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By R. H. Brown

EARLY workers attempted to study the structure of alloys by measurement of equilibrium electrode potentials in aqueous solutions containing ions of the metals from which the alloy was made.1 The method was subject to such limitations (e.g., the difficulty in attaining electro-chemical equilibrium at low temperatures) that it has not been widely used by metallurgists. Recently, Seltz and co-workers have introduced a greatly improved method for studying alloys by measurement of equilib-rium electrode potentials in molten salts.2-4 The mathematical treatment is the same, of course, as for equilibrium potentials of amalgams in aqueous solutions.5 This method will probably find extensive use, since it makes possible not only the deter-mination of phase fields of equilibrium diagrams but also the determination of certain thermodynamic quantities which can be used advantageously in metal-lurgical calculations. However, the method presents difficulties. With many metallic and alloy electrodes, reversibility is not readily obtainable. Also, the difficulty of obtaining suitable material from which to make the cells is increased as the temper-ature is increased. Moreover, the necessity of carrying out measurements in a vacuum requires additional apparatus and intro-duces considerable difficulty, especially at the higher temperatures.

Jan 1, 1940

By D. C. Seidel, E. F. Fitzhugh

The cementation of nickel from acidic solutions by metallic iron is discussed. The cementation is carried out in pressure vessels at temperatures above 100°C. The results from bench scale studies on variables such as retention time, temperature, and solution pH are presented. A continuous processing flowsheet is proposed. Cementation is one of the oldest known hydrometal-lurgical reactions. The cementation of copper on iron was recorded by 'Paracelsus the Great' in about 1500,1 and by 1600 the technique was being used to recover copper at the Rio Tinto operations in Spain.2 At least one early author felt that cementation may have been one of the primary reasons for the alchemists' belief in the transmutation of metals.' The early writings state that when iron was placed in the clear waters from some mountain springs, the iron disappears and copper is found in its place. To the alchemists this may well have been one of the most convincing proofs that transmutation could and did occur. Since these early times the recovery of copper from acidic solutions by cementation has been practiced in plants throughout the world. Probably the cementation technique in some form has been common to more copper mining and milling operations than any other single recovery process. During current hydrometallurgical extraction studies, which were sponsored by the Republic Steel Corp. at the Colorado School of Mines Research Foundation, Inc., it was found that under the proper conditions, metallic nickel could be cemented from acidic solutions by powdered iron. The reactions are apparently similar to those that occur during the cementation of copper, but the nickel cementation had not been anticipated because iron and nickel are nearly adjacent in the electromotive series. The potential difference between iron and copper is approximately 0.78 v, while the potential difference between iron and nickel is less than 0.21 v. The cementation of nickel with iron at room temperature is almost negligible, but when the reaction is carried out in a closed vessel at temperatures in excess of 100°C, the nickel can be cemented almost quantitatively. The part played by this discovery in a practical method of nickel recovery is set forth in a separate paper.3 The following paragraphs are a discussion of experimental studies that were made to investigate this cementation reaction. The technique has been designated the HTC or High Temperature Cementation procedure. The cementation work was part of a study on hydrometallurgical techniques for the extraction of nickel from the garnierite or silicate type nickel ores. A hydrothermal extraction procedure had been developed, and this technique produced an acidic pulp or solution that contained both nickel and appreciable amounts of magnesium.3 Small quantities of ferric and ferrous iron were also present along with cobalt, manganese, and chromium. The potential for recovering the nickel from these acidic solutions by ion exchange or solvent extraction did not appear to be promising because of the relatively high magnesium content. The Ni ++ and Mg++ have nearly identical ionic dimensions and tend to be co-absorbed or extracted during ion exchange or solvent extraction treatments. Preliminary tests indicated that the nickel could be precipitated as a sulfide when using the high pressure H2S precipitation technique developed for the Moa Bay operations of the Freeport Nickel CO.4 This technique gave good recoveries, but the nickel sulfide product requires considerable additional processing before a marketable form of nickel is realized. The process also requires clarified feed solutions, and the solids-liquid separations on the garnierite residues are difficult. A program was initiated to investigate alternate procedures that might shorten the route to a marketable nickel product, and hopefully also permit bypassing the difficult solids-liquid separation steps required for the H2S precipitation technique. It was during these studies that the nickel cementation reaction with iron was encountered. EXPERIMENTAL EQUIPMENT AND PROCEDURES The bench scale precipitation tests which were conducted during this experimental program were made in 2-liter stirred autoclaves.* A photograph showing the form and arrangement of the autoclave

