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By W. F. Flanagan, D. H. Polonis, S. D. Dahlgren

Rotation diffraction patterns of Cu-4.84 wt pct Si polymystalline samples were taken during the course of isothel-ma1 affing of the suPersaturated a phase, a diffraction spots were obserzled to streak during the initial stages of aging, and this streaking was similar to the streaking of a spots observed earlier by Barvett with deformed super saturated samples of the same composition. Although it was suggested that stacking faults were the sole cause of styeaking in the deformed samples, the present study has shown that plates with one small crystallite dimension can also contribute to the streaking when there is lattice coherency across close-packed planes. THE decomposition of the supersaturated a phase in Cu-Si alloys has been reported to occur by means of both thermal and stress activation.1-4 According to the Cu-Si phase diagram,3 Fig. 1, the supersaturated a phase (fcc) is expected to transform during aging by the precipitation of the y phase. The results of earlier studies2,4 have indicated that metastable k phase (hcp with nearly ideal close packing) forms initially at temperatures below the eutectoid temperature, after which the k transforms to the a and y phases. Hof-mann et al.4 have proposed a metastable version of the phase diagram, showing the approximate boundaries for k formation below the eutectoid temperature. In view of the close-packed nature of both the a and k phases, it is essential to consider the role assumed by stacking faults in the transformation. Streaking effects have been reported by Barrett 1 in the rotating crystal X-ray patterns of strained Cu-Si alloys and were attributed to stacking faults rather than particle size effects. This deduction was based on the observation that streaks in the diffraction patterns did not occur tangent to the 220fee Debye ring. It is known that the atom movements involved in faulting leave some X-ray reflections unaffected while others are broadened,' and, in particular, it has been shown that faulting will not cause streaking of 220fee reflections tangent to the 220fee Debye ring as would be expected if all the reflections were broadened.' The formation

Jan 1, 1967

By David B. Reger

Exploration for new pools of gas in the Oriskany sand and continued exploitation of areas already known to be productive in that sand were the main features of petroleum activity in West Virginia during 1938. To a considerable extent the exploration program resulted in failure, but the extension of former areas was eminently successful. Throughout the state, in general, less drilling was done than in 1937. According to the West Virginia Department of Mines, only 631 permits to drill were issued, as compared to 1034 in 1937. The account of operations, as reported by trade journals and other sources, shows that 766 wells were drilled, resulting in 131 oil wells with 1609 bbl. of daily production; 484 gas wells with 1,232,216,000 cu. ft. of daily open flow; and 151 dry holes. Several discoveries indicate new pools of oil and gas; and several extensions of old gas pools have been made. In spite of a decreased number of total wells, the figures for new gas and oil are both larger than in 1937. The new oil average is 12.3 bbl. per well per day; the gas average is 2,545,900 cu. ft. per well per day, the ratio of dry holes to completions is 19.71 per cent. No general attempt was made to discover new pools of oil. A continued low price, coupled with reduced takings, combined to make drilling unattractive. The principal oil wells completed, by counties are: Boone, 6; Calhoun, 10; Clay, 7; Gilmer, 5; Kanawha, 5; Lincoln, 7; Pleasants, 13; Ritchie, 32; Roane, 6; Tyler, 7; and Wirt, 14. Production for the year, according to the Oil and Gas Journal, was 3,724,750 barrels. The leading counties in gas, with the number of successful wells in each, are: Boone, 16; Braxton, 13; Cabell, 47; Calhoun, 29; Doddridge, 10; Gilmer, 55; Kanawha, 127; Lincoln, 18; Ritchie, 29; Wayne, 19; and Wetzel, 26. Production for the year is estimated as 150,000,000,000 cubic feet. Pipe-line construction, which was extensive in 1937, was insignificant in 1938. Exploration was not as active as in 1937. Field prices of both oil and gas have severely declined.

