Search Documents

By Hongmin Zhu, Qiuyu Wang, Shuqiang Jiao, Guojing Hu

"The equilibrium between titanium ions and metal titanium was investigated in fluoride-chloride molten salt. The electrochemical properties of titanium ions in fluoride-chloride were studied on a molybdenum electrode by cyclic voltammetry (CV) and square wave voltammetry (SWV). The equilibrium constant of the equilibrium between titanium ions and metal Ti was calculated in KCI-NaCl- 2.5wt %K2 Tif 6 at the temperature of 1073K.IntroductionTitanium, the ninth most abundant element in the earth's crust, is endowed with high strength, low density, excellent flexibility, strong spring back characteristics, high-temperature performance, corrosion resistance and biocompatibility. These characteristics make titanium eminently suitable to be used in aerospace, marine industries, and harsh chemical environments. Although it has many excellent properties, the application of titanium in industry was limited by its high-cost. Therefore, many methods have been investigated for producing high-purity titanium at low cost. Electrolysis, involving the extraction and preparation of pure metal from ore using an electrolytic process, is considered a promising method for titanium metallurgy. Many studies have focused on the electrochemical behaviour and electrodeposition of titanium in molten chloride, fluoride, and chloride-fluoride electrolytes (1-IOJ. The electroreduction mechanism of Ti3+ ions in molten alkali chlorides has previously been studied by several workers. Two reduction steps, Ti3+ -Ti2+ -Ti, have been observed in various molten alkali chlorides [IJ. One reduction step, Ti3+ -Ti, has been observed in alkali fluoride molten salts l21. The behaviour of Ti4+ in fluoride or chloride-fluoride molten salts has also been investigated in the literature; it was proposed that the reduction of Ti4+ ions in the molten salts proceeded in a two step process: Ti4+-Ti3+-Ti l3l or a three step process: Ti4+ -Ti3+ -Ti2+-Ti ri. 4l Indeed, the stability of the titanium oxidation states depends on the bath composition l5l. The valence state was Ti2+ in alkali chloride melts, which was a lower oxidation state and correspondingly, in alkali fluoride melts, the higher oxidation states ofTi4+ and Til+ were more stable.The aim of the present work is to explore the effect of F/Cl atomic ratio on the equilibrium between titanium ions and metal titanium in fluoride-chloride at the temperature of 1073K. The electrochemical properties of titanium ions in fluoride-chloride were studied on a molybdenum electrode by cyclic voltammetry (CV) and square wave voltammetry (SWV). The solubility product of the equilibrium between titanium ions and metal Ti was calculated."

Jan 1, 2012

By S. D. Bechtel

Bechtel Civil and Minerals, Inc., one of the Bechtel group of companies, is a large engineering and construction firm that services the mining industry, among others. The firm's head, S. D. Bechtel Jr., comments on how his E&C company is dealing with the recessionary economy. First, he offered a historical perspective. About a half century ago-in the middle of the Great Depression-W. A. Bechtel and several business partners drew up a fixed price bid to build the Hoover Dam. At that moment in history, the W. A. Bechtel Co. was a modest success, but the times were troubled and uncertain. Money was scarce and a lot of contractors across the country were one project ahead of bankruptcy. The bid for Hoover was a make-or-break proposition for Bechtel, and it turned out successfully. The Hoover Dam was a no-frills operation in an isolated and harsh environment. There was plenty of hard work, long hours, and not many amenities. Controlling costs was critical. Everyone knew what had to be done, and why and what the consequences were. Today's Challenge Bechtel is now a bigger, more complex organization whose management views the current economic recession as a challenge to be met in much the same way W. A. Bechtel met the challenge of the Hoover Dam: by pulling together with a sense of purpose and direction. In many respects, Bechtel's situation today has a number of parallels to that which faced my grandfather. The company is eminently successful, but times are tough and there are plenty of signs that they could get tougher. My grandfather bet on the Hoover Dam to insure the future health of his company and I think we can work together again in that same tradition, make some tough decisions together, and the company's future can be just as promising. The first and most important requirement is to make certain that everyone understands the situation. The Bechtel group of companies are in an excellent financial position now. Its workload hit an alltime high in 1982 and it is well positioned in its principal markets. But the next two years may be critical for the company. Traditionally, Bechtel's work load lags behind general developments in the economy. Although many of its clients continue to suffer serious business difficulties, Bechtel is only beginning to feel the impact. The worldwide market for basic metals remains soft; relatively low prices and abundant supplies of oil and gas have flattened the petroleum market and made once promising synfuels projects economically unattractive; utility clients are still caught in the vise between overregulation and escalating costs. And persistently high, long-term interest rates have made capital investments expensive and difficult to justify. The company maintained a healthy workload through 1982. In some areas it has had little new work and consequently has been forced to lay off some staff as projects have been canceled or concluded. In other areas new work has tided the company over and more people have been hired. But new work bookings have fallen off, creating some uncertainty for the near future. 1983 requirements are clear, although seemingly contradictory. Belt tightening and cost reduction are necessary for Bechtel to remain healthy and competitive, enabling it to handle a possible further downturn with a minimum of turmoil and dislocation. At the same time, we need to allocate resources and funds in areas that will keep us positioned for the turn-around marketplace.

