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Charles H. Fulton, Rapid City, So. Dak. (communication to the Secretary*): Professor Lodge takes issue with Mr. Crawford and myself on results obtained by the scorification-method of assay on " zinc-box precipitates," which we published in a paper on the subject in the publication named below.' In our work we found that the normal seorification-method, employing only test-lead and a very little borax-glass as a flux, gave results on cyanide precipitates which mere invariably very low, loss having taken place by slag-absorption and volatilization, as repeated slag-assays failed to bring up results similar to those obtained by other methods. Professor Lodge anil his students made a large number of what he terms " scorification-assays," but which, I would like to point out, have claim to that name only in that they are made in a scorifier, for the charge consists of test-lead, a very considerable quantity of borax-glass (10 grams), at times also of litharge and even charcoal, so that the assays are in reality crucible assays. A scorification-slag proper is an oxide-slag to all intents and purposes, while the slags made by Professor Lodge are borates, certainly acid-slags. It has been our experience since our paper, The Assay of Cyanide Precipitates, was published, that the nature of the assay slag in the crucible assay has a great influence on the result. A " basic " or oxide-slag invariably causes high slag-losses, while an " acid " slag gives very fair results on material containing much zinc. This has also been the experience of a mellknown cyanide chemist with whom I have corresponded on the subject, who found that acid crucible-slags gave good results on zinciferous material, but that the scorification-method, as ordinarily employed, gave high slag-losses. I believe that if the conditions are such that the zinc can be

Jan 1, 1904

By F. T. Selleck, H. H. Reamer, B. H. Sage

An experimental investigation was made of the effect of temperature upon the three-phase pressure associated with the propane-water and propene-water systems when hydrates were present. In addition, the characteristics of the propane-propene-water system were established over a limited range of ternperatureo under conditions such that hydrate was formed. The hydrate phase for this system may he a solid solution and the distribution of propane and propene in it is similar to that found in the coexisting hvdrocarhon liquid phase. INTRODUCTION A knowledge of the characteristics of hydrates of the hydrocarborrs encountered in industrial practice is of importance in connection with the design of process equipment. Villardl.1,2 carried out early studies of hydrates, and de Forcrand1 con-sidered the more probable compositions of the hydrates of hydrocarbons. Hammerschnid1 presented information about the propane-water and the isobutane-water systems. Scheffer5 studied the hydrate of hydrogen sulfide in detail, and de For-crand reported on the hydrates of krypton, argon, and xenon.1 Roberts and co-workers1,2 determined the nature of the hydrates formed in the methane-water and ethane-water systems. Carson and Katz10 studied the methane-propane-water, methane-pentane-water, and the methane-hexane-water systems in the four-phase region. The results of this rather extensive investigation indicated that the paraffinic hydrates formed solid solutions. The experimental evidence now available does not Support the existence of hydrates of the pentanes-antl-heavier hydrocarhons but it cannot be stated with certainty that such hydrates are not formed. Stackelherg. 11,12,13 made extensive studies of the crystal structure of paraffinic hydrate; by means of x-ray techniques and found that hydrates poses; a definite structure and composition. The existence of such a Structure does not preclude the firmation of Solid solutions of hydrates in aqueous systems containing two or more hydro-carbon~. Wilcox, Carson and Katz" reviewrd the information on the hydrates of importance in the processing of natural gas and presented data concerning their formation from natural gas. Kobayashi and Katz1' made studies at high pressure of the Hydrate of methane. and Unruh and Katz"' investigated hy-drates in mixtures of carbon rlioxide and methane. Frost and Deaton contributed to the knowledge of the composition of the paraffinic hydrates The irregularities in the experimental results were several times the expected uncertainties. This experience confirms the behavior encountered by other investigators indicating that hydrates tend to occlude water during their formation, thus rendering difficult the direct measoremeut of their composition. Miller and Strong2 investigated a number. of paraffinic hydrates from the standpoint of their possible application to (, the industrial storage of gas. Powel1 studied the effect of solutes upon the decomposition temperature of paraffin hydrates. Marked lowering of the decomposition temperature at a given pressure may he obtained by the use of such additive agents as ethylene glycol, urea. and sodium chloride. APPARATUS AND METHODS Two method* were here employed to study the behavior of hydrates. The first involved a glass capillary within which the hydrocarbons and water were confined over mercury. The second made use of a double-ended weighing bomb technique." The glass capillary equipment has been described elsewhere.'" A schematic drawing of it is presented in Fig. 1, where the arrangement of the agitator and mercury reservoir is shown in some detail. The lower part of the glass capillary, D, was enlarged to afford space within which the fluids used in the investigation could he stored at low pressures after their introduction through the valve. G. The temperature of the capillary was controlled by the circulation of a hydrocarbon oil of low viscosity from the agitated bath, B, through the vacuum jacketed column. C. The pump, A, was employed for the circulation of this oil. A relatively clear view of the capillary tube, D, was obtained through the vacuum jacket. Mercury was introduced into the lower part of the vessel, E, from

