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By Cyril Smith

SOMEWHAT over ten years ago the author described studies1,2 on the constitution of the copper-silicon system. The copper-rich portion of this diagram is shown in Fig. 1. The experimental points freely dotted about the diagram seemed to justify an otherwise unconvincing diagram and for several years the curious reverse bend in the alpha-phase bound-ary was accepted as substantially correct, even by later investigators3,4 of the system who introduced changes in the high-silicon phases. The binary diagram has been used as a base for several ternary systems" without any suggested changes. Voce10 suspected the existence of another phase from his study of the cast alloys in the copper-manganese¬silicon system, but evidently hesitated to extrapolate this to the binary diagram, particularly in view of the too ingenious explanation that was advanced" to account for the pools of constituent clearly visible in castings; namely, that they were secondary alpha of twinned orientation deposited from beta. Von Schwarz,12 in 1932, called attention to the fact that this micro-constituent in copper-silicon alloy castings was anisotropic under polar-ized light and asserted that a new phase, not cubic, should be placed in the diagram adjacent to alpha. Sautner,13 on the basis of investigations with the polarizing microscope and with X-rays, introduced this phase into the diagram at about 6 per cent Si. The relevant part of his dia-gram is shown in Fig. 2. Sautner called the new phase beta, renaming the old beta phase zeta. To avoid confusion, in redrawing Fig. 2 the phases have been renamed in accordance with the terminology adopted in the present paper, in which the new phase is called kappa and the other phases retain the designation given them by Arrhenius and Westgren.4

Jan 1, 1939

By R. Scot Clark

The reactively sputtered silicon dioxide capacitor -was developed for use in the monolithic integrated circuit, thereby requiring the capacitor to be fabricated on an oxidized silicon slice. The silicon dioxide film is formed by reactively sputtering silicon in a 50 pct Ar-50 pct 0, atmosphere and the physical properties are indistinguishable from silica. A practical upper limit of capacitance per unit area of 0.25 pf per sq mil is reached with the capacitors fabricated from the Si0, film. Methods shown to enhance this value are double stacking the thin-film capacitors and addition of aluminum to the silicon cathode during sputtering to form an aluminosilicate dielectric. A major contribution to the field of diffused integrated circuits would be the addition of auxiliary passive devices for replacement of diffused passive devices which are currently being fabricated for many integrated circuits. This accomplishment would increase the flexibility of the diffusion process in order to concentrate more on transistor parameters rather than on fabricating diffused resistors and capacitors. To pursue this technique, a thin-film SiOz capacitor was developed which has _ proven applicable to many integrated circuits. Although the SiOl capacitor has an application, the major deterrent from extending the integrated circuit into many useful areas such as low-frequency linear application is the low dielectric constant of SiO, and the low usable capacitance in an integrated circuit. This paper will cover the sputtering techniques used for forming the SiO, film, the physical and electrical properties of sputtered SiO,, and yield information concerning the application of these capacitors to integrated circuits. REACTIVE SPUTTERING Reactive sputtering is simply the sputtering of a metal or semiconductor in glow discharge in the presence of a reactive gas. The material to be sputtered is seen in Fig. 1 as the cathode of the system and is bombarded with positively charged ions of the ambient gas. In this investigation, the ambient gas is composed of 50 pct Ar and 50 pct O2 at a pressure of approximately 2.5 X l0-' Torr. The ions are accelerated toward the cathode in the cathode dark space by the electric field and upon striking the cathode effect a momentum energy transfer to the surface atoms. The transferred energy is sufficient to dislodge a surface atom or atoms and these particles diffuse through the glow discharge to the collector or anode. Several mechanisms of oxidation in the reaction chamber can be considered during reactive sputtering. 1) The surface of the cathode is oxidized and the oxide is subsequently sputtered. 2) Oxidation and sputtering occur simultaneously. 3) Sputtering of the cathode material is followed

