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By B. H. Bergstram, C. L. Sollenberger

When glass spheres are crushed by slow compression loading, the outer lune-shaped fragments resulting from the fracture consistently fly outward at high velocity. About 45 pct of the strain energy fed into the sphere-platen system reappears in the form of the kinetic energy possessed by these fragments. These measurements were obtained from high-speed photographs. This kinetic energy can be utilized for addtional comminution if the fragments are allowed to impact against a suitable structure. Comminution theory has advanced considerably in recent years by the study of this unit operation under laboratory conditions. Some of the parameters have been isolated, but the experimental measurements of the pertinent quantities, such as energy, particle size, etc., are still only made prior to and after the conclusion of a fracture sequence. The catastrophic fracture process itself has not been adequately studied from a comminution point of view. It has recently been suggested by Gilvarry that the fragments which result from the free crushing of a single glass sphere by slow compression contain a considerable amount of kinetic energy after fracture. This kinetic energy, if properly directed, possibly can be partially utilized to cause additional fracture. In this paper a hypothesis will be presented which suggests that this kinetic energy is necessarily present and that its dissipation is the process by which a large part of the thermal energy imparted to the crushed product is generated. Evidence supporting the existence of kinetic energy and its utilization for secondary fracture will also be presented. THEORETICAL A previous paper4 has shown that the load-deformation curve of a system composed of an elastic sphere gripped by a pair of parallel platens, can be predicted by a consideration of the theories of Hertz as summarized by Timoshenko.' The deformation A, of one half of the system is given by which states that the deformation is a function of the mutually applied load, P, the radius of the sphere, R; and the respective physical properties of Poisson's ratio, v, and Young's modulus of elasticity, Y. The shape of experimental load-deformation curves conform to this relationship. The energy input to the sphere-platen system, can be predicted from the integral of the load acting through the appropriate distance, dA. Since dA can be evaluated in terms of P from the derivative of Eq. 1, this integral can be integrated between limits of 0 and P. The test sphere, however, is loaded at not one but at two points of contact, i.e., at both ends of a diameter, and hence the total energy input, E, is twice the energy input at each end, or The energy input to the system calculated from this equation corresponds to the energy computed from the measured area under the load-deformation curve. Timoshenko, considering the impact of two perfectly elastic spheres, has shown that the inter-penetration distance A is given by - m f (D (^ * ^t w as modified for the special case where one sphere is of infinite radius, i.e., its surface is a plane; where M is the mass of the finite sphere of radius R, and V is the velocity of approach at the start of an impact and also equals the final velocity of separation for perfectly elastic bodies. Because A is also a function of the load and the elastic properties, as shown in Eq. 1, the velocity, V, can also be calculated in terms of the elastic properties and maximum load, P, or

Jan 1, 1961

By N. F. Dyson, T. R. Scott, M. R. Thornber, W. E. Ewers, M. Bussell

Leach liquors derived from the processing of nickel ores are generally highly contaminated and contain appreciable free acid. Methods are described for obtaining a commercial grade of concentrate from such solutions using pyrrhotite as the seed material to abstract nick- el, cobalt, etc. from solution. At temperatures in excess of 160° C., recoveries of 99% can be obtained from contaminated solutions where the free acidity is as high as 0.5 M in sulphuric acid. At lower temperatures down to 80° C., high recoveries can also be obtained either by adding H2S to the system with appropriate adjustment of the free acidity or by using "activated" pyrrhotite or artificial FeS in the system without prior addition of H2S. The methods are applicable to liquors derived from either oxide or sulphide ores, and the products are suitable for smelting or other known processes used to obtain pure metals. The mechanism of the reaction appears to vary with the operating temperature, and the results ye therefore discussed in the light of electron probe and optical microscopic studies.

