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By J. B. Hiskey, V. M. Sanchez

Electrochemical oxidation of arsenopyrite (FeAsS) has been investigated as an attempt to gain a better understanding of its dissolution chemistry. Rest potential measurements, cyclic voltammetry and constant potential experiments were conducted in the pH range from 8 to 12 in the absence and the in the presence of cyanide. A two-step reaction sequence is suggested by the electrochemical measurements. The initial step is described by: [FeAsS+6H20=Fe(OH)3+H2AsO3- +S°+7H++6e] The second step involves the oxidation of the arsenite and sulfur according to the following reactions: [H2As03-+H20=HAsO24-+3H++2e and S° +4 H2O=SO4-+3H++6e] Stoichiometric determinations confirm that 14 electrons are involved in the overall reaction.

Jan 1, 1992

By J. W. Lowry

After years of processing copper porphry ores, the Ray concentrator of Kennecott Minerals Company installed a concentrate regrind mill in its flotation circuit. The first cleaner concentrate is reground rather than the usual rougher concentrate. An additional cleaning of the reground product yields an increase in copper content of the final concentrate and a significantly lower insol content. The desired goal of decreasing the energy requirements for smelting the concentrate has been achieved.

Jan 1, 1980

By M. N. Semenoff

On July 8, 1999, EPA announced the RCRA Cleanup Reforms, a set of administrative reforms designed to achieve faster, more efficient cleanups. This paper will discuss the Reforms, the status of their implementation and assess these potential impacts on the mining industry.

Jan 1, 2001

By Richard J. Adams

Coal jigs have played a predominant role in U. S. coal preparation for fifty years. Recently, an improved fine coal jig has been used to prepare the middle size range coal. These efficient machines are changing the historical thinking about jigs and is consistent with trends in coal preparation throughout the world. The performance achieved and operating cost savings are causing a change in fine coal cleaning strategy. With the exception of a handful of operators, fine coal jigs are generally not well understood by the industry. The objective of this paper is to provide some insight into the past use of fine coal jigs and their potential in the future. Improved Fine Coal Jig Since the mid 701s, an improved fine coal jig has been employed to an important niche in preparation, the 19 mm x 100 M range of cleaning. Several factors due to mining and liberation considerations have caused an expansion of this middle range of coal resulting in a host of challenges for coal preparation engineers. Fine coal jigs have been commissioned in several installations in North America to handle these important applications as shown in Table No. 1.

Jan 1, 1988

By V. F. Marsters

THE main producing oilfields in Peru are located in the department of Piura and province of Thumbes, adjoining Ecuador on the south and west. In the department of Puno, a small field known as the Pirin or Hauncané Area was exploited some years ago by Fred Brown and associates and considerable production obtained. As. shown by the statistical table of production, this area reached its maximum production about 1909; since 1915, operations have been suspended. During the past year, however, the Peruvian Corpn. has acquired some interests in this section. It is reported to have made a few shallow tests with the hope of obtaining sufficient production to supply fuel for its railway lines, which operate between Mollendo on the coast and Puno and Cuzco in the interior. Only partial success has accompanied these efforts; nevertheless, exploitation is being continued. The petroleum of this region contains a paraffin base with small amounts of asphalt. While the gasoline content is small, the kerosene content runs as high as 30 per cent., with the fuel element varying from 50 to 72 per cent. While it is known that the structural conditions of the Huancané area are somewhat complicated, it is believed that exploitation based on a careful interpretation of the geology of the region will eventually yield commercial production of at least modest proportions. In the main fields in Piura and Tumbes, drilling operations were somewhat more active during the first half of the year, than in 1922. The latter half of the year witnessed curtailment, owing to the abnormal situation in the petroleum industry at that time. For the same reason, no attempt was made to obtain the maximum production from existing .wells. Production was pinched down and exportation of crude was correspondingly reduced during the latter half of 1923. Nevertheless, the total production of the Peruvian fields is considerably in excess of that for 1922, as is also the production of the Negritos area alone.