Jan 1, 1965

THE CHAIRMAN (E. G. SPILSBURY, New York, N. Y.).-The relation of the character of manganese ore to the surrounding rocks was called to my attention very strikingly in a recent investigation in Costa Rica. In the foothills of the main coastal range there is a large deposit of manganese which extends for over 150 miles along the coast. This is in a porphyry district and the occurrences are almost exclusively along the lines of contact between a recent diorite intrusion through the porphyries. Wherever that intrusion appears to have exerted great force, the line of contact is very clear between the porphyries and the diorites. Where the action has been slower and the lifting force of the intrusion more gradual, there has been a zone of fracture of very considerable width. Those ores which occur where the fractured zone has not been very extensive carry a, lower percentage of manganese than where it has been deposited along a wider zone of fracture. In the so-called narrow veins, which are really the predominant ones, the solution carrying the manganese has evidently attacked the silica in the intrusive rock, and the resulting ore is practically a combination of manganese and silica, running froth 20 to 30 per cent. of manganese and from 20 to 40 per cent. of silica: hence those ores are not likely for a long time to become a factor in our manganese supply :for this country. On the other hand, where the disturbance to the porphyritic schist has been more intense; the manganese deposits are not so extensive, but the ore is richer, running from 45 to 51 and 52 per cent. manganese, with a silica content of from 4 to 5 per cent. There seems to be some resemblance in these deposits to those of the Cuyuna range. EDMUND NEWTON, Minneapolis, Minn.-The State Bureau of Mines has been working on the problem of concentrating manganiferous iron ore for two years or more. I should consider hand sorting as the best form of treatment, because it is practised at all of the mines which ship ore for making alloys, but not, however, oil the ore that is being used for pig iron. Hand sorting, assisted by selective mining, is readily applicable to some of this ore because the gangue is practically the original rock and is easily separated. However, it is only in rather limited zones that we find clean patches of rock. Generally the silica exists as a skeleton of the original rock structure, in which the manganese has been precipitated; some of the silica may have been dissolved, but if any of the original rock remains, the silica must be eliminated by ore-dressing processes.

Jan 1, 1918

By T. E. Leontis

ONLY a limited amount of information has been published on the effect of thorium as an alloying ingredient in magnesium. McDonald13'2 showed that the addition of thorium in amounts up to 3 pct increases significantly both the ductility and the strength of rolled magnesium sheet. A recent publication by Sauerwald" indicates that thorium contributes strength and creep resistance at elevated temperatures to magnesium in both the cast and wrought states. The observations of Sauerwald are confirmed in this paper, which presents the results of a systematic study of the effects of compositional variation on the tensile properties, creep resistance, conductivity, density, and metallography of Mg-Th alloys containing up to 50 pct Th both in the sand-cast and in the extruded states. The effect of the addition of cerium to Mg-Th alloys is also reported. Experimental Methods The alloys studied in this investigation were pre.pared in small laboratory melts according to the melting practice described by Nelson4 as the crucible method. Electrolytic magnesium was used as the starting material to which the thorium* was introduced in metallic form. It was observed that the behavior of thorium in molten magnesium with respect to reaction with protective fluxes is similar to that of rare-earth metals. In order to obtain the highest possible alloying efficiency, it is necessary to use non-MgC1, fluxes and to apply all the precautions described by Marande6 for melting, alloying, and casting magnesium-rare-earth alloys. .Under these conditions it is possible to obtain an alloying efficiency in the range of 85 to 95 pct. The Mg-Th-Ce alloys were made with cerium of the highest purity available, not with the commercial product "misch-metal" which contains approximately 50 pct Ce. The total rare-earth content of this material was 97.1 pct, of which 0.3 pct was rare-earth metals other than cerium; the major impurities comprising the balance were iron and magnesium. The thorium and cerium contents of each alloy were determined chemically. Test bars 6% in. long with a 2% in. long reduced section of % in. diam were cast in sand molds using a four-baf pattern. In most cases, a 3 in. diam extrusion billet 10 in. long was cast in a steel mold from the same melt used for making the sand-cast test bars. For the higher thorium alloys, it was necessary to remelt the foundry scrap from the test bars in order to make the extrusion billets. The billets were scalped to a diameter of 2 15/16 in. and the ends faced to a length of 9% in. as limited by the size of the extrusion container. The alloys were extruded into % in. diam rod on a 500-ton direct-extrusion press. The details of the extrusion process are as follows: Billet preheat 925°F (2 to 16 hr) Container temperature 900 °F Die temperature 900°F Extrusion speed 10 ft per min Reduction ratio 36:1 Percent reduction 97.3 Alloys containing up to 10.2 pct Th were preheated at 925°F for 2 hr; all alloys with higher thorium contents were preheated for 16 hr. In order to establish the effect of extrusion temperature, billets of