Jan 2, 1983

By Aziz NI, Guo H

Most of the existing models of the mechanisms of drilling and cutting processes are oversimplified in both stress state and failure criterion. On the other hand numerical modelling techniques are a more versatile method with great potential for development. In reviewing drillability and predicting performance of excavation machines the empirical tests, which simulate the physical breakage action in excavating processes are seen to be the best in terms of penetration rate predictability. Future methods of determination of drillability should concern the breakage characteristics and rock abrasivity involved in the two basic types of attack, i.e., percussive and rotary drilling.

Jan 1, 1988

By M M. M LT Tassinari, A B. Braz, L M. SantÆAgostino, C Ulsen

Several mineral resources have been recognised to alkaline igneous rocks. In general, these mineralisations present low P grades, so a complex concentration process is required to achieve commercial grade concentrates. This process is guided not only by the ore characteristics, such as apatite grain size and liberation degree, gangue minerals and slimes content, but also by different apatite varieties, iron oxi-hydroxide surface coating and roughness. The main techniques applied to apatite and phosphate ore characterisation, such as optical microscopy, cathodoluminescence (CL) microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), surface techniques and magnetic separation are discussed, aiming to evaluate distinct apatite varieties and their technological behaviour.

Jan 1, 2008

In addition to capital and operating costs, the accurate estimation of ore reserves is a key component to the successful outcome of any feasibility study. In recent years, there have been many project failures caused by the improper estimation of ore reserves. The accurate estimation of an ore reserve relies heavily on an understanding of the geology and the underlying assumptions unique to the estimation techniques being used. These assumptions are reviewed, and the shortcomings of the estimation techniques and their possible impact on a given project's economics are discussed. The latest developments in geostatistics in overcoming existing reserve-estimation problems are presented.

Jan 1, 1998

By G. L. Oldright, Virgil Miller

It is well known, in metallurgical circles, though less recognized in the technical press, that there have been remarkable increases in the capacity of the blast furnace in the last five .years. In places this capacity has been almost doubled. This paper will brief the experimental work carried on during more than five years with the direct assistance of the technical staffs of three lead smelters treating three distinctive types of feed. The first is the custom smelter of the International Smelting and Refining Co. at Tooele, Utah1, with a multiplicity of ores; the second, the Kellogg, Idaho, smelter of the Bunker Hill and Sullivan Mining and Concentrating CO.2, treating an exceedingly rich lead charge, such as is now being made more and more as the practice of concentration is improved; and the third, the smelter at Trail, B. C., owned by the Consolidated Mining and Smelting Company of Canada, Limited3, which treats highly zinciferous charges and later recovers zinc from the slag. In comparing operations at these three smelters it must be clearly recognized that the objectives in smelting differ through differences in economics. Many operations are not, then, strictly comparable. There have also been decided improvements in operation since all of the smelters were examined, though this was but a relatively short time ago. The general factors that govern speed in smelting and the loss of metals in the smelters examined will be stressed. (For details of operation the reader is referred to the original papers.) This paper will then be an examination of the fundamentals of operating units in a search for improvements, and not a description of three great lead smelters. Capacity of Blast Furnace Assuming a well prepared and self-fluxing charge to start with, enough coke must be added: (1) to melt the charge, particularly the slag-forming