Jan 1, 1968

By Pol Duwez

IN the course of an investigation of the V-CO system, two intermediate phases were found. One of these phases corresponds approximately to the stoichiometric composition VCo and is isomorphous with the sigma phase in the Fe-Cr system.' The second phase has the composition V3Co; its crystal structure is described in the present note. The alloys were prepared by mixing the two metals in the powder form, pressing a small disk weighing about 5 g at 80,000 psi, and arc melting this disk on a water-cooled copper plate in an atmosphere of pure helium. The details of this technique have been described.' The vanadium powder was obtained from Westinghouse Electric Corp., Bloomfield, N. J. This powder is probably of very high purity, since when it is properly sintered or melted in the above-mentioned arc furnace, ductile specimens are obtained. The cobalt powder, from Charles Hardy, Inc., New York, contained 0.5 pct Ni, 0.1 pct Cr, and traces of Si and Fe. After melting, the V,Co samples were sealed in evacuated quartz tubes and homogenized for ten days at 800°C. Powder diffraction patterns were obtained with a 14.32 cm diam camera, using Ka copper radiation. The patterns were readily indexed on the basis of a primitive cubic lattice with a parameter equal to 4.675A. The density, determined by the immersion method, was 6.71 g per cu cm; hence the number of molecules per unit cell is approximately 1.95; i.e., 2. At this point, the possibility that the structure might be that of beta tungstena became apparent. The beta tungsten structure is described as follows: Space group 03,, — Pm3n 2 Co in (a) : 000; ?4lhYZ (hhl) reflection present only if 1 = 2n. Assuming this structure to be the correct one, intensities were computed by means of the usual eauation: 1 + cos220 I oc p F sin 0 cos 6 where F is the structure factor, 0 the Bragg angle, and p the multiplicity factor. The observed and calculated values of sin 0 and the intensities are given in Table I. The agreement between the observed and the calculated sin 0 is good and there are no flagrant discrepancies between the calculated intensities and those estimated visually. The (hhl) reflections for which 1 is odd are not observed, as required by the space group. In addition, the (410), (430), and (531) reflections are missing as expected, because of the special (a) and (c) positions in0%. However, six reflections—(llo), (220), (310), (411), (422), and (510)—which have very weak computed intensities were not observed. For these reflections, the structure factor is proportional to the difference between the scattering factors of the two atoms in the structure. Since the scattering factors of vanadium and cobalt are not very different, these reflections are weak. However, by using Ka chromium radiation, whose wavelength is just above the absorption edge of vanadium, the effective scattering factor of vanadium may be decreased by one or two units; consequently the difference between the cobalt and vanadium scattering factors is increased. It was, indeed, found that in a powder pattern taken with chromium Ka radiation, the three reflections (110), (220), and (310) were actually present. The three other reflections (411), (422), and (510), with spacings smaller than half the wavelength of chromium Ka, were obviously not obtainable with chromium radiation. All the experimental results appear to confirm the beta tungsten structure for V,Co. In this structure, each cobalt atom is surrounded by twelve vanadium atoms at 2.61A; each vanadium atom is surrounded by two vanadium atoms at 2.34A, four cobalt atoms at 2.61 A, and eight vanadium atoms at 2.86A. Acknowledgment This work was done at the Jet Propulsion Laboratory, California Institute of Technology, under contract number W-04-200-ORD-455 with the Army Ordnance Department, Washington, D. C. The author wishes to thank this agency for the permission to publish the results of this investigation. References 'P. Duwez and S. R. Baen: X-Ray Study of the Sigma Phase in Various Alloy Systems. Symposium on the Nature, Occurrence, and Effect of Sigma Phase. ASTM Special Tech. Pub. No. 110, pp. 48-54. Philadelphia, 1951. 2 C. H. Schramm, P. Gordon, and A. R. Kaufmann: The Alloy Systems Uranium-Tungsten, Uranium-Tantalum, and Tungsten-Tantalum. Trans. AIME (1950) 188, pp. 195-204; Journal of Metals (January 1950). 3 M. C. Neuburger: The Crystal Structure and Lattice Constants of Alpha and Beta Tungsten. Ztsch. fiir Krist. (1933) 85, pp. 232-237.

Jan 1, 1952

By T. A. Wilson, S. L. Hoyt

THE plastic deformation of slender single crystals of zinc has been described in some detail in the paper by Mark, Polanyi and Schmid,1 which has become a classic, and also by one of the present authors in a somewhat shorter account.' The study of single-crystal zinc is termed classical because zinc single crystals offer, perhaps, the best material yet available for the study of atomic behavior during deformation and the effect known as "strengthening" in metals. A considerable amount of additional work has also been done on single-crystal zinc, but as it is not closely related to the present paper it will not be considered. Throughout all the former work, the mechanism of plastic deformation first described by Mark, Polanyi and Schmid has been assumed to hold. This may be said to offer the strongest confirmation of its correctness. Even so, the picture of the process has never been as completely portrayed as is desirable. The first object of the present paper is to describe work that has been done in this field, and which is even yet being carried on, in the hope that a more complete picture may be obtained. Mathewson and Phillips' have recently described a new mechanism of the deformation of zinc based on their study of large rectangular crystals. One of their conclusions was that deformation produced twinning with a rotation of some of the basal planes into positions 94° removed from their original position; a position almost the same as that of the prismatic planes before twinning. A second conclusion was that fracture occurred along these basal planes in their new position, and, therefore that fractures previously regarded as prismatic were in reality basal. Such findings are of great significance and they raise a question as to the generality of such behavior. Professor Mathewson's opinion is that even the slender cylindrical single crystals behave in the same manner as his large rectangular crystals when strained by simple tension.