Jan 1, 1953

By H. Clare Horwood

"Three types of structures, the main shear zone, the north shear zone, and a series of hanging-wall fractures, contain all the orebodies so far discovered at the McKenzie Red Lake mine. Lenses and veins of quartz in these zones and fractures are the sources of the ore. The ore-bearing structures are unusual in that they are in a complex intrusive mass known as the McKenzie-Gold Eagle stock. They are believed to have been produced by compressive stresses from the south andsouthwest.The mine is on the northeast side of McKenzie island, in Dome township in the central part of the Red Lake area. The original discovery, the main shear zone, was made in 1928, about 3 years after the property was staked, by M. L. Bouzan who was in charge of prospecting and development work on the property. Subsequent diamond drilling and underground exploration led to the installation of a mill, which came into production early in 1935. The hanging-wall fractures were found branching out from the main shear zone during development work on the 350-foot level. The north shear zone was discovered in 1940.From 1935 when the mill began operation until the end of 1946 total production from the mine was approximately 269,349 oz. gold and 69,317 oz. silver, having a value of $9,679,739, recovered from 823,527 tons of ore.GENERAL GEOLOGYThe McKenzie-Gold Eagle stock has a total length of approximately 1 ½ miles and a width of about ½ mile. It was intruded into a complex synclinal fold in Timiskaming sediments. The sediments, which have been cut in only one place in the underground workings, are principally wellbedded greywackes. The stock is composed of large masses of diorite and granodiorite, a small mass of hornblende pyroxenite, and basic dykes of two ages. The diorite occurs as irregular masses in large measure surrounded by the granodiorite that it intrudes. It contains tabular crystals of andesine, having a maximum length of3/4 inch. The hornblende pyroxenite is an elongated lens or dyke in the diorite. The granodiorite masses occupy about two-thirds of the stock. Along its eastern side the main mass tends to become darker and more dioritic toward the diorite contact.Basic dykes of pre-vein and post-vein age are the youngest intrusive rocks at the mine."

Jan 1, 1954

The work of the Committee during the year 1914 was especially directed to the securing of a larger representation in the Institute of those engaged in coal mining and coking. While these industries exceed in volume and in monetary importance all other mining industries in the United States, the membership of the Institute representing them has in recent years been relatively small. It was thought that an increase in the membership of the Institute obtained from among those engaged in these industries was desirable in order to increase interest in the work of the Institute, for this result can only be reached by securing the presentation and publication of a larger number of papers relating to these industries. It is evident that the reading of such papers will tend to increase the attendance at the local and general meetings of the Institute. Sessions of the Coal and Coke Committee were held and a number of papers relating to these subjects were presented at the meetings at Butte, Salt Lake, and Pittsburgh, the Pittsburgh meeting especially being planned with this in view. The activities of the Local Section of the Institute organized in the Pennsylvania Anthracite region have reawakened interest in that district and it is hoped that the same object can be obtained in the bituminous coal fields, either through the organization of one or more. local sections, affiliation with some of the local coal-mining societies, or through activities of the Coal and Coke Committee. Referring to the work of the Committee in its efforts to increase the membership of the Institute, the Committee desires to acknowledge the services rendered by many members scattered throughout the various coal-mining districts of the United States, in compiling lists of those qualified for membership in the Institute, but who have not yet become members. The lists so compiled comprised about 1,100 names, which were furnished to the Committee by the co-operation of 40 or 50 members of the Institute.