Jan 1, 1937

By Dorsey Lyon

INTRODUCTION THE electric furnace has always been found to be especially adapted to melting, refining, and finishing processes throughout its gradual acceptance by metallurgists, as a practical apparatus for conducting metallurgical operations. In the steel industry, the electric furnace is firmly established in the manufacture of steel of the highest grade, equal to crucible steel. For the production of the cheaper grades of steel in large tonnage, the electric furnace gives a higher-grade product than the open-hearth or converter, but due to the high cost of power prevailing in steel centers, considered from the electric furnace standpoint, it is not economical to produce tonnage steel in the electric furnace. As a refining and finishing agent for open-hearth or Bessemer steel, the electric furnace has had some degree of success in the production of tonnage steel. After a study of the use of the electric furnace in the steel industry, it appears that there may be a possibility of its use to advantage for the melting of cathode copper. In the case of copper the problem is not one of actual refining, because the copper if refined properly y the electrolytic method needs no further refining; it needs simply to be cast into a marketable shape. The name" refining". is applied to the present finishing process, because in the operation oxygen and other impurities are removed, which the electrolytic copper absorbs in being melted in the reverberatory furnace. Considering that processes may be positive, negative, and neutral; the electrolytic method would be positive; reverberatory melting of cathode copper, negative; and electric furnace melting, neutral. The electrolytic method produces about as pure a copper as is possible, if operated properly and the anodes are not too impure. The final reverberatory melting of this cathode copper lowers the grade of the final product, due to the absorption of gases and impurities.

Jan 8, 1914

By C. L. Wilsey, K. M. Oakes, W. J. Reich, M. J. Protani

The time frame required to complete the National Environmental Policy Act (NEPA) process for a new mine, or for the expansion of an existing mine, can range between 9 months to 24 months, or more. The time frame will vary depending on whether an Environmental Assessment (EA) or an Environmental Impact Statement (EIS) will be completed. Completing properly designed baseline studies to collect natural resource data to support the EA or EIS prior to the start of the NEPA process can shorten this time frame. The two year natural resource baseline study completed by Homestake Mining Company for the Ruby Hill Mine, located in Eureka County, Nevada will be used as the case study to describe how properly designed and executed natural resource baseline studies streamlined the NEPA process.

Jan 1, 2001

By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d'etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By Roger Lafrance

"This paper discusses various aspects affected by the use of large-diameter boreholes in underground mines. Topics covered consist of noxious fumes, vibrations, post-blast effects, various types of explosives, the cordine system in production blasts, the slider primer system and wall-control methods. In general, the paper is an overview of this important fact of underground mining.IntroductionWith economical factors leading the way, many reasons motivated drilling equipment companies to develop equipment that can drill holes up to eight inches in diameter and even larger for underground applications. One of these other reasons is the fact that many orebodies were considered marginal, given the high costs of conventional mining methods utilizing small diameter boreholes. With these criteria in mind, accelerated programs were put in motion to develop equipment that would reduce both-development and production costs in underground mines. Change s in any basic program often affect other areas down the line. This is particularly true with the ad vent of large-diameter boreholes underground.C-I-L Inc. is certainly no stranger to this phenomena. Whether production headings increase in size and tonnage or whether production increases due to lower costs, one fact remains unchanged and that is the fact that all development and production holes are loaded and blasted whether they be of small or large diameter. Due to this fact, C-I-L Inc., as a leading explosives manufacturer, initiated a program to examine blasting methods in use in surface work with the intent of revising these method s for underground applications. Research facilities were also oriented toward developing appropriate products. This was a task that was accepted with anticipation, with the result that many new blasting systems and methods were brought forward, thanks to the collective efforts of both the consumers and manufacturers."

