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By G. F. Tagg

EARTH-REISTIVITY measurements are often of service in obtaining information regarding geological formations, particularly when applied to structural problems. In such problems the masses of the various bodies are large, and have a corresponding effect on the average resistivity of the soil. Much work has been done using such measurements, but in general the method of interpretation employed is empirical. Since certain simple cases can be investigated mathematically, it appears to be quite sound to endeavor to apply the mathematical solutions to the practical results, in order to deduce from the latter such unknown quantities as depth. This paper deals with such a method of interpretation for the simple case of a single horizontal stratum. SURFACE Of EARTH In the method described by FIG. 1.-WENNER'S METHOD OT MEASURING Wenner1 for measuring earth resis- EARTH RESISTIVITY. tivity, four stake electrodes are driven into the earth in a straight line as shown in Fig. 1. A current I amperes is passed between the two outer stakes and the potential difference . V volts between the two inner stakes is measured. Then if a is the electrode separation, the specific resistance of the soil, which is assumed to be homogeneous, is given by the formula

Jan 1, 1932

By R. E. Zimmerman

THE separation of fine sizes of coal from its impurities by means of various flotation methods has become of increasing importance in the coal industry. This, no doubt, will be even more so in the future as the quantity of high grade coal is depleted, particularly that used for metallurgical purposes. The purpose of this paper is to describe and report the results of research work done under the auspices of the Pittsburgh Coal Co. to determine the amenability of their bituminous fine sizes of coal to flotation, to investigate the value of various reagents and factors affecting their use, and compare the results between froth flotation and bulk oil flotation. Compared with the preferential flotation of complex minerals, or ores, the flotation of coal is comparatively easy. However, this statement should not lull one into the feeling that there are no special problems involved. For instance, the separation of coal from pyrite in high sulphur coals is still far from being 100 pct successful. Size consist has considerable effect on reagent consumption and recovery. Other factors will be described and finally it must be remembered that in the flotation of coal a low priced material is being treated and thus economic considerations govern more closely its application than is generally the case in treating other minerals. As a result of the research work done by the Pittsburgh Coal Co. on the flotation of coal, it was concluded that it was practical to clean the -48-mesh coal commercially by froth flotation and after several different types of flotation units and circuits were investigated by means of pilot plants, large scale units were installed at their Champion Nos. 1, 4 and 5 Preparation Plants for the cleaning of -48-mesh slurries. These large scale operations have been recently described by D. H. Davis. 1 C. P. Proctor and C. B. Carlson2 in their chapter on Froth Flotation of Coal in the AIME Seeley W. Mudd series book on Coal Preparation describe some of the practical applications of our Pittsburgh Coal Co. laboratory work in actual plant practice as well as summarizing part of the investigational work. The author presents this paper, however, as a supplement to their reports, and records the basic research accomplished in the laboratory investigational work as well as the results of experi¬ments using bulk oil flotation. In presenting this work the author wishes to state much more work must be done in applying the principles of flotation to cleaning coal, especially in view of recent studies and practices in other mineral beneficiation fields. METHODS OF CONDUCTING LABORATORY TESTS The bulk of the research work was conducted in the laboratory of the Champion No. r Preparation Plant. This plant has elaborate facilities for sampling and analyzing coal and proved to be an admirable location

Jan 1, 1948

By Raymond P. Maloney

The Rhyolite mercury prospect is on the south flank of Juninggulra Mountain--a large rhyolite intrusive in the Kuskokwim River region about 36 airline miles northwest of Red Devil, Alaska. Bulldozer trenching by the Bureau of Mines exposed bedrock at intervals in a 2,000-by 3,000-foot area where previous prospecting by the owners had disclosed abundant float and several in-place stringers containing cinnabar in widely varying amounts. The additional trenching indicated that the mercury mineralization in the limited area investigated was confined to erratically distributed short stringers and to small lenses, occurring in discontinuous zones in numerous silica-carbonate dikes and sills or along their altered contacts with sedimentary rocks. The geologic relationship of the mercury-bearing silica-carbonate dikes and the nearby rhyolite intrusive is similar to that existing at several other mercury mines and prospects in the. Kuskokwim region. The depth of over-burden and the presence of permafrost were serious obstacles to bulldozer trenching, and only a comparatively small part of the mineralized area was thus investigated.