Jan 3, 1924

By Charles L. Mantell, James E. Hoffmann

Mechanical inclusion, electrophoretic deposition, and adsorption were studied as mechanisms for code-position of aluminas present in copper-plating electrolytes as an insoluble disperse phase. Mechanical inclusion was not a significant factor. That codeposi-tzon of aluminas by an electrophoretic mechanism was unlikely was substantiated by measurements of the potential of the aluminas. The alumina content of the deposits was studied as a function of the pH of the bath. These tests in conjunction with sedimentation studies demonstrated the absence of an isoelectric point for the alutninas over the pH range examined. Thiourea in the electrolyte (a substance known to be adsorbed on a copper cathode during electrodeposition) affected the amount of alumina in the electrodeposit. However, no adsorption of thiourea on aluminas in aqueous dispersions was detected. If it were possible to produce a dispersion-hardened alloy of copper and alumina by electrodeposition, an alloy possessing both strength and high conductivity at elevated temperatures might be anticipated. Investigation of the mechanism of codeposition of aluminas with copper was undertaken with the hope that knowledge of the mechanism would aid in the development of such an alloy. The word "codeposit" here does not necessarily imply an electrolytic phenomenon but rather that the materials codepositing, the various aluminas, are transported to and embedded in the electrodeposited copper by some means. Mechanical inclusion in electrodeposition implies a mechanism of codeposition which is wholly mechanical in nature; the only forces acting on a particle are gravity and contact forces. Such a particle is presumed to be electrically inert and incapable of any electrical interaction with electrodes in an electrolytic plating bath. Processes for matrices containing a codeposited phase by electrodeposition from a bath containing a disperse insoluble phase frequently state that code-position is caused by mechanical inclusion.10,2,12 If settling, i.e., gravity, be the controlling mechanism for codeposition of aluminas, then assumptions may be made that 1) the content of alumina in the electrodeposit should be enhanced by increasing the particle size, 2) the geometry of the system, that is, the disposition of the cathode surfaces relative to the di- rection of the falling particles, should affect the alumina content of the electrodeposit, 3) in geometrically identical systems the chemical composition of the electrolyte employed should exercise no effect on the alumina content of the deposit, that is, the alumina content should be the same in all cathode deposits irrespective of bath composition. A bent cathode19 evaluates the clarity of filter effluent in electroplating baths by comparing the roughness of the deposit on the vertical surface with that on the horizontal surface. Two difficulties are inherent in this technique: 1) the current density on the horizontal portion of the cathode would be substantially greater than that on the vertical surface; 2) should the deposit obtained be rough, projections on the vertical face could act as horizontal planes and vitiate the relationship between the vertical and horizontal surfaces. Bath composition should have no substantial effect on the alumina content of the deposit. Two different electrolytic baths were employed. They possessed variant specific conductances and substantially different pH ranges. The experimental tanks were rectangular Pyrex battery jars 6 in. wide by 3 1/4 in. long by 9 3/4 in. deep. The cathodes were stainless steel 316 sheet of 0.030 in. thickness, cut to 7.5 by 1.75 in. and bent at right angles to form an L-shaped cathode whose horizontal surfaces measured 1.75 by 3.0 in. All edges and vertical surfaces were masked with Scotch Elec-troplaters Tape No. 470. The anodes were electrolytic cathode copper 9 in. high by 2.25 in. wide by 0.5 in. thick. To eliminate inordinately high current densities on the projecting edge of the cathode, the anode was masked 1 in. above and below the projected line of intersection of the cathode with the anode. The exposed area of the anode was equal to that of the cathode, providing both with equal average current densities. The agitator in the cell was of Pyrex glass and positioned so its center line was equidistant from cathode and anode, and a plane passed horizontally through the center of the blade would be located equidistant from the bottom of the cathode and the bottom of the deposition tank. The assembled apparatus is depicted in Fig. 1. Hatched areas on anode and cathode represent the area of the electrodes wrapped with electroplaters tape. MATERIALS The chemicals were copper sulfate—CuSO4 • 5H2O— technical powder (Fisher Scientific Co.). Spectro-graphic analysis showed substantial freedom from antimony, arsenic, and iron. Traces of nickel were present.

Jan 1, 1967

Kaiser Sees Bright Future for Jamaica Kaiser Aluminum Co. has a big stake in the British West Indies, the Island of Jamaica in particular. There, Kaiser is busy developing one of the most promising bauxite finds in recent years. The $12 million operation was officially opened in February. Facilities have a rating of an annual capacity of 2 million tons and will supply Kaiser plants with ore for years. The ore comes across the Gulf of Mexico, up the Mississippi to stockpiles at Baton Rouge. The stockpile at Baton Rouge would throw many an old river boat skipper for a loss. Where no mountain once existed now stands a man-made bluff of bauxite, known as Bauxite Peak.

