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By Marshall B. Standing, Donald L. Katz

DENSITY data are reported on 16 saturated hydrocarbon vapors at pressures ranging from 1000 to 8220 lb. per sq. in. and at temperatures ranging from 35° to 250°F. These data have been used to extend the compressibility-factor chart for natural gases up to 10,000 lb. per sq. in. The relatively large quantity of high-boiling constituents present in high-pressure vapors in equilibrium with crude oils makes it necessary to include in the analysis of the gas the molecular weight, density, and possibly boiling range of the heptanes and heavier fraction. Relationships have been presented by which the density of gases may be obtained directly from the temperature, pressure, and gas gravity provided the gases have a common source or are similar in composition. INTRODUCTION The densities of natural gases are necessary in many engineering computations in petroleum production and utilization. Gas reserves, changes in reservoir pressure, gradients in gas wells, metering of gases, pipeline flow, and compression of gases are typical problems requiring the density of the gas. A decade ago, engineering computations used ideal gas laws with deviations up to 500 lb. per sq. in.4 Recent discoveries of pools having pressures up to 7500 lb. per sq. in., and installation of pressure-maintenance and recycling plants, have increased the need for data on gas density at high pressures. METHODS OF COMPUTATION The accepted method of computing the density or specific volume of natural gases is the use of the ideal gas law corrected by a compressibility factor. The method proposed by Kay7 of correlating compressibility factors for gaseous mixtures on pseudocritical properties5 appears to be satisfactory for natural gases.2 The methane-compressibility factor has been shown to deviate systematically from the behavior of natural gases2 and a chart giving these corrected factors is available. A method of computing specific volume of gaseous mixtures from partial molal volumes has been reported by Sage and Lacey.8 Complete data for the computation are not yet available for all hydrocarbon gases. Most of the reported data on gas densities have been in the single-phase region removed from the dew point or saturation condition. Since most gases in the reservoir or while on contact with liquid during flow are saturated, the determination of densities under conditions of saturation is particularly important. Although there is no reason to believe that the saturated gases differ in behavior from those considerably removed from their dew points, the usual experimental determinations find difficulty on approaching the dew-point conditions. This paper reports the density of 16 saturated gases in equilibrium with crude oils. The relationships developed to compute the density of gases to high pressure' have been modified and enlarged. A simplified method of obtaining gas density is presented in the form of charts, which apply for specific groups of gases.

Jan 1, 1941

By Jerome Alexander

THE object of this paper is to show that many of the important phenomena of metals and alloys are due to the facts that, at some stage, metals and alloys, or some of their constituents, are in a colloidal state and that a portion of the metal or alloy tends to remain in this state. The so-called amorphous phase in pure metals is an isocolloid, consisting of colloidal groups of metal molecules that may be dispersed in still more finely subdivided metal; these colloidal particles are not truly amorphous, but may consist, in part, if not entirely, of ultramicroscopic crystals; as a result the expressions amorphous phase and amorphous theory might be replaced by the expressions colloidal phase and colloidal theory. Any substance is in the colloidal state when the constituent particles consist of molecular or atomic groups, whose size varies approximately from about 100µµ down to about 5µµ, that is from just below the limit of microscopic resolvability to the dimensions commonly ascribed to the larger molecules. Colloidality involves no assumption as to the shape, internal structure, or orientation of the colloidal particles; size alone is the critical factor. A colloidal system may therefore contain crystalline groups, or amorphous groups (non-crystalline, random or haphazard clusters), or a mixture of the two. All colloids consist of at least two phases, the subdivided substance, or dispersed phase, and the substance into which this is subdivided, the dispersion medium. It is not necessary that there be any chemical difference between the dispersed phase and the dispersion medium. As molecular forces are extremely powerful, their application may produce marked changes in the physical properties of metals. It is doubtful whether metal in the interior, especially of large masses, possesses the same properties as that on or near the surface, which alone is open to, inspection.