Jan 1, 1939

By David B. Reger

Exploration for new pools of gas in the Oriskany sand and continued exploitation of areas already known to be productive in that sand were the main features of petroleum activity in West Virginia during 1938. To a considerable extent the exploration program resulted in failure, but the extension of former areas was eminently successful. Throughout the state, in general, less drilling was done than in 1937. According to the West Virginia Department of Mines, only 631 permits to drill were issued, as compared to 1034 in 1937. The account of operations, as reported by trade journals and other sources, shows that 766 wells were drilled, resulting in 131 oil wells with 1609 bbl. of daily production; 484 gas wells with 1,232,216,000 cu. ft. of daily open flow; and 151 dry holes. Several discoveries indicate new pools of oil and gas; and several extensions of old gas pools have been made. In spite of a decreased number of total wells, the figures for new gas and oil are both larger than in 1937. The new oil average is 12.3 bbl. per well per day; the gas average is 2,545,900 cu. ft. per well per day, the ratio of dry holes to completions is 19.71 per cent. No general attempt was made to discover new pools of oil. A continued low price, coupled with reduced takings, combined to make drilling unattractive. The principal oil wells completed, by counties are: Boone, 6; Calhoun, 10; Clay, 7; Gilmer, 5; Kanawha, 5; Lincoln, 7; Pleasants, 13; Ritchie, 32; Roane, 6; Tyler, 7; and Wirt, 14. Production for the year, according to the Oil and Gas Journal, was 3,724,750 barrels. The leading counties in gas, with the number of successful wells in each, are: Boone, 16; Braxton, 13; Cabell, 47; Calhoun, 29; Doddridge, 10; Gilmer, 55; Kanawha, 127; Lincoln, 18; Ritchie, 29; Wayne, 19; and Wetzel, 26. Production for the year is estimated as 150,000,000,000 cubic feet. Pipe-line construction, which was extensive in 1937, was insignificant in 1938. Exploration was not as active as in 1937. Field prices of both oil and gas have severely declined.

Jan 1, 1939

A BRIEF account of the water-power potentialities of Tasmania is given, together with possible applications of the power commercially. A short history of the Waddamana development is then given, and the main works are described.WATER POWER POTENTIALITIESTasmania is an island of approximately 24,500 sq. miles area (exclusive of small islands). An area of 12,000 sq. miles is at an elevation of over 1000 ft. above sea-level, and of 2300 sq. miles at over 3000 ft. above sea-level. Average annual rainfall varies from' over 140 in. on West Coast to 20 in. on East Coast, and for the whole island averages 48.5 in. The total water-power available, based on conservative figures for run off and efficiency, is 6,000,000 b.h.p. Only a small percentage of this total will, under present conditions, and under likely conditions in the immediate future, be capable of being developed commercially.An extensive hydro-metric and water-power survey is at present being carried out in order to collect information concerning the most promising water-power schemes. Already 400,000 b.h.p. has been located in different proposals, and there is still a large area of very likely country along the West Coast which has not been investigated yet. Tasmania thus has very vast power potentialities, which, combined with good ports and communications and wonderful mineral and timber resources, should augur well for the establishment of the great key industries, particularly chemical and metallurgical.

Jan 1, 1923

By Rudolph G. Wuerker

With stepped-up work in rock mechanics, more and more data on strength and elastic properties of rocks has become available. Results of measurements of tensile strength, in addition to determinations of compressive strength, allow us to deter- mine, even if only in an approximate way, the third property influencing failure of a brittle material: shear strength. It is fairly generally agreed upon in rock mechanics, in drilling and blasting research, that Mohr's theory provides an acceptable method for explaining the failure of a brittle material. Mohr states that a material may fail either 1) through plastic slip when shearing stress Y in the planes of slips has reached a limiting value (which in general depends on the normal stress, X, acting normal to the surface), or 2) when the largest normal tensile stress has reached a limiting value. The mode of failure depends upon which of the two stresses is the smaller.