Jan 6, 1953

By I. I. Maximov

The paper describes the results of studies performed with a view to develop an improved technology for processing high-grade massive and cupriferous ores of the Talnakh deposit, the main valuable components being nickel, copper and PGM. The studies? main task was production of nickel concentrate with nickel content of approx. 15%, nickel recovery being as high as possible. The studies were performed on two ore samples. One sample was a mix containing high-grade massive (78%) and cupriferous (22%) ores with nickel content of 1.93% and copper content of 3.6%; the other sample was a mix of high-grade ores with nickel content of 2.25% and copper content of 3.72%. Main ore minerals were copper sulfides ? chalcopyrite and cubanite, their total content being 10.5% ~ 11%, pentlandite (5.2% ~ 6.1%) and pyrrhotite (36.7% ~ 42.9%). Influence of grinding media on pentlandite and pyrrhotite separation results, achieved through combined use of triethylenetetramine (TETA) and sodium sulfite (SS), was also investigated. It is shown, that combined application of TETA/SS in the ratio of 1:2, permits to grind products in metal mill (mild steel) with metal balls (mild steel), achieving results that are similar to those achieved by means of grinding in inert grinding media with TETA/SS ratio of 1:1. Application of the developed technology provided for production of high-grade nickel concentrate with nickel content of 14.7% ~ 15.6%, nickel recovery being 76 % ~ 77%. Earlier experiments performed on the above mentioned ore mix permitted to produce nickel concentrate with nickel content of 10%, nickel recovery being 75.9%. Consequently, nickel content was increased by 4.7% ~ 5.6%, and a higher nickel recovery was achieved. The paper also describes metallurgical results related to nickel, copper and PGM with regard to all processing products.

Jan 1, 2014

By H. Stocker, C. E. Makepeace

"This paper presents the statistical analyses of several sets of data acquired in several programs of sampling of radon daughters in uranium mines. The measurements were taken over periods of days or weeks for given locations or location occupations within these mines. Because the sampling applies to specific intervals of time and specific locations, a method is suggested f or the eventual application of a monitoring program which would be suitable on an annual basis for these locations. The present data and analyses thereof are not justifiably applicable to a monitoring regimen on an annualbasis, without a number of additional assumptions.The aim of the present analyses of concentration measurements is the determination of the minimum number of measurements required to achieve an annual radon daughter exposure estimate, for individual workers, having an error no greater than 50% at the 95% confidence level. The criterion of accuracy is taken from a statement in the American National Standard, Radiation Protection in Uranium Mines (ANSI NI3.8-I973), and is currently used, in somewhat modified form, as a guide to uranium mining licensees in Canada. Uncertainties associated with occupancy time are ignored in the present analysis. IntroductionOne of the principal aims of any scheme of radiation protection is that of improving the accuracy of exposure estimation for workers. The example presented here is from the area of radon daughter exposure estimation for uranium miners. The conventional means of estimating workers' exposures is grab sampling of radon daughter concentrations combined with occupancy time weighting in the various work and travel locations. Uncertainties exist in each of these components, and in an environment of highly variable radon daughter concentrations (such as an active uranium mine) one is always uncertain as to the representativeness of the grab sample (compared to the average concentration) unless a sophisticated monitoring scheme has been implemented based on previous experience in such an environment.Improvements in the accuracy and precision of employee radon daughter exposure records depend, primarily, on three factors;"

Jan 1, 1980

The combustion characteristics of Australian coals which contain high inertinite have been studied in a laboratory drop tube furnace and a Thermogravimetric Analyser. The pyrolysis chars and combustion residues were microscopically characterised using a modified coal petrography technique. Results indicated that the overall burnout of inertinite-rich Australian coals under pulverised fuel combustion conditions could be generally within a range of 97 - 99 per cent burnout. The studies showed that poor coal burnout cannot be generally related to high inertinite content in the Australian coals. The extent of coal burnout varies from coal to coal and vitrinite as well as inertinite may contribute to the unbumt chars in combustion residues. Combustion conditions had greater influence over char formation and coal burnout than the coal properties. However, under similar pf combustion conditions, coal rank and coal maceral composition had a strong influence over the coal combustion behaviours and final coal burnout. Simple correlations using coal properties may be used but with caution to determine coal volatile release and burnout at high temperature and rapid heating conditions.

