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By David Bequette, Ray D. Peterson, Cynthia K. Belt

"With a need to cut production costs in the metals industry, cost savings from energy efficiency improvements are critical. Opportunities can be found by reviewing furnace systems and practices so that the melting and holding processes operate at the highest energy efficiency. Many of the changes can be implemented with a minimum of expense or capital investment. This paper will review several low cost methods to optimize energy efficiency on reverberatory melting or holding furnaces. These five methods (furnace utilization, idle procedures, fire rate, controls, furnace pressure) will be explained and information given to implement these changes. Included are several rules-of-thumb and benchmarks for aluminum reverb furnaces.IntroductionEnergy can be a significant portion of the total manufacturing costs for metals and materials manufacturing involving thermal processing such as heat treating, melting, and high temperature processing. Natural gas prices have dramatically varied over the last few years. While no one can foresee the future, prices are expected to increase from the current low prices. More recently, emphasis is being put on the reduction of greenhouse gases with the potential of additional costs to industry.One of the first steps in an energy management program is to measure the energy usage of the process [1]. The results are typically understood in relation to the mass melted in kWh / mT [BTU / lb]. For the purposes of this paper, furnace energy efficiency is calculated over a month or even a year and thus includes hold times. This efficiency is typically different from the values quoted by furnace manufacturers. Those values are for limited short term tests at highutilization.Once you know the performance for your furnaces, these should be compared to industry benchmarks. For aluminum melt furnaces with cold air burner systems, a benchmark value or goal is 1800-2000 BTU/lb [1160-1290 kWh/mt], though some of the best have reached 1600 BTU/lb [1030 kWh/mt]. Furnaces with regenerative burners can attain 1100-1200 BTU/lb [710- 775 kWh/mt]. There are some designs of multi-chamber furnaces or oxygen furnaces that have improved on these numbers, perhaps as low as 950 BTU/lb [615 kWh/mt]. Typically, as the degree of sophistication and energy efficiency of the furnace increases, so does the cost."

Jan 1, 2010

By Michael A. Trevits

The National Institute for Occupational Safety and Health (NIOSH) in partnership with Strata Products tested the sealing capability of Ventstop®? as part of an ongoing mine fire control and suppression research program. Ventstop®? is a multi-purpose, inflatable device that is produced by Minvent Solutions and is available world wide for use in the metal and nonmetal mining industry. Ventstop®? is also used in the Australian coal industry as a temporary ventilation control device. The device can be quickly deployed, is reusable and can be placed in horizontal and vertical mine voids to control dust, fumes and smoke. Deployment, multi-day inflation and air leakage tests were conducted at the NIOSH Lake Lynn Laboratory to determine the capability and limitations of Ventstop®? in a simulated coal mine setting. During the tests, Ventstop®? was also subjected to low level forces of a nearby methane gas ignition. It is thought that Ventstop®? could be used by the US coal mining industry to temporarily close an underground mine area in response to a fire or spontaneous combustion heating event, to temporarily redirect mine ventilation during longwall equipment moves or during stopping construction. This paper describes this inflatable temporary mine sealing technology and presents the results of the NIOSH tests.

Jan 1, 2009

By E. Kumar, L. A. Kumar

"A methodology is proposed to develop an optimization model to understand the impact of transporting minerals, from mines to the final destination, on air quality. Recently, there has been increasing concern about the combined effects of multiple activities over many years, and the regional environmental changes brought about by a single project. Environmental issues in the iron ore industry have highlighted the need to broaden the cumulative impact assessment. In this study, we simulated the optimal routes and quantity of materials needed to meet the destination plant demand based upon environment constraints (level of air pollution), as well as the cost of transportation and availability of materials. Multiple scenarios were developed to analyse the effects of changes in routes, alternative transport system (or multi-modal split), traffic congestion, and the cumulative impacts on air quality. The air quality impact zones of the study area were demarcated using a GIS technique. The expected outcome of the study is the selection of a suitable transport system for a particular site with the least impact on air quality, including the transportation route, relative to the minimum cost of transportation of the minerals from the mines to their final destination. The proposed methodology is evaluated with a case study. IntroductionIn India, the process of environmental impact assessment (EIA) has been focused primarily on the local impacts of projects, without considering regional environmental effects. Environmental clearances for proposed projects are based on reports of local impacts. However, any developmental project poses a potential risk to the environment as a whole, and not just in the immediate vicinity of the project. Recently, there has been increased concern about the combined effects of multiple activities over many years—the regional environmental changes due to development of a single project (Dutta, Mahatha, and De, 2004). Environmental issues throughout the country, particularly in the iron ore industry, have emphasized the need to broaden the analysis to include the combined impacts, or those forecast for a proposed region, on an existing environment. The most significant adverse environmental consequences of iron ore transportation are the deterioration of biodiversity and air quality (Kumar and Ajay, 2015)."