Jan 10, 1920

The discovery of economic uranium miner alisation in unique geological conditions at Yeelirrie, 700 km NNE of Perth, presented Western Mining Corporation Limited with a num- ber of sampling and evaluation problems. Carn- otite mineralisation occurred in a porous cal- crete-clay lithology in close proximity to the water table; background information on such a deposit was non-existent and sampling in these conditions could be difficult. The deposit was sampled initially by aug- er drilling with X-ray fluorescence analysis of drill cuttings, followed by reverse circulation and diamond drilling with analyses by X-ray fluorescence and gamma logging of the holes. Two costeans provided lithological and grade distribution data and mining experience in the deposit. Spoil from the costeans was stockpiled according to location in the first costean and according to location and grade in the second costean. Samples from the various stockpiles were analysed by X-ray fluorescence. No. 1 costean was extensively sampled by channel sampling of the walls and by pit sampling of the floor of the benches of the costean by back hoe. No. 2 costean was sampled by Geiger counters mounted in T-probes and by the gamma logging of auger holes to establish the valid- ity of the T-probe results. Samples were taken

Jan 1, 1976

By H. E. Parkinson, Y. P. Chugh

About 90 percent of the coal mined underground in the U.S.A. today is mined by the room-and-pillar system. The productivity of the system dropped from about 14,1t per man-day in 1969 to about 7,3 t per man-day in 1978. Since 1974, the U.S. Department of Energy (formerly the U.S. Bureau of Mines) has been engaged in research to improve the production and productivity of the room-and-pillar system. The effort involves the development of integrated, automated, and remote-controlled equipment and systems including remote-controlled continuous miners, automated miner-bolters, automated extraction systems, continuous haulage systems for use behind miners, and remote-controlled equipment for miners, bolters, and shuttle cars. These systems are discussed briefly, the discussion being related primarily to coal winning, although the concepts could be utilized in room-and-pillar systems in mines other than coal mines.

Jan 1, 1981

By Henry S. Munroe

THE earliest accounts we have of Japan represent the country as having great mineral wealth, especially of precious and useful metals. Marco Polo, the Venetian traveller, in the thirteenth century, writes of "Zipangu:” "They have gold in greatest abundance, its sources being inexhaustible. The king does not allow of its being exported. To this circumstance we are to attribute the extraordinary richness of the sovereign's palace. The entire roof is covered with a plating of gold. . . . The ceilings of the halls are of the same precious metal ; many of the apartments have tables of pure gold of considerable thickness, and the windows also have golden ornaments." Marco Polo also gives an account of an unsuccessful Tartar expedition against Japan, prompted by the supposed great wealth of the country. Columbus also, as well as many other explorers, were attracted and encouraged by these prevalent reports of the wealth of the islands of Zipangu. Kaempfer, writing in 1727, speaks of the great mineral wealth of Japan, and especially of the abundance of gold, which, he says, is found in many provinces. The Portuguese and Dutch, while they had trading-posts in Japan, furnished tangible evidence of the truth of the early reports. Between 1550 and 1639 the Portuguese merchants sent home from Japan nearly three hundred million dollars' worth of bullion, most of which was gold. As the relative value of equal weights of gold and silver was then six to one, while in Europe, at the same time, it was nearly twelve to one, the exchange of silver bullion for gold was by no means an unimportant part of their business. After the Portuguese, the Dutch continued the exportation of bullion, and the exchange of silver for gold, though with less profit, as the relative value of gold increased with the demand. Between 1649 and 1671 the Dutch traders sent home over two hundred million dollars in bullion, of which, however, nearly two-thirds was silver. In 1671 the Japanese government, alarmed at the rapid rate at which the precious metals were leaving the country, issued an edict forbidding the exportation of gold or silver, under heavy penalties, which had the immediate effect of stopping this trade. Besides bullion, copper formed at this time a most important article of export. According to Dr. Geerts,* who has examined the old * Transactions Asiatic Society of Japan, vol. iii, p. 41.

Jan 1, 1877

By Oliver Bowles

Enormous quantities of limestone are used for metallurgical purposes. Approximately 23 million tons were so used in the United States in 1925 chiefly for smelting iron ores in the blast furnace. Smaller amounts are used in basic open-hearth steel manufacture, and in smelting lead, copper and antimony ores. Most limestone producers lave little knowledge of the way in which their stone is used in metallurgy. Maximum tolerances of silica, alumina, sulphur and possibly magnesium; and minimum content of calcium carbonate may be arbitrarily fixed for the guidance of the producer, but aside from these requirements little information is available to producers on the manner in which their stone is used, the office it performs in smelting, or the effects of impurities. More complete [wledge] of utilization would enable limestone operators to solve their production problems more intelligently.

