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By J. W. Rutter, K. T. Aust

Observations are presented of the formation of annealing twins during the growth of a recrystallized grain into a striated, melt-grown crystal of high-purity lead. The formation of an annealing twin resulted in replacement of the original migrating boundary by a large-angle grain boundary of the caincidence-site type or by a near-twin boundary. The results support the Fullman-Fisher theory of annealing twins and demonstrate the usefulness of the coincidence-site model. FULLMAN and Fisher1 have advanced the following theory to account for the formation of annealing twins during grain growth. Whenever a grain A grows into a matrix of grains S1 and S2, a twin A' of grain A may form, as shown in Fig. 1, if the following energetic condition is satisfied: where "E" and "a" refer to the specific interfacial free energy and the area, respectively, of the boundaries indicated by the subscripts. In effect, the twinned grain will persist when the energy of the boundary between the twin(A') and the matrix grain (S, or S,) is less than that of the boundary between the original growing grain (A) and the matrix grain by an amount which exceeds the energy of the coherent twin boundary between A and A'. Experimental observations on the changes in grain boundary free energy accompanying the formation of twins1 are in agreement with the theory outlined in Eq.[l]. Direct observations of the formation of annealing twins at moving grain corners1"3 and the depend-

Jan 1, 1961

By Allen J. Johnson

Anthracite coals have been divided into three groups: (I) meta-anthracite, a high-carbon coal that is usually very slow to kindle and difficult to burn, at least on conventional equipment; (2) anthracite, a high-carbon low-volatile coal of widely accepted value as both a domestic and industrial fuel; and (3) semianthracite, a coal lying between anthracite and bituminous coal in carbon and volatile content, and also, generally speaking, in burning characteristics. Anthracite Groupings The technical differentiation between these groups, as defined by the A.S.A.-A.S.T.M. Sectional Committee on the Classification of Coals, is as shown in Table I. Tables 2 and 3 show typical analyses of anthracites and semianthracites and Figs. I to 3 show graphically the range of analytical samples. Table 4 shows the commercial sizes of coals. Meta-anthracite and Graphitic Anthracite Typical analyses from virtually every field in the United States indicate that there are few if any extensive deposits of meta-anthracite. Some of the anthracites of Rhode Island contain almost negligible quantities of volatile and would thus fall into the meta-anthracite grouping on a basis of analyses alone. However, their other characteristics indicate that it is doubtful whether they should be considered as fuels at all, but rather as graphite. In fact, this material is being mined for use as foundry facings and furnace linings.4 A typical analysis of Fenners Lodge graphite,4 from Rhode Island, is: graphitic carbon, 55.9 per cent; silica (ash), 40.6; sulphur, 1.6; moisture, 1.9; volatile, o. Other Rhode Island coals possess percentages of volatile that would throw them into the normal anthracite rather than the meta-anthracite class. However, this "volatile" is nearly all noncombustible,3,4 being composed almost entirely of carbon dioxide and inert gases, therefore its definition as volatile is open to discussion, leaving the exact classification of the fuel a moot question. One factor is certain, Rhode Island coal is so different from nor-mal anthracite in both analysis and burning characteristics that it should have a

Jan 1, 1944

By Allen J. Johnson

Anthracite coals have been divided into three groups: (I) meta-anthracite, a high-carbon coal that is usually very slow to kindle and difficult to burn, at least on conventional equipment; (2) anthracite, a high-carbon low-volatile coal of widely accepted value as both a domestic and industrial fuel; and (3) semianthracite, a coal lying between anthracite and bituminous coal in carbon and volatile content, and also, generally speaking, in burning characteristics. Anthracite Groupings The technical differentiation between these groups, as defined by the A.S.A.-A.S.T.M. Sectional Committee on the Classification of Coals, is as shown in Table I. Tables 2 and 3 show typical analyses of anthracites and semianthracites and Figs. I to 3 show graphically the range of analytical samples. Table 4 shows the commercial sizes of coals. Meta-anthracite and Graphitic Anthracite Typical analyses from virtually every field in the United States indicate that there are few if any extensive deposits of meta-anthracite. Some of the anthracites of Rhode Island contain almost negligible quantities of volatile and would thus fall into the meta-anthracite grouping on a basis of analyses alone. However, their other characteristics indicate that it is doubtful whether they should be considered as fuels at all, but rather as graphite. In fact, this material is being mined for use as foundry facings and furnace linings.4 A typical analysis of Fenners Lodge graphite,4 from Rhode Island, is: graphitic carbon, 55.9 per cent; silica (ash), 40.6; sulphur, 1.6; moisture, 1.9; volatile, o. Other Rhode Island coals possess percentages of volatile that would throw them into the normal anthracite rather than the meta-anthracite class. However, this "volatile" is nearly all noncombustible,3,4 being composed almost entirely of carbon dioxide and inert gases, therefore its definition as volatile is open to discussion, leaving the exact classification of the fuel a moot question. One factor is certain, Rhode Island coal is so different from nor-mal anthracite in both analysis and burning characteristics that it should have a