Jan 1, 1973

By Artur Camposo Pereira

Cerâmicas argilosas foram processadas com adição de até 30% em peso de resíduos de pedra ornamental e queimadas a 900, 950, 1000 e 1050°C. Esta adição contribuiu para ajustar a plasticidade do corpo da argila e aumentar a densidade seca aparente, que ocasiona um empacotamento mais elevado das partículas. A cerâmica adicionada diminuiu sua retração linear com a quantidade de resíduos e evita assim alterações dimensionais excessivas nos produtos finais. Outra vantagem foi a diminuição na absorção de água com resíduos adicionados. As resistências à flexão e à compressão sofreram uma diminuição associada à adição de resíduos. Isto foi atribuído à grande quantidade de quartzo nos resíduos, que gera rachaduras e enfraquece o produto final. No entanto, até 30% em peso de adição a resistência mecânica, de acordo com a norma ASTM, é ainda satisfatória para utilização como cerâmica de pavimentação.

Oct 30, 2017

By C. W. Macgregor

The observation of the flow layers, or Luders' lines, produced in mild steel when it is stressed into the plastic range often provides considerable useful information for the study of the fundamental mechanism of the plastic flow of metals. It is a commonly observed fact that as soon as the upper yield point in a mild-st'eel tensile-test bar is passed, an unstable condition develops in the equilibrium, the load on the testing machine drops and if the surface of the bar contains a thin mill scale, the latter begins to flake off rapidly along certain "lines." These "lines" are ill reality traces of wedge-shaped flow layers and are formed by the inter-section of the surface of slip and the surface of the bar. The average plane of the flow layer itself has been found by various experimenters to be inclined at an angle of approximately 45" to the axis of the test bar. In a body of more complicated shape stressed in possibly a different man-ncr, the tangent planes to the flow layers at each point seem in many cases to be inclined at an angle of about 45" to the principal stress direct-tions at the point. As examples of the latter may be mentionecl the logarithmic spirals obtained when a rivet hole is punched in a thin plate, or when a tube is subject,ed to internal pressure only, etc. IIencc if the flow layers are observed from an experiment, the shear-st'ress trajectories —the curves indicating the direct,ions of the maximum shearing stresses in the body—may then be approximately determined. Since the latter curves form an orthogonal family inclined at 45" to the principal stress directions, the family of principal stress trajectories, or the curves irldicating the directions of the principal stresses, may be thus obtained Although the discontinuous type of stress-strain curve at the yield point is commonly observed with test bars of mild steel, more recent experiments have shown that this is by no means the only material exhibiting this interesting phenomenon. A similar effect has been observed in zinc and cadmium crystals, by Becker and Orowai~; in duralumin and other aluminum alloys, by Dawidenkow,~Elam,~ Fell4 an(l others; in copper and copper-alloy crystals, by Elam;~ in brass by Elam;3 in brass wires by deForest;" in higher carbon steels, tungsten steel, and

Jan 1, 1939

By C. W. MacGregor

The observation of the flow layers, or Luders' lines, produced in mild steel when it is stressed into the plastic range often provides considerable useful information for the study of the fundamental mechanism of the plastic flow of metals. It is a commonly observed fact that as soon as the upper yield point in a mild-st'eel tensile-test bar is passed, an unstable condition develops in the equilibrium, the load on the testing machine drops and if the surface of the bar contains a thin mill scale, the latter begins to flake off rapidly along certain "lines." These "lines" are ill reality traces of wedge-shaped flow layers and are formed by the inter-section of the surface of slip and the surface of the bar. The average plane of the flow layer itself has been found by various experimenters to be inclined at an angle of approximately 45" to the axis of the test bar. In a body of more complicated shape stressed in possibly a different man-ncr, the tangent planes to the flow layers at each point seem in many cases to be inclined at an angle of about 45" to the principal stress direct-tions at the point. As examples of the latter may be mentionecl the logarithmic spirals obtained when a rivet hole is punched in a thin plate, or when a tube is subject,ed to internal pressure only, etc. IIencc if the flow layers are observed from an experiment, the shear-st'ress trajectories —the curves indicating the direct,ions of the maximum shearing stresses in the body—may then be approximately determined. Since the latter curves form an orthogonal family inclined at 45" to the principal stress directions, the family of principal stress trajectories, or the curves irldicating the directions of the principal stresses, may be thus obtained Although the discontinuous type of stress-strain curve at the yield point is commonly observed with test bars of mild steel, more recent experiments have shown that this is by no means the only material exhibiting this interesting phenomenon. A similar effect has been observed in zinc and cadmium crystals, by Becker and Orowai~; in duralumin and other aluminum alloys, by Dawidenkow,~Elam,~ Fell4 an(l others; in copper and copper-alloy crystals, by Elam;~ in brass by Elam;3 in brass wires by deForest;" in higher carbon steels, tungsten steel, and