Jan 1, 1991

By David A. Collins

Red Dome Gold Mine classifies ore types within the pit by gold and copper grades. Copper grades are further distinguished by total copper and cyanide soluble copper levels. At present, Cyanide Soluble Copper samples take six hours of agitating before they can be assayed. This agitation time produces results which are a proportion of the total cyanide amenable copper. This relates to our plant's performance. Frequently the total copper result is needed before we can begin the cyanide soluble copper analysis. This caused a protracted tum around time. Mennetech Pty. Ltd has produced a catalyst proven by David Martin Menne to accelerate the cyanidation of gold. David said that the information at hand indicated that Leach WELL TM also accelerates the leaching of cyanidable copper substantially. Test work was undertaken on-site at Red Dome Gold Mine to investigate the potential of Leach WELL TM to reduce the leaching period and therefore, the overall tum around time required for cyanide soluble copper determinations.

Jan 1, 1995

By John M. Pitt

Shear strength assessment and the associated variability in rock masses historically have been hindered by high costs and biases in laboratory testing programs. An in situ direct shear device was developed on the principle of the previous borehole shear device for soils. Using wedge action to simultaneously apply normal and shear stress to an envelope of material on the periphery of a borehole, the device develops a complete Mohr-Coulomb failure envelope. Tests performed in homogeneous materials show expected strengths and their variability equivalent to laboratory tests. However, tests in a structurally non- homogeneous coal did not display significant variability. A 38 mm diam borehole was used in this work; however, larger or smaller bore- holes may also be used within the size limits of the device. The device is employed in holes commonly drilled for rock bolt placement, at 1 to 2 minutes per test.

Jan 1, 1984

By A. Shtiza

This literature review discusses the role of the Albanian institutions, the natural resources industry, potential investors and stakeholders in order to provide a set of indicators that can help to monitor amelioration within sustainable development principles. A map with the potential prospects of the natural resources will be a first step in identifying the further potential for exploitation. Mineral resource policies and governance, sustainable processing and supply chain as well as environmental management information system are some of the crucial tools identified, that will help to set up the indicators and quantify the achievements in environmental management in Albania. Moreover, the integration of practices that will support institutional capacity building; follow-up practices; the mainstreaming of global environment into planning; and the compliance monitoring process will additionally improve the environmental situation in Albania. Aligning business strategy with environmental policy, socio-economic analysis, environmental auditing are decisive tools in order to provide the Albanian authorities with a clear overview of the economic costs and the social benefits for sustainable development.

Jan 1, 2011

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By D. Farrow

Future development of kimberlite mines is now focused on mining at deeper levels. The consequences are increased difficulty and costs of the mining operations. The decisions on investments require accurate resource evaluation and quantification of the risk. In the decision process the first step consists in choosing the number of boreholes sampling the pipe relative to the level of uncertainty that can be accepted. The uncertainty in the volumes of rocks of different types can be assessed as soon as we can estimate these volumes from a given borehole layout and calculate the error by means of its variance for instance. In theory this can be achieved by using geostatistical techniques (‘transitive theory’), but in practice the calculation of the error on volumes can be achieved in very particular cases, assuming some regular sampling patterns. A different approach has been chosen based on simulations, giving maximum flexibility to reproduce the reality of the sampling procedure. The idea is to simulate the geometry of several ‘possible’ pipes with their internal geology and estimate them by kriging. Several experimental errors are obtained on which risk analysis can be performed. The aim is to find a feasible method to perform the simulations with reasonable chance to correctly represent the reality, without data on the pipe extension. The methodology applied is based on some hypotheses that can be assessed by the geologist as well as by the geostatistician. The procedure assumes a geological model based on current knowledge including appropriate geostatistical variation. What make these simulations specific and powerful in this case comes from the fact that the boundaries between the different rock-types can be simulated using a transformation of the real 3D space into a 2D space defined by means of polar coordinates. Ultimate transformations to account for smoother variations with morphological transformations allow the generation of realistic pipe geometries on which sampling pattern can be used to evaluate the estimation errors. By estimating the simulated pipe geometries with different boreholes layouts a risk curve expressing the uncertainty in the volumes of the different rock-types versus the number of holes can be developed.

