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By Xu Tianrui, Jin Xiang, Pen Dianhua

Based on the results of research or investigation, this paper describes the causes of and countermeasures for unexpected accidents, such as premature, postponed or spontaneous explosions in blasting practices in China.

Jan 1, 1996

By D. M. Davidson

THE drill sampling and evaluation of the Piney River ilmenite property was carried out during the early part of 1944 by E. J. Longyear Co., using the company's standard core-drill outfits to complete 44 holes to an average depth of 110 ft., from which were collected 1100 samples. The Piney River ilmenite-apatite lode is 25 miles north of Lynchburg, in Nelson and Amherst Counties, Virginia (Fig. I). Its elevation is about 900 ft. above sea level and it lies in the old pre-Cambrian complex of crystalline rocks that make up the Piedmont physiographic province lying east of the Blue Ridge Mountains. The terrain is gently rolling and well watered, and is drained by the Piney and Tye Rivers, which are tributary to the James. GEOLOGY The Piney River ore body comprises the upper, weathered part of a tabular basic rock, which occurs in a large area of granite-gneiss. The section containing profitable ore is about 3000 ft. long. It is separated naturally by thinning, into northeastern and southwestern segments with widths of 300 and 100 ft. respectively. The dip averages 45° southeast but steepens locally (Figs. 2 and 3). The unaltered rock is an even, granular mixture of feldspar, ilmenite, and apatite, to which Watson1 gave the name Nelsonite. The decomposed ore body, which is now being exploited by open cut, is a yellowish clay material in which black ilmenite and glassy apatite are the only conspicuous minerals. An economically important structural feature of the deposit is a banding of minerals coinciding with the dip and strike of the dike. This is more promounced in the footwall of the northeastern part of the intrusive, where there is also a higher than average concentration of ilmenite. According to Watson,1 the Ti02 content of the Nelsonites of this region ranges from 10 to 42 per cent, while P205 varies from 4 to 15 per cent. It is inexpedient at present to disclose exact metal content of the Piney River ore body; suffice it to say that the average tenor lies well within the extremes noted by Watson. SAMPLING METHODS AND PROCEDURE During a preliminary inspection of the ore body, Longyear engineers surmised that because of its soft, clayey character, drill sampling would yield little core, therefore they made all possible preparations to procure accurate samples of the drill cuttings, or sludge. The first requisite in obtaining representative drill cuttings is to secure their full recovery. Only under certain conditions, and by employing a most careful and rigid sampling technique, is this possible. There must be no loss of the water circulating in the hole, and the velocity

Jan 1, 1946

By E. G. Langille

"The Premier mine; owned by Silbak Premier Mines; Limited; is 14 miles from Stewart at the head of Portland canal. Development of the property began in 1918; and since chat time a very large amount of gold and silver as well as some lead and copper have been produced from the mine.The area in the vicinity of the mine is underlain by greenstones tuffs, and sediments of Mesozoic age, belonging to the Bear River formation of the Hazelton group. These rocks are intruded by a stock 2 miles in diameter, composed of orthoclase porphyry and called the Premier porphyry. It sends numerous sill-like and dyke-like tongues into the Bear River formation, and is intruded in turn by a granodiorite outlier of the Coast Range batholith. The orebodies occupy fractures and fracture or shear zones. Primary ore consists chiefly of pyrite, galena, and sphalerite, with some chalcopyrite. The upper 300 feet, or locally 600 feet, contained presumably secondary silver minerals."

Jan 1, 1954

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By C. K. Donoho

SILICON is used in almost all commercial steels; up to about 0.20 pct in killed wrought steels and 0.50 pct in steel castings. Above about 0.50 pct in wrought steels and 0.70 pct in cast steels, silicon is considered an alloy. As an alloy, silicon is useful for several purposes: (I) for its effect on magnetic properties of parts for electrical apparatus; (2) for increasing the yield strength of carbon and low-alloy steels without too much sacrifice of ductility and weldability; (3) for adding hardness and toughness to spring and chisel steels; (4) for adding resistance to scaling and carburization to heat-resistant steels; and (5) for its graphitizing effect in graphitic steels. In acid electric steels for casting we are principally interested in the effect listed second; i.e., increase of strength with minimum sacrifice of ductility.