Jan 1, 1962

By F. F. Aplan, D. W. Fuerstenau

This chapter presents modern concepts of the flotation of nonmetallic minerals. In particular, it is concerned with such minerals as metal oxides, silicates, sulfates, carbonates, and halides. It is not the purpose to duplicate the two excellent, recent treatises by Gaudin l and by Sutherland and ark,^ but rather to expand their correlations of data, particularly in view of recent, ex- citing new experiments which are shedding new light on the principles of non- metallic flotation. Outstanding success has been achieved over the past 50 years in separating one sulfide from another or from the gangue constituents using a minimal amount of reagents. In contrast to this, selective flotation in nonmetallic systems is often difficult in that one class of compounds alone, the carboxylic acids, may float nearly the entire array of nonmetallic minerals under the appropriate conditions. Moreover, while lime, cyanide, sodium sulfide, and copper sulfate constitute the principal modifiers used to obtain selectivity among the various sulfides, the nonmetallic mineral flotation engineer is con- fronted with a vast array of modifying reagents. In sulfide and native-metal flotation, a strong chemical adsorptive bond is generally formed between the mineral and sulfhydral collector. In fact, re- cent radio-tracer studies show that below monolayer coverage as much as 98% of added mercaptan is adsorbed on the surface of gold.? Contrasted to this, Bloecher's data indicate that for the quartz-amine system only about 60% of the collector is adsorbed.4 This greater residual concentration in the solution results from weaker forces of adsorption in the quartz-amine system. In the flotation of nonmetallic oxide minerals, collector adsorption results from rather weak physical forces, primarily electrostatic attraction and van der Waals attraction between hydrocarbon chains. In the flotation of salt-type minerals, carboxylic acids are adsorbed both by physical and chemical forces. It is a study of the effect of the electrical forces superimposed on the chemical adsorptive forces that contributes most toward understanding nonmetallic mineral flotation. The need for quantification of general rules for the flotation of nonmetallic minerals is so great that Taggart 5 with unmasked sarcasm suggested that after trying anionic and cationic collectors:

Jan 1, 1962

By Charles M. Brown, Russell Franks, W. O. Binder

Occasionally in the application of the austenitic chromium-nickel steels to corrosive conditions, failures have occurred by cracking without serious general over-all attack of the metal. As pointed out by Foyt and Scheil(1),2 and by Scheil, et al.(2) as well as by Hodge and Miller(3), the stress-corrosion failures that have occurred have been limited in number, and have taken place only when the steels were exposed to certain corrodents. These investigators have stated that while stress- corrosion cracking can be intergranular in nature and originate at the grain boundaries of the austenitic chromium-nickel steels, it can also take place in trans- granular fashion. They have shown that the cracking may be either initiated at the grain boundaries and may propagate along grain boundaries for some distance and then suddenly extend across grains, or it may begin in a transgranular fashion and suddenly proceed along grain boundaries until the cracking stops. Their data further show that when austenitic stainless steel is subject to intergranular attack, stress will concentrate and cause cracking in service. These investigators have studied the effect of the metals titanium and columbium which are added to the steels to impart immunity to intergranular attack, and molybdenum which is added to improve resistance to general corrosion.

Jan 1, 1945

By Gerald M. Ellis

Introduction Gold exploration in the Dominican Republic has not received much publicity. The fact is, however, that a continuous program has been underway for some time. For the past two years, the Restauracion area of the western Dominican Republic, near the Haitian border, has been the scene of mineral exploration by the Dominican Department of Mines geologists, and later by geologists of Rosario Dominicana. The latter is a state-owned gold mining company and operator of the Pueblo Viejo open-pit gold mine. The exploration is for mineral deposits with the goal of finding another Pueblo Viejo-type deposit. Geology Exploration is being carried out in the western central Cordillera, the backbone of the Island of Hispaniola. Geology consists of quartz veins and veinlets and ramifying stringers carrying pyrite, barite, minor amounts of copper, and significant amounts of gold in places. They are associated with regional faulting in a complex of Cretaceous beds of andesites, dacites, argillites, siltstones, and shales. They are intruded by tonalites, diorites, and gabbros. Lesser amounts of zinc-lead mineralization occur in some locations. The showings appear as disseminations along the faults. To date, the work has been mostly geologic mapping - 1 to 50,000 with details on a scale of 1 to 20,000 and 1 to 10,000-stream and soil lithogeochemistry, and geophysics. Trenching and sampling were used to follow possible vein extensions. Particular emphasis has been placed on the Los Candelones district that was taken over by Rosario Dominicana. Here is where drilling has been initiated in the past months. The first hole drilled showed assays of 21 g/t (0.6 oz per st). The second hole intersected an interesting oxidized zone that reminded observers of the original Pueblo Viejo oxidized zone. A third drill hole went deeper than 75 m (246 ft), the depth to which the first two holes had been scheduled. An assay of 50 g/t (1.46 oz per st) was cut during drilling. The presence of an oxidized zone of any vertical and horizontal extent is important. This gives rise to continued exploration, as the