Jan 10, 1959

By Walter Kauenhowen

Germany's crude oil production during 1935 totaled 3,007,711 bbl., an increase of 36.6 per cent over the 2,202,214 bbl. produced in 1934. The Nienhagen-Haenigsen field furnished 77 per cent of the total 1935 production. Cumulative production figures for Germany's two most important oil fields, Wietze and Nienhagen, show that during the period from 1872 to the close of 1935 the Wietze field produced 13,325,536 bbl. and the Nienhagen field 9,340,870 bbl. Table 1 gives statistics of German production since 1928, arranged both by fields and by oil provinces. Fig. 1 demonstrates the production of the various German fields since 1890. New Fields Discovered During 1935 five new fields came into production. The first of these, the Moelme-Hoheneggelsen field near Hanover, was opened up in April. This region has been sporadically drilled for oil since 1882, but not until 1935 was production on a commercial scale obtained. The oil comes from Mesozoic sandstones on the flanks of a shallow salt plug. Also during April, oil was found in commercial quantities in the Rhine valley at Forst, near Bruchsal. Tertiary and Mesozoic sandstones cut by faults of the Rhine Graben form the reservoir structures in this area. In July a wildcat well drilled on the Fallstein structure, a broad Triassic anticline near Halberstadt, came in as a producer from Permian (Zechstein) dolomite. In September commercial oil mas found at Gifhorn, near Braunschweig, in Wealden sandstones associated with a shallow, geophysically discovered salt plug. During the same month production was obtained at Heide, in Holstein, from the Permian Rotlie-gendes formation, in a structural high on which oil seepages have been known for years. Drilling Activities Published information indicates that during 1935 drilling totaled 574,000 ft., as compared with 436,000 ft. in 1934; 233,000 ft. in 1933 and 151,000 ft. in 1932. The German Government is subsidizing wildcat

Jan 1, 1936

By Walter Kauenhowen

Germany's crude oil production during 1935 totaled 3,007,711 bbl., an increase of 36.6 per cent over the 2,202,214 bbl. produced in 1934. The Nienhagen-Haenigsen field furnished 77 per cent of the total 1935 production. Cumulative production figures for Germany's two most important oil fields, Wietze and Nienhagen, show that during the period from 1872 to the close of 1935 the Wietze field produced 13,325,536 bbl. and the Nienhagen field 9,340,870 bbl. Table 1 gives statistics of German production since 1928, arranged both by fields and by oil provinces. Fig. 1 demonstrates the production of the various German fields since 1890. New Fields Discovered During 1935 five new fields came into production. The first of these, the Moelme-Hoheneggelsen field near Hanover, was opened up in April. This region has been sporadically drilled for oil since 1882, but not until 1935 was production on a commercial scale obtained. The oil comes from Mesozoic sandstones on the flanks of a shallow salt plug. Also during April, oil was found in commercial quantities in the Rhine valley at Forst, near Bruchsal. Tertiary and Mesozoic sandstones cut by faults of the Rhine Graben form the reservoir structures in this area. In July a wildcat well drilled on the Fallstein structure, a broad Triassic anticline near Halberstadt, came in as a producer from Permian (Zechstein) dolomite. In September commercial oil mas found at Gifhorn, near Braunschweig, in Wealden sandstones associated with a shallow, geophysically discovered salt plug. During the same month production was obtained at Heide, in Holstein, from the Permian Rotlie-gendes formation, in a structural high on which oil seepages have been known for years. Drilling Activities Published information indicates that during 1935 drilling totaled 574,000 ft., as compared with 436,000 ft. in 1934; 233,000 ft. in 1933 and 151,000 ft. in 1932. The German Government is subsidizing wildcat

Jan 1, 1936

By M. Ghiani, P. Massacci, A. Manni, R. Peretti, Center for Mining and Mineralurgical Studies, S. Serranti

"The research study has been devoted to point out the better way to process a colemanite concentrate characterised by a high content of two kind of As sulphides (realgar and orpiment) finely disseminated in the matrix of the boron mineral.Scanning Electron Microscopy analyses have been carried out to determine all the mineralogical constituents and to evaluate their distribution, frequency and mutual relationships.There is a not neglectable part of realgar highly disseminated into the colemanite crystals.The orpiment recurs in small acicular crystals of 20÷30 µm in length and 5 µm in width, very difficult to liberate from the colemanite mineral particles.The colemanite concentrate, in fact, has been addressed to a chemical plant which products were boric acid and gypsum, the contaminated by As. It was unacceptable for further applications and very dangerous if rejected in the environment.Grinding tests under dry and wet conditions have been carried out in order to evaluate the liberation modality of the As sulphide minerals from the colemanite.Some difficulties have been overtaken in order to obtain a selective liberation of the As sulphides from the colemanite even if a certain decreasing in As grade in the higher size classes has been registered.All the comminution products have been analysed by SEM monitoring the liberation degree of the mineralogical constituents.Flotation tests have been carried out after different comminution flow sheet adopting different modulating conditions in order to evaluate the influence of the following parameters:• collector concentration versus contaminants concentration (As minerals) in the froths;• kind and quantity of the frothing agent to maximise the mineral recovery in the froths;• kind and quantity of the modulating agents to maximise the selectivity of the process;• conditioning modalities in order to obtain a suitable dispersion of fines and to avoid segregation of Asbearingparticles together with colemanite ones;• solid/liquid ratio of the pulp to minimise the water flow into the plant."