Jan 1, 1947

By G. R. Kotler, W. A. Tiller, W. C. Johnston

Experiments carried out on 100 g samples of molten tin and Sn-Pb alloys showed that the magnitude of the field strength, H, does not effect the supercooling, aTn, at which the initial nucleus of solid forms. However, the nuwlber of nuclei forming per cc, n, is found to increase greatly with H for fixed ATN and to increase with ATN for fixed H. The value of n increases greatly with the presence of solute and is found to he indefiendent of the cooling rate of the simples. Further, the most effective time for stirring to enhance n is immediately following the initiation of recalescence. The effect of inducing nucleation with the aid of a mechanical impact both in the presence and absence of stirring has also been studied. All proposed mechanisms for the enhancement of n by physical means seem to be inadequate in accounting for these results. IN any real nucleation experiment there are two effects influencing the results that would not be predieted from classical homogeneous nucleation theory. These may be separated into chemical and mechanical effects. The chemical effects are twofold. 1) Nucleation catalysts are present which enhance the nucleation frequency of new grains over that predicted by classical homogeneous nucleation theory.' 2) Solute will restrain the growth of nuclei so that many others may form.2,3 The mechanical effects are also two-fold. 1) Vibration (sonic or ultrasonic) of the freezing liquid enhances the nucleation frequency of new grains over that given by the chemical effects alone.4-6 2) Macroscopic fluid-flow effects produce the same effect as l).'7' It is also possible to influence the nucleation experiment by certain physical effects such as the application of electric and magnetic fields.9 From classical homogeneous nucleation theory one would predict the following relationship between the nucleation rate, N1 (number of nuclei formed per unit volume per unit time), and bath supercooling, AT, for an isothermal experiment.

Jan 1, 1963

By James A. Barr

Ferrophosphorus, an alloy of phosphorus and iron or perhaps a physical mixture of definite compounds of iron and phosphorus, has become of increasing importance as the use of the basic open hearth has extended. Commercial ferrophosphorus is a porous, brittle metal of crystalline structure and often with a bluish metallic luster. A typical analysis is as follows: Per Cent. Phosphorus......................................... 18.0 to 22.0 Iron............................................... 80.0 76.0 Oxygen............................................ 0.2 Sulfur............................................. 0.3 Silicon............................................. 0.1 Carbon............................................ 0.1 Manganese......................................... 0.2 This alloy was first made in an electric furnace, as it was thought that the high heat of the electric arc together with the reductive effect of carbon was necessary. About 1898, J. J. Gray, Jr., was producing a high-phosphorus pig iron in his furnace at Rockdale, Tenn., by using high-phosphorus, local iron ores. As these high-phosphorus ores were difficult to obtain, he conceived the idea of increasing the phosphorus content of the pig iron by the addition of phosphate rock to the furnace burden. When the phosphorus content of the pig was kept low and only small amounts of phosphate rock were added to the burden, no particular troubles were encountered, but when he increased the amount of phosphate rock to produce an 18 per cent. alloy, his furnace troubles rapidly multiplied. After many failures and freeze-ups, he was partly successful in making short campaigns on 18 to 20 per cent. "ferro." At first, when the furnace got in bad shape on ferro, he would switch to a regular pig-iron burden until the furnace was brought around sufficiently to start on ferro again. About this time, Mr. Gray applied for and obtained his first patent. As he grew more skilled in the furnace operations, he was enabled to extend the furnace campaigns and produce ferrophosphorus continuously for the life of the furnace lining. These improvements were made the subject of another patent issued in 1916.

Jan 1, 1925

By R. F. Pilgrim

A digital computer program to mathematically simulate the effect of limited changes in feed rate in the range of 80 to 95 tph on a plant-scale wet grinding circuit has been developed and tested. The circuit studied included an 8-ft-diam X 12-ft rod mill operating in open circuit and feeding two parallel 12-ft-diam x 10-ft pebble mills, each one operating in closed circuit with an 8 X 32-ft rake classifier. The simulation is an empirical one based on two sets of data collected manually from the operating circuit under what was said to be steady-state feed rates of 80 and 95 tph with all other operating variables also at steady state. The procedure is a combination of several published approaches to the modeling of grinding mills and classifiers and it is applicable to a wide range of circuits. The program permits the computing of the size distributions of all feeds and discharges of all grinding units and classifiers in the circuit for a specified feed rate. The data used in this report for demonstrating the program are unsatisfactory since the circuit was not operating under steady-state conditions when it was sampled. Consequently the circuit model parameters could not be accurately estimated. The predictive power would be greatly improved if new data were obtained under true steady-state conditions.