Jan 1, 1939

Jan 1, 1967

By S. E. Malouf, W. Thorpe

"The Chibougamau Explorers property comprises 35 claims or 1,726 acres in La Dauversiere and Rohault Townships along the west shore of Norhart Lake. The property is serviced by a twelve-mile all-weather high-way leaving the main St. Felicien-Chibougamau highway at mileage 121. This road junction will be a railway siding on the C.N.R. St. Felicien-Chibougamau branch line in early 1957. The property lies 30 miles due south from the town of Chibougamau. The mine-sponsored Chibougamau Explorers town has a population of 250 with 28 residences and a well equipped recreation centre.The original showing was found by Rider Storn, a prospector financed by Val d'Or interests during the 1950 field season. This showing did not stand up to detailed prospecting but it did lead to the discovery of the main zone by A. Oakley during the following winter.The company was incorporated in I 950 under the presidency of E. Ayrhart. Financing following the initial drilling involved an increase of capitalization from 3 to 5 million shares and the advent of financing and management control by Anacon Lead Mines Limited.Exploration and development to Jan. I, 1956, has included 42,331 feet of surface diamond drilling; 31,363 feet of underground drilling; a 3-compartment shaft to 1,245 feet, with 8 levels at 150-foot intervals; and I 1,054 feet of drifts, crosscuts, and raises. Ore reserves to the 900-foot level, proven and partly developed, total 546,725 tons averaging 0·30 ounces gold and 0·93 per cent copper. A mill with capacity of 500 to 750 tons will be installed by January 1956.GeologyThe Chibougamau Explorers property lies along the belt of Keewatin volcanics striking through Bachelor Lake, Opawica Lake, Doda Lake, Coapatina, Norhart Lake, and Rohault Lake, where it is in close proximity to the paragneisses of the Grenville series. The boundary of the paragneisses, a gradational contact, lies within a mile of the Chibougamau Explorers shaft collar."

Jan 1, 1949

By Gordon M. Matheson, David K. Miller

Sinkhole development in karst terrains is a serious problem and risk to facilities built in these areas. The potential for sinkholes are a function of many things including the chemistry of the underlying rock, the location of water conductive fractures and fissures in the rock, the natural fluctuation of the ground water table, vibrations from various sources and surface regrading activities. When sinkhole open near quarry operations the occurrence of these features is occasionally attributed to vibrations from quarry blasting. The purpose of this paper is to review the evidence regarding the development of sinkholes as a result of quarry blasting. In general, it has been found that sinkholes result from collapse or piping of overburden soils into cavities or caverns developed within underlying carbonate rocks that have been in existence for many thousands of years. The overburden soils in karst areas are typically clayey and as a result are not subject to densification or liquefaction as a result of vibrations. The primary cause of an increased rate of sinkhole development can be attributed to changes in the ground water table or local surface water drainage. These changes may be caused by seasonal fluctuations, ground water level lowering in drought periods, dewatering of excavations or quarries, or local changes in surface drainage resulting from grading activities.