Jan 1, 1927

By Ian Masters, A. R. Khoei, D. T. Gethin

This paper describes an experimental investigation into the effects of process parameters on product quality during an aluminum recycling process. In order to build a model relating recovery to the process parameter variables and then use the model for prediction, process optimisation, or process control, a historical data analysis is employed by observing patterns in the datalogged information at IMCO Recycling Ltd. In previous work, we emphasised the importance of expressing the results of an experiment quantitatively, by implementation of a Taguchi approach, to facilitate understanding, interpretation and implementation. This research presents the technical tools that are needed to achieve quality improvement in recycling of aluminum. In this study we apply the use of historical data matching through a Taguchi orthogonal analysis, in order to control and improve the quality characteristic. For this purpose, a numerical model is developed to characterise the inputs and outputs of the process. A response surface methodology (RSM) is employed to find a suitable approximation for the true functional relationship between response and the process parameter variables. The method of least squares is used to estimate the approximating polynomials. Subsequently, Taguchi's method is used to determine the relative significance of each of the parameters. Finally, process management software (written in Visual Basic) is described, and its interface with the process modelling and optimisation routines is discussed.

Jan 1, 2000

By M. Muskat, R. D. Wyckoff, H. G. Botset

The flow of liquids through porous media is known to follow Darcy's law which states that the velocity of flow is proportional to the pressure gradient. This law is but a statement of the facts obtained from experimental studies and is, therefore, uncontroversial. It should be men-tioned, however, that it applies only when the flow is viscous in nature and that at excessive velocities which tend to produce turbulence, the velocity is proportional to some power of the pressure gradient, the exponent ranging from 1 to 0.5 as the degree of turbulence increases. However., experiments with media having permeabilities corresponding to those of actual producing horizons show conclusively that the actual flow of liquids in a producing horizon must be viscous except perhaps in the immediate vicinity of a well producing at a high rate. Therefore, one is justified in assuming Darcy's law to hold for cases of practical interest, as will be implicitly assumed in this discussion Given this basic law of flow it is possible, theoretically to obtain solutions to any problem of viscous flow of dead liquids1 by the usual methods of potential theory. However, problems of practical interest often present such complex geometrical configurations of sources and sinks (driving sources and output wells) as to make the analytical solutions extremely difficult or even impossible. It is useful, therefore, to note that Darcy's law is precisely equivalent to the law of electrical conduction, so that the pressure distribution in steady state porous flow of liquids is exactly the same as the potential distribution in an electrical conducting medium.2 This analogy permits the use of electrical models wherein the potential distributions may be measured with far greater facility and accuracy than is possible in actual fluid-sand models. Such electrical models were used in determining the pressure distribution about complex arrays of wells, an example of which will be shown later in the discussion of the 5-spot flood. One phase of the porous flow problems which is of considerable practical interest involves the tracing of an advancing fluid front. Thus,

Jan 1, 1933

By J. C. Barker

Alaska, with about 74% of the US continental shelf, is largely unexplored for placers in its vast shallow marine waters. Nevertheless, there are numerous occurrences of marine minerals including gold, platinum, and cassiterite. Offshore dredging has recently begun in the Nome area. State and Federal agencies are preparing additional acreage for leasing. With 76,200 km (47,300 miles) or 54% of the US coastline, Alaska is a vast, largely unexplored frontier for shallow-water marine placers. Despite the general lack of mapping and only sporadic past prospecting, many prospects are known and a major mining operation for gold has recently begun offshore of Nome. Due largely to the demonstrated success of the Nome operation, the US Minerals Management Service is preparing to conduct a lease sale of additional acreage further offshore from Nome. And future sales are being considered elsewhere by both the Federal and state leasing agencies.