Jan 1, 1928

By T. A. Wilson

THE plastic deformation of slender single crystals of zinc has been described in some detail in the paper by Mark, Polanyi and Schmid,1 which has become a classic, and also by one of the present authors in a somewhat shorter account.2 The study of single-crystal zinc is termed classical because zinc single crystals offer, perhaps, the best material yet available for the study of atomic behavior during deformation and the effect known as "strengthening" in metals. A considerable amount of additional work has also been clone on single-crystal zinc, but as it 'is not closely related to the present paper it will not be considered. Throughout all the former work, the mechanism of plastic deformation first described by Mark, Polanyi and Schmid has been assumed to hold. This may be said to offer the strongest confirmation of its correctness. Even so, the picture of the process has never been as completely portrayed as is desirable. The first object of the present paper is to describe work that has been done in this field, and which is even yet being carried on, in the hope that a more complete picture may be obtained. Mathewson and Phillips3 have recently described a new mechanism of the deformation of zinc based on their study of large rectangular crystals. One of their conclusions was that deformation produced twinning with a rotation of some of the basal planes into positions 94° removed from their original position; a position almost the same as that of the prismatic planes before twinning. A second conclusion was that fracture occurred along these basal planes in their new position, and, therefore that fractures previously regarded as prismatic were in reality basal. Such findings are of great significance and they raise a question as to the generality of such behavior. Professor Mathewson's opinion is that even the slender cylindrical single crystals behave in the same manner as his large rectangular crystals when strained by simple tension.

Jan 1, 1927

By T. A. Wilson, S. L. Hoyt

The plastic deformation of slender single crystals of zinc has been described in some detail in the paper by Mark, Polanyi and Schmid,' which has become a classic, and also by one of the present authors in a somewhat shorter account. 2 The study of single-crystal zinc is termed classical because zinc single crystals offer, perhaps, the best material yet available for the study of atomic behavior during deformation and the effect known as "strengthening" in metals. A considerable amount of additional work has also been done on single-crystal zinc, but as it is not closely related to the present paper it will not be considered. Throughout all the former work, the mechanism of plastic deformation first described by Mark, Polanyi and Schmid has been assumed to hold. This may be said to offer the strongest confirmation of its correctness. Even so, the picture of the process has never been as completely portrayed as is desirable. The first object of the present paper is to describe work that has been done in this field, and which is even yet being carried on, in the hope that a more complete picture may be obtained. Mathewson and Phillips3 have recently described a new mechanism of the deformation of zinc based on their study of large rectangular crystals. One of their conclusions was that deformation produced twinning with a rotation of some of the basal planes into positions 94" removed from their original position; a position almost the same as that of the prismatic planes before twinning. A second conclusion was that fracture occurred along these basal planes in their new position, and, therefore that fractures previously regarded as prismatic were in reality basal. Such findings are of great significance and they raise a question as to the generality of such behavior. Professor Mathewson's opinion is that even the slender cylindrical single crystals behave in the same manner as his large rectangular crystals when strained by simple tension.

Maps and Mining Data for the Library. I suggest that the Institute Library can increase its usefulness by systematically soliciting from the engineers and mining companies all published reports and maps, and parts of reports and records, not of a private or confidential nature. If this is done an engineer assigned to report on a well-known property or district may depend on finding at the library a large amount of preliminary data and general information from these official and engineering reports relating to his prospective investigation. In many mining reports a large part of the report is of a general technical and scientific character, and there could be no good objection on the part of either the engineer, or his client to making such information thus of record. I believe there would be a great deal of information furnished by the engineers if they were properly solicited under this plan. I have found on different occasions that much work could be saved by such records now in the Library. The plan would also have the advantage of keeping the Library in closer touch with the active engineers, a feature to be desired. I also have in mind that the Library should undertake to collect all the prospectuses and financial literature which is issued in connection with mining. Of course a great deal of this is unreliable, but even this is valuable for record in the matter of legal and other investigations. I shall be glad to co-operate with you, and do anything I can to develop more in detail the general ideas above noted. Yours very truly, KIRBY THOMAS NOTE.-The Library of the Institute makes a specialty of collecting and filing material of this character, and the letter printed above is brought to the attention of members in the hope that they will co-operate by sending in copies of maps, reports of properties, etc.