Jan 1, 1952

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013

By Effingham Humphrey

THE Lehigh Valley. Coal Co. finished the rebuilding of its Drifton No. 2 breaker at Drifton, Pa., in the summer of 1917. The new construction comprises an addition and the complete remodeling of the old breaker. It is of interest to note that the old structure was the first iron breaker erected in the anthracite region. THE OLD BREAKER This old breaker was built by the Cross Creek Coal Co., under the direction of the late Eckley B. Cole, in 1888-89, and was fully described by him in the Transactions.1 The columns were cast iron, 8,'10 and 12 in. square. The floors and partitions in pockets were cast-iron ribbed plates. The struts were cast iron of "H" section; the other members were of structural iron either rolled I-beams or built-up sections. The sizes of the rolled beams varied from 6 to 20 in. deep, while the built-up sections, made of plates and angles, varied from 6 to 63 in. in depth, so that there apparently was no rule to determine the type of section used. In the remodeling of the old structure, practically everything was taken clown excepting the columns and roof, and such beams as were necessary for temporary construction purposes, and, therefore, a close inspection of the old structural members could be made and the effect of the acid water oil them could be noted. The cast-iron members were but slightly attacked by the water, while the wrought-iron beams, in the wet places, were corroded almost to failure.

Jan 2, 1918

By Kershaw M. G, Maughan R. C A

A process for eliminating nickel from electrolytic zinc plant solutions by precipita- tion with dimethylglyoxime (DMG) was developed to enable the Electrolytic Zinc Company of Australasia Limited (EZ) to treat nickel-bearing zinc dust precipitates. These precipitates are leached to recover their Cd and Zn content. The final Zn bearing solutions contain relatively high Ni concentra- tions (20-100 mg/1) and are treated with DMG and then neutralized to pH 4.6-4.8. The pre- cipitate is filtered off and the solution returned to circuit. DMG consumption is about 200% of theo- retical requirement, and Ni removal is 80% complete overall.

Jan 1, 1977

By E. C. Lane

"INTRODUCTION This is the fourth in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36 3/. The second resort gave the same data for motor gasolines sold during the summer of 1936 4/. The third report of the series gave the same data for motor gasolines sold during the winter of 1936-37 5/.This report covers 63 brands of gasoline represented by 1,136 samples excluding the Pacific Coast. Those from the Pacific Coast were averaged by the Pacific Coast technical group before being submitted and are published exactly as they were submitted. In some areas reports were received from five or six companies on the same brands of gasoline, whereas in other areas only one company reported on a brand. Thus, it can be seen that some of the data are more representative than others."

Dec 1, 1937

By C. J. Tsai, K. Olson, R. Caldow, B. Cantrell, D. Y. H. Pui

"The amount of new surface generated during fracture of coal and rock has been found to be directly proportional to the amount of energy associated with the fracture. To confirm this and study the relationship between the new surface and dust aerosol formed during fracture the U.S. Bureau of Mines has conducted experiments simulating fracture as it occurs during mining operations. In addition to fracture energy measurements, fragment size distributions were determined over a size range of 0.5 microns to 1 inch. The size measurements accounted for the mass of the original sample. Material studied was Illinois No. 6 coal, coal from the Taggart seam of Virginia, and Berea Sandstone. The experiment employed a chamber to confine sample fracture fragments and a combination of particle measuring systems. Measurement methods included aerodynamic sizing of entrained dust aerosol with optical counting and inertial impaction techniques, physical sizing of non-airborne fragments by sieving, and optical sizing of fragments using optical counting and scanning electron microscopy.Results of the size distribution measurements indicate that a single size distribution law does not adequately describe the entire fragment size distribution. A combination of two size distribution laws, such as the Rosin-Rammler and log-normal distributions, is necessary to describe this size distribution. New surface created by fracture is primarily found 1n particulate between 2 and 50 microns with a mean size of 12 microns. It was also found that the specific energy of fracture can be linearly related to the .concentration of aerosol in this size range.Only a .small fraction, between 0.02 and 0.16 pct, of the dust particles .generated during fracture become airborne. The remainder adhere to the new surface created during fracture. An entrainment fraction, defined for a given particle size is the ratio of the mass of airborne particles to that of the total particles generated in that size range. This experimental entrainment fraction is related to the Van der Waals adhesion force and the electrostatic forces operating during fracture and is used to derive empirical parameters to model these two processes."