Jan 1, 1990

By Shahzad Moosa, John M. Pitt

Statistical variability in rock strength can be evaluated by rapid, inexpensive ultrasonic pulse velocity measurements, an important consideration since rational probabilistic design in rock is often hampered by the cost of obtaining sufficient strength data. Experimental ultrasonic pulse velocity measurements on a set of 96 limestone specimens showed two distinct statistical populations. Both populations followed Weibull distributions, with flexural strength distributions paralleling pulse velocity distributions. Thus, experimental results suggest that strength variability may be predicted from a few rationally selected strength measurements and several ultrasonic tests. The correspondence between strength and velocity may then be used to develop an experimental transformation function, allowing the development of a statistical distribution function for strength based on the known statistics of velocity. Comparison of experimental groups with full sets of corresponding strength1 velocity data showed the technique offers a fairly accurate description of the statistics of strength.

Jan 1, 1986

By Peter J. Suardini

Over the last few years, researcher have been working on improving procedures for fine-coal (minus 150 microns) washability analyses. The effort was stimulated by past difficulties in obtaining accurate and reproducible results from the various commercial laboratories providing fined washability services. This paper contains the results from fine-coal washability testing, performed by Process Technology, Inc. (PTI), as part of a U.S. Department of Energy (DOE)-sponsored project. The testing focused on comparing the performance of a number of media options (i.e., aqueous solutions and organic solvents), as well as evaluating the impact of a number of procedural steps on separation performance. The paper summarizes PTI's recommended washability procedures for various size fractions and ranks of coal, and makes recommendations for future studies of certain phenomenon, such as void penetration and particle density changes, which are not well understood.

Jan 1, 1995

At Black Lake, Quebec, Lake Asbestos of Quebec Ltd., a wholly-owned subsidiary of American Smelting and Refining Co., has opened a $36-million mining and milling operation which will produce about 100,000 tons of asbestos fiber a year and add 7 pct to the Free World's supply. The orebody once lay beneath Black Lake, and readying the ore deposit for open pit mining meant removing about 37 million cu yd of overburden- 30 million cu yd by dredging and pumping, and 7 million by power shovels and trucks. The enormous amount of material to be dredged, control of drainage during dredging, the need to cope with drainage problems in the area and to provide for flood control to replace the regulating effect of the lake, posed unusual engineering challenges and required tremendous capital investment.

Jan 1, 1959

By L. Dison, J. A. Hahn, G. E. Blight

A system of artificial support for shallow mines is described, analysed, and evaluated. The system can be designed rationally to support a predetermined overburden load, and tests have shown that the design theory gives accurate predictions of strength. The support system, consisting as it does of two basic materials, reinforced granular material and reinforced cemented material, is flexible and can be varied to suit changing requirements of height and load. The system of preloading to the design load by jacking off the roof ensures that the walls are both stiff and prooftested.

Jan 1, 1982

By Ross E. BROWNE, Ross B. HOFFMANN

IT seems strange that a theory so devoid of value in its application to our practical problems should attract such widespread acclaim. This appears still more remarkable when one considers the foundation on which it is built. The criticism naturally suggested is as follows: First; the special theory of relativity is based on an assumption which is counter to the fundamental conception of relative motion. Second; the theory claims only a slight modification of Newtonian mechanics-a modification so minute that, even if true, it would have no practical value in its application to any visible occurrence here on earth.

Jan 1, 1931

By B. H. Sage

VARIATIONS in the composition of the liquid phase of natural reservoirs which are continuous through significant ranges in elevation have been noted by petroleum technologists. In general, there is a greater gas-oil ratio and the gravity of the oil is higher in production from the upper parts of the formation. In the present paper the possible changes in composition with elevation which would result from the attainment of thermodynamic equilibrium in a uniform gravitational field have been evaluated for a naturally occurring hydrocarbon liquid, a binary hydro-carbon liquid phase and a binary hydrocarbon gas. The results indicate a progressive decrease in the mole fraction of the components from methane through the butanes with increasing depth, accompanied by a corresponding increase in the amount of the heavier components making up the system. The magnitude of these variations is perhaps insufficient to explain completely the variations in the properties of the liquid phase that are encountered at various elevations within a particular producing horizon. However, the changes are significant and the treatment presents an example of the application of thermodynamic data to the evaluation of the properties of hydrocarbon fluids under the conditions approaching those encountered in natural reservoirs.