Jan 1, 1984

R. C. J. Goode (President): South Africa is known for its sunshine and mineral deposits-especially its gold and its diamonds-and as this year marks the 75th Anniversary of the establishment of the South African Institute of Mining and Metallurgy, it is appropriate that I say a few words about mining and metallurgy and the part this industry and our Institute has played in the life of this country. Africa, as the Dark Continent, with its fascinating tales of Prester John, Ophir, Queen of Sheba and its myths and legends has throughout the ages fired the public imagination. Pharaoh Necho, 600 years before the birth of Christ, sent an expedition from Egypt around the Cape to probe this strange land. The gold for King Solomon's throne was said to come from Monomotapa-the country now known as Rhodesia. Centuries later the Arabs and Portuguese searched for this mineral wealth. The Arabs found little gold but unfortunately established a lucrative trade in black slaves. Now let us take a brief look into the closing stages of the Stone Age when the indigenous population of the lower portion of this continent consisted of the Bushmen, a nomadic hunting people who knew no metals and kept no stock, and the Hottentots who were a pastoral folk with cattle and sheep. Then somewhere about the 11th century the Bantu started their long migration southwards and brought with them the knowledge of smelting of iron ore. One of their settlements was here in Johannesburg on the Melville Kopje at Emmarentia. These people were the first miners and metallurgists on the Witwatersrand and the beautifully preserved iron smelting furnace constructed nearly 1,000 years ago is a tribute to their technical ability. This ability to use iron to make better spears for hunting or to fashion hoes for cultivating the soil led to their establishment as a superior tribe. The earlier Bushmen were pushed back to the inhospitable swamps and deserts and the Hottentots fled to the south. The Bantu also knew the art of copper smelting. In the days of the Dutch East India Company, at the end of the seventeenth century, Bantu workers brought copper from the north-west Cape to Simon van der Stel, but it was another two hundred years before the white man turned this to advantage. Stories of the Bantu mining gold spurred the early European hunters to travel deeper into the heart of Africa in search of wealth, and we are told that Karel Kruger, in 1834 whilst leading an ivory hunting expedition, discovered gold on the Witwatersrand, and took samples to Cape Town; but when he returned with a larger expedition a few years later his party was attacked by Moselekatze's Matabele near Potchefstroom. Kruger was killed and only the legend survived. The real spur to mining in this country was the discovery of diamonds in Griqualand West in 1867. The field seemed fabulously rich and diggers flocked to the scene from the four corners of the earth. With them came Cecil Rhodes, Barnato, Beit and some of the finest mining and financial brains the country had yet seen. These giant entrepreneurs were not tempted by the small deposits of gold in the Barberton and Pilgrim's Rest areas when these were made a few years later but

By J. D. Ridge

The geologic setting and mineral relationships of seven European massive sulfide deposits that more or less conform to the bedding of the largely noncal-careous sedimentary rocks and/or bedded volcanics in which they are found are considered here. These orebodies consist largely of massive beds or lenses of sulfides usually surrounded by halos of disseminated sulfides and distorted by tectonic activity. The formations containing these deposits have been metamorphosed in varying degrees at times subsequent to their lithification. The ore-forming process is thought to be essentially volcanic, with the ore constituents being brought to the shallow-water site of deposition through tectonic fissures from magma chambers at depth as gases or relatively concentrated hydrother-mal solutions. Certain European ore deposits of base metal sulfide have previously been considered to be of hydro-thermal or magmatic origin, but today a number of European mining geologists consider them to be syngenetically produced. In an effort to provide American geologists with some idea of the reasons behind this change in thought, the geological settings of seven of these deposits have been studied. These are: Ldkken, Meggen, Rammelsberg, Ergani-Maden, Outokumpu, Boliden and Roros. These deposits lie in bedded rocks that have undergone metamorphism from causes not universally agreed upon; most of the formations were originally shales, and may have been intercalated with limey and occasionally quartzitic beds, volcanic tuff, agglomerate, extrusive lavas and usually basic intrusives. Deposits of the conformable type, however, are not confined to these rock types but may be in calcareous and associated igneous rocks or almost entirely in volcanics. These deposits may be closely associated in space with igneous rocks that, again, are usually basic types. Although the ages of the enclosing rocks range from mid-Precambrian (Boliden and Outokumpu) to Eocene (Ergani-Maden), the bulk of them are Paleozoic, with two (Meggen, and eammelsberg) being upper middle Devonian and two (LØkken and RØros) being Cambro-Ordovician. Geographically, two are in West Germany, four in Scandanavia and one in Turkey. Of the seven deposits, six are mined for copper, with three of these also producing zinc, and two lead; one is mined for zinc and minor lead. In the discussions of the seven conformable deposits that follow, I have attempted to present as uniform a treatment as their varying characters will permit. For each deposit, I have considered the stratigraphy of the area, its major structural characteristics, the form of the orebodies, their mineral content, and the origin of the ore. In the last of these subdivisions, I have presented only the viewpoint of those who believe the ores to have been formed by syngenetic processes, processes that went on at the same time as those which produced the beds that enclose the ores but that are not, in the deposits in question, thought to have been sedimentary in the strict sense of the term. The materials of which these orebodies are composed, it is suggested, did actually collect by falling through sea water to the floor of that portion of the sea in which they accumulated. The ore constituents, however, are believed by a considerable number of European geologists to have been added to the sea water from intratelluric sources, probably igneous magma chambers, as exhalations — hydrothermal solutions or volcanic gases. The effect of the encounter with sea water on these ejected gases or water-rich vapors was to precipitate their potentially solid constituents with great rapidity; they were deposited so quickly, in fact, that the amounj of normally accumulated mechanical or chemical sediment deposited over the same period of time was essentially negligible. The ores formed in this manner, however, are generally interbedded with normal sediments or with lava flows, or with any combination of these two types of rock-forming materials. Such departures as these deposits may have from their original mineral content and attitude are thought to be directly related to the degree of dynamic or static metamorphism that they may have undergone after their accumulation. I have not attempted here to present alternate hypotheses to that of so-called exhalative sedimentation although, of course, such exist and, in my