Jan 1, 1989

By E. Seidl

THE basic material for testing aluminum, copper and zinc is a cast metal, principally in the form of wire bars (Figs. 1 to 3) and plates for the produc- tion of sheets or strips, (Figs. 4 to 7). Experience has proved that the chemical and crystallographic proper-ties of such cast metal exercise a certain influence when it is being worked, which is usually done while the metal is hot. In a chemical sense the slight impurities, which even the purest industrial metal contains, have a disturbing effect. They settle either along the outside limits of granulation, as in the case of aluminum and copper, or else in the interior of the crystal, as in the case of zinc; but frequently are also found accumulating at certain points (formation of the blowholes and skin) (Fig. 7). The crystallographic character of the metals is either that of uniformly fine granulation, or else there occurs a certain distinct casting texture marked by sharply defined cooling conditions and consisting of crys-tals of a pronounced stalk-like or blade form. Since we generally distinguish between a crystal texture and a crystal structure, the term crystal texture is used here for the arrangement of the crystals relative to each other and their microscopic composition; crystallic structure is used to mean the radioscopically ascertain-able structure of the crystal. The influence of the impurities and of the crystalline character on the working of the metals has been fre-quently pointed out in practice as well as in science.

Jan 11, 1927

By T. E. Marshall, D. R. Dolinar, T. M. Barczak, T. P. Mucho

Over a portion of the older limestone mine workings at the NIOSH Lake Lynn Laboratory, a mining health and safety research facility, a large sinkhole formed caused in part by the intersection of several tightly spaced joint sets and unusual weather conditions. The anticipated propagation of the associated roof failures threatened to encroach upon a portion of the facility’s secondary escapeway. To protect the escapeway, two cribs walls and over 80 cable bolts were installed. In addition, extensometers were installed to monitor roof movement in the escapeway. However, a large roof fall associated with the propagating roof failures in the sinkhole area partially destroyed one crib wall where the adjacent escapeway was not reinforced by cable bolts. Recent roof movement information indicates that this area is still active. Based on these measurements, steps have been taken to stabilize this portion of the escapeway. This paper discusses roof monitoring, the roof movement, the large roof fall, propagation of the roof failures, and the recent support measures undertaken to stabilize the escapeway.

Looking forward to growing demand for the output of the coal mines over the next decade, producers face serious problems in meeting the market. Among the difficulties are the Coal Mine Health and Safety Act of 1969, wildcat strikes, growing shortage of skilled and supervisory labor, pollution control and rising costs. The two-day program, planned by R. L. Frantz, covered all of these subjects and presented a few remarks on such wholesomely noncontroversial matters as ground support. A prediction of coal for electricity generation in 1980 was made by Philips amounting to 550 million tons, an amount equal to total output now, With respect to competition in this market, he said: "For the foreseeable future there is enough energy demand for all participating fuels." Banana oil conies not from bananas but from coal and science may just convert coal to meat loaf or some other surprising application may come out of research for product markets. Philips sees no revolution in mining methods although longwall mining will be expanded.

Jan 1, 1970

By S Zaffron, O Loffredi

A critical concern of any mining company today is its relationship with the different stakeholder groups impacted by the operational activity û communities, unions, vendors, local partners and competitors, local and federal governments, interest groups and non-government organisations. What ten years ago would have gone unnoticed, now, and even more so in the future, can drastically impact the profitability and even existence of a mining operation. This paper describes the development and delivery of a new paradigm for creating effective external stakeholder relationships. We report on the actual measurable results of an integrated and highly complex initiative led by Lonmin Plc (Lonmin) and Landmark Education Business Development (LEBD) that significantly altered the nature of the relationship with the stakeholders. Given the nature of the long-term investment required in a mining operation, any breakdowns or surprises in its relationship with external stakeholders brings with it the potential for major loss. The transformation of executive and senior management and community leadership was required to enable them to be effective in managing this complex set of circumstances.

