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By M. M. Fine

A satisfactory mean: of beneficiating a Brazilian phosphate rock was developed in a mineral-dressing-research study by the Bureau of Mines. High-grade concentrates well ever the specified minimum grade of 70 percent tricalcium phosphate, were produced, with goad recoveries by agglomerate tabling and flotation. A lower gads but usable secondary product was recovered by sedimentation of the minus-200-mesh fraction of the ore. The ore wan representative of an extensive deposit recently discovered near Recife in the State of Pernambuco, Brazil, which will be exploited in a plant planned to eventually produce at the rate of 500,000 tons of concentrate annually. Although Brazil has been reported to Lave a substantial reserve of phosphate rock,3/ the country has never been more than a small producer of this commodity. From 1945 to 1950 the highest production of phosphate rock attained in Brazil amounted to 10,421 tons. Production in 1949, the most recent year for which figures are available, was 4,553 tons.4/

Jan 1, 1954

By Toshihiro Kuzuya

A hydro metallurgical process has been developed for the recovery of metal values such as Co, Ni and rare earths from the electrode materials of spent nickel metal-hydride(Ni-MH) secondary battery. MmNis_xCo. (Mm : Misch metal) intermetallic compound could be separated from the electrode materials mixture by sedimentation. A typical chemical composition of MmN5-xCox was approximately, in mass%, 56.0%Ni, 13.4%Ce, 10.6%La and 7.9%Co. The time dependency of leaching intermetallic compound with sulfuric acid solution was examined with processing factors such as sulfuric acid concentration, temperature and agitation intensity, The leaching of rare earth metals proceeded very rapidly, reaching completion in less than 1.8ks. On the other hand, the slow leaching of nickel was observed. The percent of nickel leached at 328K could only reach about 70%.

Jan 1, 2003

By Sam McNary

The U.S. Bureau of Mines used the East Fork Pine Creek watershed to conduct a pilot study for an inactive and abandoned mine lands inventory, during which techniques and methodologies would be developed for subsequent inventories. A total of 177 waste dump samples, 191 mill tailings samples, and 36 stream sediment samples were collected. Water samples were collected from 18 sample sites during five sampling events. Waste dump, tailings, and stream sediment samples were analyzed for antimony, arsenic, cadmium, copper, iron, lead, mercury, and zinc. Results indicate a multidisciplinary approach is necessary: disciplines should include geology, geostatistis, geochemistry, geophysics, biology, hydrology, and remote sensing; small prospects do not generally contribute to watershed contamination, major mine and mill sites may contribute metal enriched sediment of metal enriched water; speciation studies and bioavailability studies are important.

Jan 1, 1995

By Bryn Harris

Chesbar Resources Inc.1 is developing a nickel-cobalt laterite project in Guatemala, Central America, by applying existing atmospheric chloride technology to a known resource. The tropical laterite project has an inferred resource of 133 million tonnes grading 1.51% nickel, which represents ~20% of Chesbar?s land holdings in Guatemala. Within its boundaries, the Sechol area has a measured resource of 14 million tonnes grading 1.46 % nickel and 0.08% cobalt, and an indicated resource of 23 million tonnes grading 1.34% nickel and 0.08% cobalt. Notwithstanding the impressive overall resource, the company has taken an innovative approach to a laterite project and is concentrating on El Inicio, a high-grade starter pit with five million tonnes grading 2.1% nickel and 0.08 % cobalt. The process flowsheet is based on atmospheric chloride leaching in a slightly acidic magnesium chloride brine, solution purification by recycled magnesia, precipitation of a mixed nickel/cobalt hydroxide intermediate product, and lixiviant regeneration by modified pyrohydrolysis technology. Initial results suggest that >90% of the contained nickel and cobalt in the non-magnetic fraction of the feed can be recovered, with <5% of the iron leaching. A metallurgical scoping study has established preliminary capital and operating costs for a production facility at a proposed rate of 20,000 tonnes per year of nickel as the intermediate mixed hydroxide. A preliminary assessment of producing a magnesium oxide by-product has also been carried out. This paper reports on the current development of the project and highlights the advantages of working in a chloride medium at atmospheric pressure and slightly elevated temperatures.