Jan 1, 1998

By Robert W. Baker

"Brunswick Mining and Smelting commenced production at the No. 12orebody, a lead/zinc/copper/silver deposit, situated some seventeen miles southwest of Bathurst, New Brunswick, in 1964 at 4100 tonnes per day. Today it operates at 10500 tonnes per day.Brunswick has utilized underground incentives since commencement of operations. Early incentive systems were “off the wall"" based on those in effect at other properties then manipulated to fit, often hack calculated from actual performances to tm1ve at the desired result. If subsequent payouts were considered too high the rates were simply reduced, often retroactively. A large amount of this was' subjective and depended to a large extent on whoever was handling the bonus, in conjunction with senior mine department staff.In 1971, it was' decided that a more scientific approach was needed, particularly with the introduction of the new cut-and-fill mining. After some research, a system based on Work Study was selected. Another major mining company employing such a system loaned one of their experienced employees to train some Brunswick personnel in the art of Work Study and conversion of data to incentive rates, and in 1972, the first such developed incentive rate was-introduced.Along the way, borrowing from others where necessary, a set of Brunswick principles and parameters were developed. While refined to some extent, these remain basically the same today.Improvements in methods and equipment have resulted in improved performance and reduced costs. The use of underground incentives has played an important role in this. A/though individual bonus earnings have steadily increased, bonus cost per tonne has remained nearly constant - in real dollars, it has regularly decreased. These are two of the main parameters of a successful system."

Jan 1, 1995

By Yves Dardel

INTRODUCTION SINCE the first determination of Dumas1 in 1880, many authors have tried to measure the solubility of hydrogen in solid aluminum, or at least the amount of dissolved gas in it. However, the interpretation of the results which have been obtained is still difficult. Sieverts,2 then Baukloh and Oesterlen,3 during their gassing experiments could not determine any solubility of hydrogen in solid aluminum. On the other hand, Portevin, Chaudron and Moreau,4 leaving the determination of the hydrogen solubility beyond the scope of their experiments, measured only the amount of gas that they could extract by high voltage positive ion bombardment and found up to 151 cm3 of gas per 100 g of metal. Winterhager,5 by repeated vacuum extraction during severe cold rolling, extracted up to 161 cm3 per 100 g. In both series of experiments, the extracted gas contained chiefly hydrogen with a small amount of nitrogen, carbon monoxide, carbon dioxide and methan. Later, Schmidt and von Schweinitz6 as well as Chaudron and Moreau7 showed the importance of the adsorbed layer of hydrogen, the extracted quantities being proportional to the surface and not to the weight of the sample, when its cleaning was not perfect. In earlier experiments, Steinhauser8 extracted from more massive samples nothing but a little amount (< 0. 5 cm3 per 100 g) of hydrogen, carbon monoxide and methane. Thus, according to these experiments the quantity of dissolved gas is probably very small and the effect of the surface could falsify the results of the extraction. However, owing to the care taken by Chaudron and his coworkers, it was clear that all the hydrogen extracted could not come from the superficial layer, or that the links which bound hydrogen to the surface were so strong that the usual method of cleaning could not destroy them. After the main parts of the experiments reported here had already been carried out, Eborall and Ransley9 published the results which they obtained with an analysor having an accuracy of 0.03 cm3 per 100 g, while that of the usual apparatus was only about 0.2 cm3 per 100 g. During all their experiments the adsorbed layer would have been a difficulty, for the value of the adsorbed hydrogen was approximately equal to that of the dissolved amount. [ ] Since always keeping the same adsorbed layer is very difficult, an error in the correction for the adsorption can be made when using the apparatus of Eborall and Ransley, as well as the earlier apparatus,