Jan 1, 1944

By P. A. Albert

THE to a transformation has been investigated by Newkirk1 in sponge titanium alloys which had been relatively slow-cooled so that several grains formed in a former grain. For a nucleated from , Newkirk assumed the following relationships and found them consistent with his experimental results: (00.1)a (110)Pll.01. II [111] Liu and Margolin,' in their investigation, found that the habit planes of martensitic in titanium consisted of planes of the families (3341, and (3441,. Using Newkirk's orientation relationship, the (3341 habit plane is found to correspond to the (1450) plane of a.

Jan 1, 1954

By Matthew I. G, Hall P. G

The Selective Precipitation (Basics) Process is a means of controlling impurities such as the ions of Mn, Mg, and Cl as well as sulphate and water, in an electrolytic zinc plant circuit. This is achieved by precipita- ting zinc selectively as a basic zinc sulphate from a portion of impure circuit solution. The impurities remain in the solution, which can be discarded, while the zinc, substantially free of impurities, is returned to the main circuit by using the precipitate as a neutral- ising reagent. A description of the process and its development to a full scale operating plant at the Risdon Works of the Electrolytic Zinc Company of Australasia Limited is Presented.

Jan 1, 1977

By H. Firmstone

DEPOSITS of cadmia, or impure oxide of zinc, are of common occurrence in the upper parts of blast furnaces using ores containing zinc, and were very common in the charcoal furnaces of Virginia working the brown hematite ores found near the Cadent black slate. These deposits were known to the old charcoal founders as "sulphur rings," and the characteristic green flame of burning zinc frequently to be seen at the tymp of furnaces working ores containing zinc, was held by them to indicate the presence of a "sulphur fall." When zinc is burning in considerable quantities at the tymp, the

Jan 1, 1879

By L. S. Deitz

This part of the symposium deals with the problems encountered by the consumer of nonferrous scrap, that is, the smelter and refiner who melts the selected scrap items and produces foundry ingots of specified compositions or billets for rolling or extrusion in nonferrous mills. The fundamental problems are quite similar for all secondary' nonferrous metals. However, these remarks will be confined to the copper-base alloys since in the sorting, melting and refining of these alloys probably all the usual types of problems are encountered; in addition, papers are being presented later on secondary lead, zinc and aluminum. While metallurgical

Jan 1, 1943

The failure of finely-divided sulfide particles to respond to flotation has resulted in a significant loss of our natural resources. As mentioned by Professor Arbiter, the overall recovery of copper from porphyry copper ores is generally between 80 and 85 percent. The recovery of copper sulfides from these ores is about 90 percent, the difference in these recoveries being due to failure of oxide copper minerals to respond to flotation. The 10-percent loss of sulfide copper has not been studied. Losses are known to be in the fractions finer than 74 microns, but the sizes that are not responding to flotation have not been established. In the case of molybdenite, however, it is known that particles finer than about five microns are not recovered. Work in other systems, notably the hematite-quartz system, has shown that good flotation of very fine particles from natural ores is possible (1, 2). The size distribution of one ore that was researched is given in Table 1, and as shown, approximately 50 percent of the ore was finer than 10 microns. Flotation experiments were conducted with this ore, which contained 45 percent iron, utilizing octyl hydroxamate as collector and without any desliming (1). The results of these experiments are presented in Table 2. From the standpoint of mechanisms of collector adsorption, similarities exist between those occurring in the hydroxamate-hematite system and many xanthate-sulfide systems. .This is, multilayers of ferric hydroxamate are present on hematite under flotation conditions (1,3).