Jan 1, 2003

By Milene Muniz Eloy da Costa

Devido à grande aplicação de polímeros no nosso dia a dia sob condições de trabalho reais, ou seja, sob a influência de intempéries, surgiu a necessidade de estudos visando a avaliação de resistências estruturais e mecânicas desses polímeros. O envelhecimento é um processo que envolve mecanismos simultâneos que influenciam diretamente suas propriedades mecânicas, degradando os materiais. Com esse intuito, foi avaliado o envelhecimento por análise de espectroscopia no infravermelho por transformada de Fourier (FTIR) do PEMD de controle (tempo 0) e das amostras ensaiadas sob raios UV por 300, 600 e 900 horas. Os resultados obtidos mostraram o aparecimento e desaparecimento de bandas nos espectros de FTIR, que, relacionados aos resultados de emissão acústica (EA), indicaram a ocorrência de cisão de cadeias, ramificações e reticulações.

Aug 16, 2017

By Wenshan Zhang

Three important methods of removing Fe in hydrometallurgy of zinc, manganese, copper, nickel, cobalt and etc are described, including neutralized hydrolysis method, jarosite method and goethite method. The reactions, technical requirements and thermodynamic analysis during Fe removal process are also discussed in this paper.

Jan 1, 2006

By M. Hardy, K. Nielsen, M. Ramey

American Soda, LLP has commissioned the first solution mine for recovery of naturally formed sodium bicarbonate (nahcolite) from low-grade deposits using high-pressure, high-temperature injection fluid. This project, known as the Yankee Gulch Project, was commissioned33 years after discovery of the deposit and followed an intensive four-year feasibility study that included a full-scale pilot test. The nahcoliteis co-mingled with oil shale and is impermeable. Solution mining is achieved by a combination of thermo-mechanical cracking and dissolution. Elevated temperatures are required to initiate the thermally induced cracking and to enhance solubility of the nahcolite, which is highly temperature dependent. This paper will provide an overview of the development of the project from discovery, characterization, pilot testing, permitting and commissioning, with emphasis on the solution mining aspects.

Jan 1, 2003

By Edward B. Cook

The installation of the Gayley dry-air process appealed specially to the management of the Warwick Iron & Steel Go., for the reason that for fifteen years records had been kept at the works of the company, showing the amount of water entering the furnace in the form of aqueous vapor, and careful observations had been made of its effect upon the working of the furnace. Some years had proved much worse in their effect than others, on account, not only of excessive moisture, but also of great variation in the moisture from day to day, and sometimes within a few hours. It had been found impossible to make a satisfactory percentage of high-silicon foundry-iron in summer, even on high fuel; and for some years the endeavor had been made so to arrange the sales that, during July and August, only a small percentage of the iron produced would be required to carry more than 2 per cent. of silicon. Our larger furnace, running on basic iron, year after year, produced in February a tonnage 20 per cent. higher than in August, 011 a much lower fuel-consumption, while, at the same time, the summer months were marked by " messes," tuyeres closed by slips, and other irregularities, constituting serious additional business losses. It will be easily understood, therefore, that the records made at the Isabella furnace after the installation of the dry blast in 1904 possessed special interest, and were closely watched by us. On the basis of our own experience, we argued that if the moisture could be kept low, and also uniform, the cost of installation would be more than justified. The subject was brought before our Board of Directors in the fall of 1905; and in the spring of 1906 it was decided to install a plant of sufficient

Jan 1, 1909

Here, in what is partly a review and partly a personal viewpoint, I take stock of changes in emphasis and comprehension on the subject of basaltic volcanism in the decade that has passed since the completion of the landmark Basaltic Volcanism Study Project (1981). I concentrate attention on the relatively neglected physical-volcanology aspects (in 1988 it was still possible to publish a 340-page book on flood basalts with barely any mention of physical mechanisms).I adopt the useful unifying concept of "volcanic system" to embrace the invariably-present intrusions as well as the volcano; I consider controls exercised by magma-supply rate and modulator-mechanisms on the nature of the system;I emphasize that sheeted-intrusion complexes, consisting either of dikes or inclined sheets (depending on the ability of the system to expand laterally) occur in all eroded major systems and fuel geothermal systems; I show how constraints set by cooling of narrow intrusions cause such complexes to be wedge-like and produce considerable rotations; I consider the role of the level of neutral buoyancy in making magma chambers possible, causing lateral subsurface magma flow and localizing intrusions, while the LNB itself can be accentuated by intrusions; and I examine the possibility that underwater systems could have very different internal structures from systems on land.