Jan 3, 1915

By Jitka Jandová

A laboratory process based on simple and environmental friendly operation, aimed at recycling of spent Li/MnO2 batteries, is described in this study. This process involves roasting Li/MnO2 batteries in a vacuum furnace at 650°C, followed by selective leaching Li2CO3 from calcined electrode material in distilled water at ambient temperature and controlled crystallization of pure Li2CO3.

Jan 1, 2006

By J. P. M. Hojem, C. Dimitriou, N. C. Joughin

This paper describes the design and construction of the first experimental underground rockcutting machine from measurements of cutting forces determined in tests on small rock specimens in the workshop. The deficiencies of this design, revealed by stoping with almost identical rockcutting machines, are described. An account is given of the design and construction of further experimental machines incorporating substantial improvements which made them technically feasible for use in production.

By John T. Watson, Jim Bailey

Increasing public awareness is probably the single most important challenge faced by any blasting contractor today. This increased awareness usually results in an outcry for tighter regulations and restrictions on those in the blasting industry. Those affected do not often understand the dynamics of blasting and are simply fearful of the unknown. This reaction very often results in more regulations and restrictions which frequently fail to address the real problems.

Jan 1, 1990

By Leonard A. Eros

In many mining applications it is not practical to use gravity takeups. In these situations hydraulic takeups are often utilized. Performance specifications are often compromised by designs which have inherently high internal friction and inefficient hydraulic designs. This results in performance which does not match the requirements of the conveyor system. A computer model has been built to check unit efficiencies and field measurements have been taken which verify the results.

Jan 1, 1993

By Richard Dooley

This paper is one sided because it presents the problem, but not the solution. The problem of blisters (bubbles) and occasional tears in caisson liners occurred when blasting and we have not found a conclusive cause nor a preventive solution. (For back ground information, consult Techniques of Precision Blasting in the Excavation of Drilled Piers, by George Mosteller at the Sixth Conference on Explosives & Blasting Technique in Tampa, Florida 1980).

Jan 1, 1983

By G. M. Ritcey

Sulphuric acid leaching has been up to the present, the most popular of the leaching routes. Oxide ores are usually leached with sulphuric acid directly by dump leaching, as practiced at the Bagdad or Bluebird Mines in Arizona, or by vat leaching as done at Inspiration Mining in Arizona. Upgrading of the low-grade oxide ores by dump leaching followed by cementation of the copper from solution by scrap iron has been replaced by the leaching-solvent extraction-electrowinning route which results in a high purity product at the mill site at reduced production costs compared to previous practice. High-grade oxide ores, vat leached with H2SO4, can contain, for example, 25 g Cu/l and 25 g H2S04/,l, or higher concentrations of both, and are presently fed directly to electrorefining plants. Advantages of coupling solvent extraction-electrowinning with the low cost dump leaching instead of using cementation, are as follows (1): a) the production of high purity electrolytic copper rather than cement copper;

Jan 1, 1978

By M. W. Cox, V. F. Hollister

Exploration for metallic mineral deposits is carried on by those special adaptations of methods which the explorer believes will yield most economically or satisfactorily the particular answer sought. In this project the usual methods of geologic observation, recording, and interpretation, when combined with magnetic geophysical methods and geochemical soil sampling, led to disclosures of appreciable zinc mineralization where none was visible in surface exposure. Since 1945 considerable work has been done with geochemical prospecting methods, chiefly in determining the presence and distribution of various elements existing in minor amounts in rocks, soil, vegetation or waters of mineralized areas. Such work, in which the U. S. Geological Survey has taken the lead, finds a ready place in the field repertoire of the exploration geologist as a supplement, not a substitute, for other methods. The Chollet project was carried out in 1951 by the American Smelting & Refining Co. near its Van Stone mine in northern Stevens County, Wash., in the area shown in Fig. 1