Jan 2, 1986

By A Baensch, E Grimsley

Eloise Copper Mine is situated 56 km east-southeast of Cloncurry, Queensland, Australia. The deposit was discovered by BHP Minerals in 1986 during follow up diamond drilling of EM anomalies associated with major aeromagnetic anomalies. The deposit is overlain by 60 m of Mesozoic cover. Amalg Resources NL commenced mining during 1995 by means of decline access and long hole-stoping. The total mineral resource comprised 1.77 million tonnes at 4.10 per cent Cu as at the end of June 2003. Proved and probable reserves are 930 000 tonnes at 3.97 per cent Cu. Mineralisation is hosted within a strongly foliated Proterozoic meta-sedimentary sequence comprising arenites and schists. The metasediment sequence also contains a coarse-grained amphibolite body possibly representing an early intrusion of gabbroic composition. Economic mineralisation characteristically occurs as a number of steeply plunging lenticular bodies with strike lengths of between 100 and 200 m and maximum widths approaching 25 m. The principal orebody, the Levuka (B) Lode, displays a down plunge extension exceeding 1000 m and is open at depth. Ore mineralogy is almost exclusively chalcopyrite with the principal gangue phases consisting of pyrrhotite + quartz + carbonate. A biotite + hornblende + magnetite assemblage represents locally intense mafic alteration of the metasedimentary host sequence. Magnetite is present in variable amounts and may be locally significant in some of the smaller satellite orebodies. Within the orebodies the sulfides display a range of textures from massive through to vein like. Sulfides commonly display brecciated textures at a range of scales. Post-mineralisation faulting has severely dislocated the orebodies, resulting in a complex arrangement of fault bounded ore blocks. These faults display considerable variability in regard to strike, dip and amount and direction of throw. A recent review of the fault system by means of large-scale structure underground mapping, re-interpretation of drill core and 3D modelling has led to a significant improvement in the understanding of these structures. A significant upgrade of the geological database has accompanied the structural review. The overall improved understanding has aided the mine design processes with particular regard to decline and access development and pillar location. This has also impacted on the design of drilling programs and exploration for additional satellite ore zones.

Jan 1, 2003

Sixteen executives, technicians and operative personnel from the French mining industry, now touring mining operations in the U.S., will wind up their visit to this country at the AIME Annual Meeting. Traveling under ECA auspices, they will be in Denver on Feb. 5, Salt Lake City, Feb. 8 to 13, Bonne Terre on Feb. 16. Four of the group are engaged in bauxite mining, nine in lead and zinc, two in pyrites mining. All are interested in American mining equipment and methods, and hope to contact manufacturers' representatives in the various areas they visit. A $600,000 manganese pilot plant is expected to be put into operation by Sept. 1, by the Bureau of Mines at Boulder City, Nev. S. R. Zimmerly, chief of the Bureau's metallurgical div. for the region, recently completed the mill design and flow sheet; and the Bureau is awaiting steel priorities before building. Ore from the Artillery Peak area, 60 miles south-west of Kingman, Ariz., will be used in the mill. Construction will be handled by Rex Lloyd of Boulder City.

Jan 2, 1951

By John F. Blandy

IT is not my intention in this article to consider this subject in the light of the geographer or geologist, but rather in that of the mining engineer, and to endeavor to show the necessity and value to him of studying the minor details of the field or district in which he may be engaged. It has been said by a distinguished geologist that "the natural boundaries of the geographer are rarely described by right lines. Whenever they occur, however, the geologist may look for something remarkable." And again ; " Physiognomy is no idle or doubtful science in connection with geology. The physiognomy of a country indicates almost invariably its geological character." Our country furnishes examples enough of the truth of these remarks, and in no part of it is it so beautifully illustrated as in our own State, which has been so ably described by Prof. Lesley in his admirable little work on the "Topography of Coal." As the great mountain lines become guides to the geologist in determining and mapping out the geography of the formations, so do the minor details of topography become guides to the mining engineer in conducting his explorations, discovering of dislocations, and determining the character of the deposits which are the object of his search. It is therefore requisite that he should, whilst making his surveys, pay the strictest attention to every variation of the landscape and surface of the ground. Until he has mapped out every feature he may be unable to read the geological changes which may have