Jan 1, 1973

By D. M. Davidson

The drill sampling and evaluation of the Piney River ilmenite property was carried out during the early part of 1944 by E. J. Longyear Co., using the company's standard core-drill outfits to complete 44 holes to an average depth of IIO ft., from which were collected 1100 samples. The Piney River ilmenite-apatite lode is 25 miles north of Lynchburg, in Nelson and Amherst Counties, Virginia (Fig. I). Its elevation is about 900 ft. above sea level and it lies in the old pre-Cambrian complex of crystalline rocks that make up the Piedmont physiographic province lying east of the Blue Ridge Mountains. The terrain is gently rolling and well watered and is drained by the Piney and Tye Rivers, which are tributary to the James. Geology The Piney River ore body comprises the upper, weathered part of a tabular basic rock, which occurs in a large area of granite-gneiss. The section containing profitable ore is about 3000 ft. long. It is separated naturally by thinning, into northeastern and southwestern segments with widths of 300 and 100 ft. respectively. The dip averages 4.5° southeast but steepens locally (Figs. 2 and 3). The unaltered rock is an even, granular mixture of feldspar, ilmenite, and apatite, to which Watson1 gave the name Nelson-ite. The decomposed ore body, which is now being exploited by open cut, is a yellowish clay material in which black ilmenite and glassy apatite are the only conspicuous minerals. An economically important structural feature of the deposit is a banding of minerals coinciding with the dip and strike of the dike. This is more pronounced in the footwall of the northeastern part of the intrusive, where there is also a higher than average concentration of ilmenite. According to Watson,' the TiO2 content of the Nelsonites of this region ranges from 10 to 42 per cent, while P205 varies from 4 to 15 per cent. It is inexpedient at present to disclose exact metal content of the Piney River ore body; suffice it to say that the average tenor lies well within the extremes noted by Watson. Sampling Methods and Procedure During a preliminary inspection of the ore body, Longyear engineers surmised that because of its soft, clayey character, drill sampling would yield little core, therefore they made all possible preparations to procure accurate samples of the drill cuttings, or sludge. The first requisite in obtaining representative drill cuttings is to secure their full recovery. Only under certain conditions, and by employing a most careful and rigid sampling technique, is this pos sible. There must be no loss of the water circulating in the hole, and the velocity

Jan 1, 1949

By D. M. Davidson

The drill sampling and evaluation of the Piney River ilmenite property was carried out during the early part of 1944 by E. J. Longyear Co., using the company's standard core-drill outfits to complete 44 holes to an average depth of IIO ft., from which were collected 1100 samples. The Piney River ilmenite-apatite lode is 25 miles north of Lynchburg, in Nelson and Amherst Counties, Virginia (Fig. I). Its elevation is about 900 ft. above sea level and it lies in the old pre-Cambrian complex of crystalline rocks that make up the Piedmont physiographic province lying east of the Blue Ridge Mountains. The terrain is gently rolling and well watered and is drained by the Piney and Tye Rivers, which are tributary to the James. Geology The Piney River ore body comprises the upper, weathered part of a tabular basic rock, which occurs in a large area of granite-gneiss. The section containing profitable ore is about 3000 ft. long. It is separated naturally by thinning, into northeastern and southwestern segments with widths of 300 and 100 ft. respectively. The dip averages 4.5° southeast but steepens locally (Figs. 2 and 3). The unaltered rock is an even, granular mixture of feldspar, ilmenite, and apatite, to which Watson1 gave the name Nelson-ite. The decomposed ore body, which is now being exploited by open cut, is a yellowish clay material in which black ilmenite and glassy apatite are the only conspicuous minerals. An economically important structural feature of the deposit is a banding of minerals coinciding with the dip and strike of the dike. This is more pronounced in the footwall of the northeastern part of the intrusive, where there is also a higher than average concentration of ilmenite. According to Watson,' the TiO2 content of the Nelsonites of this region ranges from 10 to 42 per cent, while P205 varies from 4 to 15 per cent. It is inexpedient at present to disclose exact metal content of the Piney River ore body; suffice it to say that the average tenor lies well within the extremes noted by Watson. Sampling Methods and Procedure During a preliminary inspection of the ore body, Longyear engineers surmised that because of its soft, clayey character, drill sampling would yield little core, therefore they made all possible preparations to procure accurate samples of the drill cuttings, or sludge. The first requisite in obtaining representative drill cuttings is to secure their full recovery. Only under certain conditions, and by employing a most careful and rigid sampling technique, is this pos sible. There must be no loss of the water circulating in the hole, and the velocity