Jan 11, 1913

By T. Koulomzine

The theory of the Askania mag-netometer, as well as a complete discussion of all factors influencing magnetometer readings, is very ably described by J. Wallace Joyce.1 We will assume that the reader is thoroughly familiar with this theory and we will use whenever possible the same notations for the physical values involved in the theory. On the other hand, we believe that the principal formulas of the magnetometer can be deduced much more easily by the use of differential calculus than by the methods employed by Joyce. Consequently, we are presenting herewith a resumé of the theory of the vertical magnetometer in order to determine the correct formula of the temperature coefficient which we propose to compensate. Short Theory of the Vertical Magnetometers We shall accept the following notations: m = total mass of the magnet system, in grams. g = acceleration of gravity, in dynes. a = projection on the axis of the magnet system of the distance between the axis of support and the center of gravity of the magnet system, in centimeters. h = projection on the perpendicular to the axis of the magnet system of the distance between the axis of support and the center of gravity of the magnet system, in centimeters. M = 2pL = M, magnetic moment of the magnet system. Z = vertical component of the earth's magnetic field. ? = deflection angle of the magnet system. = focal length of objective lens in the optical system S = scale reading. In a vertical magnetometer the axis of the magnet system is kept horizontal within 2". Therefore, referring to Fig 1, we see that the magnetic torque of the magnet system influenced by Z must be counterbalanced by the gravity torque. MZ cos ? = mga cos ? + mgh sin ? or dividing by cos ? MZ = mga + mgh tan ? If we now move to another magnetic station and the temperature conditions change, the values of all the variables will change also: M, a, and h under the influence of temperature. 2, both with time and space. ? and S, as a result of all the above changes. Taking increments in Eq 2 we obtain: (Mo + ?M)(Z + ?Z) = mgao + mg?a + mg(h + ?h) tan (? +??) but tan (? +??), because ? is small, can be replaced by tan ? + tan ??; in fact tan (?+ ??) = sin ?.cos ?? + cos ?.sin ??/ cos ?.cos ?? — sin ?sin ?? but sin ? sin ???0 tan (8 + ??) ? tan ? + tan ??. Fur-thermore, neglecting all terms of the equation containing two differentials becomes: or a differential and a tan ??, Eq 3

Jan 1, 1950

By W. R. Johnson, M. Hansen, John M. Parks

AS part of a research project sponsored by the Signal Corps Engineering Laboratories, which had the objective of obtaining a magnet wire of good conductivity and low temperature coefficient of resistance, a comprehensive literature survey, supplemented by experimental work, revealed that a linear relationship exists for solid-solution alloys between the electrical conductivity, K, and the temperature coefficient, a, as expressed by the equation: k = a/ß where ß is constant for the solvent metal and a - per°C. tR0 It has long been known that the electrical conductivity at a given temperature and the temperature coefficient of resistance of binary alloys are related to their constitution by the LeChatelier-Guertler rules, as illustrated by Figs. 1 and 2: Rule 1—In alloy systems consisting of a heterogeneous mixture of two phases, the electrical conductivity and temperature coefficient vary as a straight line, if the composition of the alloys is given in volume percentage, Fig. 1. Rule 2—In solid solutions, the electrical conductivity and temperature coefficient are always lower than those of the solvent metal, and usually a considerable decrease occurs with the first small percentage additions of the solute metal, Fig. 2b. If the two components form a continuous series of solid solutions, the electrical conductivity and temperature coefficient curves take the form of a U-curve, Fig. 2a. That some kind of proportionality exists between electrical conductivity and temperature coefficient of resistance is implied by the LeChatelier-Guertler rules and by study of data such as those given by Smith and Palmer,' Fig. 3. Dellinger2 in 1910 first recognized this relationship in a number of commercial copper wires, ranging in conductivity from 94 to 100.7 pct I.A.C.S. He gave the ratio of temperature coefficient to the percentage of conductivity as a constant, C = 0.003939. A year later, Lindeck observed that the linear relationship was valid for a wider range of conductivity in "various sorts of copper," and concluded that the product of resistivity and temperature coefficient was 6.78x10-5 1.5 pct. Since then, this relationship seems to have been entirely ignored. Conductivity-Temperature Coefficient Relationship If the electrical conductivity of copper solid-solution alloys with phosphorus, silicon, arsenic, antimony, aluminum, nickel, manganese, and iron is plotted against the temperature coefficient of these alloys, the diagrams in Figs. 4 and 5 are obtained. Similar data were found with copper-rich solid solutions containing magnesium, cobalt, and titanium,'" as shown in Fig. 6. In all cases, a linear relationship exists. The point representing the highest

Jan 1, 1952

By Masayasu Kawahara, Toshiyuki Kozuka

"Lorentz force, which has the functions of wave suppression and mixing control, is very useful for many metallurgical processes. In this paper, it is found that vertical Lorentz force which can change 'the gravitational force is able to modify the dispersion relation of the surface wave generated by gravity and also modify the instability phenomena on the interface so that the lower layer can be scattered into upper layers to realize the strongly mixed region.IntroductionIn metallurgical industries, recently, a new direction of process developments is required backed not only by severer operating conditions, e.g. small amount production, rapid refining, etc. but also by environment and energy problem. Because almost technologies in conventional processes have saturated, an innovative process, which can break the limits in the conventional processes, is now strongly required. Especially, controlling of mixing phenomena between two liquid phases is considered to be one of the most important technologies for the promotion of slagrnetal reaction, wave suppression, etc. On the other hand, electromagnetic forces which have various functions have been applied to many processes. And Lorentz force is able not only to suppress the wave motion of molten _metal surface but also to promote the mixing or separation of two liquids. In this paper, new controlling methods of mixing phenomena between two liquids are proposed, where a direct electric current and a stationary magnetic field are utilized. Vertical Lorentz force due to the interaction between the electric current and the magnetic field can modify the gravity force so that the dispersion relation of surface wave and the instability on the interface can be change to improve or develop the innovative processes(l,2).In case that a direct electric current is imposed on two liquid layers with a stationary magnetic field, Lorentz force of each layer becomes different due to the difference of electrical conductivity. If Lorentz force acting on the lower layer is stronger than that on the upper layer, resonance frequency of the wave motion on the interface due to the gravity can be shifted from the frequency of a outer disturbance to suppress the wave motion. And also, the lower layer can be scattered into the upper layer as liquid particles by an instability phenomenon."

