. The current work of walker1 and Colligan Metal reports undercooling large continuous samples of nickel by imposing appropriate restrictions upon the parameters of solidification. The silver-nickel equilibrium diagram3 reveals the presence of a monotectic reaction at 1435°C. At this temperature the maximum solid solubility of silver in nickel is approximately 3 wt pct, but this solubility decreases with decreasing temperature and the solute is rejected as a silver-rich liquid phase at temperatures below 1435°C. Thus, the 1.0 wt pct solute should be held in solution during undercooling and solidification and subsequently precipitate as a silver-rich liquid phase at grain and subgrain boundaries following solidification during cooling below 1435. This assumes no solute segregation sufficient to cause the monotectic reaction. One would expect this second phase to inhibit grain and subgrain growth by retarding dislocation motion after solidification is complete. The effectiveness of silver addition in growth retardation of high-angle grain boundaries has been demonstrated by Colligan and suprenantS4 The principal [l00] dendrite growth directions in a 2 wt pct Ag-Ni alloy undercooled 53 all radiated from the nucleation site. A similar pure nickel ingot undercooled 59°C exhibited a random orientation of [l00] dendrite directions with respect to the nucleation site. Since undoped nickel ingots do not retain any evidence of the casting or solidification texture and silver-doped ingots do retain this texture, it is reasonable to assume that considerable grain growth has taken place in the pure nickel. These particular experiments were performed in order to reveal the differences, if any, in the features of the crystallographic substructure of undoped undercooled nickel and silver-doped undercooled nickel. 1) EXPERIMENTAL PROCEDURE Data are reported on selected specimens from two massive (approximately 260 g) undercooled ingots of nickel. One ingot consisted of electrolytic nickel and the other of this same material with 1.0 wt pct addition of high-purity silver. Powder patterns were taken of both the as-received and as-solidified materials; in all cases the reflections recorded were attributable to the individual elements nickel and/or silver. Fig. 1 is a. schematic diagram of the apparatus employed for the undercooling experiments. The equipment consists in part of a fused silica crucible for containing the charge. A fused silica tube encloses the system, which is covered by a brass cap to permit partial sealing of the inert atmosphere. This cap contains a hole through which a Pt-Pt 13 pct Rh thermocouple is inserted for temperature measurement. The charge is inductively heated under a purified argon atmosphere.

Jan 1, 1963

By F. P. Haver

The Bureau of Mines developed a process to extract about 90 percent of the sulfur from molybdenite flotation concentrate by compacting the concentrate with one-quarter of its weight of aluminum powder, heating it at 800° C for 30 minutes, and then allowing the product to react with water. This thermite reduction yields an impure molybdenum alloy plus aluminum sulfide. The latter readily hydrolyzes, to yield pure hydrogen sulfide which can be converted to elemental sulfur by the Claus process. At least 95 percent of the molybdenum can be subsequently recovered as 99.95-percent-pure molybdic oxide.

Jan 1, 1968

By Gerald I. Finfinger

Identifying the properties of overlying rocks in underground mining operations is important to ensure the appropriate roof support design is used to maintain stability of the mine entries. Recently J. H. Fletcher & Co. developed a monitoring and control system for roof bolters for the underground mining industry. The system records the drilling parameters used during roof bolt drilling and the information can provide insight into the physical properties of the roof strata. The parameters include thrust, rotational speed, torque and velocity and the measurements are collected every 0.1 second during the operation. The drilling parameters were analyzed to determine the application of identifying the strength of rocks being drilled from the measurements. The data was converted into the specific energy of drilling which is a measure of the amount of energy required for removing a given unit of rock during a drilling operation. The laboratory studies completed to date indicate a fairly high correlation between the specific energy of drilling and the unconfined compressive strength of the rocks that were drilled. Additionally, the drilling parameters were shown to be effective for identifying the presence of fractures or bed separations between rock ]avers. The thrust, torque and specific energy of drilling were all good indicators for identifying the fractures or separations. Regardless of the drilling parameters used during the drilling experiments, the location of the fractures were identified, In order to determine the application of the drilling parameters for identifying rout rock properties, two series of experiments were conducted. The first series of experiments used three "manufactured" roof layers that had various rock samples embedded in concrete blocks. The rock samples included three types of sandstone, marble. and argillite. Another concrete block was poured with foam inserts to simulate large bedding separations (2 to 8-in). Two other manufactured blocks were constructed using high-strength concrete with cardboard layers embedded to simulate smaller fractures or bedding separations. The size of the cardboard layers varied from 1/8- to 1-in thick. One of the blocks had the cardboard layers embedded at an inclined angle to determine the effect of the orientation or, the drilling parameters. A series of experiments was conducted with the rotational speed and the penetration rate held constant and the thrust and torque allowed to vary. The information collected from the experiments is used to determine the application of the drilling parameter measurements for identifying rock properties, fractures and bedding separations.