Oct 1, 1955

By W. Griffith

The purpose of this paper is to make public record of new information in regard to the sustaining power of artificial mine-roof supports (not timber props), the result of investigations recently made in the anthracite coal fields of Pennsylvania. First.—By the "Scranton Mine Cave Commission," appointed to investigate the mining conditions under the City of Scranton. Second.—By the "Pennsylvania Mine Cave Commission," appointed by the Governor to investigate the general subject of mine caves in the anthracite region of Pennsylvania. Third.-—By the personal researches and tests made by the author in an effort to secure a better artificial mine-roof or surface support. During the progress of the work of the Scranton Mine Cave Commission, the Engineers for the Commission, Messrs. Conner and Griffith, being aware of the general lack of exact information in the engineering profession as to the strength of the ordinary artificial mine-roof or surface support, and particularly the stronger kinds, such as mine cogs, rock piers, etc., had tests made at the Fritz Engineering Laboratory at Lehigh University, to determine the sustaining power under various compressions of the several kinds of artificial mine supports in use in the anthracite region of Pennsylvania. A report of these tests wasincluded in the report of this Commission, which was published as Bulletin No. 25 of the United States Bureau of Mines, Washington. A similar series of tests, more extensive and more elaborately planned, were subsequently made for the Pennsylvania Minc Cave Commission at the U. S. Government Testing Laboratory at Pittsburgh, Pa. The report of this Commission was made to the Governor, but has not yet been published. The author, during his connection with the Scranton Mine Cave Commission, observed that of all the various devices employed for sustaining the roof of coal mines, the one universally used and the best

Jan 1, 1918

By O. C. Blade, E. L. Garton

Louisiana is one of the major oil-producing States of the country. Commercial production of crude oil in the State began in 1902 and has increased to an estimated output of 157,409,000 barrels in 1945, which is the maximum production up to this time and places the State fourth in the nation. The cumulative production for Louisiana through 1944 is 1,544,481,000 barrels, and, adding the output for 1945, the total to January 1, 1946, is 1,681,890,000 barrels. Data on annual production of crude oil in Louisiana and tentative statistics for 1945 are given in table 1. The large production of crude oil in Louisiana and the present trend to utilize petroleum in accordance with its general characteristics make it increasingly important to present analytical data for crude oils. This report is the fifth of a series presenting such data obtained on crude oils from Louisiana according to the procedure used by the Bureau of Mines. Individual analyses are given for 82 samples from 64 fields; many of the samples are from recently discovered fields, and some are from new producing formations.

Dec 1, 1946

The truly scientific method in the study of such questions at the present day is the reverse of that which was followed in the early days of geology, when after the observation of a few isolated facts, some great geological mind was led to a general theory, and humbler followers were only too apt to do mild violence to nature in order to make her facts conform to it tt accumulates year after year a multitude of facts of patient observation, supported by studies with the microscope, and in the laboratory, avoiding general theories, and only making such deductions in regard to locftl conditions as are supported by the overwhelming evidence of facts. S. F. Emmons, on the geological distribution of minerals in the United States, at the "world's congress" of mining engineers, Chicago. Fig. l.-This exhibits the general stratigraphical characters of the southern lodes. The" Indicator" veins, the great barren lode masses, a later fissure than all of these (" B "), and the auriferous lodes of last series cleaving the wrinkled terraces and the older lodes also are" Indicator" veins. B is a later formed vein that leaves no " depositions" behind. ooe are fragments of the" most ancient'' lode wreckage. Db are the auriferous lodes and correspond with those lodes, also whose auriferous characters are not result of secondary impregnations.