Jan 1, 1948

Promoters for Soap Flotation of Phosphate Minerals

Sep 13, 2010

By Songlin Ye, Frank Su

"Recycling valuable metals from waste streams has become increasingly important to the mining and smelting industry in China due to resource depletion and environmental concerns. Predicated on multiple large scale metal recovery operations designed by BQE Water at active mines in the Jiangxi Province of China, this paper presents a case study demonstrating recovery of zinc and copper from the waste stream at a major gold smelter in the Shandong Province of China. One of the issues facing the smelter is the lack of a cost-effective and robust process to recover zinc from the acidic process waste stream. As such, significant amounts of zinc-containing wastewater are neutralized with lime, resulting in not only the loss of zinc metal but also the generation of large volumes of sludge. In the case study, a sulphide precipitation process is chosen to selectively recover zinc and copper from the wastewater, in the form of commercial grade metal concentrates that can be sold as regular concentrates at the going market price. In the current project phase, over 2,500 tonnes of zinc metal and 40 tonnes of copper metal can be recovered on an annual basis. This not only generates revenue to offset waste treatment costs, but also eliminates significant amounts of sludge that would otherwise require storing and further disposal if the metals are not recovered.Introduction / Background With resource depletion becoming a global concern and environmental regulations becoming increasingly strict, companies in the mining and smelting industry are actively seeking technologies to maximize resource recovery and provide concurrent minimization of waste residue production from operational activities. Mining and smelting companies have typically used lime neutralization as the primary method to reduce metal concentrations from mine waters prior to reuse or discharge to the environment. However, this process creates large volumes of metal laden sludge with long-term liabilities in the form of ongoing storage and management (Zinck et al 1997). Recovering metals of value from mine water not only reduces sludge volumes and the costs of associated liabilities, it produces a commercial grade metal concentrate that can be sold to generate revenues to offset treatment costs. ChemSulphide® is a sulphide precipitation process developed by BQE Water that has been successfully applied at mine sites in the Jiangxi Province of China to remove and recover copper from acid mine drainage. The success of these copper recovery water treatment plants demonstrates both the economic and environmental benefits of recovering residual metals from mine water and provides reference for the copper and zinc recovery project at a gold smelter in the Shandong Province that is the subject of this case study."

Jan 1, 2017

By G. W. Preckshot, N. G. DeLisle, C. E. Cottrell, D. L. Katz

MOST crude oils contain asphaltic substances that may be naturally or artificially precipitated. In the Greeley field, California, this asphaltic bitumen is precipitated during the flow of the oil from the reservoir to the stock tank. The mechanism of such precipitation is not well understood. This paper presents the progress that has been made by using the electron microscope as a new tool and by observing the effects of the streaming potential on the formation of bitumen particles. Crude oils at atmospheric pressure viewed in the electron microscope in very thin films under a vacuum showed no asphaltic particles. A technique of preparing slides of thin films by dilution of the oil with benzene and washing in petroleum ether was used at first, and these observations showed that the solvents caused the formation of the particles, varying from 0.01 to 0.2 micron in diameter. The electrical effects of fluids flowing through porous solid were studied, with emphasis on the formation of colloidal particles by the streaming potential. The streaming potential of crude oil flowing through sand was measured and was shown to be responsible for the formation of bitumen particles. These results bring out a new phenomenon, which may occur when crude oil flows through the porous oil reservoir.

Jan 1, 1942

By Samuel G. Vera

INTRODUCTION The Climax Mine is a property of Climax Molybdenum Company, a division of AMAX Inc. Climax is located in the central part of the Colorado Mineral Belt on the west slope of the Tenmile Range, Lake County, Colorado at 3,425&apos; m. above sea level. Climax Mine, the largest single producer of molybdenum in the free world, has been a cornerstone of mining in the State of Colorado for many years. Before molybdenum was known, the early hunters of gold and silver laid their hands on the outcrops of the Climax deposit and left it as low quality lead or graphite without much value. Today, 44,000 TPD of ore is extracted from the heart of Bartlett Mountain. The molybdenum, separated from the ore, is vital for mankind, being used for everything from fertilizer to fine components of aerospace ships, because of its valuable physical and chemical properties. The operations at Climax have never remained static. Constant demand for the "gray gold", and technological advancements, have converted Climax into an "open book of technology", where learning the still-hidden secrets of mining is a continuing process. (All figures related to tons are metric tons) BRIEF HISTORY The mine produced its first molybdenum ore in 1918. It was shut down in 1919, resumed production in 1924, and has been in continuous production since that time. During World War 11, a peak of 20,000 tons per day was reached, then tonnage dropped from 1945 to 1950. Since 1951, production has been in- creasing, reaching a peak of 46,000 tons per day during the month of June, 1980. Early mining used shrinkage stoping. Block caving using the grizzly system was introduced in the early 1930&apos;s. Caving methods were improved through empirical studies of rock behavior and by trial and error, evolving a very efficient mining method by the late 1940&apos;s. This form of continuous retreat panel caving, with small modifications, is still used today, and has made the Climax Mine one of the biggest underground mines in the world. The Climax Mine, synonymous with molybdenum, was essentially an underground mine until 1973 when the open pit was introduced. Since then, both mining methods have operated successfully. Current production is 60% from underground, and the remaining from the open pit. Climax has been in continuous operation for 56 years, and as of December 31, 1980, more than 386 million tons of ore have been mined. The orebody is not fully defined, and at the present mining rate, the known life span of the mine will be to the year 2020. GEOLOGY The Climax deposit is a large low-grade porphyry molybdenum deposit somewhat similar to porphyry copper deposits, with a well- mineralized quartz molybdenum stock work sys- tem. It lies within the pre-Cambrian granites and schists and the Tertiary Climax porphyry. The age of mineralization is thought to be mid-Tertiary and is characterized by fracture filling and replacement through silicification. The main economic mineral is molybdenum, with pyrite, cassiterite and wolframite as by-products. Fluorite and topaz also occur, but are not recovered at this