Jan 1, 1873

By John F. Blandy

IT is not my intention in this article to consider this subject in the light of the geographer or geologist, but rather in that of the mining engineer, and to endeavor to show the necessity and value to him of studying the minor details of the field or district in which he may be engaged. I t has been said by a distinguished geologist that "the natural boundaries of the geographer are rarely described by right lines. Whenever they occur, however, the geologist may look for something remarkable." And again : " Physiognomy is no idle or doubtful science in connection with geology. The physiognomy of a country indicates almost invariably its geological character." Our country furnishes examples enough of the truth of these remarks, and in no part of it is it so beautifully illustrated as in our own State, which has been so ably described by Prof. Lesley in his admirable little work on the "Topography of Coal." As the great mountain lines become guides to the geologist in determining and mapping out the geography of the formations, so do the minor details of topography become guides to the mining engineer in conducting his explorations, discovering of dislocations, and determining the character of the deposits which are the object of his search. I t is therefore requisite that he should, whilst making his surveys, pay the strictest attention to every variation of the landscape and surface of the ground. Until he has mapped out every feature he may be unable to read the geological changes which may have

By J. H. Bassarear, J. D. Vincent

General. Copper, the first metal used by man, today is the third in consumption after iron and aluminum. Compared to these it is relatively rare, with less than 0.01% of the earth's crust copper, 8% aluminum, and 5% iron. Nevertheless. our modern civilization is heavily dependent upon copper because of its high conductivity and resistance to corrosion, ease of working, durability, wide range of properties by virtue of its readiness to form alloys with other metals, and its attractive colors and texture that make it so desirable for many crafts and arts. These attributes explain why copper is chosen for a long list of uses, including electrical wiring, switchgear, and bus bars; piping, roofing, and siding; and manufactures of brass, bronze, and other alloys. The fact that copper ore is mined in nearly all parts of the world is significant. Its importance is shown in Table I, which gives figures on world production from 1968 to 1977. In the Free World, North and South America and Africa are preeminent. The table also shows the generally upward trend of production in this period; accurate figures for 1978 and 1979 from the same source are not yet available (1980), but it is certain that major environmental, economical, and political factors continued to disturb the industry in those years and into 1980.

Jan 1, 1985

"The largest variety of asphalt and related bitumen deposits in this country is found in Utah. Utah is one of the few places in the world where the hydrocarbon minerals, gilsonite or uintaite, wurtzilite (trade name elaterite) and ozokerite are produced. These bitumens occur in an area embracing nearly 10,000 square miles in eastern Utah near the Colorado line. This area is largely in the western part of the Uintah basin. The bitumens are in the Tertiary horizon in the various divisions of the Eocene series.Gilsonite is an asphaltite derived from petroleum, wurtzilite is an asphaltic pyrobitu¬men derived from petroleum, and ozokerite is a native mineral wax resulting from the met-amorphosis of paraffinaceous petroleum.Gilsonite is produced by the Gilson Asphaltum Company, a subsidiary of the Bar¬ber Asphalt Company, at Watson, Utah. A narrow guage railroad, seventy miles in length and with a 7 1/2 percent grade over the Book Cliffs on Baxter Pass, was constructed by the company from the Denver & Rio Grande Western railroad main line in order to open up the gilsonite deposits. The veins range from narrow upward to 18 feet in width. The Rainbow vein at the present wokings is eight feet wide, vertical, and has sandstone walls. This vein has been opened up for a distance of about three miles and in some places four hundred feet deep. Forty men usually are employed with a production of eighty tons per day."