Jan 1, 2017

By A. B. Hooker, Iilsley. L. C.

"Flame safety lamps have been used for about one hundred years in coal mines where a dangerous accumulation of explosive mine gas (methane) might occur and thus render the use of ordinary unprotected flame lamps dangerous. Flame safety lamps are not only used for illumination, but also for detecting the presence of dangerous percentages of methane mixed in the air of the mine.The safety of the lamp depends chiefly upon the cooling qualities ofThe safety of the lamp depends chiefly upon the cooling qualities of the wire gauze used to permit free circulation of the air through the lamp. If one enters a part of the mine where methane is present in the air, the methane enters the lamp and coming in contact with the wick flame is ignited and continues to burn within the gauze without igniting the methane surrounding the lamp. If the air within the mine is traveling at a velocity of several hundred feet per minute the burning gases may be driven through the gauze by the air current. If the gauzes are properly designed and of the proper material, these burning gases will be so cooled as they pass through the gauze that they will not cause an ignition of the gas surrounding the lamp. In order to test the effectiveness of a given safety lamp, tests are made in moving explosive mixtures of gas and air arranged to simulate mine conditions.The Bureau of Mines investigated many features relative to the safety of flame lamps and in 1915 established an official schedule known as Schedule 7 whereby flame lamps having certain prescribed qualifications would be approved as permissible for use in gaseous mines."

May 1, 1920

By W. S. McDonald

PRACTICALLY all dusts derived from organic matter are explosive and instances are recorded of explosions-some of them extremely violent-having occurred in grain elevators and flour mills. While a discussion of the explosibility of dusts in general, doubtless, would be of more than academic value, it will be of greater interest, on this occasion, to consider various phases of the problems connected with the hazards arising from coal dust. Extensive and valuable research has been carried out during the past few decades on the subject of coal-dust explosions and a great part of this work has been concerned with the preventive effect of stone or other incombustible dusts. Four men have been outstanding in this very substantial achievement. The first is Dr. W. Galloway, who succeeded in demonstrating by experiments that one pound of coal dust mixed with 150 cu. ft. of air formed an explosive mixture. The next is Sir W. Garforth, who proved that stone dust is an effective preventive for coal-dust explosion. The third is G. Haon, and last but not least, L. G. Hill, both of whom laboured incessantly to produce a suitable stone-dust and a satisfactory method of application. Today, mining men all over the world are satisfied and convinced that stone dust, if properly applied, will prove effective in greatly minimizing, if not completely preventing, explosions of coal dust, as has been demonstrated in experimental mines, as well as in actual explosions, in practically every coal mining industry.

Jan 1, 1938

By J. Botin

Traditional risk quantification methods provide little information on the sources of risk, and tend to produce static over-conservative evaluations, which do not account for changes in the performance of the project. Capital investment decisions for large mining projects require more complex risk evaluation models that include the value of flexibility and the different risk levels associated with uncertainty on project variables (price, grade, dilution, and production rates, among many other). In this context, real option valuation (ROV) methods have proven potential to quantify the risk associated with such variables and integrate alternative scenarios and management strategies into the evaluation process. In this paper, a risk quantification model is developed that successfully quantifies the risk associated with dilution, as a function of production rate. This model is then validated in a case study on the Chuquicamata Underground Mine project. Keywords real options, risk management, risk quantification, dilution, minine planning.