Jan 1, 1981

By Michael Robert Hodson

I. Introduction The free market cash price of aluminium in the third quarter of 1985 is approximately $1000/tonne, well below the short as well as the long run marginal costs of production. The current disparity between marginal costs and price, as well as the pattern of prices since their high level in 1980, has led many economists to question whether prices are governed by the &apos;fundamentals&apos;. Prices, some would argue, are the result of speculation; and speculation is irrational, little influenced by the fundamentals of the industry. The object of this paper is first to examine the relation between the fundamentals and price. A number of simple models are formulated and some empirical evidence is given to show that prices are not very different from costs. There are good reasons why costs and prices have fallen since 1980. Second, the connection is drawn between the fundamentals and speculation. To do this the concept of &apos;rational expectations&apos; is defined and applied to a model of the aluminium industry. Then speculation is introduced into the model and the characteristics of the solution are examined. The object is to discover the new factors that determine prices and the basic change in the nature of the solution that is caused by speculation. 2. Prices and the Simple Supply-Demand Model Consider a simple model of the aluminium industry. Demand, D, is determined by economic activity, A, given exogenously, and inversely by the price, P. Supply, Q, is determined by the inverse of the rnarginal cost curve, and so varies inversely with exogenous factor costs, C, and directly with price. Price is determined by the equality of supply and demand. Given the equilibrium level of demand, price in this model is equal to the rnarginal cost of producing the required level of demand, P = MC (Dl. Algebraically, [ ] How well does this simple model explain the change in prices during the last five years? Table I shows the LME cash price and the estimated marginal cost of producing consumption during the second quarters of 1980 through 1985. The figures in the table show that price and the marginal cost of supplying demand both fell between 1980 and 1982, rose in 1983 and by 1985 had fallen again. Only in 1984 is the direction of change different. And during the 1980 to 1985 period, marginal costs fell by approximately $560/tonne while the LME cash price fell by $678/tonne. There is a correspondence between the fundamentals of cost and price over most of the individual years and the period as a whole.

Jan 1, 1986

By George Smith

THE discussion of production control at the Insti-tute&apos;s annual meeting was profitable in that it started some thinking. One pertinent question there raised was how the opening of new mines, whose now unneeded output would inevitably react on prices, could be postponed until the market was ready to ab-sorb their output. In transportation some restraint is being exercised on building new and unneeded fa-cilities, but in production no general solution of the problem has been offered. Yet in a special field of new development of increasing importance a quick and easy solution has been suggested. I refer to the leasing of mineral deposits on the public domain. The report of the United States Coal Commission says: "In its possession of approximately 60,000,000 acres of public coal lands the Federal Government has its own responsibility in restraining overdevelopment. The Department of the Interior, which has control of these lands under the leasing law, construes the law as giving the department no discretionary right to refuse applications for leases regularly made by qualified citizens or corporations for coal deposits on the pub-lic domain. It presumes, that the applicant believes there is a need for an additional coal mine in his local-ity and expects to find a market for the coal produced. Overdevelopment, however, is a fact in the West as well as in the East, and wherever present involves needless investment and excessive costs of operation. Plainly, the leasing law should be so amended as to give the executive department full discretion in its approval of the opening of a new coal mine on the, public domain, making that approval contingent on the showing that the new mine would serve the in-terest of the consuming public." A similar view of the Federal Government&apos;s re-sponsibility in restraining overdevelopment of its oil lands has been presented by the Federal Oil Conser-vation Board. The leasing law vests little or no dis-cretion in the Secretary of the Interior, who must grant a lease to a qualified applicant regardless of any obvious country-wide condition of surplus produc-tion. This wide-open invitation to exploit and dissi-pate the people&apos;s own oil resources could be restricted by simple legislation, although as remarked by the board, such a legislative remedy for a plain economic ailment "does not evoke popular support when its purpose is avowedly to put the brakes on development of natural resources."