Jan 1, 2003

Discussion of the paper of W. G. MATTESON, presented at the New York meeting, February, 1918, and printed in Bulletin No. 134, February, 1915, pp. 429 to 468. WILLIAM KENNEDY, Fort Worth, Tex. (written discussion*). -In his discussion of this paper, Mr. Sherburne Rogers offers voluminous figures to show that the salt forming the. cores of the various domes could not have been derived from sea water, and gives as an illustration the immense quantity of water required to form the salt found in the Humble dome. He refers to the theory advanced by Van der Gracht apparently in support of this contention, and claims to have disposed of the views held by some that the domes were, in a great measure, formed by lateral secretion. Van der Gracht says the immense salt plugs found throughout North Germany and other countries in that region were apparently formed by orogenic movements acting upon what he calls the Mother Bed of Salt, which he gives a thickness of about 1000 ft., and an extent of several thousand square miles. The age of this "mother bed" is given as Permian. Harris, in addition to his growing-crystal theory, also says probably a great portion of the salt found in the Coastal dories may have been derived from the salt water of Permian time. Both of these theories require an abundance of water, and consequently oppose Mr. Rogers' idea that the immensity of water required disproves the formation of the salt from that source. I do not suppose, however, that either Van der Gracht or Harris absolutely limits his view to the Permian as being the only source from which the salt could have come, but would probably agree to consider any other age as being the beginning. Although the Permian is very strongly represented throughout North Texas, we have none anywhere throughout the region from which the salt may be considered as having been derived. Many deep wells have been drilled along the eastern outcropping of the Carboniferous and each has passed directly from Cretaceous to Carboniferous formations. Thus we may eliminate the Permian as a source of salt in this region. But, although the Permian may be absent, we have with us the Carboniferous with probably a thickness of 3000 to 4000 ft., and something like 3000 ft. of Cretaceous, to say nothing of approximately 8000 ft. of Tertiary and later beds, all of which, if we may judge by the quantity and density of the waters obtained from the numerous wells drilled, carry immense quantities

Jan 7, 1918

By Morris Muskat

A general theory has been developed for the effect of permeability stratification on the efficiency of the gas-injection phase of cycling operations. It has been applied to three special types of permeability variation; namely, exponential, probability, and linear. In the case of the exponential permeability distribution the effect of areal pattern sweep efficiency was also taken into account. The exponential permeability distribution can be characterized by the ratio of the maximum to minimum permeability, which has been termed the stratification constant. Curves were calculated for the variation in total wet gas recovery and total gas throughflow, to give that recovery to various abandonment limits of the wet gas content in the produced gas, as a function of the stratification constant. The cumulative wet gas recovery decreases monotonically as the stratification constant increases and is generally higher at the lower values of the wet gas content abandonment limits. The total gas throughflow first rises to a maximum as the stratification increases, and then ultimately declines. The effect of the areal sweep pattern efficiency is relatively minor as compared to that of the stratification constant, except in the region of low values of the latter where the formation is substantially uniform. The probability distribution can be characterized by a "variation" parameter varying from o to I as the formation changes from strict uniformity to extreme variability. The curves of total wet gas recovery and total gas throughflow to different abandonment limits of wet gas content versus the variation parameter have the same general characteristics as for the exponential permeability distribution. In the linear permeability distribution the ratio of maximum to minimum permeability also serves as a stratification constant index defining the distribution. The curves of total wet gas recovery and gas throughflow to fixed abandonment limits versus the stratification constant are similar to those for the exponential permeability distribution. However, for the higher values of the stratification constant the recoveries and throughflows do not asymptotically fall to o as in the latter, but approach constant values determined by the abandonment limit of wet gas content in the produced gas. Introduction It is becoming generally recognized that one of the most important factors determining the economic feasibility of cycling operations is the areal continuity and permeability distribution of the producing formation. While the effects of areal variations in permeability, porosity, thickness, and well pattern on the sweep efficiency can be evaluated by electrical model studies,' those due to permeability stratification require separate treatment. Several studies have been reported2,3 on the' influence of permeability variations on the wet gas recovery by cycling. In these, however, discontinuous permeability variations either have been assumed explicitly, or the analysis has been carried through as if they were discontinuous. While, in fact, the actual permeability profiles will undoubtedly be discontinuous, recent develop-