Jan 1, 2006

By A. M. Esteves

This paper addresses the question ?What constitutes the right level of investment in community goodwill?? Mining companies are still grappling with this subject even though the business case for community investment has been accepted at a general level, as a strategy for competitive differentiation, risk mitigation and a desire to deliver - and to be seen to deliver - a ?net benefit? to affected communities. Gaining senior management commitment to long term social projects, by definition characterized by uncertainty and complexity, is made easier if projects are shown to benefit the site?s strategic goals. Case study research amongst mining companies, including interviews with social investment decision-makers, has assisted in developing a SI-DAT (Social Investment Decision Analysis Tool), a decision model for evaluating social projects in order to create value for both the company and community. Multi-criteria decision analysis techniques integrating business planning processes with social impact assessment have proved useful in assisting mining companies think beyond seeking access to required lands and peaceful relations, to how they can meet their business goals and contribute to regional development.

Jan 1, 2007

By T. C. Rao, Vanangamudi. M., J. P. Barnwal

Experiments were carried out on 76 mm laboratory heavy medium cyclone treating -2.0 t 0.5 mm coal and on two 600 mm industrial heavy medium cyclones treating coal in the size range -13.0 t 0.5 mm. The variables studied were spigot diameter and feed medium gravity. The generalised distribution curve for the separation of coal in these heavy medium cyclones has been defined by the equation [ ] The specific gravity of separation SG has been found to increase linearly with increase in feed medium, gravity (SGf). The relationship for SG of industrial cyclone is given as 50 SG = -6.801 t 6.463 SGf t 0.0327 Spig 50 -0.02625 SGf. Spig. Further, the probable error for the separation has been found to be linearly related to (SG50 - SGf ) according to the equation [ ] The model equations developed have been used to select appropriate levels of operating conditions to achieve an increase in the yield by about 2 to 4% without affecting the quality of the product.

Jan 1, 1990

With the recent increase in the number of underground secondary sulphide dust explosions in Canada, Australia and elsewhere in massive sulphide ore mining industry, establishment of quantitative and realistic methods of analyzing the mine dust is of paramount importance. This paper examines and analyses dust samples from a mine area that has very recently experienced sulphide dust explosions. Also, it attempts to evaluate the physical and chemical characteristics of the dust. Explosibility of the dust samples was determined by quantifying the oxidation reaction of the sulphide dust particles in a 1.2 L, Lindenberg open horizontal tube furnace. Percentage sulphur', % S oxidised during ignition of a dust sample of known assay, % S and dust concentration (g/m3) were determined by the quantitative chemical analysis of SO2 gas produced during the oxidation reaction. A dust sample with high sulphur content, 22.3% S (assayed) and mean particle size 9.82 pm, was found to exhibit a low degree of oxidation compared with a sample of low sulphur content, 15.44% S and mean particle size 21.7 tcm, at the same Temperature.

Jan 1, 1988

The mining. operations of Bougainville Copper Pty Limited are located at Panguna on the Island of Bougainville which is part of the Territory of Papua and New Guinea. Mineralisation in the Panguna area was first established by C.R.A. Exploration Pty Ltd in 1964. Exploration work since then has established ore reserves estimated to be 760,000,000 tons of.0.47% copper and 0.4 dwt./ton gold. An economic feasibility study completed in July of this year has enabled a decision to be made to proceed with a major mining operation. The ore will be mined by open cut methods and will be treated in a conventional concentrator with a nominal capacity of 90,000 short tons per day. The concentrate will be pumped as a slurry through a 15 mile long pipeline to a port established on the east coast where it will be filtered and dried ready for export. Other supporting facilities for the mine include two towns, a 135 megawatt steam power station, and access roads.

Jan 1, 1970

By Dale S. Preece

In 1975 Congress passed the Energy Conservation Act to establish a U. S. Strategic Petroleum Reserve (SPR) with a capacity of 750 million barrels of crude oil. The most economic storage medium was determined to be salt caverns leached in salt domes in Louisiana and Texas. Salt caverns existed at several sites when the reserve was created. These were obtained by the U. S. Department of Energy (DOE) and used to initiate SPR oil storage. In order to meet the storage capacity approved by Congress, new caverns also had to be leached. To support the resulting design effort, finite element computer program have been used to determine the creep closure and structural stability of salt caverns. Using site specific material properties including creep models, elastic moduli and fracture data, the finite element analyses have replaced earlier empirical approaches to cavern design. This report presents results of such finite element analyses to determine the best cavern roof shape and the minium pillar to dimeter ratio. , P/D. These numerical predictions indicate that the current cavern design is safe.