Jan 1, 1979

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By Federico Ma. Aspíllaga

El presente estudio señala la importancia del control radiográfico que el Departamento de Seguridad e Higiene Industrial realizó al personal de Cerro de Pasco. La empresa -a través de este método de control- conoce el porcentaje de salud y enfermedad de sus servidores. El diagnóstico de las enfermedades neumoconiosis y silicosis deben ser evaluadas por un médico especialista en enfermedad ocupacionales. Asimismo, una vez diagnosticada la enfermedad se busca el control adecuado de la enfermedad, la profilaxis, y se refuerza las medidas de prevención tanto en el ambiente de trabajo como en el trabajador mismo.

Aug 20, 1965

By S. Zendejas-Mendivil, E. Pérez-Segura

The Cananea porphyry copper-deposit is the site of the second largest mining operation in Mexico. Mineralization is related to quartz-monzonite Laramide stocks that intrude volcanic and volcaniclastic Mesozoic rocks. The ore deposit is a stockwork and breccia-pipes system with Cu-Mo sulfides and pervasive quartz-sericite hydrothermal alteration. A study was made of the arsenic distribution in the mine and the ore-dressing plants. The arsenic (As) in the mine is related to a feldspathic quartz-porphyry type rock associated mainly with the breccia pipe structures (100-700 ppm As in the Veta 7 Breccia). There is vertical zoning, with As decreasing in the deepest part of the breccias. This As mineralization corresponds to a later sulfide hydrothermal stage. The concentrates are made of Cu, Fe and Mo sulfides and some minor quantities of As minerals. The most important copper minerals are chalcocite-covellite, bornite and chalcopyrite. Some of these minerals have 390-880 ppm As. The main As mineral is enargite[ [Cu2.97Fe0.06(As0.90 Sb0.01Pb0 01 )0.92 S4 051 and there are traces of stibioluzonite-luzonite I Cu, .95(Aso.4vSbu.49)0.9rfS4.07-Cu2 93(Aso.H4Sba.10)0.94S4.13] and of another stibioluzonite mineral type with substitution of As by Bi[Cu,96(Ascr,,'Sb0ccrB'OJ3jI~6S] These minerals contribute 80% of the As in the concentrates.

Jan 1, 1992

By Sheldon Rideout, E. L. Kamen, B. S. Lement, Paul A. Beck, W. D. Manly

The 1200°C isothermal sections of the following ternary phase diagrams were investigated: Cr-Co-Nil Cr-Co-Fe, Cr-Co-Mot and Cr-Ni-Mo. In all these systems the u phase was found to form extended solid solutions. Two new ternary phases of unknown structure were identified. The existence range of intermediate phases of transition elements was correlated with 3d electron vacancy concentrations. THE occurrence of extensive ternary d solid solutions in the Cr-Co-Ni and in the Cr-Co-Fe systems was described in a brief note.' More recently d- solid solutions were also found in the Cr-Fe-Mo system by two independent groups of investigators.2,3 The existence of binary d phases in the V-Co and V-Ni systems, predicted in ref. 1, was experimentally discovered recently by Duwez and Baen and independently by W. B. Pearson, J. W. Christian, and W. Hume-Rothery.5 Duwez and Baen stated two general conditions for the occurrence of the d phase in alloys of the transition elements: "(1) The atomic diameters of the two metals do not differ by more than 8 per cent. (2) One of the two metals has a body-centered cubic structure while the other is face-centered cubic, at least in one of its allotropic forms." In the course of an extensive research program conducted at this Laboratory under the sponsorship of the NACA, several ternary systems, containing d solid solutions and also certain new ternary phases, were investigated. The present report describes the investigated portions of the 1200°C isothermal sections of the following ternary phase diagrams: Cr- Co-Ni, Cr-Co-Fe, Cr-Co-Mo, and Cr-Ni-Mo. It was found that the range of existence of the d phase in these four ternary systems, as well as in one of two ternary systems which were investigated by others, can be fairly consistently described in terms of electron vacancy concentrations. This supports the suggestion of Sully and Heal" that the d phase is an electron compound. Experimental Procedure The ternary alloys were prepared by vacuum induction melting in zirconia and alumina crucibles. Lot analyses of the metals used are given in Table I. Specimens of all alloys were annealed at 1200°C in an atmosphere of purified 92 pct helium and 8 pct hydrogen mixture. Alloys consisting mainly of