Jan 1, 1949

By J. B. Scott, J. S. Nelson, G. H. Kruse, W. S. Johnson, K. L. Zerneke

The economics of pressure tunnel design emphasize the utmost utilization of the least expensive pressure-resisting material available, namely, the rock surrounding the tunnel. A major difficulty in the design is the problem of transferring internal hydraulic pressure to the rock through a tunnel lining or membrane provided to maintain watertight conditions. The lining is necessary not only to prevent water loss, but to prevent the diffusion of water at high pressure through joints and fractures beyond the confines of the tunnel, an occurrence which could ultimately affect the stability of the rock mass through which the tunnel passes. Because of its toughness and ability to bridge localized areas of weakness, steel is used for a lining material whenever high internal pressures are involved. The steel lining is coupled to the surrounding rock mass through an annular ring of concrete backfill. It is paradoxical that the steel lining, needed primarily to assure water tightness, must of necessity be incorporated into the structure as a major pressure-resisting component, not to augment the bearing capacity of the concrete and rock, but to limit the strain for the safety and preservation of the steel lining itself. With the deformation modulus of the steel so much greater than that of the rock, the liner approaches its yield strength before the load capacity of the rock can be fully mobilized. An economical determination of plate thickness for steel liners is therefore dependent upon measurement of the properties of the surround-

Jan 1, 1970

By Richard Pearce

I am deeply sensible of the honor you have conferred on me in electing me your president for this year. It is difficult to understand why I have merited such distinction at your hands, except that I may possibly have helped, in some small way, in the develop ment of metallurgical practice in the West. I fear, however, that I shall fall far shirt of the expectations you may have in regard to my fitness for such a position. The responsibility of preparing an address for this occasion has caused me considerable thought and anxiety. Unlike my predecessors in office, many of whom have dealt in their presidential addresses with subjects covering a wide field, which they could survey with the confidence born of their own extensive knowledge, I have been confined by my experience, during the last twenty-five years, almost wholly to that portion of metallurgical science which bears especially on the treatment of gold and silver. Yet perhaps some sort of general review of the progress of this branch of metallurgy in the West, besides being the contribution I feel myself best qualified to offer, may prove acceptable to many of the members of the Institute. Some few of the gentlemen present will remember the crude condition of metallurgical practice as it was conducted in Colorado only twenty-five years ago. My own personal experience covers a period of eighteen years; and during this comparatively short time I have seen the most astonishing changes in the conduct of metallurgical works. In all probability the marked progress which this country has exhibited could hardly be reached anywhere else, and this result has been achieved mainly by the activity and enterprise so characteristic of the men of the West. The first little successful attempt at smelting made at Black Hawk, in 1867, by Ex-Senator N. P. Hill, representing the Boston and Colorado Smelting Company, proved a great boon to the miners,