Jul 1, 2013

By I Govender, T L. Moodley

Tumbling mills are grossly inefficient, using only 5 per cent of the total energy supplied for actual breakage. A significant proportion of this inefficiency is unavoidable owing to geometric limitations; rotating drum systems are prone to exhibiting certain regions (energy barriers) that resist particle entry thereby restricting the transfer of energy. Though such systems are inherently inefficient, improved modelling schemes may lead to slightly enhanced efficiency through better microscale predictions of key breakage drivers (stress, force). Central to achieving such incremental advances is the development of a universally accepted rheology for dense granular flows. Armed with a better understanding of these macro-scale ingredients, classical process modelling offers an efficient, spreadsheet friendly framework for recovering the spatial distributions of the comminution drivers. At this real-time level of process control, it should be possible to tune comminution operations towards more energy efficient configurations – the ultimate goal of this research. The present work employs validated DEM data to recover the full continuum field which will ultimately serve as a basis for calibrating process model outputs based on different rheological hypotheses. Such a continuumbased approach captures tensor properties like the shear stress and strain rate – both of which are necessary to developing a dense granular rheology. Moreover, DEM captures this data at the momentum transfer timescale of 10-6 s – no other measurement technique is capable of this level of spatial and temporal resolution. Importantly, the confidence in this DEM data is strengthened because it has been validated at the continuum scale using Positron Emission Particle Tracking (PEPT) kinematic measurements. Validated DEM data is derived from batch experiments conducted within a 300 mm ID laboratory drum using three and five millimetre glass beads at 60 and 75 percent critical speed; such mill speeds are typically encountered in the tumbling mill industry. Dimensional analysis is conducted using critical rheological parameters (shear rate, shear stress, granular temperature etc), which are key to not only developing a granular rheology but ultimately will be used to tune our mechanistic models.

Aug 24, 2022

Cospidie (3CaO*2SiO2*CaFe2) is one of the most important compounds crystallized in mold flux films during casting in the continuous casting process of steel, The primary crystallization field of cuspidine has been experimentally developed in the CaO-SiO2-CaF2-SiF4 system. The cuspidine-NaF binary and cuspidine-CaF2-NaF ternary systems have been also experimentally determined to study effects of addition of NaF on the primary field of cuspidine. In order to discuss its thermodynamic stability the standard Gibbs energy of formation of cuspidine has been deterimed by an electromotive force methods using CaF2 as solid electrolyte and a transpiration method as follows: ^fG° (cuspidine) /kjmol-1 = 5198 + 0.825T (+12) (1313<T/K<1329): EMF method ^fG° (cuspidine) /kjmol-1 = 5178 + 0.813T (+8) (1221<T/K<1469): Transpiration method The chemical potential diagram and constituent activities for the CaO-SiO2-CaF2 System have been evaluated based on the obtained thermodynamic data.

Jan 1, 2003

By John D. Campbell

Alberta Plains coals exhibit an almost rectilinear system of vertical fracturing called "cleat", which is best traced by mapping true bearings of underground coal mine rooms. The cleat pattern is approximately conformable with a pattern of surficial features and a pattern of bedrock jointing in the Alberta Plains, and with the trend of the Rocky Mountain Trench, but not with the distribution pattern of coal rank nor with the trend of the eastern boundary of the Rocky Mountains and Foothills physiographic province. The processes resulting in cleat remain in doubt, but cleat is always of practical importance in extracting coal from deeply buried deposits.