Jan 1, 1938

By J. D. Meakin

The self-diffusion coefficients of ß tin have been deterttlltled using a plating and sectioning technique. The principal diffusivities pavallel and perpendicu1ar to the "c" axis are given by the Arrhenius relations Dc = 8.2 exp (-25,600/RT) sq cnl per sec and Da = 1.4 exp (-23,300/RT) sq cm) per sec. The results are discussed in terms of a vacancy mecharism of diffusion. In conjunction with an investigation of diffusion in dilute indium-tin alloys we have reexamined self-diffusion in tin single crystals. The published self-diffusion coefficients of tin, eensham') have always appeared anomalous in comparison to diffusion data for other metals and do not correlate with parameters derived from creep tests.' In addition to the necessity of confirming the self-diffusion values for use in analyzing the alloy work, self-diffusion in an anisotropic lattice is of considerable fundamental interest and confirmation of the published data seemed worthwhile. For a crystal with an axis of symmetry three-fold or higher the diffusivity at an angle 6 to the axis is given by D? = (Da - Do) sin2?+ Do [1] where Da and Do are the principal diffusivities perpendicular and parallel to the axis. For a particular diffusion mechanism, again in a crystal of axial symmetry, these principal diffusivities are [2] Do - ? ?i2 COS?i In these expressions ?i is the displacement undergone by the ith atom and 8, is the angle this displacement makes with the symmetry axis. In this, as

Jan 1, 1961

By Charles L. Kimbell

While the statistical summary focuses on 1991 data, this update and outlook section draws on information available to the author as of the date of final preparation in early 1993. For all the press notoriety associated with the shift in the Near East crisis from the defensive posture of Desert Shield to the restoration of Kuwaiti sovereignty through Desert Storm, this was not the dominant event governing global economic thinking in 1991 and the first half and more of 1992. From the global perspective, the momentous political changes in the area that was the U.S.S.R. and in the smaller emerging transitional economy states of Eastern Europe will have even greater current and long-lasting effects on world mineral industry activities than the crisis in the Near East.

Jan 1, 1993

By D. R. Packard, J. D. Verhoeven

The resistivity us atom fraction relationships for dilute solutions of cadmium, mercury, and tin in molten sodium have been determined. With these data and the resistivity capillary-reservoir technique, the electro-transport mobilities, effective valences, and the diflusion coefficients of the three solutes have been determined. The mobilities are found to be higher than in other molten alloys by a factor of around 20. The results are compared to the Mmgelsdorf model for electrotrmtsport. The high values found for the mobility to diffusion coefficient ratio indicate that small quantities of the alkali metals should be susceptible to purification from many solutes by means of electrotransport. PASSAGE of a direct electric current through a liquid metal containing a solute will usually cause a relative motion between the solute and solvent atoms of the alloy. This electrotransport phenomenon may be described experimentally in terms of the mobility of the solute atoms, i.e., the drift velocity of the solute relative to the solvent per unit electric field. In dilute solutions of liquid alloys this relative mobility becomes a measure of the velocity of the solute with respect to the observer since the motion of the solvent is negligible. The mobility is a significant parameter in evaluating the potential usefulness of electrotransport for such things as purification or solute control upon solidification. Prior to around 1958, quantitative data for the mobility of solutes in liquid metals were restricted to some solutes in liquid mercury. Since that time ad- ditional data have been reported for the mobility of solutes in liquid mercury, bismuth, tin, and lead, as shown in Table I. In 1963 Drakin et al.11 reported some values of a transport number for mercury and thallium in molten sodium and potassium. When these values were converted to mobilities, it was found that the mobilities were higher than any of the previously reported values by a factor of around 20, as shown in Table I. Drakin's experimental technique did not eliminate the presence of back-diffusion and consequently his data were expected to be lower than the true values. The purpose of the present investigation was to determine the mobility of a number of solutes in molten sodium with an experimental technique which eliminates back-diffusion errors. EXPERIMENTAL The technique used to determine the mobility was a resistivity capillary-reservoir technique which had previously been used with a high degree of precision on Sn-Bi alloys.4 This technique consists of dipping the vertical Pyrex capillary cell shown in Fig. 1 into a molten bath of alloy while the bath and capillary are under vacuum. The capillary is then filled by intro-