Jan 1, 1952

By K. S. Lane

As the initial chapter in this section entitled "Role of Fluid Pressure in Rock," this attempts to fulfill an assignment for (1) summarizing the state-of-the-art and (2) illustrating engineering problems resulting from rock pore pressure. Hence, the chapter is presented in two parts: 1) Basic Concepts, and 2) Examples of Engineering Problems, including failures. Neither of these objectives has necessarily been completely met: partly from limitation of space and partly as the case histories have been restricted to the author's own field in civil engineering, and there deemphasizing those applications which will be covered in more detail by subsequent papers in this section. As with any state-of-the-art attempt, contributions of some have undoubtedly been overlooked (or omitted for brevity). Notwithstanding the foregoing limitations, it is hoped that this summary of the situation will at least: 1) Outline current concepts on effects of fluid pressure in rock-both as a pore pressure in interconnected void spaces of the intact rock and as a cleft pressure or hydraulic force acting in the joints or other discontinuities of the rock mass. 2) Indicate the often fragmentary nature of evidence presently available to support these concepts and thus encourage further research. 3) Illustrate the major significance of fluid pressure in several types of engineering problems and thus stimulate its consideration as designers encounter related situations.

Jan 1, 1970

By Aníbal Gastañaga Coll

El objetivo del texto es evaluar el problema de los accidentes ocurridos en las minas del Perú a través de un estudio que se realizó a 3,191 mineros de diversas zonas del país, los cuales fueron evaluados por Instituto de Salud ocupacional por una supuesta enfermedad ocupacional. Dicho grupo de trabajadores presentaron reclamos por una indemnización a causa de una enfermedad ocupacional y no por accidentes, considerándolo como muestra para ciertos estudios del problema de accidentes. Asimismo se analizó el tiempo perdido por los obreros accidentados, las lesiones sufridas de 1109 accidentados, el aspecto económico y los costos de la incapacidad del trabajador. En conclusión, se encontró que el 47.1% de los accidentes fueron leves y el 52.9% graves, es decir, con menos de 15 días y más de 15 días de incapacidad, respectivamente y se asumió que el costo total de los 1305 accidentes es de S/64'287,000.00.

Aug 20, 1965

By De Broglio R

The Mae Moh coal deposit was discovered some 60 years ago by villagers who noticed spontaneous combustion of coal outcrops. The first production began in the 1950's to fuel a fertilizer plant and a 12.5MW power station. During the period 1976 to 1979, three 75MW power station units were constructed on site. These have a total daily coal consumption of some 5000 tonnes and are served by a stockyard of approximately 60 000 tonnes total capacity. Stacked coal is reclaimed by means of a front end loader onto reclaim conveyors. During the years 1983 to 1986 four 150MW power station units were constructed east of the eastern seam subcrop, sons 2 km from the original power station complex. These have a daily coal consumption of nearly 12000 tonnes and are served by a stockyard of total capacity 270000 tonnes, equipped with two stackers and two bucket-wheel reclaimers for a totally mechanised system.

Jan 1, 1986

By Richard W. Kimball, Richard F. Coon

This paper describes drill and blast excavation and groundwater control measures at the Lake Mead Intake No. 2 project. The construction includes a deep access shaft, intake shaft, surge chamber, forebay chamber, intake tunnel, 22 well shafts and East Tunnel. Grouting ahead of the excavation face was used extensively during shaft and tunnel construction. Lake Mead Intake No. 1 was constructed in the early 1970’s under less severe groundwater conditions and this work was delayed by ground conditions and water control problems. Excavations for Lake Mead Intake No. 2 must be completed in 23 months to meet SNWA’s water delivery schedule.