Jan 1, 2000

By F. P. Dewey

The subject of this paper does not embrace the consideration of ways and means for the increase of analytical accuracy, or the question what could or should be attained in that direction. I desire simply to call attention to the degree of accuracy exhibited in actual every-day practice. In estimating this, little weight will be given to the evidence afforded by the agreement of duplicate or multiple determinations by the same chemist; for I am convinced that such agreement is a delusion and a snare. Nor will special importance be attached to the agreement of two or even three analyses in special cases, or to the agreement between two methods practiced by the same analyst. I propose to compare the results obtained by several chemists, working upon the same sample and by various methods, in order to exhibit, as I have said, the actual condition of practice. The available material for illustrating this phase of the question is unfortunately scanty; but something has been done; and I hope, by calling attention to some of the work in this line, to stimulate further work in the same direction by inducing others to prepare suitable samples and submit them to various chemists who are competent and willing to make the necessary determinations, and fully describe the methods they employ. I draw most of my illustrations from the Transactions of the Institute, the Proceedings of the Association of Official Agricultural Chemists, and from personal experience. Manganese in Steel.—In May, 1881, Mr. William Kent presented a paper to the Institute entitled " Manganese Deter-

Jan 1, 1897

By Danny J. Van Roosendaal

An investigation was undertaken to determine hydrogeological effects of subsidence over a longwall coal mine in the Illinois Basin. At this mine, approximately 200 ft of bedrock overburden is overlain by up to 150 ft of glacial till and localized water-bearing glacial sediments within a buried bedrock valley that overlies the longwall panel. A finite-element mechanical model of the subsided longwall panel shows sufficient strain to enhance permeability throughout the bedrock portion of the overburden. However, examination of the actual surface subsidence profile indicates that the overburden deformation is localized in narrow zones at the panel edges. The aquifer units at the base of the glacial sediments are confined by glacial clays (above) and weathered shales (below). Elevated water levels were observed in the glacial aquifers during subsidence, which indicates that the clays and shales maintained confinement as the overburden subsided and deformed. A three-dimensional ground-water flow model was used to simulate the effects of subsidence on the hydrogeologic system and to estimate inflows into the mine. Longwall retreat was simulated by several model runs, each representing a new longwall face position. Simulated heads and mine inflows were calibrated with recorded water levels and observed inflow conditions by modifying the hydraulic conductivity of particular model layers. Model calibration indicates that the permeability of certain lithologies, such as plastic underclays and weathered shales, is not significantly enhanced by subsidence. A worst-case scenario was simulated by inserting a deeply incised, sandfilled valley into the model, which had only minimal impact on the simulated mine inflows.

Jan 1, 1995

By P. W. Bridgman

FLOW and fracture are admittedly complicated phenomena of which we are yet only partially masters. There is not even universal agreement as to the details of the language best adapted merely to describe the phenomena, to say nothing of any theory. Certain points of view, however, are widely held, and there are certain general expectations as to what sort of procedures will prove permissible. A complete description of any situation involving fracture would demand a complete history of all the variables in the control of the experimenter. The experimenter endeavors so to choose his independent variables that they are adequate to determine completely the situation in the sense that when an experiment is repeated on the same initial material and with the independent variables running through the same sequence, all the other measurable properties of the system will also run through the same course. It is, I think, the universal conviction that when we are dealing with phenomena of flow and fracture, the most important of the necessary variables are the external forces acting on the various parts of the body; when the force history repeats, with certain obvious restrictions such as that temperature must be constant and non- mechanical forces, such as magnetic field, must be small enough to be ineffective, then the history of all measurable properties will repeat; in particular the alteration of geometrical shape due to flow will run through the same course, and when fracture comes, the character of the fracture will be reproduced. Complete mastery of merely the descriptive aspects of flow and fracture would demand the ability to predict the entire course of flow and complete characterization of the final fracture for every possible combination of forces, varying in time in all possible ways, when applied to bodies of all possible shapes. This full situation is obviously of prohibitive complexity. The first stage in reduction to manage- able simplicity is to resolve the total situation into the sum of contributions made by small elements. Our thesis is that if each of the elements is adequately characterized, the behavior of the whole system is fixed. The element is usually taken of a simple geometrical shape, suggested by the mathematics best adapted to the particular situation. The forces acting across the faces of the elements are ultimately determined by the forces acting across the free faces of the whole system. The detailed process of finding the precise forces on the faces of all the elements in terms of the external forces involves the use of a special mathematical invention, the stress, a constructional quantity consisting of six components. The stress at any point in the body is determined by both the external force system and by the physical properties of the body at all points; quite different stresses prevail at the interior of bodies of the same shape under the same external forces in the elastic and plastic ranges. The forces on the faces of any element are, however, uniquely determined by the stress system at the element. Our fundamental thesis