Jan 1, 1990

By C. M. Campbell

Canadian newspapers from coast to coast, have been, for months, denouncing those articles entitled, "The Whisper of Death," which have been appearing in the Montreal Star. I have not read these articles as the newspapers do not print them; they just denounce them or class them as jokes. Apparently they think that they are not suitable for the ordinary Canadian to read. It appears, however, that the Star has said that unless we balance our budget, and that soon, we shall be bankrupt. That seems to me like common sense, though the Victoria Times says editorially that the Star claims will "shortly find a place in the joke column". In this editorial the Times quotes with much enthusiasm from the Quebec Telegraph. "Canada," says the Telegraph, "is all right. Her natural resources are so vast that no one need worry. Her future possibilities are limitless; her assets beyond figures". Does it not seem like the limit of nonsense for a country that is not paying its running expenses to make such pretensions? After fifty-five years of Confederation and much talk of national status we are still sponging on the mother country for our external defense; we still allow the hard pressed tax-payer in the old land to shoulder the entire burden. We even now refuse to accept able-bodied working-men from that small and overcrowded country and yet blatently talk of limitless resources.

Jan 1, 1923

The primary purpose of the Institute is to advance the technologic and engineering arts embraced by it through interchange of knowledge. This can best be done by the presentation and discussion of technical papers by its members. Short practical papers are especially welcome. An author should always satisfy himself that his material is of a quality that will be a credit to him and to the Institute. The preparation of a good paper frequently leads to a reorientation of the author&apos;s thoughts, and publication contributes much to the professional standing of the author. Members are urged to submit papers presenting the results of their work. Attention to the following suggestions will greatly further the prompt and efficient handling of manuscripts.

Jan 1, 1944

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?&apos; eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? &apos; phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?&apos; eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By F. M. Lewis, J. E. Goodman

A larger, slow-speed, under-loaded ball mill and hydraulic classifier have almost doubled grinding efficiency at the lsabella mill. TENNESSEE Copper Co. operates two ore con-A centrators, the London and Isabella mills near Copperhill, Tenn. In 1948 and 1949 the small ball mills and rake classifiers in the London concentrator were replaced by one large ball mill and one hydraulic classifier. This new ball mill was designed oversize so that it could be operated at slower than normal speed. The proper operating conditions were established and the results published.&apos; Later it was found that this mill operated more efficiently with a small ball charge." While this London grinding practice was being developed, the Isabella grinding circuit was not changed in any way. It remained a conventional two-stage rod mill—ball mill combination, the rod mill in open circuit and the ball mill in closed circuit with a rake classifier. Study of the data indicated that grinding cost could be lowered by converting to the London practice, but not enough would have been saved to warrant the expense of converting. No plan for improving this grinding operation could be developed. In 1953 this study was reopened when plans were made to increase the Isabella mill output from 1150 to 1500 tpd. At this time the grinding circuit consisted of a 6x12 rod mill followed by a 6x12 ball mill in closed circuit with a 6-ft rake classifier. Another 6x12 ball mill and 6-ft rake classifier would have been sufficient equipment and would have been the simplest and cheapest installation. However, this would have offered no improvement in grinding efficiency or operating cost. If, on the other hand, the grinding operation could be converted to the London practice, by installation of one large 101/2x9x9 tricone mill and a 10-ft hydroscillator,2 lower operating costs would justify the additional investment. Economics: Table I presents estimates for the two schemes for enlarging the Isabella mill. In the first scheme, column 1, one 6x12 ball mill and one 6-ft rake classifier were to be added. In the second scheme, column 2, the existing small ball mill and rake classifier were to be retired and one large mill and hydroscillator were to be installed. Estimated savings from the difference in operating costs made an attractive return on the additional investment for the large mill and hydroscillator. Actual costs of carrying out this plan are tabulated in column 3b. It will be seen that these costs follow the estimates in column 3a very Closely. The return on the additional investment is calculated from the difference in the operating cost in column 1 and the actual operating cost in column 3b. This too come very close to the estimate. Power and Steel: Power requirements and steel consumption for the rod mills and ball mills, both actual and estimated, are presented in Table 11.