Jan 1, 1963

By A. Knoll, J. W. Beck, W. C. Brice, E. K. Lehmann

A cooperative study was undertaken in a neutral atmosphere by representatives of the environmental community, the mining industry and state government to identify and resolve environmental issues associated with base and precious metal mining before a commercial mining development is announced. The study included testing Minnesota's as-yet-untried nonferrous mining regulatory program using three hypothetical mining developments sited in environmentally sensitive areas where future mining could occur. Results include identification of critical paths for regulatory decision making, identification of particularly sensitive environmental issues that mill need continued deliberation before resolution and characterization of data necessary for environmental review and permitting decisions.

Jan 1, 1992

By E. Fahrenkrog

An intelligent supervisor developed using expert system tools and applied to a crushing plant is presented in this paper. The structure of this supervisor, based on a model of a human operator, consists of a Knowledge base containing a qualitative model of the process, and a Rules base with the heuristic logic used by an operator when supervising a plant. The simulation results obtained show the potential of this type of systems to supervise the automatic operation of a plant.

Jan 1, 1989

By Frank C. Di Luzio

REMARKS BY FRANK C. DI LUZIO, ASSISTANT SECRETARY OF THE INTERIOR FOR WATER POLLUTION CONTROL, BEFORE THE ANNUAL MEETING OF THE AMERICAN INSTITUTE OF MINING ENGINEERS, NEW YORK CITY, FEBRUARY 25-29, 1968 POLLUTION PROBLEMS AFTER MUNICIPAL-INDUSTRIAL WASTE CONTROL I am happy to have this opportunity to discuss pollution problems related to the mining industry and the role of mining engineers in protecting our environment. Technological Power and Pollution of the Environment The increasing power of technology to destroy and disrupt the natural environment and the ecological systems upon which life depends has reduced man's margin for error in the use of this power. We must act, therefore, to deter and prevent the occurrence of future ecological disasters such as that caused on the British and French coasts by the sunken oil tanker, the TORREY CANYON, the Clinch River fish kill which occurred when a dam broke and released coal ash from a power plant operation, or that which threatened on the Clark Fork River in Montana when a strike at the Anaconda Copper Company threatened to shut down pollution control activities, thereby endangering fish and plant life on the Clark Fork River with copper waste. In the past, pollution of the environment has tended to be slow. But now, the increased power of technology to damage nature, the loss of in¬sulating space and the compression of time--all reduce our margin for error and the cushion which space and time once provided for our mistakes.

Jan 1, 1968

By Yuting Xue, Danqing Gao, Brijes Mishra

Heterogeneity and discontinuity significantly affect rockmass strength. Past studies have largely used arbitrary scaling approaches to produce rockmass strength from laboratory rock tests. This paper proposes a stochastic approach to produce rockmass strength from laboratory rock tests. Based on the laboratory data, MATLAB with an extreme value stochastic model generated a database for each physico-mechanical property of the rock. Then finite-difference software FLAC2D simulated laboratory-sized rock specimens. Random material properties in MATLAB were generated using the grids developed in the numerical model. The random properties were then applied to the final FLAC2D model. Model runs simulated the approach performed in the laboratory. The results from the model indicate that a stochastic approach produced compressive strengths that were lower than those from the deterministic approach. Failure modes for each specimen were different from those observed in the laboratory. In addition, random density also influenced the failure mode, highlighting the importance of stochastic analysis in rocks.