Jan 1, 1944

By Robert M. Dreyer

Diamond is the hardest known material. The diamond industry is separated into two major segments: (1) industrial and (2) gem. The major industrial use of diamonds is as a high-grade abrasive in a wide variety of applications for which no effective low-cost substitute is available. Table 15.4C.1 gives data on diamond production and on United States diamond imports. In both gem and industrial diamond production, but especially in the case of gems, the quantity of stones produced is not directly correlated to value, for the determination of value is markedly affected by quality. South Africa long has been the world leader in gem diamond production with an estimated production in 1968 (including South-West Africa) of about 4 million carats, equal to 43% of world production. During the past decade there has been a marked rise in gem diamond production in the USSR, so that nation is now the second-ranking world producer, with Angola (Portuguese West Africa) third. In natural industrial diamonds, the major production comes from Congo-Kinshasa (former Belgian Congo) which had a production of 15 million carats in 1968, equal to 47% of world production. In the past six years, there has been a remarkable increase of industrial diamond production in the USSR, which now ranks second with a production of 6 million carats, equal to about one-fifth of world production. South Africa now ranks third followed by Congo-Brazzaville and Ghana. No natural diamonds are produced in the United States. Since the discovery of an economical method for synthesizing small diamonds, there has been a rapid increase in synthetic production from 4 million carats in 1962 (1 carat equals 200 mg) to 11.5 million carats in 1968. Table 15.4C.1 gives the gradually increasing imports of industrial diamonds and indicates a relatively stable price. In 1968, the imports of industrial diamonds were 13.5 million carats with a value of $59.2 million. Table 15.4C.2 shows the rapidly increasing imports of cut and uncut gem diamonds into the United States. In 1968 the United States imported 2.5 million carats of uncut stones with a value of $166 million and 1.5 million carats of cut stones with a value of $175 million. Diamond marketing is dominated by DeBeers Consolidated Mines, Ltd., which, through subsidiaries, controls many of the major African diamond deposits. More important economically, however, through its Central Selling Organization, DeBeers markets 86% of the non-Communist world's natural diamonds, including most of those derived from deposits outside of corporate control. In 1967 the mines owned by DeBeers produced nearly 8 million carats, and the Central Selling Organization sold over $600 million in gem and industrial diamonds. The dominance of diamond sales by

Jan 1, 1976

By D. J. Griffiths

Beyond doubt it is practically impossible to eliminate all chances of accidents from falls. Mother Earth is not going to give up her treasures without some sacrificing on our part. This particular question ranks among the important subjects connected with coal-mining, and has been given less attention as a factor of life- and limb-destroyer than any other cause. The single fatalities which happen create very little attention; nevertheless, when counted up at the end of the year, they outnumber the unfortunate ones that are mowed down by the wholesale by mine explosions. Fire-damp and coal dust were often considered the greatest evils in coal-mining. All records, however, prove this conclusion to be wrong. The second annual report of the Bureau of Mines gives the loss of life caused by falls of coal and roof in 1910 as 1,310, and in 1911 as 1,321. The reports of Pennsylvania mine inspectors for a period of thirty-three years show that 59.38 per cent of all the accidents underground were caused by falls of roof and coal. Also, the Bureau of Mines shows in its last issue on fatalities that accidents from fall of roof and coal killed more men than any other two causes combined, and that they account for more than half of the deaths under- ground. It seems we are getting too accustomed, taking too many things for granted, running too many risks, trusting too much for the best, and preparing too little for the worst. We must remove the cause; then the effects will cease. However, I can see that a better day is here. The main damaging factors underground are falls of roof and sides. A bad roof is tender and lacks the adhesive qualities to sustain its own weight over comparatively small areas. A roof of any character which is frequently penetrated by well-defined slips and cleats, is characterized as a treacherous roof. The carelessness of men has been one of the main causes of most of the accidents in mining as well as in any other industries. Three Grades of Miners Miners can be classified into three distinct grades, to-wit: the experienced and careful, the experienced and reckless, and the inexperienced. The accidents which the first class usually meet with occur through the carelessness of their co-workers, as well as through accidents which are termed unforeseen, such as falling roof between timbers, and between the timbers and the face of the coal. This may have 'previously given evidence of being absolutely sound and safe, but be released by invisible slips or by sudden outburst of occluded gases in large quantities, as we term big blowers or feeders,