Jan 1, 1890

By Kenneth C. Vincent, A. M. Gaudin

In a study1 of the action of amyl xan-thate on chalcocite in water suspension, it was found that if the xanthate is added in relatively large quantity the xanthate group can be accounted for in three forms: (1) as xanthate ion remaining in water, (2) as benzene-soluble cuprous xanthate on the chalcocite, (3) as a benzene-insoluble coating on the chalcocite. Reduction in the amount of xanthate added leads to disappearance of form I then of form 2. With minute quantities of added xanthate, substantially all the reagent is of the "unleachable" kind. Yet this unleach-able xanthate can be dissolved by pyridine to form a soluble cuprous xanthate complex, and it is sufficient in effectiveness to make chalcocite flotable even if insufficient in quantity to form a complete mono-molecular film on the mineral. In that study it was also found that chalcocite abstracts cuprous xanthate from benzene so1ution, in what may (or may not) be a case of molecular adsorption. It seemed desirable, therefore, to study further the "unleachable" xanthate on the chalcocite, and particularly to ascertain whether it is formed as a result of the benzene leach or is actually formed during the conditioning of chalcocite in aqueous xanthate solution. A 'splendid tool to make such studies has recently been perfected; that is, the use of radioactive spies or tracer atoms. With this tool, it was thought possible to answer the problem stated above, but, unfortunately, this did not prove to be true. Answer to the flotation question was clouded by the existence of rapid and selective diffusion of copper atoms in the solid mineral—a phenomenon that was totally unexpected yet remains interesting and perhaps important. Method of Radioactive Spies The method of radioactive spies is discussed in many places. Two convenient references are the article by Evans2 and the book by pollard and Davidson.3 The method was first developed by van Hevesy and paneth in 1013, when only natural radioactive isotopes were available. These isotopes are few in number, and so the method remained limited in scope. Recently the synthesis of over 350 active isotopes of all the known stable chemical elements4 has opened widely expanded possibilities for the method, A fundamental tenet of the method is that a radioactive atom and a nonradio-active atom are exactly alike until disintegration of the radioactive atom. Then, by its sudden death, the spy reveals its location. The relative abundance of spies at various locations makes it possible to ascertain the relative abundance of the corresponding nonradioactive atoms at the same times and locations. A second fundamental tenet of the method of radioactive tracers is that the radioactivity lies in the nucleus of the atom: transfer of radioactivity from one

Jan 1, 1947

By Kenneth C. Vincent, A. M. Gaudin

In a study1 of the action of amyl xan-thate on chalcocite in water suspension, it was found that if the xanthate is added in relatively large quantity the xanthate group can be accounted for in three forms: (1) as xanthate ion remaining in water, (2) as benzene-soluble cuprous xanthate on the chalcocite, (3) as a benzene-insoluble coating on the chalcocite. Reduction in the amount of xanthate added leads to disappearance of form I then of form 2. With minute quantities of added xanthate, substantially all the reagent is of the "unleachable" kind. Yet this unleach-able xanthate can be dissolved by pyridine to form a soluble cuprous xanthate complex, and it is sufficient in effectiveness to make chalcocite flotable even if insufficient in quantity to form a complete mono-molecular film on the mineral. In that study it was also found that chalcocite abstracts cuprous xanthate from benzene so1ution, in what may (or may not) be a case of molecular adsorption. It seemed desirable, therefore, to study further the "unleachable" xanthate on the chalcocite, and particularly to ascertain whether it is formed as a result of the benzene leach or is actually formed during the conditioning of chalcocite in aqueous xanthate solution. A 'splendid tool to make such studies has recently been perfected; that is, the use of radioactive spies or tracer atoms. With this tool, it was thought possible to answer the problem stated above, but, unfortunately, this did not prove to be true. Answer to the flotation question was clouded by the existence of rapid and selective diffusion of copper atoms in the solid mineral—a phenomenon that was totally unexpected yet remains interesting and perhaps important. Method of Radioactive Spies The method of radioactive spies is discussed in many places. Two convenient references are the article by Evans2 and the book by pollard and Davidson.3 The method was first developed by van Hevesy and paneth in 1013, when only natural radioactive isotopes were available. These isotopes are few in number, and so the method remained limited in scope. Recently the synthesis of over 350 active isotopes of all the known stable chemical elements4 has opened widely expanded possibilities for the method, A fundamental tenet of the method is that a radioactive atom and a nonradio-active atom are exactly alike until disintegration of the radioactive atom. Then, by its sudden death, the spy reveals its location. The relative abundance of spies at various locations makes it possible to ascertain the relative abundance of the corresponding nonradioactive atoms at the same times and locations. A second fundamental tenet of the method of radioactive tracers is that the radioactivity lies in the nucleus of the atom: transfer of radioactivity from one