Jan 1, 1925

By F. H. Wilson, E. W. Palmer

G. L. Bailey (British Non-Ferrous Metals Research Association, London, England)—I was glad to see this further work on the structure and properties of the Cu-Ni-Fe alloys of low nickel content in which we have been so interested in the United Kingdom since before the war." The authors' data on the variation in solubility of iron in both 5 and 10 pct Ni alloys with temperature is based on more detailed observations than we have made but is generally in line with our own work. The difficulty in these matters is in the identification of the structures obtained. The precipitation of the second phase which we presume to be the a' solid solution, richer in nickel and iron, from the a solution with which it is in equilibrium occurs in such a fine state of division that its resolution by ordinary micro-graphic methods is impossible in the early stages. We have published some electron micrographs which illustrate the effects observed more clearly but we agree with the authors when they say that dark staining characteristics when the alloys are subjected to sea-water corrosion are more sensitive in detecting the presence of the a' phase than is the microscope. After taking this point into consideration, however, I confess to some difficulty in understanding Fig. 4. I can only assume that the precipitates visible at such a low magnification as 150 diam in these relatively coarse forms are produced from iron-rich areas of the initial solid solution due to inadequate homogenization. If this is so I find it difficult to accept the authors' contention that such local variations in iron concentration as are capable of giving the heavy precipitates shown in Fig. 4 do not in fact materially affect the solvus surfaces of their equilibrium diagrams. I share the authors' enthusiasm about the resistance to corrosion of these alloys by seawater but I am not fully in agreement with them on the vexing question of the best iron content for these alloys. In Fig. 3 of ref. 8, we give many results showing that the resistance of these alloys to impingement attack in the Jet Test increases as the iron content rises to 2 pct. With higher iron contents pitting at shielded areas is likely to occur. Admittedly the addition of 0.75 pct Fe produces a large improvement in corrosion resistance compared with a pure 90/10 Cu-Ni alloy, but the further improvement on raising the iron to 2 pct is substantial. We recommend from 1.5 to 2 pct Fe as the desirable range from the point of view of corrosion resistance. While it is true that British practice generally uses a hard tube, the corrosion resistance of the 10 pct Ni alloys has in our work been little affected by the structural condition. Although the annealed alloys blacken in seawater, this effect seems to be superficial and not to be accompanied by any real decrease in

Jan 1, 1953

By J. P. Nowlan

"This paper is an attempt to outline the structural problems at the Cochenour Willans mine, in so far as their details have been tentatively worked out. It must be emphasized that there are considerable data that can be interpreted in more than one way, and that further work may modify or completely change some of the hypotheses presented herein. Certain features, however, are sufficiently constant to warrant reliance on them when searching for extensions of orebodies.As the individual ore shoots usually have relatively small dimensions, but are often very high grade, structural details are of more than usual significance in laying out a mining programme. An illustration of this is a small shoot recently located and mined as a result of studying a minor slip cutting off a part of high grade gold ore in No. 319 stope. The shoot, which is bounded on three sides by slips, and on the fourth by the original stoping, was roughly triangular in plan, 20 feet on the base, and 40 feet in length. The average width mined was 4.5 feet, but the gold obtained totalled over 1,800 oz.The property lies in Dome township, east of McKenzie island, and consists of an original group of thirteen claims acquired from the Cochenour Willans syndicate, plus one additional group of five claims obtained by purchase from the Kelson Red Lake Gold Mines, Limited, and one other claim that rounds out the southeast corner of the block.The claims of the original group were staked by W. M. Cochenour, Dan Willans, and Horace Young, during 1926 and 1927. The Cochenour Willans Syndicate was formed in 1928, and until incorporation of the present Company work was carried on at varying intervals by several different interests, including Ventures Limited, Hollinger Consolidated, who sank a shaft to open up the 150-foot level, and by the Syndicate itself. The first ore from the property was shipped to the Gold Eagle mill by the present Company in 1939, and amounted to 4,959 tons, from which 2,360 oz. gold was recovered. The first brick was poured in December, 1939, and production has been continuous since that date. To the end of June, 1946, gold having a value of $5,982,000 has been produced from 345,033 tons of ore treated."

Jan 1, 1954

By Charles White Merrill

A forecast of mineral demand during the remaining years of the 20th century can serve as an excellent starting point for student mining and mineral engineers in planning their professional careers. This approach of appraising demand before seeking supply is not new. of course, but, it is quite the opposite of the traditional attack on mineral resources in which adventurous prospectors, followed by practical miners and engineers, have in the past sought out and developed mineral supply with a faith that markets existed for the products they were preparing to offer. Such faith, even to this day remains fully justified if the product is gold, which still enjoys an unlimited market at $35 a fine ounce, but other mineral products must compete in markets of varying stability and capacity for adsorbing new supply. The world is in a period of rapid expansion. Most basic is the worldwide increase in the number of people which has reached proportions popularly termed "the population explosion." Conservative demographers, noting an increase from 1 ?h billion people at the beginning of the 20th century to 3 billion today, are predicting 5 billion by the year 2000; some predictions are much higher.