Jan 1, 1984

By P. W. Guild

DURING 1956 the application of geology and related scientific disciplines to the search for new mineral deposits went forward on an ever widening front. Spurred on by record-breaking consumption of many of the established commodities and new uses for minerals and metals that were hardly known a few years ago, the profession is figuratively leaving no stone unturned in the effort to insure that adequate raw material supplies will be avail- able for the future. More money was spent and more people were engaged along more lines of research than ever before. A huge project to map much of the Canadian Shield area by photogeologic methods stands at one extreme; application of isotope ratios to ore finding stands at the other; between them the more traditional techniques are being increasingly refined. In the Fiftieth Anniversary volume of Economic Geology, published late in 1955, Alan Bateman sketches the development of fundamental concepts as recorded in the pages of the journal over the first five decades. An additional 24 review articles cover individual aspects of the field and constitute a base for further advances.

Jan 2, 1957

By Gray J, Krouse HR, Changkakoti A, Morton RD

A group of stratabound-stratiform Fe-Ba-Zn-Pb-Ag deposits within the La Minita mining district of Michoacan, southwest Mexico have been investigated. The results of the study show that these deposits were generated around submarine hot-springs issuing in a Cretaceous island-arc environment. The exhalative mineralization, which is both epigenetic and syngenetic in character, was developed above fault-systems which constituted the loci of both volcanism and subsequent hydrothermal systems.Fluid inclusion data suggest two hydrothermal events during ore mineralization, one at 240¦C and the other at 161 to 205¦C, with salinities between 2.1 and 12.8 wt.% NaCl equivalent. Stable isotope data support a marine origin for the ore-fluids, as well as, for carbon and sulfur. Strontium isotope data suggest that Sr in the barites was extracted from the volcanics and limestones by circulating seawater. The ore-depositional environment was one of shallow, sub-tropical marine character, where mineralization was in part geochemically controlled by carbonate reefal facies within the volcanic/pyroclastic suite.

Jan 1, 1990

By Frederick K. A1lgaier

The Bureau of Mines' Denver Research Center initiated a subsidence research program in 1978. The short ten goals of the program were to determine practical methods and equipment for measuring subsidence and demonstrate these methods by monitoring subsidence at several mines having mining, geologic and topographic variables typical of those encountered in the western United States. Data from the monitoring program would be supplied to cooperating mining companies and used by the Bureau to accomplish the long term objective of developing and validating subsidence prediction techniques applicable to mines in the West. Subsidence monitoring is being conducted at five mines in Colorado and Utah with substantially different mine plans, mining methods, depths of cover, and topography. The monitoring procedures used at each site are similar and include designing the monitoring network layout, installing the subsidence monuments, initial and periodic surveying of the monuments, and processing the survey data. The network layout, surveying methods, and types of monuments vary according to the conditions at the individual sites and the type of data being collected.

Jan 1, 1982

By Y. C. Kim

One aspect of long-range mine planning in an open-pit mine is first to define the ultimate pit limit, i.e., the projected size and shape of the pit at the end of its life. This chapter is concerned with various techniques that are currently in use today in determining the ultimate pit limits using the computer. Prior to the early 1960's, open-pit limits analyses were entirely performed manually. This manual technique has been well explained by Soderberg and Rausch in Surface Mining (1968). Soderberg and Rausch also explain clearly the need for establishing the ultimate pit limits in long-range mine planning, i.e., location of surface facilities, dumps, etc. Consequently, the need for ultimate pit limit design will not be reiterated here. Nor will the definitions of the most commonly accepted terminologies such as break-even stripping ratio, economic cutoff grade, ultimate and working slope angles, preproduction stripping, etc. be repeated here. Briefly, the objective of the ultimate pit limit design (which is also frequently referred to as pit design in short) is to determine the projected final pit limits of an ore body and its associated projected grade and tonnage, which will maximize some prespecified economic criteria while satisfying practical operational requirements.

Jan 1, 1979