Jan 1, 1947

By T. A. El-Bassyouni, Paul Gordon

Grain-gvowth data in zone-refined aluminum and in dilute alloys of copper with this aluminum have been obtained. The amounts of copper added were from 4 to 400 at. ppm. It was found that in both the unalloyed aluminum and the alloys grain growth was characterized by a high value of n in the isothermal growth equation 6n = Kt The inadvertent presence of 1 at. ppm Fe in the alloys was found to he more potent in slowing growth than the purposely added copper. Possible rationalizations of these observations and their general relevance to the theoretical use of gvain-grozvth data have been discussed. Grain growth data of Winegard and his co-workers' on zone-refined tin and dilute tin alloys were analyzed with some success2 in terms of approximate theoretical equations for boundary migration.2-4 In view of this success, experiments were carried out in an effort to obtain similar data on zone-refined aluminum and on dilute copper-in-aluminum alloys. The results obtained were anomalous in several respects and could not be used to test theory. A discussion of these anomalies is presented here; they have been attributed to impurity effects and serve to emphasize the sensitivity of grain growth in general—and the particularly high sensitivity in aluminum—to impurities. The resulting difficulties in the theoretical use of grain-growth data are also discussed. EXPERIMENTAL DETAILS An aluminum bar was zone-refined and leveled by methods similar to those described previously.' The degree of purity obtained is indicated in Table The data in Table I were determined by mass-spectrographic methods through the courtesy of Mr. Thomas A. Johnson of AIAG Metals, Inc.* Three dilute copper alloys with this aluminum were prepared also by methods described previously.' The alloys contained nominally 4, 40, and 400 at. ppm of Cu, respectively (0.001, 0.01, and 0.1 wt pct). Each material was fabricated by swaging and rolling into a round bar about 1/4 in. in diameter with an annealed penultimate grain size of approximately 0.003 to 0.007 cm. In order to minimize preferred orientation the fabrication was carried out in several steps, each consisting of a reduction of about 40 pct followed by a recrystallization anneal. Annealing temperatures for the grain-growth studies were attained by the use of boiling liquids up to 213°C and molten metal baths at higher temperatures. Temperatures were controlled to within 1°C. Samples for measurements were cylinders about 3/4 in. long and 1/4 in. in diameter cut from the fabricated rods. In the interests of sample economy a single sample was used for the grain-growth measurements at each temperature. Each sample was, thus, annealed for several successive periods of time, the grain size being measured at each annealing period on a transverse surface exposed by

Jan 1, 1965

By Donald I. Bleiwas

World primary nickel production in 1987 is projected to be 770,000 mt, slightly higher than that in 1986. Market economy country (MEC) production in 1987 is projected to be about 524,000 mt, an increase of almost 5 pct over 1986 production. Production cutbacks and closures at Japanese ferronickel plants in 1987 resulted primarily from the strong yen and higher energy prices. Cutbacks also caused reductions in ore production from Indonesia, New Caledonia, and the Philippines. Technical problems affected production, to varying degrees, in Botswana, Indonesia, and Yugoslavia. World primary nickel production for 1988 is projected to be 787,000 mt, of which 536,000 mt will be produced in MECs. Increased production is projected from Botswana, Canada, Cuba, and possibly Greece and Yugoslavia, while slight production decreases are projected for Indonesia, New Caledonia, the Philippines, and Zimbabwe. .. South African nickel production in 1988 could be severly curtailed by social strife. In the early 1990's Brazil and China could be major economic competitors to Western nickel producers.

Jan 1, 1988

By Alden B. Greninger

The study of mosaic structure of crystals1 has been confined until recently to the field of theoretical physics. Crystallographers, in general, have neglected the subject, although X-ray crystallographers constantly make use of formulas for intensities of X-ray reflection as modified by mosaic structure. Work on mosaic structure has centered chiefly on the task of proving or disproving the secondary-structure theory of Zwicky,² and very little attention has been paid to the visible imperfections of crystals. A. Goetz has been responsible for most of the supposed experimental confirmations of Zwicky's theory.3 On the other hand, Smckal,4 and Orowan,5 among others, maintain that there is neither theoretical nor experimental evidence to substantiate Zwicky's secondary structure. Lately the subject has been intensively investigated by Buerger,6 one of whose recent papers led to a symposium on mosaic structures.'