Jan 5, 1928

By Patrick Doig, Ross Webb

The Bradshaw Section 5A Interceptor involves the construction of two miles of 108-inch, finished diameter tunnel in dry soils. Excavation is generally by Lovat TBM with ribs and lagging support. The tunnel is beneath a recreational parkway and stringent measures have been enacted to preserve the parkway and minimize disruption to the neighborhood. Apart from these constraints, the project would have been unremarkable but for the intervention of CalOSHA and the local fire department who ordered extraordinary fire protection measures. The paper discusses the cause and effect of these measures and comments on the potential repercussions for other projects.

Jan 1, 1999

By H. Y. Sohn, H. K. Lin

The leaching of primary porphyry chalcopyrite ore under simulated solution-mining conditions was studied using a packed-bed reactor. A mathematical model incorporating the intrinsic leaching kinetics of chalcopyrite and pyrite grains, the pore diffusion of dissolved oxygen within the ore fragments, liquid-solid mass transfer, and the effect of fluid flow and axial dispersion was formulated and tested for the overall leaching process. The dependence of oxygen solubility on ionic strength of the solution was also incorporated into the model. Satisfactory agreement between model pre- dictions and experimental data was obtained. The model can also predict the rate of the leaching process under different temperatures, oxygen pressures, solution flow rates, and different size distributions of ores.

Jan 1, 1991

By Brian Hester

Many Third World African countries are well-endowed with minerals - especially gold and diamonds - while only a few have important base metal deposits. For decades since colonial rule, political and economic conditions discouraged interest by Western capital. Influence from Soviet Bloc countries, however, has declined with the move toward multi-party rule. And the left wing orientation, once widely favored by Third World African countries, has almost disappeared. With International Monetary Fund (IMF) encouragement, these Third World African countries now encourage representational government and solicit western finance to expand their industries. Mining is especially encouraged. The North American mining industry is following the same trail as other capital intensive industries and looking abroad for opportunities. The Prospectors and Developers Association of Canada released figures that show exploration expenditures in that country were halved between 1987 and 1990. Figures for the United States are not so easily found but every indication points to a downward trend. While total annual expenditures on US exploration by corporations as a group are either declining or remaining constant, expenditures away from North America is increasing. Gold exploration expenditures in 1991 by the major companies tracked by Minerals Economics Group were less in the United States than for Latin America and the Southwest Pacific combined. The same study showed as much was spent in the Republic of South Africa and "Other" areas combined as in the United States. Expenditures by major corporations in these "Other" areas amount to only 5.2% of their total budget. Third World Africa is a major component of these "Other" areas.

Jan 1, 1993

By Orlando Bernal

El presente texto aborda el aspecto termodinámico del sistema de lixiviación -en tanto predice los fenómenos que ocurren en el interior de la pila para luego continuar con el análisis del mecanismo cinético. La metodología aplicada en cuanto a los mecanismos de lixiviación, difiere de otros trabajos porque aquí se considera los tres mecanismos por separado (óxidos, sulfuros secundarios y primarios) basados en el análisis secuencial del cobre. Asímismo la cinética per se obedece las leyes de la termodinámica ergo, cuyo aspecto no puede ser ignorado en un análisis global. En este sentido, se presenta el modelo de desarrollo matemático como una herramienta óptima que controla y predice este proceso del lixiviación por medio de la simulación utilizando la ecuación de continuidad, la cual supone flujo tipo pistón de la fase líquida en el interior de la pila.

Sep 9, 2007