Jan 1, 1958

Although geophysical methods of prospecting have proved indispensable in the search or oil deposits elsewhere; it is only &apos;in recent years that they have been used to any significant extent in Australia. The increase in their use has been quite remarkable over the past two or three years, due in Sao small measure to the encouragement given by means of Commonwealth subsidy. There is no doubt that the use of&apos; geophysical methods will coxi-tinue to increase and this increase could be greatly accelerated as and when oil is discovered in commercial quantities,This review of their use A in Australia and the remarks and statistics are confined to work on the mainland. There has been, a substantial amount of geophysical work in Papua, but as operating conditions are so very different to the mainland Papua has been regarded as a separate province.

Jan 1, 1962

By Dobos SK

The Black Ridge Gold Deposit is located in the northern part of the Clermont Goldfield, which is situated at the boundary of the Bowen Basin and Anakie Inlier, Queensland. The goldfield comprises a series of NNW-trending semi-isolated basins, which are tectonically aligned with the Denison Trough, the west-most division of the Bowen Basin (Fig. 1-1).The main stratigraphic units in the deposits in younging sequence are the Anakie Metamorphics, the early Permian Blair Athol Coal Measures, the late Permian(?) White Section, and the Tertiary basalts which are regionally widespread, and intruded by abundant mafic and felsic plugs.

Jan 1, 1990

By Antoine F. Mulaba

Introduction Copper and cobalt oxide mineral deposits formed by the atmospheric weathering of near surface sulphide deposits are commonplace in the Democratic Republic of Congo. The most common route for the extraction of these metals is a hydrometallurgical one in which the base metal oxides are dissolved in sulphuric acid and then concentrated further by solvent extraction. However, as many of these deposits are relatively low grade (i.e. 0.5-1.8%Co and 2-4% Cu) and can also contain large amounts of acid consuming gangue minerals (i.e. dolomitic, micaeous, and/or siliceous), the hydrometallurgical route becomes uneconomic due to the excessive acid leaching costs. Some means of pre-concentration ahead of leaching is then desirable to improve the process economics. Apart from the small scale mining (Pan. Afr. News Agency, 2000) handpicking, although not easy, oxide concentration by flotation has been suggested. For the flotation process, the two most common approaches are controlled potential sulphidisation (CPS) and the fatty acid flotation method. The preferred method is dictated by the nature of the mineral makeup of the gangue. Being secondary deposits, the gangue associated with these ores is often complex and can play a significant role in the overall flotation efficiency. Laboratory flotation experience gained from the testing of a number of different ores of this type has revealed that it is not possible to prescribe a set method for the flotation of various ore types. Each ore needs to be analysed very carefully before and after laboratory flotation on an individual basis in order to arrive at an acceptable flotation technique Laboratory flotation testwork was carried out on three different samples from the DRC in attempts to isolate some of the more important variables affecting the flotation of copper and cobalt oxide minerals from these weathered deposits. This paper describes some early results achieved and experiences gained with these different ores ahead of a more detailed flotation test program which will follow in the near future on receipt of a significant quantity of a more representative sample. Controlled Potential Sulphidisation (CPS) was used in an attempt to achieve acceptable recoveries of both copper and cobalt.

Jan 1, 2005

By Marcel Michaud

Over the past five years, the two-fold growth in Canada&apos;s coal industry "Figure, 1" results primarily from the coking coal market to Japan and, to a lesser degree, by the increasing use of sub-bituminous and lignite coal for power generation in the Prairie Provinces. This expansion will continue, but production of coal for domestic thermal generation of electricity will grow at a faster rate than coking coal exports "Figure, 2". Half of the 20 million tons of thermal coal used for electrical power generation in Canada during 1974 were imported by Ontario Hydro from U.S. coal companies in West Virginia and Pennsylvania. Ontario Hydro&apos;s Nanticoke station on Lake Erie which will consume 7.5 million tons of coal in 1977 when fully operative, as well as other future planned projects, could cause Ontario Hydro&apos;s coal consumption to rise from 10 million tons today to 20 to 25 million tons by 1985