Jan 1, 2000

By Jalna R. Zatko

The Bureau of Mines, U.S. Department of the Interior, has developed a novel method of flocculation dewatering of phosphatic clay wastes using polyethylene oxide as the flocculant. Research was conducted to determine whether ethylene oxide gas was present in the air in the vicinity of disposed waste materials which had been flocculated with polyethylene oxide. Samples of clay waste materials containing polyethylene oxide were prepared in stoppered glass bottles in simulated disposal environments. Gaseous samples, removed over a 75-day period using an airtight syringe, were injected into a gas chromatograph that was capable of separating ethylene oxide from air. The presence of ethylene oxide gas was not detected in any sample. To determine possible degradation products of polyethylene oxide, the properties and reactions of ethylene oxide and its polymers were reviewed. Based upon the literature survey and experimental study, it was concluded that adverse environmental effects were not likely to result from the use of polyethylene oxide for flocculating phosphatic clay waste products.

Jan 1, 1980

Operating and Social Considerations from a Contractor?s Perspective

May 1, 2013

By Roberto Palacios, José Morán, Cristian Fernández

El presente trabajo cuenta con la experiencia, metodología y tecnología desarrollada en minera aurífera retamas frente al problema de la sismicidad inducida por el minado y los controles estratégicos y tácticos a seguir para reducir los eventos microsísmicos y dar sostenibilidad a las operaciones mineras, priorizando la seguridad de nuestros colaboradores e infraestructuras de la mina. En este trabajo, se muestra la metodología y controles de mitigación que se utilizan para reducir los incidentes por impacto de los eventos microsísmicos en las operaciones mineras. Haciendo una mina segura y sostenible.

Sep 29, 2023

By G. M. T. Marshall

Plans to bring the Geco Mines property in Manitouwadge, Ont., into production began in 1954. At that time over 12 million tons of copper-zinc ore were indicated in a zone 2700 ft long. A concentrating plant was built to handle 3300 tpd of ore and a production shaft was sunk about 1500 ft. MINE LAYOUT Vertical attitude, width, rake, and competent country rock of a 4-million ton orebody west of the main diabase dike suggested a system of blasthole stopes, undercut with scram drifts connected by a transfer raise system to a crusher on the 1250-ft level and this system was employed. A 42-in. conveyor on this level transfers the ore about 1200 ft to a loading pocket at the No. 1 shaft. The system has a number of advantages: 1) Cost of tramming is eliminated. 2) Rate of extraction from any stope is controlled only by the scraping capacity of the scram. 3) Rate of extraction from the stoping area can be very rapid. Fast extraction makes it possible to cut mining costs for the following reasons: The number of stopes actively producing is kept to an economical minimum; the operating area is concentrated-manpower can be used more effectively; and active life of the stoping block is short, making ground support problems simpler and less costly.

Jan 8, 1959

By John S. Berber

Bureau of Mines research on the production of phthalic anhydride by vapor phase oxidation of hydrocarbons began at Morgantown, W. Va., in October 1960. For these preliminary studies, a known solution containing naphthalene and 1-methylnaphthalene was used. In another series of tests, pure naphthalene was dissolved in different solvents. A series of investigations was conducted with the neutral oil fraction (210° to 270° C) of a low-temperature tar obtained from the Texas Power and Light Company's low-temperature carbonization unit. The neutral oil fraction was first dealkylated, and then the product was distilled into 210° to 250° C and 250° to 270° C fractions. These two fractions were then subjected to catalytic vapor phase oxidation. Although a number of catalysts was tested, most of the experiments were made using 9 percent vanadium pentoxide on inert alumina. The activity of this catalyst did not decrease after 162 hours at 1,030° F. Studies were conducted over a temperature range from 610° to 1,180° F. An operating temperature of 1,030° F yielded 47.50 percent of phthalic anhydride from a synthetic mixture of naphthalene and 1-methylnaphthalene. The highest yield (84.40 percent phthalic anhydride) was obtained with naphthalene dissolved in toluene and also with naphthalene dissolved in methyl ethyl ketone. With a 210° to 250° C fraction the highest yield of phthalic anhydride obtained was 12.32 percent at a temperature of 900° F, and, with a 250° to 270° C fraction, it was 15.80 percent at a temperature of 875° F.