Jan 1, 1949

By JAS. F. McCARTHY

THE present Hecla Co. is a Washington corporation; the Hecla Co. of Idaho was the old company. The older corporation owned two claims, the Hecla and the Katie May, and was incorporated for 500,000 shares of one dollar par value. The principal shareholders and officials of the older company were among the early mining men of the camp. Among the active officials were John A. Finch and A. B. Campbell. Among the directors and share- holders were Patrick Clark, J. R. Smith, Frank Upman, F. J, Kipp, Chas. Kipp, B. A. Kipp and Carl Landsee. F. J. Kipp and Carl Landsee are now directors of the Company. All of the others mentioned have died, but the surviving members of their families retain their ownership in the Company's shareholders. B. A. ,Kipp, who recently died, was the largest shareholder at the time of incorporation and Patrick Clark was the second largest shareholder. B. A. Kipp is a brother 'of F. J. Kipp, director of the Company.

Jan 1, 1924

By Lee A. Goetz

Cost control is a lot like motherhood - everyone proclaims its need and its worthiness, but is it really appreciated and used to successfully complete a project on time and within budget? Good Cost Control is a yardstick - requiring fixed definition but this does not mean rigidity for the project. It provides the means for telling: 1. Where you are going 2. When you will complete and 3. What it will finally cost. Cost Control does not fix the price of dreams nor the cost of projects loosely defined. It does not control costs in itself but provides the tools whereby engineering decisions can be made which will ultimately affect the project cost It does not even guarantee that a project will be completed within the original funds - but only, if this reflects management desires.

Jan 1, 1970

By Marcel Antonio Arcari Bassani

In the mining industry, it is common to have data collected in various formats. In an open pit mining operation, at the early stages of exploration samples are obtained from diamond drillholes. During the production stage, samples are collected from blastholes. The last is more numerous but less precise. From a geostatistical view, this dissimilarity has to be considered to integrate the two sources of information. To combine this different data, three methodologies were investigated: simple kriging with local varying mean, cokriging and ordinary kriging. The exhaustive Walker Lake data set was used and it is considered the source to obtain the true grades. Initially, samples were obtained from the exhaustive data set at a regular spacing grid of 20 x 20 meters. Next, samples were obtained again from the exhaustive dataset at a regular spacing of 5 x 5 meters and a relative error of 25% was added. Then, both data were used to estimate blocks using the three methods mentioned. The grade tonnage curves were compared with the true block grade distribution. Moreover, the block misclassification was evaluated. The results showed that ordinary kriging produced estimates closer to the true block grade distribution and reduced the block misclassification.

Aug 8, 2018

By Kung-Lee Wang, Brian W. Mackenzie, Warren E. Morrison, DeVerle P. Harris, George F. Sharrard

The term "mineral economics" is applied to a wide range of activities in the mineral industries. Earlier chapters have described the application of economic concepts to the mineral industries-supply, demand, conservation, tariffs, etc. The solution of mineral economics problems is often assisted by the application of quantitative methods. The purpose of this chapter is to describe a number of quantitative methods-econometric, operations research, and management science techniques-which find application in the analysis of mineral economics problems. These methods include input-output analysis, trend analysis, forecasting techniques, simulation, multivariate statistical analysis, mathematical programming, and market research techniques. The purpose of this introductory section is to provide a mineral economics framework for the application of these methods. Mineral economics is a subdivision of economics that is justified by a sufficient number of economic problems in the mineral industry requiring special experience and an unusual combination of skills. These problems are concerned with the conversion of minerals as geologic resources to minerals as economic goods. The mineral conversion process is outlined in Fig. 8.A.1. The physical occurrence of mineral deposits in nature and the market demand for mineral products in the economy provide the basic stimuli. The conversion process embodies a number of sequential stages-exploration, the development of mineral deposits, and mineral processing facilities and, consequently, productive activity to supply market demand. Changes in demand and the depletion of deposits illustrate the dynamics of the process. Mineral economics applies economic con-