Jan 1, 1999

By Keith S. Liddell

he selection of mill design parameters to suit the applica­tion requirements can result in quite different operating parame­ters for each generic type of application, even though the basic mechanical layout of the mills may remain similar. The selection of the type and size of grinding media is very important to efficient and cost-effective operation, and to ensuring that the milled product achieves the required properties. Accordingly, the grinding media selection is seen as an integral part of the mill design. Consideration of the requirement for classification is important in order to achieve the optimum mill and circuit performance. This can lead to the circuit feed not being classified for a steady feed with minimal slimes and a low size reduction ratio. Feed containing on-size particles would be deslimed by open circuit classification. Closed circuit classification is performed where the feed fluctuates. The rheological characteris­tics of the circuit feed slurry can have an influence on mill performance, and needs to be allowed for. A common misconception frequently encountered is the belief that "a mill is just a mill". This is not the case with stirred types of mills, since the operating parameters selected for the mill can have a large effect on the product characteristics. For example, horizontal shaft high speed stirred mills have a com­pletely different grinding action to vertical shaft low to medium speed stirred mills, which results in large differences between the surface area produced at a given product size (Liddell, 1986). Hence, it can be misleading to apply test results or design procedures obtained from one type of mill to other types for scale-up. The Metprotech stirred mill, as applied in the mining and minerals industries, is a low to medium speed vertical shaft mill. The basic design has been discussed previously (Liddell, 1989). Currently, the largest mills that have been manufactured have an installed power of 400 kW. The largest chamber volume at this power is 6000 litres, containing IO t of grinding media. It is intended that the installed power will increase up to lMW as applications requiring larger sizes arise.

Jan 1, 1995

By A Sinuhaji, H Kalangi, T B. Setyoko

Ore fragmentation at the DOZ block cave mine is highly variable, both as a function of rock type and column height of draw. Initially, the mine was constructed and equipped with limited capability to handle drawpoint oversize material. Significant issues with drawpoint availability and achieving overall mine production targets resulted. A suite of secondary sizing tools was added to the mine equipment fleet over a one-year time frame. Although significant oversize continues to be experienced, use of the correct secondary breakage tool for each particular oversize or hang-up occurrence has resulted in increased drawpoint availability, production rate, draw compliance, and operator safety. Currently, a range of secondary breakage techniques is being utilised to size material for delivery to the primary crusher. Run-of-mine material (3) is directly mucked to ore passes fitted with grizzlys that have one-metre square openings. Ore containing small boulders (>1 m3, 3) is loader-trammed to ore passes fitted with rockbreakers. Medium-sized boulders (>2 m3) accessible from the drawpoint are drilled with Sandvik Tamrock Commando drills. Boulders hung-up within the drawbell are drilled and charged with a Sandvik Tamrock Secondary Breakage Unit. Compacted, fine-grained muck is blasted utilising 55 mm cartridge powder concussion bombs.

Jan 1, 2005

By R. T. Gallagher

FOLLOWING recent precedent, the Mineral Industry Education Division opened its first session on Sunday afternoon at the Columbia University Men's Faculty Club with an unexpectedly large attendance. The first session was presided over by the Division Chairman, A. F. Greaves-Walker. The first paper, a preliminary report on college enrollments in mineral technology curricula, by W. B. Plank, though incomplete, pointed to a general over-all reduction of 38 per cent in enrollment in mineral industry curricula. Following that, A. C. Callen's paper elicited many comments. It presented the results of a survey (no direct questions asked) addressed to officials in the mining industry. J. L. Bray spoke on war production drive methods and results and his slides gave visible evidence (and much laughter) of the success of the drive. C. L. Wilson's able presentation covered not so much present status but the future status of accelerated mineral technology programs after the war. The last paper of the first session by Edward Steidle, was handed out in mimeographed form.

Jan 1, 1943

High precision GPS systems for mining are accurate to within a few centimetres. Typical systems consist of one or more GPS antenna, GPS boards, sensors to detect the position of the blade or bucket of the machine radios to pick up correction signals, a computer to control the system and a display screen to give instructions and information to the operator. GPS systems offer two benefits û they give information to the operator to get his job done faster and more accurately and they can send information to management about how the job was done. On dozers, GPS systems allow the operator to accurately complete earthmoving jobs with no survey pegs. On hydraulic excavators the systems can be used to accurately locate the position of the bucket teeth for selective mining. On blasthole drills the systems can guide the operator to each hole and record accurate as-drilled plans. By reporting the position of the blade or bucket in three dimensions it is possible to continuously upgrade a mapfile of the excavation. From this file it is then possible to report productivity numbers in real time. High precision GPS works best with a minimum of five satellites visible. This may be difficult in a pit. Systems which also access the Russian GLONASSS satellites offer significantly better uptime. GPS systems will become indispensable for efficient mining operations in the future.

Jan 1, 2003