Jan 1, 1975

By H. S. Munroe

As elaborate discussion under this heading formed a chapter in one of the reports made by Professor Raymond as Commissioner of Mining Statistics." In a subsequent report? was printed a paper., by Mr. William Main, Jr., of Columbia, South Carolina, containing a theoretical investigation into the effect of the velocity of impact on the effective ditty of stamps. A visit to the Lake Superior copper region last summer suggested an inquiry into the relative efficiency and economy of the enormous steam stamps of the copper-mills, as compared with the results obtained with the cam and tappet stamps commonly used in the West. The atmospheric stomp used at the Phoenix Mill promised to add interest to the inquiry, as giving an example of unusually high speed, this stamp making 160 drops per minute. In introducing his subject Dr. Raymond makes the following remarks, which are quite apropos of the present investigation: "In considering the economical application of stamping machinery, we meet, at the beginning, with serious difficulties in obtaining accurate data for comparison. The weight and fall of stamps vary as the shoes and dies wear out; and this may lead to a change of speed also. Moreover, defects in engines, boilers, or machinery for the transmission of power, may occasion serious losses, which cannot fairly be charged to the arrangements of the stamps proper. Again, the capacity of stamp-mills is directly dependent, in some degree, upon the nature and extent of discharge, fineness of screens, and other peculiarities of the battery. Finally the hardness and tenacity of the rock crushed varies so much that comparisons between different localities cannot be implicitly trusted. The safest experiments are those made in the same mill, by changing first one arid then another condition of working; but this is seldom possible for such

Jan 1, 1881

By Jianbo Lan, Desheng Huang, Xiaoying Qiu, Zhaohua Ke, Liusheng Ge, Xinjin Xiao, An Guo, Qiaofa Lan

Magnesium salt rare earth enrichment (MREE) is a crucial intermediate raw material in the deep processing of rare earth elements and material preparation, serving as a front-end raw material for the synthesis of rare earth oxides. With the current disposal process for MREE, neutralization slag with high rare earth residue is generated during further extraction of rare earth from the MREE and accumulates in huge piles. Therefore, the combined disposal process of MREE and neutralization slag was put forward. MREE was solubilized using 4 mol/L sulfuric acid to achieve an endpoint pH of 0.75, dissolving the rare earth and obtaining an acid solution. The MREE and neutralization slag were added in a mass ratio of 1:2 to the acid solution sequentially. The pH of the endpoint was controlled to 4.8~5.0 for neutralization and decontamination. This resulted in the production of rare earth sulfate liquid of similar quality to the original MREE disposal process, meeting subsequent extraction requirements. The neutralization slag underwent a water washing process, with two washes (first with 0.2 mol/L acidity water at a solid-liquid ratio of 1:2 and second with deionized water at a ratio of 1:4), resulting in water-washing slag with a rare earth content of 0.24% and a rare earth yield of 97.08%. Notably, zero wastewater discharge was realized. This innovative process effectively addressed the challenges of high rare earth residue in neutralization slag and stockpile accumulation, offering valuable theoretical and practical insights for MREE disposal.

May 31, 2024

By R. S. Busk

A PREVIOUS paper1 has summarized the effect of A all metallic elements on the lattice parameters of magnesium. The present paper deals with the effect of temperature on the lattice parameters and the way in which that effect is modified by alloyed elements. The experimental techniques for sample preparation, exposure to the X-ray beam, measurement of line diameters, and calculation of the parameters were the same as reported in the previous paper. The temperature of the specimen was raised by surrounding the mounted compact with a conical Glas-Col,* the base of which was sealed with Saran film. In this way the temperature of the specimen could be raised to 200 °C, which was the maximum desired in the present study. Control of temperature was effected by maintaining a constant, desired voltage to the resistance coils of the Glas-Col through a Variac. Temperature was measured by an iron constantan thermocouple embedded in the body of the specimerl so that the thermocouple bead was within 1/16 in. of the surface exposed to the X-ray beam. Variation of temperature during an exposure was less than + 1/4 oF. A series of eight alloys, consisting of pure Mg, Mg+Ag, Mg+Al, and Mg+Sn were studied. All percentage values are in atomic percent. The results are given in Table I. The density values given in Table I were calculated from the lattice parameters, using an equation due to Foote and Jette:"

Jan 1, 1953