Jan 1, 1963

By S. Chander

Neutralization of acidity by addition of alkaline materials is a commonly used method to treat acid mine drainage. However, this procedure requires large amounts of reagents based on acid-base accounting. The potential use of organic additives in preventing or ameliorating acid mine drainage was investigated in this research. The tests were conducted in weathering columns using refuse samples from a coal cleaning plant. Both cationic and anionic compounds were tested. For a comparison, tests were made in the presence of limestone and lime. The results show that some of the reagents substantially retarded the rate of oxidation whereas others even enhanced it. The suppression of the rate of pyrite oxidation was ascribed to surface chelation. Formation of surface compounds prevented the pyrite particles from further oxidation. Such a treatment required only small quantities of reagents since the reaction was confined to the surface.

Jan 1, 1992

By J. J. Pye, J. B. Drew

The surface-diffusion coefficients of Ni63 diffusing on low-index planes of nickel single crystals have been measured over the temperature range from 400° to 1000°C using a precision autoradio-gvaphic technique. The activation energy for sur -face diffusion appears to he the same on the {111}, {110), and (100) planes and amounts to -0.60 ev. This is in good agreement with the value (-0.62 ev) reported for (111) planes obtained by mass-transport techniques. In an earlier paper, the authors have reported self surface-diffusion coefficients on silver.' In that work, a deviation of the diffusion coefficients from linearity in the Arrhenius plot was observed at high temperatures. This effect was attributed to a loss of tracer atoms into the bulk by volume diffusion. The purpose of the present work was to extend the technique developed to the nickel surface-diffusion system up to the point where volume diffusion would come into play. The nickel system especially lends itself to this technique due to the high efficiency of the isotope in darkening the film and the large absorption of the weak radiation (0.063 mev /3- particle of the trapped tracer atoms. The diffusion coefficients and ictivation energy for different orientations on nickel can also be compared with a report published by Blakely and Mykura 2 where a mass-transfer technique was used. This paper reports the self surface diffusion of nickel on the low-index planes over a wide temperature range using a precision autoradiographic technique. EXPERIMENTAL PROCEDURE The experiment is similar to that described in the earlier publication consisting of a radioactive needle as a source resting on a flat, smooth, chemically polished surface annealed in a dynamic dry-hydrogen atmosphere. The needle is held snugly on the surface by a holder fabricated from commercially pure nickel. The point source is made by grinding down a small-diameter nickel rod until a tip of approximately 0.1 mm radius is formed. It is then etched and the needle tip plated with the radioactive isotope Ni63. Nickel single crystals were used whose main impurities were spectrographically determined as Co 0.05, Fe 0.007, C 0.005, and S 0.003 pct. The surfaces, oriented to within 1/2 deg of the low-index planes, were carefully mechanically polished and etched in a 50-30-10-10 hot solution of acetic, nitric, sulfuric, and phosphoric acids giving a smooth polished surface. The crystals were then washed in distilled water and alcohol. Annealing temperatures ranged from 400° to 1000°C with a furnace arrangement in which the crystals could be brought up to temperature in times short compared to diffusing times. The temperature was maintained constant to ±10°C. In the temperature range investigated, the ratio of the surface-diffusion coefficient to the volume-diffusion coefficient (Ds/Du) was 105 or more and the mean bulk-penetration values, calculated from literature values of volume-diffusion coefficients,3 were on the order of 10-5 cm. After the diffusion anneal, the sintered needle is removed, and both the radius of the needle point and spot left on the crystal face are measured. The crystal is then placed on photographic film. Diffusion profiles are obtained by scanning the film with a recording microdensitometer which has a slit width of 10µ. DISCUSSION AND RESULTS The experimental conditions are such that the source strength and needle radius are essentially constant and the time is adjusted such that the mean bulk penetration is small. An exactly analogous heat-flow problem has been considered by Carslaw and Jaeger4 and the solution can be written in integral form as:

Jan 1, 1964

Without doubt Arizona was the scene of the first use of coal in North America, that by the Hopi Indians as early as the 10th century in burning their pottery and in heating their houses and kivas (ceremonial rooms). As has already been said this is the only use of coal by Indians of which we have any knowledge, but it has been well established through investigations conducted by the Peabody Museum of Archaeology and Ethnology of Harvard University. The apparatus for burning was crude, but they did have fireplaces and chimneys which would draw. The evidences of coal use were found in the Jeddito Valley, in Navajo County, during the excavation of the pueblo of Awatovi, only a short distance from the Keams Canon School. "Many fire pits and primitive stone stoves containing coal ash have been found in the houses, and in most of the kivas built between 1300 and 1600, two firepits have been found, one containing wood ash exclusively and the other coal ash."' The expedition of 1939 found that coal was used much earlier than this, as stated above. It is probable that these Indians were using coal regularly before it came into general use in England and northern Europe. Apparently the use of coal was largely stopped about the time the Spaniards came to that country. The ruins are located on the southern edge of the Black Mesa and the coal seams outcrop on the mesa edge below the ruins. "The coal occurs principally in one large seam which varies from a foot and a half to six feet in thickness."1 This coal is sub-bituminous and burns well, leaving a large percentage of white ash. Another seam is found about 40 ft. above this large seam; it is from six inches to a foot thick and burns to a red ash. Both of these seams were used and coal from the larger seam was used at other houses in the valley. The pottery was usually burned close to the coal seams, and the coal was used to obtain a uniform and satisfactory color. In the Jeddito Valley, the mining was done by stripping, and the methods used are described as follows by J. 0. Brew and John T. Hack, the investigators.

Jan 1, 1942

By W. H. Smith

IN the course of an investigation on chromium containing minor amounts of alloying elements, the information herein has been obtained on the crys-tallographic orientations resulting from arc melting, rolling, and annealing. The chromium used in this investigation was electrolytic flake obtained from the Electro Metallurgical Co. This material was heated for 20 hr at 1600°C in hydrogen with a dew point of about — 100°C. The oxygen and nitrogen content of the chromium after this treatment was 0.0003 pct 0 and 0.005 pct N. Five pounds of this chromium were arc melted in a water-cooled copper crucible. After arc melting, the oxygen and nitrogen contents were 0.002 and 0.025 pet, respectively. A section of this ingot is shown in Fig. 1. By means of a back-reflection Laue technique, the crystal habit of the cast ingot was determined. As expected, it was found that the [loo] was approximately the axis of the columnar grains. In this respect, chromium behaves like other body-centered-cubic metals in that a cubic axis is normal to the cold surface of the mold. A slab cut from this ingot was rolled at 600°C as follows: four 30 pct reductions were made with intermediate anneals at 1200°C for 15 min. Rolling was done with the [loo] of the columnar grains in the rolling direction. Following the final anneal, an 80 pct reduction was taken at 600 °C. The final sheet thickness was ten mils. By polishing and etching, the thickness was reduced to four mils and the grain orientation determined by the transmission Laue method using molybdenum radiation with a zirconium filter. Fig. 2 is the (110) pole figure for this material with the ideal (100) [011] and (111) [112] orientations indicated. The orientation is typical of most cold rolled body-centered-cubic metals having the [llO] of the grains approximately in the rolling direction and the (100) planes approximately in the plane of the rolled sheet. There is also evidence of some 10) [1 orientation. The grain orientation of sheet rolled 40 and 80 pct in the same direction as before at 600°C followed by recrystallization at 12000 C for 15 min was determined by a back-reflection Laue technique. A random texture was found in both cases. This 1200°C 15 min anneal was found to give complete recrystallization and some grain growth.