Jan 1, 1913

By Herbert H. Kellogg

In 1930, Taggart, Taylor and Knoll1 found that addition of various electrolytes to suspensions of ground minerals resulted in the stopping or starting of Brownian movement of the suspended particles. On the basis of the many new facts found, they rejected the " classical"† theory of Brownian movement and proposed an "ioniza-tion " theory. This new theory was further supported in later publications by Taggart.3,4 The acceptance of the ionization theory by men in the field of flotation may be judged by the mention given this theory in Gaudin's "Principles of Mineral Dressing,'16 Wark's "Principles of Flotation,"8 as well as in a recent paper by Fitt, Thomas and Taggart.7 The proponents of the ionization theory have gone further than the mere statement of the new theory. A parallelism between the Brownian movement of mineral particles and their behavior in flotation was reported.1,3,4 Likewise, the correlation between flocculation-dispersion of mineral particles and the Brownian movement of these particles has been investigated.' Bankoffl5 has suggested that "slime-coating" can also be directly correlated with the Brownian movement of the slime particles. In each of the instances mentioned it is the ionization theory of Brownian movement that has been used to "explain" the correlations that were found. The essential conflict between the kinetic theory and the ionization theory can be understood best by a brief description of each. The kinetic theory* proposes that Brownian movement is caused by the impacts of liquid molecules against the solid particles. At any instant of time, the molecular impacts on all sides of the solid particle will not balance, and the particle will receive a push in some direction. According to this theory, dl particles suspended in a liquid are in Brownian movement. However, if the particle is very large, the impacts on all sides will very nearly balance and the motion will not be noticeable. Another factor, besides the size of the particle, that affects the magnitude of the Brownian movement is the viscosity of the liquid—the greater the viscosity, the less the displacement of particles by Brownian movement. This theory has been verified experimentally by measurement of the velocity of Brownian movement, and by measurement of the compacting of suspensoid particles under the influence of gravity.2 The originators of the ionization theory found that he addition of various electrolytes to slime pulps caused cessation or commencement of Brownian movement, depending upon the chemical nature of the particle and the electrolyte. The Brownian movement of quartz particles was observed to stop upon the addition of Certain electrolytes, where the conditions of the experiment prevented flocculation

Jan 1, 1947

By Herbert H. Kellogg

IN 1930, Taggart, Taylor and Knoll1found that addition of various electrolytes to suspensions of ground minerals resulted in the stopping or starting of Brownian movement of the suspended particles. On the basis of the many new facts found, they rejected the "classical "[t] theory of Brownian movement and proposed an "ionization" theory. This new theory was further supported in later publications by Taggart.3,4 The acceptance of the ionization theory by men in the field of flotation may be judged by the mention given this theory in Gaudin's "Principles of Mineral Dressing,"5 Wark's "Principles of Flotation,"6 as well as in a recent paper by Fitt, Thomas and Taggart.7 The proponents of the ionization theory have gone further than the mere statement of the new theory. A parallelism between the Brownian movement of mineral particles and their behavior in flotation was reported.1,3,4 Likewise, the correlation between flocculation-dispersion of mineral particles and the Brownian movement of these particles has been investigated.7 Bankoff15 has suggested that "slime-coating" can also be directly correlated with the Brownian movement of the slime particles. In each of the instances mentioned it is the ionization theory of Brownian movement that has been used to "explain" the correlations that were found. The essential conflict between the kinetic theory and the ionization theory can be understood best by a brief description of each. The kinetic theory* proposes that Brownian movement is caused by the impacts of liquid molecules against the solid particles. At any instant of time, the molecular impacts on all sides of the solid particle will not balance, and the particle will receive a push in some direction. According to this theory, all particles suspended in a liquid are in Brownian movement. However, if the particle is very large, the impacts on all sides will very nearly balance and the motion will not be noticeable. Another factor, besides the size of the particle, that affects the magnitude of the Brownian movement is the viscosity of the liquid-the greater the viscosity, the less the displacement of particles by Brownian movement. This theory has been verified experimentally by measurement of the velocity of Brownian movement, and by measurement of the compacting of suspensoid particles under the influence of gravity.2 The originators of the ionization theory found that the addition of various electrolytes to slime pulps caused cessation or commencement of Brownian movement, depending upon the chemical nature of the particle and the electrolyte. The Brownian movement of quartz particles was observed to stop upon the addition of certain electrolytes, where the conditions of the experiment prevented flocculation