Jan 1, 1979

By P. T. Bissert, L. Yan, M. D. Klein

"Since 2008, the U.S. Mine Safety and Health Administration (MSHA) has required the installation of refuge alternatives (RAs) in underground coal mines (MSHA, 2008). MSHA requires that RAs provide an environment with breathable air for entrapped miners for a 96-hour period. Heat buildup inside an occupied RA is a serious concern. Without a means to dissipate the heat and humidity generated by the occupants and the carbon dioxide scrubbing system, the temperature and humidity inside RAs could lead to severe discomfort or heat stress depending on the mine ambient temperature before and during occupation of the RA. In its 2006 report, the West Virginia Mine Safety Technology Task Force (2006) recommended an apparent temperature limit of 35 °C (95 °F) for RAs. In Title 30 Code of Federal Regulations Part 7.504, or 30 CFR 7.504, MSHA specifies a maximum apparent temperature of 35 °C (95 °F) inside an occupied RA (MSHA, 2016). The apparent temperature is calculated using both air temperature and relative humidity (Steadman, 1979).Calculations can be used to deter-mine if the air within an occupied RA will reach the apparent temperature limit. In these calculations, the mine temperature could be assumed to re-main constant. With this assumption, the effects of the mine strata thermal mass and thermal conductivity on the heat buildup in an RA are ignored. Re-search conducted by the U.S. National Institute for Occupational Safety and Health (NIOSH) shows that the mine air and strata temperatures surrounding an RA increase when subjected to the heat of an occupied RA (Yantek, 2014). Thus, calculations performed with the assumption that the mine temperature is constant would underpredict the resulting dry-bulb temperature and apparent temperature for a given RA occupancy. The mine air temperature has been used as the basis for RA temperature calculations. However, there has been no research to confirm that the mine air temperature is the appropriate basis."

Apr 1, 2017

By Jon K. Ahlness

The Bureau of Mines investigated technologies for testing the integrity of in situ leach mining wells, as required by environmental regulations. To test for leaks, inflatable packers were used to seal the well casing. Laboratory testing determined that the packers could contain a casing pressure up to 50 to 60 psi (345 to 414 kPa) less than the packer inflation pressure. Single-and double-packer configurations were successfully field-tested in 32 wells ranging from 500 to 530 ft (153 to 162 m) in depth. A rigid pipeline and a hoist truck were used to run the packers in and out of the wells for the double-packer tests, which averaged 2-1/4 h each. In an effort to decrease the time of the rigid-pipe double-packer test. a self-contained trailer-mounted test system was designed and built. It utilizes a winch and steel cable to run the packers in and out of the well and high-pressure nylon tubing for packer inflation. This system was successfully field-tested in eight wells averaging 650 ft (198 m) in depth and resulted in a time savings of 13 pct and an operator-hour reduction of 42 pct.

Jan 1, 1985

By Mikael Ramström, Mark Board, Clayr Alexander, Wes Johnson

"The Coeur d’Alene mining district in northern Idaho was first discovered more than 130 years ago and has been the most prolific silver producer in the United States. The Lucky Friday Mine of Hecla Mining Co. (Fig. 1) is the oldest (76 years) and deepest mine in the district, producing approximately 725 t/day (800 stpd) from narrow, vertical lead-zinc-silver veins. Cut-and-fill stoping is currently employed at depths to about 2.3 km (7,500 ft) below ground surface, making it one of the three deepest mines in the western hemisphere. The #4 Shaft, a winze collared at approximately 1.8 km (5,900 ft) below surface and extending to a depth of nearly 2.9 km (9,600 ft), was recently completed to exploit the high-grade 30 Vein, whose resource has been identified to at least 3 km (9,700 ft) in depth.As with other deep mines worldwide, a number of challenging engineering issues occur, including: high in situ rock stress, squeezing ground, seismicity, high in situ rock temperature that requires refrigeration, diesel equipment that generates diesel particulate matter (DPM) requiring high ventilation airflow rates and long travel times for worker transport to mining areas.This article describes the methods that Hecla Mining Co. has employed during the past 50 years to combat these issues, with emphasis on the current efforts to implement continuous, mechanical mining with automated or teleremote operation and to introduce electric and battery-powered equipment to minimize refrigeration and ventilation requirements for the removal of DPMs.Geology and in situ stressThe host rock mass is an extremely thick sedimentary sequence (the Belt Series) that has been tilted vertically by mountain building. The rock mass in the current section of the mine consists of weak, heavily foliated argillites and stronger, bedded silty-argillites termed siltite. The vertical veins (80° to 85° dip) are parallel to the foliation with an approximate width of around 3 m (10 ft). There are two regional, vertical faults that parallel the vein; one forming the hangingwall of the orebody and one approximately 90 m (300 ft) in the footwall. Additionally, there are several thin, rough northdipping faults that occur in the footwall of the vein which terminate on the major vertical faults.Both the argillite and vein package rock have moderate strength, with uniaxial compressive strength averaging about 100 MPa (14,700 psi with a range from about 70 to 125 MPa), and are moderately abrasive, with CERCHAR abrasivity index of 2 to 3. The major in situ stress is horizontal and oriented in a northwest direction with magnitude about 1.5 times the vertical stress. Consequently, the Lucky Friday stress magnitude at depth is analogous to significantly deeper South African gold operations."