Jan 1, 1956

By A. E. Wraith, N. J. Petch, J. D. Embury, E. S. Wright

The two most important parameters controlling the fracture behavior of a solid are its intrinsic properties, e.g.,grain size, and the operative stress system. The latter may be modified in laminates by the presence of weak interfaces. This is studied in notch-impact tests on a mode1 system of mild steel laminates containing a variety of interfaces. The effect of these is evaluated in terms of the ductile/cleavage transition. Two laminate geometries are distinguished, here called "crack-arrester " and "crack-divider". In both, cleavage is inhibited. This arises because of relaxation of a state of triaxial tension. In the crack-avrester laminates, cleavage initiated at a notch is confined to the layer containing the notch. In crack-cliuider laminates, a thick specimen behaves as the Sum of a number of thinner ones. Additional benefit may derive from improved intritnsic propevties of- the lanlinate layers arising from greater deformation in their manufacture. It has long been recognized that the two most important parameters controlling the fracture behavior of solids are their intrinsic properties (e.g., grain size friction stress,3 distribution of second phase particles4) and the operative stress system under which fracture occurs. In solids that show a ductile/cleavage transition, cleavage is favored by the presence of a notch. This is because triaxial tensions, generated by the localized plastic constraint at the notch, are operative when fracture occurs.= Anything that suppresses these triaxial tensions will be unfavorable to cleavage. Such suppression may possibly occur in laminates containing weak interfaces and the purpose of the present paper is to explore this possibility. Two basic laminate geometries, here termed "crack-avrester" and "cvack-divider", are examined. They are illustrated in Fig. 1. With the crack-arrester laminates, there is the possibility that, when the fracture crack approaches the interface, this, if weak, may delaminate due to the tensile stress acting parallel to the plane of the crack.= If this happens, energy will be used in delamination, the crack will be completely blunted, and the triaxial tension associated with the crack will be relaxed. To fracture the second portion of the laminate, crack reinitiation will be necessary and, because of the relaxation of the triaxial tension, this reinitiation will occur under conditions of nearly uniaxial tension, which are unfavorable to cleavage. Thus there is the possibility of cleavage suppression in the second and subsequent subunits of a crack-arrester laminate. With the crack-divider geometry, there is again the possibility of delamination at the interfaces. This will divide the crack into a series of cracks propagating through the individual laminate subunits. If these are sufficiently thin, the triaxial tension will be relaxed towards a state of biaxial tension in each of them. Thus, with the crack-divider laminates, there is again the possibility of cleavage inhibition. In the present work, these possibilities are explored using a notched impact test on mild steel laminates bonded with soft solder, silver solder or copper. Even if delamination does not occur, it is still possible that cleavage may be inhibited in laminates. With the crack-arrester geometry, the cleavage crack in the first layer may be blunted and arrested by plastic deformation in the laminate bond, if this is ductile. Partial relaxation of the stress transmitted ahead of the crack into the second layer will then result and this will reduce the significance of this stress in the fracture of the second layer. With the crack-divider geometry, there cannot be much effect in the absence of delamination unless a large amount of energy is absorbed in rupturing the ductile material. EXPERIMENTAL DETAILS The composition of the mild steel (wt pet) was: 0.04 C, 0.29 Mn, 0.01 Si, 0.006 P, 0.008 S. "As-received" plate was annealed for 2 hr at 900°C and slowly cooled to give a grain size of 0.04 mm. The laminates were made by brazing or soldering together mild steel plates 8 by 3 in. by various thicknesses. These were obtained from the annealed plate by machining, so that the intrinsic material properties were .kept constant. Laminates containing two to six steel layers were studied using standard Charpy V-notch specimens cut from the bonded plates. Standard homogeneous specimens from the annealed plate and subsize ones from the laminate components

Jan 1, 1968

By Maxwell Gensamer, Vsevolod N. Krivobok

It is generally recognized that "low temperatures" have a definite effect on the properties of metals and alloys. Furthermore, it is also generally understood that the effect is decidedly adverse. The possibility that the same low-temperature treatment might be employed for the purpose of improving certain properties of the alloys has received less attention until recently, and the experimental and theoretical knowledge consequently is meager. The effect of low temperatures may be studied in two ways: by studying such properties as tensile strength, hardpess, impact resistance, etc., at low temperature, and by studying the properties of alloys at room temperature after these alloys have been subjected to a low-temperature treatment. Even in the latter case, certain properties will differ materially from the same properties obtained on identical material but without cold treatment. In other words, subjecting alloys to cold treatment results in an irreversible change in mechanical properties. Changes of this character are usually indications of the appearance of a new phase or phases, and would be likely to occur in alloys which, either by virtue of their composition or by heat treatment, are retained at room temperature in a metastable condition. Consequently, studies of the effect of low temperatures logically should be conducted from the physicochemical point of view, since the results of such studies not only would furnish metallurgists with interesting theoretical data but would clearly indicate the classes of alloys that would hold promise of improvement, and, possibly, of new applications. As the present investmigation deals with chromium and chromium-nickel alloys of iron of the stainless variety, it has been thought desirable to present the data concerning low-temperature properties of these alloys, available from the most recent and most comprehensive work of H. S. Russell.l A summary of these data is given in Table 1. The data are confined to a limited number of alloys of the type dealt with in the present

Jan 1, 1931