Jan 1, 1945

By Herbert H. Kellogg

In 1930, Taggart, Taylor and Knoll1 found that addition of various electrolytes to suspensions of ground minerals resulted in the stopping or starting of Brownian movement of the suspended particles. On the basis of the many new facts found, they rejected the " classical"† theory of Brownian movement and proposed an "ioniza-tion " theory. This new theory was further supported in later publications by Taggart.3,4 The acceptance of the ionization theory by men in the field of flotation may be judged by the mention given this theory in Gaudin's "Principles of Mineral Dressing,'16 Wark's "Principles of Flotation,"8 as well as in a recent paper by Fitt, Thomas and Taggart.7 The proponents of the ionization theory have gone further than the mere statement of the new theory. A parallelism between the Brownian movement of mineral particles and their behavior in flotation was reported.1,3,4 Likewise, the correlation between flocculation-dispersion of mineral particles and the Brownian movement of these particles has been investigated.' Bankoffl5 has suggested that "slime-coating" can also be directly correlated with the Brownian movement of the slime particles. In each of the instances mentioned it is the ionization theory of Brownian movement that has been used to "explain" the correlations that were found. The essential conflict between the kinetic theory and the ionization theory can be understood best by a brief description of each. The kinetic theory* proposes that Brownian movement is caused by the impacts of liquid molecules against the solid particles. At any instant of time, the molecular impacts on all sides of the solid particle will not balance, and the particle will receive a push in some direction. According to this theory, dl particles suspended in a liquid are in Brownian movement. However, if the particle is very large, the impacts on all sides will very nearly balance and the motion will not be noticeable. Another factor, besides the size of the particle, that affects the magnitude of the Brownian movement is the viscosity of the liquid—the greater the viscosity, the less the displacement of particles by Brownian movement. This theory has been verified experimentally by measurement of the velocity of Brownian movement, and by measurement of the compacting of suspensoid particles under the influence of gravity.2 The originators of the ionization theory found that he addition of various electrolytes to slime pulps caused cessation or commencement of Brownian movement, depending upon the chemical nature of the particle and the electrolyte. The Brownian movement of quartz particles was observed to stop upon the addition of Certain electrolytes, where the conditions of the experiment prevented flocculation

Jan 1, 1947

By Tracy C. Jarrett

The alloying of various elements with gold to produce different colors is an old art, but the effect of each element or combination of elements is not generally known. Investigations have been made in this field by F. E. Carter,' E. M. Wise,2 and L. Sterner-Rainer.3 It is the intent of this paper to present in schematic diagrams the effects of various elements upon the color and the melting point of gold alloys. In this investigation 2-oz. melts made in a high-frequency inductiorl furnace were used for all tests. The melting points were determined by the use of a calibrated chromel-alumel thermocouple sealed in a thin-walled alundum tube. The couple was then submerged in the molten metal and the freezing and melting points were determined by using a Leeds and Northrup potentiometer. By checking several melts using copper, zinc and gold, it was found that the accuracy of determining the melting point was within ± 5" F. To determine the differences in colors and to classify them, a wet tissue paper was placed over the polished samples and examined under a uniform white light. The 2 by 45 by 0.045-in. samples were cut from 50 per cent cold-worked strip. The original ingot was 3 by % by % in. This visual comparison, although not scientifically exact, served as a quite satisfactory means for determining and classifying these differences. The base alloys, or "hardeners," were first made up and analyzed, after which the gold and silver were added. This method of making up the alloys was chosen so that the same base alloy could be used for the gold alloys of different karats. The first series consisted of gold, copper, zinc and nickel, the copper comprising from 85 to 65 per cent of the content of the "hardener" and the zinc and nickel replacing copper. The second scries consisted of gold, silver, copper, zinc and nickel, the copper comprising from 85 to 65 per cent of the content of the hardener with the silver, nickel and zinc replacing copper. There was no particular reason for choosing these combinations, except that they gave a color range from red-pink to white.

Jan 1, 1940

By Tracy Jarrett

THE alloying of various elements with gold to produce different colors is an old art, but the effect of each element or combination of elements is not generally known. Investigations have been made in this field by F. E. Carter,1 E. M. Wise,2 and L. Sterner-Rainer.3 It is the intent of this paper to present in schematic diagrams the effects of various ele¬ments upon the color and the melting point of gold alloys. In this investigation 2-oz. melts made in a high-frequency induction furnace were used for all tests. The melting points were determined by the use of a calibrated chromel-alumel thermocouple sealed in a thin-walled alundum tube. The couple was then submerged in the molten metal and the freezing and melting points were determined by using a Leeds and Northrup potentiometer. By checking several melts using copper, zinc and gold, it was found that the accuracy of determining the melting point was within ± 5° F. To determine the differences in colors and to classify them, a wet tissue paper was placed over the polished samples and examined under a uniform white light. The 2 by ½ by 0.045-in. samples were cut from 50 per cent cold-worked strip. The original ingot was 3 by ¼ by ¾ in. This visual comparison, although not scientifically exact, served as a quite satisfactory means for determining and classifying these differences. The base alloys, or "hardeners," were first made up and analyzed, after which the gold and silver were added. This method of making up the alloys was chosen so that the same base alloy could be used for the gold alloys of different karats. The first series consisted of gold, copper, zinc and nickel, the copper comprising from 85 to 65 per cent of the content of the "hardener" and the zinc and nickel replacing copper. The second series consisted of gold, silver, copper, zinc and nickel, the copper comprising from 85 to 65 per cent of the content of the hardener with the silver, nickel and zinc replacing copper. There was no particular reason for choosing these combinations, except that they gave a color range from red-pink to white.

Jan 1, 1939