Jan 1, 1976

By E. W. Cokayne

GENERAL DESCRIPTION OF THE METHOD The original application of sublevel caving was in ground so weak that it would collapse even in small headings when the support was removed. Heavily tim¬bered drifts were driven across the ore body; the timber was removed at the end of the drift, and the ore caved and slushed out. When dilution became excessive the next set was removed and so on. This method gave high dilution and poor recovery and was slow, but it was the only way to mine this type of ore body at that time. In more recent times the method has been adapted to stronger ground which needs to be drilled and blasted, so it is not a caving method as far as the ore is con¬cerned. However, the method does rely on the walls to cave and so the name sublevel caving has been retained. The method as presently generally applied is shown in Figs. 1, 2, and 3. Sublevels are established at approximately 7.6 to 12.2-m (25 to 40-ft) vertical intervals. They are usually accessed from a ramp system. A haulage drift is driven down the strike of the ore body, but in the waste. Production drifts are turned off the haulage drift and driven across the ore body on about 10.7-m (35-ft) horizontal centers. This divides the ore body into a geometrical pattern. Slot raises are driven at the end of the drifts near the ore-waste contact and the slot is expanded to the shape of the fan drilling. Up holes are drilled to break towards the slot at burdens of 1.2 to 1.8 m (4 to 6 ft). They are drilled past the next sublevel to the production drift im¬mediately above. When a sufficient number of fans has been drilled, production can start by blasting one or two fans at a time towards the slot. Load-haul-dump (LHD) units are used to muck the ore, which rills out into the drift. At first, when only a small area is mined, the walls may not cave, and the operation will be similar to open stoping. Later, sloughing from the walls will fill any voids created, and the ore after blasting will be con¬tained by the caved waste and gravitate downwards as mucking proceeds. This process is repeated in each of the production drifts as the face is retreated towards the haulage drift. When the top level has been retreated back a safe dis

Jan 1, 1982

By M. Rudman, L. Pullum, L. J. W. Graham

Centrifugal pumps are the workhorse of hydraulic conveying systems but their performance is derated when viscous non-Newtonian fluids, such as pastes and/or coarse solids are present. The reduced performance for purely viscous Newtonian fluids may be calculated using techniques such as the Hydraulic Institute method, but similar deration for non-Newtonian fluids is not so easy to apply. As part of the AMIRA P599 project investigating high concentration suspension pumping, centrifugal pump tests were systematically conducted on a wide range of non-Newtonian coarse particle suspensions. Suspension sup to 38% v/v of coarse particles with mean diameters in the range of 1.1 < d50< 3.4 mm suspended in carrier fluids with dynamic yield stresses of 0 < t?< 17.2 Pa and shear thinning indices in the range 0.35 < n< 0.79 were examined. Techniques such as the Hydraulic Institute de-ration method require a characteristic shear rate to be assigned before application with a non-Newtonian fluid, and a method based on pump geometry, fluid rheology and flow rate is proposed. This method predicts the dramatic characteristic reduction in head at low flow rates that is often observed and explains why larger pumps are relatively insensitive to this form of head deration. Head deration due to the presence of coarse particles in non-Newtonian carrier fluids is seen to follow similar trends to that of Newtonian suspensions and often dominates the total deration procedure.

Jan 1, 2007

The basic model for the evaluation of any coal-bearing property is the cash flow projection, the major components of which are operating costs, capital charges, taxation and revenue. A range of cash flow projections can be produced by varying the assumptions which underlie the operating costs, by assuming various forms of capital funding, by making assumptions as to future taxation and by speculating upon the present and future market value of the product. As for any model, the informational inputs and assumptions are vital because, no matter how sophisticated the processing, the informational inputs and assumptions cannot be improved by it. That is to say, the validity of the output (the total evaluation itself) cannot be of greater certainty or significance than that of the inputs. The total evaluation can of course be expressed in a number of ways such as the Discounted Cash Flow (D.C.F.) Rate of Return, the Net Present Value or, the Payback Period. The foregoing statement may seem trite. However, it is necessary to be clear about it so as to avoid unnecessary complication and a preoccupation with techniques as opposed to the informational inputs and assumptions. So far as techniques are concerned, much has been written and said about them during the last decade. Most of us have heard, if not always understood, something about probabilistic models, Monte Carlo simulation, sensitivity and risk analysis to say nothing of inflationary costing and the relative merits of developing cash flows in terms of current or constant money. Those techniques have their value, particularly if they can serve to illuminate conclusions which could not be reached on a simple and even perhaps on an intuitive basis. I am, however, reminded of one major coal mining project in which 20 or more major variables were identified, many cash flow projections were run on the computer and a detailed sensitivity analysis was carried out. The major conclusion reached was that the D.C.F. Rate of Return was predominantly sensitive to variations in selling price and operating cost. Of course, the funding and fiscal elements of a cash flow projection have to be dealt with as rigorously as possible. However, in the development of any coal property, capital requirements and taxation are, in part at any rate, dependent upon the assumed operational parameters. If the latter are misjudged, the whole evaluation process is deeply affected. The same is true of revenue, in the sense that, the positive cash flow is a function of output as well as selling price and again, misjudgements about achievable and maintainable levels of production also deeply affect the final evaluation. I shall try to underline the fundamental influence of the technological factors upon lead times, capital costs, operating costs, taxation, funding and the achievable and maintainable levels of production. In turn, these affect the whole question of coal property evaluation and indeed, the likely success or failure of any coal mining venture. I make no apology therefore that this paper does not set out to discuss the more esoteric aspects of the evaluation process but rather, directs attention towards some of the informational inputs and assumptions which merit clarification and discussion.