Jan 2, 1964

By Van H. Manning

In substance, the international aspects of the petroleum industry, as these relate to the United States, are as follows: The domestic production is not keeping pace with the domestic demands; our best engineering talent warns us of the imminence of a decreased production by our oil wells, although more oil is needed; and the only practical source whence this increasing demand can be supplied for some time to come will be the foreign fields. Other nations have given thought to the future and, in recent years, have shown a tendency to adopt strong nationalistic policies regarding their petroleum resources, policies that hinder or prevent the exploitation of these resources by other nationals. In consequence, we find that, facing a probable shortage of the domestic supply, our nationals are excluded from foreign fields; and this in spite of the fact that foreign nationals have been permitted to enter into and exploit our own oil resources on an equality with American citizens and without hindrance or restrictions. This country has supplied the larger part of the petroleum consumed by the world and yet, with a failing supply imminent, it finds that those countries that, have been drawing upon our resources to supply their needs are showing a tendency to exclude us from their resources. In this way we shall be transferred from a position of dominence to one of dependence; and only by sufferance of those countries that are now seeking financial or political control of petroleum supplies, shall we be able to obtain the oil we will need. Impoetance of Petroleum Petroleum has become, during recent years, one of the essentials of our social and industrial life. All civilized countries recognize that the world is dependent on petroleum as on nothing else except textiles: foodstuffs, coal, and iron. Today, the tendency is toward an ever-increasing consumption of petroleum and its products as new and more efficient uses are found for them. The utilization of petroleum is extending more and more into the structure of our civilization. Consequently,

Jan 1, 1921

By Tetsuo Yamazaki

Natural methane hydrate has been scientifically studied as a carbon reservoir globally. However, in Japan, the potential for energy resource has been industrially highlighted. There is less domestic oil and natural gas resources in Japan, but many potential deposition areas for methane hydrate in ocean around Japan are the reasons. Less CO2 discharge from methane compared with coal, oil and conventional natural gas when the same calorie value we get is considered as the advantage for energy resource. However, because methane hydrate distributes in shallower sediment layer in ocean floor, accidental leakage of methane may occur while we utilize methane hydrate. Methane itself has 21-times impact on the greenhouse effect, if it reaches the atmosphere. Therefore, it is necessary to estimate the behavior in the environment after the leakage, if we want to use methane hydrate as energy resource. The mass balance after leakage of methane on seafloor and in water column is numerically studied through the analyses of methane emissions from natural cold seepages and hydrothermal activities in this research. The outline structure of mass balance ecosystem model shown in Fig. 1 is introduced. A numerical early diagenetic model CANDI (Carbon And Nutrient Diagenesis) developed by Boudreau (1996) for simulating the biogeochemical processes such as organic matter, oxidant, nutrient, bi-product, and pH diagenesis in aquatic surface sediments and C. CANDI improved by Luff and Wallmann (2003) for describing the formation process of calcium carbonates in CANDI are used as bases of the ecosystem modeling in surface sediment layer around seafloor methane emission. Two functions such as methane bubble dissolution and bacterial methane oxidation in water column are added to an existing physical plume dispersion model by Doi et al. (1999).