Edie Creek is located in the Morobe Goldfield about 17km by road from Wau in the Morobe Province of Papua New Guinea (PNG). Four distinct periods of mining development have occurred since discovery of rich alluvials in 1926. During the two years following discovery, individual expat-riate miners with gangs of native labourers mining rich alluvial gravels dominated the field. After the discov-ery of hardrock mineralisation in 1927, companies accumulated leases and devel-oped extensive underground mines and mechanical processing plants at Day Dawn Mine and Edie Creek/Karuka Mine between 1929 and 1942. After the Second World War, the underground operations were not re-opened, and mining activ-ities mostly concentrated on working alluvial and eluvial deposits. From 1962 onwards, Papua New Guinean miners became increasing producers as company activities declined. In 1990, Edie Creek Mining Company Pty Limited, a joint venture company involving Wau landowner groups commenced operations on New Guinea Goldfield's leases. It currently mines by open pit methods, rich quartz stringers and is invest-igating the open pitting of the Edie Creek/Karuka underground workings.This paper describes the mining and processing techniques employed during the various phases of develop-ment at Edie Creek in the past 70 years. The problems and hardships of operating on a new and remote goldfield are outlined.Abstract

Jan 1, 1994

By Andrzej Walentek

This paper presents the results of numerical modeling of the fractured zone around longwall gateroads. The numerical computations have been based on the results of underground measurements of the fractured zone around longwall gateroads, which were performed for various geological and mining conditions and measured with the use of the endoscopic method with a digital camera. Having results of the underground investigations, trials of duplicating them by the Finite Element Method using software PHASE and the Hoek-Brown failure criterion were performed. In order that the fractured zone predicted by the model-based computations closely simulate that measured underground, some selected parameters in the Hoek-Brown failure criterion were modified based on the earlier determined relations used for prediction of the roof-to-floor convergence in longwall gateroads. As a result, the model-based computations produce results very close to those obtained from the underground measurements. Determination of the fractured-rock zone around the mine roads is of great importance to mining practice, especially in planning and designing supports for longwall gateroads. The influence of the front abutment pressure causes the fractured rock zone around the roads to increase and results in an increase of support load. Moreover, proper determination of the fractured rock zone is one of basic elements in the process of planning roof bolting for mine workings.

Jan 1, 2009

By Chas. E. Shumate

There is assembled here this morning in Chicago the heartland of America, what is undoubtedly the greatest concentration of Technical, Scientific and "CAN DO" knowledge ever assembled in America. The participation in this Conference by the representatives of so many nations is particularly impressive and is a further indication of the importance of the subject matter of this conference which you will be discussing in much detail during the next few days. Another impressive feature of this Conference is the participation of a large segment of the construction industry in whose hands fall the job of building what others design. Also strongly represented is the manufacturing industry whose capability is well known throughout the world. They have the resources to design, develop and manufacture the machines and specialized equipment needed to do any job which the world requires. You should not expect to gain any knowledge from my few remarks this morning as I am undoubtedly the least qualified individual in this room on the highly technical and scientific subjects you will be discussing during these next few days. However, I shall offer a few broad suggestions on subject matter which I trust may generate serious thought during your discussions.

Jan 1, 1997

By Zenari L, Kent D

As our mines introduce more sophisticated production technology into their operations, the dependence on communication systems is markedly increased to allow the management of the technology. However the attention given to the communication systems has lagged that given the production equipment - namely LHDs, trucks and jumbos. At times it was treated as after thought. However, this is changing as the degree of automation increases in our mines. The communication system is now being given much more priority and is genuinely becoming a part of the mine design. The transfer of information around underground, as well as between the surface and underground, is an essential day-to-day activity, with the aim being a smoothly run operation. However the mine environment is far from static, and situations arise - such as breakdowns or other incidents - that require swift analysis of the issue, its cause and its remedy. Also, as communication systems become more sophisticated their use in areas, other than direct data flow, become available. The importance of communication, its development, and new areas being impacted by communication is the subject of this Paper.

Jan 1, 1997