Jan 1, 1975

By Robert Stefanko

This report abstracts project work performed for the USBM Grant No. GO-133077 during the period 19 June 1973 to 15 October 1974. Five reports have been separately produced and are as follows: 1. Mine Electrical Systems Evaluation - Cable Splicing, 2. Mine Electrical Systems Evaluation - Explosion-Proofing of Mine Containers, 3. Mine Electrical Systems Evaluation - Transient Analysis, 4. Mine Electrical Systems Evaluation - Mine Power System Performance, and 5. Mine Electrical Systems Evaluation - Model Coal Mine Electrical System Specifications. Abstracts of each comprise the balance of this executive summary, and 50 copies of each volume have been forwarded to the USBM under the terms of the grant agreement.

Jan 1, 1974

By Lloyd A. Morley, Robert Stefanko

The most time-consuming research segment was assembling the ref¬erences. These are provided immediately after the conclusions but are divided into two categories. The first is directly applicable publi¬cations, correspondence and personnel communications. The second listing contains those publications that are not directly tied to the research but where a probable application exists. In both listings, all important USBM publications are provided. The reference numbers used in the report apply only to the first reference portion. Further¬more, it should be noted that all entries are not used but are retained to help anyone who wishes to look further into different or allied areas of this research topic. Explosion-proof enclosures have been researched since approxi¬mately 1906. Even so, little is understood about the mechanism by which they are effective. Due to the voluminous literature published, there is a good probability that the assembled list is still incomplete. The literature search took the following directions. Work was first directed to reviewing the several references assembled by the Department of Mineral Engineering - Mining Section prior to the present project year. As a result, some duplications and inapplicabilities were found and eliminated. The primary sources of the previous search were the commonly available and usually superb library listings, such as Engineering Abstracts. Because these sources have enormous content on all subjects, they were cross-checked in the first semiannual period several times by different individuals to make sure all normally avail¬able literature were uncovered.

Jan 1, 1974

By W. L. Chu

It was observed that chromized coatings on low carbon steel could be embrittled by cooling slowly through the 475°C range. A higher chromium coating was more susceptible to embrittlement than a lower chromium coating. Coating structure and composition could be correlated with the chromizing process and prior carbon content of the steel. IT was recently observed that during the fabrication of rectangular tubings made with chromized thin gage 1010 steel, a high percentage of these parts were fractured readily in a brittle manner under the light impact-forming load employed. Ensuing investigation indicated the cause for such brittle failures to be the so-called 475°C embrittlement of the chromized coatings. The experimental work and results are briefly reported. Rectangular tube sections of normalized AISI C1010 steel, which had a cross-section of 0.5x1.5 in. and a wall thickness of 0.030 in., were chromized to yield coatings having several ranges of thickness, varying from 0.0005 to 0.002 in. Essentially, the chromizing process is similar to that described by Samuel and Lockington,&apos; which consists of heating the parts in a sealed container at about 955°C for 4 hr in intimate contact with a chromizing mixture* samples in a hydraulic press, and the other employed a simple beam bending test of the flat sides of the tubing walls. Neither, however, was able to differentiate the relative brittleness of samples known to include both the brittle and tough types, since the impact-brittle samples were found to deform readily in a manner similar to the tough ones. Both the tough and brittle samples were studied by reflection microscopy. Observation showed that the microstructures of the steel cores were similar in content and distribution of inclusions as well as in the ferritic grain size. Results of Filar micrometer measurements showed that coating thicknesses+ of the brittle samples averaged 0.0007 in., whereas those of the tough samples averaged 0.0016 in. The micrographs of Fig. 2 illustrate the structural differences between coatings of both types of samples. By dissolving the steel cores in nitric acid, coatings of both the brittle and tough samples were isolated. Simple bending tests showed that coatings of the brittle samples cracked readily at about 90" bend, whereas those of the tough samples could be bent nearly 180° without cracking. The coatings as well as the steel cores were analyzed for carbon and

Jan 1, 1956