Jan 1, 1935

By Alden B. Greninger

The study of mosaic structure of crystals1 has been confined until recently to the field of theoretical physics. Crystallographers, in general, have neglected the subject, although X-ray crystallographers constantly make use of formulas for intensities of X-ray reflection as modified by mosaic structure. Work on mosaic structure has centered chiefly on the task of proving or disproving the secondary-structure theory of Zwicky,² and very little attention has been paid to the visible imperfections of crystals. A. Goetz has been responsible for most of the supposed experimental confirmations of Zwicky's theory.3 On the other hand, Smckal,4 and Orowan,5 among others, maintain that there is neither theoretical nor experimental evidence to substantiate Zwicky's secondary structure. Lately the subject has been intensively investigated by Buerger,6 one of whose recent papers led to a symposium on mosaic structures.'

Jan 1, 1935

By A. M. Girodo

"Dorbyl Heavy Engineering has been manufacturing winders since 1949 mostly for the South African mining industry.Table 1 shows that the vast majority of winders have been double drum winders. At the greater depths with larger ropes being employed, it became apparent that multi-rope winders would be needed. The high stress variation in Koepe winder ropes at great depths especially beyond 2000 m, ruled out this possibility. Thus the original concept was borne for the Blair multi-rope winder where the stress level variations in the rope would be as per the well known, tried and tested double drum winder. The Blair multi-rope was also devised to increase payload by using multiple ropes.With the increasing costs of transporting men and material coupled with fact that orebodies are getting deeper, various feasibility studies have been carried out by South African mining houses. For this reason Dorbyl Heavy Engineering has done conceptual design work of both double drum and Blair multi-rope winders with diameters up to 8.5 m dia (still well within our manufacturing capabilities). These feasibility studies have looked at depths approaching 4000 m*.This paper covers the typical duties leading to the choice of single drum, double drum, Koepe and Blair multi-rope hoists on South African gold mines. A brief synopsis of Dorbyl hoists in use in the South African mining industry, with some indications of future trends, will be discussed.With current installed depths of wind approaching 2500 m, the Blair multi-rope hoist has been used extensively for the heavier payloads.Some of the main considerations pertinent to the design of the Blair multi-rope hoist are illustrated together with the implications of using this type of hoist to winding depths of3000 m to 4000 m in the foreseeable future."

Jan 1, 1995

By Michael K. Watkeys, Jacobus E. Potgieter, E. Guy Charlesworth, Carl R. Anhaeusser, Roger L. Gibson, Alexander F. M. Kisters

Intrusive features of cupriferous noritoids from the deeply eroded Proterozoic granite-gneiss terrane of the Okiep Copper District in South Africa illustrate the emplacement of basic magmas into a mid- to lower-erustal environment. The small, easterly trending intermediate to basic intrusions of the so-called Koperberg Suite display a wide variety of geometries, occurrence and emplacement modes, including dike-, sill- and plug-like bodies. Coeval granulite-facies metamorphism, partial melting and ductile deformation of country rock gneisses during intrusion of the basic magmas led to emplacement and dilation processes of the intrusions which differ significantly from those described for dikes and sills at shallow crustal levels. Regional tectonic stresses are largely negligible due to very low differential stress [( )] during deformation and intrusion, which permits emplacement at high angles to the principal compressive stress and which follows favorably inclined structural anisotropies. Dilation of the basic intrusions is largely determined by compositional differences of host rocks and occurs by thermal erosion, i.e., assimilation of wall rock gneisses. Low length-to-width ratios of basic to ultrabasic dikes and predominantly diapir-like outlines of mesocratic bodies are indicative of low viscosity contrasts between the mafic magmas and high-grade metamorphic host-rock gneisses. Buoyancy-controlled ascent of the basic to intermediate intrusions is expressed by a broad compositional zoning of basic bodies with respect to the granite-gneiss stratigraphy. Various intrusion modes within the stratigraphic column of the granite-gneiss sequence reflect a lithological and structural stratification of the seemingly homogeneous granite-gneiss terrane.

Jan 1, 1994