Jan 1, 2003

By G. F. Dillion, A. F. Armington

THE present method for the ultrapurification of boron involves the formation, distillation, and decomposition of boron tribromide.' However, the boron tribromide prepared contains several impurities in the ppm range, even after distillation. Some of these impurities, notably carbon, can be reduced after decomposition by zone refining. In this study, a comparison of the purity of boron tribromide at various formation temperatures is presented. The apparatus employed consisted of a bromine flask connected to a 22 mm ID horizontal quartz reaction tube packed with amorphous boron powder, which was in turn connected to a receiving flask cooled with an ice bath. Argon was used as a carrier gas. The approximate rate of passage of bromine to the reaction tube was 25 g per hr. The reaction was first investigated at several temperatures in order to determine the lowest temperature necessary to produce a colorless product which was assumed to be an indication of complete reaction of the bromine. The lowest temperature found in this study was 420oC. The amount of impurities found in the boron tribromide at various formation temperatures is shown in Table I. The data presented are emission spectroscopic results of boric oxide produced by the hydrolysis of 2 to 3 g of boron tribromide in 10 ml of distilled water. After hydrolysis, the samples were dried several hours on a hot plate. Assuming equilibrium conditions in the reactor, one can make approximate thermodynamic calculations estimatling the completeness of reaction of bromine with boron and its impurities at various temperatures. Data for these calculations were taken from Rossini,3 and must be taken as approximations since the T?S factor was not included in the calculations. The results of such calculations indicate that, with the exception of carbon bromina-tion, all impurities would react almost to completeness (> 99 pet) at all temperatures between 400" and 900oC. In the case of carbon, which cannot be accurately analyzed spectroscopically, it is estimated that only about one sixth as much carbon tetrabromide would be formed at 400" than at 900°C. Since some marked reductions in impurity content were observed at the lower reaction temperature which would not be predicted by thermo-

Jan 1, 1962

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

By G. M. Wilemon

The U.S. Bureau of Mines has conducted preliminary investigations on the leaching of phosphate ores obtained from deposits in the western United States using sulfuric acid (H2SO4) in the presence of methanol. Phosphate extractions in excess of 80 pct were obtained on an ore sample from Pocatello, ID. Initial leaching studies using the ore as received yielded extraction levels of approximately 35 pct. However, when the sample was ground for as little as 5 min in a rod mill, in methanol, then treated with HzS04, 82 pct extraction was achieved. The R2O3-P2O5 (R2O3 = Al2O3 + Fe2O3) ratio of the starting material was 0.11. Solubilized products after leaching exhibited an R2O3-P2O5 ratio of 0.02, which is well within desired limits. These results illustrate the potential of acid-alcohol leaching for recovering phosphate values from marginal-grade ores and as an alternative to methods involving current beneficiation techniques that yield lower phosphate recoveries.

Jan 1, 1992

By Gerald Sherman

IN the southern field of the anthracite region of Pennsylvania, many of the coal seams dip at angles of 40° to 50° from the horizontal. For transportation purposes, "tunnels" are driven across the coal measures and, occasionally, "rock gangways," beside the seams and parallel with them. The use of gangways driven in country rock appears to be increas-ing, as they avoid the maintenance' of long gangways in coal, which eventually are driven to the colliery boundaries, and permit mining from a number of intermediate blocks without interference. The rock consists of slates or sandstones of moderate hardness, which may range into very hard, highly siliceous, fine-grained conglomerates. In this distinctly bedded formation,' the direction of the heading, whether parallel with or across the structure, makes it necessary to distribute the drill holes in a different pattern to break the ground, but does not change loading conditions. In 1932, practically all the mucking was done by hand, and it was the established custom to use four men on two drills for drilling and breaking the ground, and five for loading it, out. A driver and mule was needed in addition, to assemble the rock cars at a siding or branching track in the rear, pending their final disposal. This might occupy the driver's whole time, or if the length of haul were short, he might be able to do other useful work. It was thought possible in 1932 to reduce the cost of driving such headings in rock by mechanical loading, and to investigate this subject a scraper loader was used in a section of tunnel then being driven. Opera-tions while driving 195 ft. of this tunnel using a scraper loader were care-fully observed. Time studies were made of the loading, and records made of the routine of breaking ground, but not in such detail. Tunnels or gangways in the colliery are 7 ft. high above the rails, by 10 ft. wide, which requires a minimum of 8 ft. in height, broken to allow for rails and ties. This cross section is of sufficient size to permit the use of any one of several types of power loaders, but for this demonstration if was found most convenient to use a scraper loader.

Jan 1, 1936