By D. F. Howarth, F. F. Roxborough

Some important aspects of the design of rock-cutting systems remain relatively unexplored. Two areas of practical significance in this context form the subject of this paper: cutting in jointed or fissured rock, and groove-deepening. A series of controlled laboratory experiments on the performance of disc cutters in jointed rock showed that the spatial and geometrical configuration of jointed rock masses needs to be taken into consideration in the design of mechanized rock excavating systems. One series of experiments showed that, under favourable geometric conditions, the energy required to cut in a jointed rock mass is at least half that required to cut otherwise intact rock. Groove-deepening-the progressive deepening of a groove by successive passes of a cutter-is a potential operational feature with most mechanized rock-excavating systems. Laboratory experiments revealed an important fundamental cycle of events associated with disc cutters when progressively deepening a groove in intact rock. Furthermore, in contrast to pick cutting, groove-deepening by discs is shown to be an efficient operation and one that should not necessarily be avoided. This can be directly attributed to increased interaction between the disc cutters as the result of an increase in magnitude of the lateral forces generated as a groove is deepened.

Jan 1, 1982

By Keivan PakIman, Maziar Pasdarpour

Transportation tunnels are highly sensitive to ground movements and are required to be stable and secure for safe operation. In urban areas, the interaction between tunnels and adjacent piles, which are widely used to support buildings and other structures, requires careful consideration. The seismic response of tunnels may vary depending on the lateral stiffness and strength of the tunnel walls, while the axial loading and seismic impact of adjacent piles may cause soil displacement and stress changes that can damage the tunnel lining. As a result, tunnel owners often impose strict limits on the design of new piles lying close to existing tunnels including maximum allowable tunnel deformation, stress change limits, and minimum tunnel to pile separation distances. This paper describes a numerical analysis of the inuence of the axial loading and seismic impact of bored pile foundations on subway tunnels, undertaen using the nite element software laxis D. ased on the results of the numerical analysis, the paper suggests a more realistic and less conservative approach for designing piles in close proximity to transportation tunnels. INTRODUCTION The interaction between tunnels and adjacent piles can cause stress changes and displacements in the soil and structures which may adversely impact structural performance and tunnel safety. It is therefore important to take account of relative load transfer and piling conguration when designing new piles in

Jun 23, 2024

By E. R. Slatick

The northern and central Appalachian coal basin in the eastern United States has been the source of about two-thirds of the nation's coal output during the 20th century. This region includes parts of Pennsylvania, Ohio, Maryland, West Virginia, Virginia and eastern Kentucky. It covers about 130,000 km2 (50,000 sq miles) of the Appalachian coal basin and ranks as one of the world's most important coal production regions (Fig. 1). The coal industry's heyday in northern and central Appalachia has passed. This was due to competition from other fuels and low-sulfur coal produced in the West and because of the declining use of coking coal for steelmaking. Nevertheless, the region still plays a vital role in US coal production. It currently produces about 40% by weight of the nation's coal (its share is about one-half when measured by the energy content of the coal), contributes substantially to electricity generation and serves as the mainstay of US coal exports.

Jan 1, 1995

By J. D. Prater, H. R. Spedden, E. E. Malouf

With the expansion of copper leaching of the various mine wastes at the Kennecott properties, additional copper recovery facilities have been required. A research and development program has been pursued to determine a suitable economic approach to the processing of the additional leach solutions contemplated. lnvestigations on laboratory and pilot plant scales covered electrowinning, solvent extraction, launder and vat type cells, activated launders, precipitation drums, and precipitation cones. This paper contains information on the development and use of a new precipitation-cone-type copper recovery plant, which provides many advantages over older systems. The application of research findings to the old art of leaching copper from copper-bearing mine waste has resulted in a significant contribution of copper to over-all copper production. For example, at the completion of the current expansion program at the Kennecott properties in the United States, copper produced from waste dump leaching will amount to about 25% of the total production. Formerly only 2% was derived from this source. This planned expansion of copper leaching focused attention on the problem of developing more efficient methods for the recovery of copper from greatly increased volumes of copper-bearing solutions.1 The detailed investigations which have been made in laboratory pilot plant and plant tests for the recovery of copper from copper-bearing solutions have included electrowinning, solvent extraction, ion exchange and cementation with iron in launders, precipitation drums, activated launders, and precipitation cones. The results of these investigations have led to the development of a new precipitation cone-type copper recovery system providing many advantages over older methods. ELECTROWINNING OF COPPER FROM COPPER-BEARING SOLUTIONS The direct electrowinning of copper from relatively dilute solutions of copper-bearing mine water, namely solutions containing 10 to 20 lbs of copper per 1000 gal, has always been an attractive possibility.2,3 By this method, high-purity copper powder can be recovered with a power consumption of 3.5 kwh per Ib of copper. However, once the solution strength de-

Jan 1, 1967