Jan 1, 2005

By J. Gurland

The effects of variations of carbon content on the constitution and properties of sintered WC-Co alloys were studied. The grain growth of tungsten carbide during sintering was measured and it was shown that it takes place mainly by solution and reprecipitation of the carbide in and from the binder at the sintering temperature. It was found that the decomposition of W3C03C by carburization during sintering is responsible for the formation of very large grains. THE properties of sintered WC-Co alloys are critically dependent upon their final composition and structure. Slight changes of cobalt and carbon contents and small variations of grain size result in marked changes of mechanical properties and performance of products. Previous investigators have studied the microstructure as a function of composition' and have dealt with the influence of cobalt upon properties.' The present work is concerned with the effect of carbon content upon constitution, microstructure, and grain growth during sintering, as well as upon the physical properties of sintered compacts. Phase Boundaries at the Sintering Temperature The WC-Co section through the ternary diagram W-Co-C has been studied by Wyman and Kelley,' Takeda,V andford and Trent," and Rautala and Norton." Two phases, namely WC and a cobalt-rich solid solution (P), appear in the sintered structure if the carbon composition corresponds very nearly to the theoretical carbon content of WC (6.12 pct C). But small deviations from the ideal carbon content will bring about the occurrence of either graphite or the double carbide W,Co3C (7) . The 7 phase was long believed to be metastable, this conclusion being based mainly on the work of Takeda. More recent studies have shown that it is a stable phase of the ternary system,"5 but the actual phase boundaries have not been established and there has been some discussion as to whether or not the 7 phase occurs at some stage of sintering in the fully carburized alloys." In view of this uncertainty it was thought advisable to undertake an investigation of the phases present during the sintering of WC-Co alloys. Commercially available tungsten, cobalt, and carbon powders were used in the present study. A typical analysis of impurities in a sintered compact is reported in Table I. The desired carbon compositions were attained by varying the amount of carbon added to the tungsten during carburization and controlling the composition during sintering by packing the compacts into beds of mixed alundum-carbon powders of suitably selected ratios. The alloys were sintered in a hydrogen tube furnace at 1400°C, then brought to equilibrium at the temperature under investigation and quenched in water. The high temperature phases were identified by metallographic and X-ray diffraction techniques. The samples were etched with a 10 pct solution of alkaline potassium ferricyanide. The phase boundaries, established by metallo-graphic examination, are shown in Fig. 1, which is a vertical section through the ternary diagram at 16 pct Co. The temperatures of the invariant planes, at 1298" and 1357°C were established by Rautala and Norton. The vertical section shows that the three-phase field, WC + 7 + L, extends into the two-phase field, WC + L, but does not include the stoichiometric composition of WC. In practice this means that the 7

Jan 1, 1955

By John V. Beall

A completed feasibility study executed by an independent agency can benefit a company in two ways. Inside the organization, it verifies the project staffs ideas and their concept of the facility. Outside the company, it can be utilized to obtain equity partners, debt financing, and other forms of credit. It is advisable to bring in a project execution contractor for the feasibility study. A project execution contractor is able to work with engineers to develop the project concept, process flowsheet, and best utilization of the site. By getting an early start on understanding a company's policies and working methods, a project execution contractor saves the company money since it does not have to go through the educational buildup twice. The contractor is a specialist in putting together a bankable document that can be taken to a financing source. It answers all the agency requirements on the first pass. In addition, the contractor can advise an owner on likely financing sources since he works on the worldwide market every day. A less obvious advantage of including the contractor in the study and predevelopment buildup stages is the importance of coordinating finance and technical input. The financing source influences equipment specifications, procurement, logistics, project schedule, cash flow, and liquidity. There are many surprises in store for any manager of a large international project involving worldwide financing and purchasing. The job does not have to be made more difficult by bringing in a contractor after all predevelopment steps are taken. The contractor can still work if the predevelopment steps have been done, even if he does not agree with them. But early contractor involvement is the preferable solution.

Jan 10, 1980

By F. J. Tuck

THE Hayden mill of the Ray Mines Division, Kennecott Copper Corporation, is now equipped with two 9 by 12-ft. rod mills having a daily capacity of 6000 tons of coarse-crushing plant product from the mine. These two mills crush a 3/4-in. product to approximately 19 per cent on 14 mesh, with only one pass through the mills. Each rod mill has taken the place of four sets of 42-in. Garfield rolls with their attendant screens, and is making a product for the fine-grinding department comparable to that formerly made by rolls in closed circuit with screens. The rod mills are lined with wave-type liners of white iron, varying in thickness from 2 to 3 in. The shell and end liners last approximately 600 to 700 clays. Manganese-steel lifter bars, 3 5/8 in. thick, are used, spaced about 11 in. apart, and they give a life of 350 to 450 clays. Fig. 1 shows the general design and thickness of the wave-type liners and lifter bars; 1 1/2 -in. liner bolts are used to fasten the lifter bars to the shell. The shell liners are held in place by the tapered lifter bars. A ¾-in. wood hacking is used between the shell and the liners. The rod-mill scoop has removable manganese-steel lips, which last 250 to 300 days. The scoop proper has shown some wear in spots; and these spots have been protected by rubber bolted over them. Water and milk of lime are added to the elevator feeding the mill, but not enough water to cause a pounding of the rods against the shell. Roughly, the water added amounts to 2.5 to 33 per cent of the ore. Addi-tional water is added to the mill discharge to facilitate distribution to the classifier bowls in the fine-grinding department.

Jan 1, 1938