Jan 1, 1969

Research and Technical Services, Department of Mines Western Australia The nine papers received for this technical session cover a very wide range of hydrological problems in various parts of the world. Three of these papers deal with hydrological predictions for new mines, while three are concerned with the prediction of water chemistry. The three remaining papers deal with gas injection as a dewatering tool, discharge formulae verification and the use of a physical model to predict subsurface strata movement and fracture development due to longwall mining. Hydrological problems in mine planning represent a major risk in many mining operations, booth as a potential life or equipment hazard and a major financial risk. The initial paper selected to review was therefore one by the president of a gold mining company, rather than by one of the specialist scientists, to remind us all that the main reason problems are faced and overcome in the mining industry is usually a commercial one. In one commercial undertaking, the ability to accurately assess future risk is a highly desirable planning tool and hence in mining, the ability to predict the nature and magnitude of hydrological problems is n i-an varxi imnnrfant

Jan 1, 1988

By J. C. Rae

A Japanese mining engineer was given a year's leave of absence by his company and dispatched on a tour of inspection of all the principal coal mining regions of the world. He visited the New Castle region of England, Wales, Scotland, France, Germany and Alsatian mines, the underseas col¬lieries at Nova Scotia and Vancouver, and our own important fields of Illinois, Pennsylvania, West Virginia, Kentucky, Colorado, Utah and Wyoming. You are probably surprised to know that after seeing all these, he pronounced the Gebo mine of the Owl Creek Coal Company as the most interesting operation he had seen. The Gebo Mine is located about three miles west of Kirby on the Chicago, Burlington & Quincy Railroad in the Big Horn Basin region of Wyoming, 500 miles north of Denver and 200 miles south of Billings, Montana. The mine is working on a coal bed five or six to eleven or twelve feet' thick, dipping 22 to 23 degrees toward the northeast. The coal occurs in what is called the Eagle formation; and is found between two massive sandstones from 25 to 65 feet thick, which, weathering into bold', gray-colored cliffs, serves as a guide to the location of the coal bed. The deepest workings have an overburden of 800 feet. Cleavage planes of the coal extend at an angle of 45 degres to the pitch, and perpendicular to roof and floor. The coal itself is generally clean and not difficult to cut. It ignites readily from spontaneous combustion, however, which circumstance makes an ever-present fire hazard which must be carefully watched and guarded against. The coal is classed as sub-bituminous with analysis about as follows: Moisture 17% Volatile Matter 33% Fixed Carbon 46% Ash 4% Sulphur, about ½ % B. t. u. value a trifle under 11,000. It is known as Owl Creek coal, is one of the best domestic and steam fuels in the West, and is very popular in Montana, Idaho, Washington, Wyoming, South Dakota and Nebraska. While the coal slacks somewhat rapidly when exposed to the weather, it stores readily for months if placed under cover. On account of the somewhat isolated position of the mine as regards manufacturing establishments, there was a decided difficulty in disposing of slack, especially during the early years of the mine (1907 to 1914), and approximately 10 per cent of the entire product had to be wasted as slack during those years. This difficulty has been largely overcome since 1914, due partly to growth of manufacturing establishments in tributary territory, and also to enlarged transportation facilities. Also largely due to its isolated position, the mine has been compelled to use an extremely large proportion of box cars, much over 50 per cent of the product (in some years 75 per cent) being shipped in box cars, which, of course, entails extensive loading equipment and increases cost of loading. The output of the Gebo Mine for 1920 was 348,000 tons, for 1921, 273,000 tons; the rate of production during the year 1922 was over 1,700 tons daily, and 2,000 tons daily in January, 1923. The mine was developed by driving three openings straight down the pitch, the main slope being 12 to 14 feet wide and 3,000 feet long. A little distance from the surface a pair of level entries were turned right and left, known as the first East and first West. From these, rooms were driven up the pitch and chute mining attempted with only indifferent success: The failure of this rise-room method of mining was attributable to several

Jan 1, 1923