Jan 12, 2017

By L. W. Vigrass

Porous and permeable rocks deeply buried in sedimentary basins contain immense volumes of hot water with the potential to supply low-grade heat energy. A part of Canada with sizeable potential for low-grade geothermal energy is the northern Williston Basin of southern Saskatchewan. In this region, the University of Regina has conducted a geological study investigating the feasibility of producing large quantities of warm water suitable for space heating in the Regina - Moose Jaw area. The study has shown that the most favourable geothermal reservoirs are in the Basal Clastic Unit (Cambrian Ordovician), which, at an approximate depth of 2,000 metres has predicted temperatures of 71°C to 74°C. We anticipate sustainable flow rates from these reservoirs of 100 to 300 ms/hr. The water contains about 150,000ppm of total dissolved solids, mostly sodium chloride. It is anticipated that the sulphate content will be 3,000 to 6,000 ppm, that the dissolved oxygen and hydrogen sulphide content will be small, and that the waters will be neutral to slightly alkaline. It is anticipated that the piezometric level will be 46 m below the ground surface for reservoirs in the upper part of the Basal Clastic Unit and 141m below the ground surface for the lower reservoirs of the unit. Plans are to build a low-grade geothermal research, testing and demonstration facility at the University of Regina. To be a practical demonstration, the facility will have to handle very large volumes of water. Because of high salinity, the water will be re injected into a subsurface reservoir. We do not anticipate insurmountable problems because of salinities or as a result of corrosion provided that the waters are not aerated during handling

Jan 1, 1979

By N. T. Oo, L. D. Hutton

"The Banora Point Upgrade Project is a 2.5km long six-lane divided freeway in northern New South Wales, Australia. The geology at the project area comprises a volcanic succession of variably weathered basalt flows and agglomerate deposits that reach 48m in thickness and overlie Mesozoic sedimentary rocks. A site specific rock classification system was developed that characterised all the rock units based on the engineering properties governing the rock mass behaviour i.e. intact rock strength and defect characteristics (spacing, aperture, infilling, wall roughness and weathering) irrespective of the geological origin. This approach simplified the design and the on-site verification processes. Based on this classification system, rigorous quantitative statistical assessments of the available geological information including various laboratory and field testing were performed to derive the geotechnical design parameters for various rock classes. These parameters were used to complete geotechnical designs of retaining wall systems. INTRODUCTIONThe Banora Point Upgrade Project is a 2.5km long six-lane divided freeway in northern New South Wales, Australia. The key features include two interchanges, a 300m long viaduct, a large cutting through Sexton Hill with an associated 100m wide Land Bridge and retaining walls reaching 490m long and up to 22m high. This paper focuses on the derivation of representative geotechnical parameters for geotechnical design of the retaining structures supporting Sexton Hill Cutting including bored pile retaining walls and soil nail walls. The geology at the project area comprises a volcanic succession of variably weathered basalt flows and agglomerate deposits that reach 48m in thickness and overlie Mesozoic sedimentary rocks. Due to the complex geological nature of the site, an understanding of the regional and local geology, the typical behaviour of individual geological units and the implication of onsite variations from design intention are the ultimate challenges to the geotechnical engineer in order to select representative geotechnical parameters for design."

Jan 1, 2015

By Y Shougu

Many mine accidents will affect the mine ventilation system when they occur. At present, there is a lack of monitoring means to capture the occurrence of accidents in time by monitoring the ventilation system, so as to take emergency measures to reduce the loss of personnel and property. Pressure wave is an elastic wave existing in air. Most accidents in mine will cause obvious changes of pressure wave. It is an innovative idea to monitor the occurrence of accidents in mine by measuring pressure wave. The development and functions of the pressure monitoring device and related software are introduced in detail. The pressure wave monitoring test is carried out in San Xavier underground mining laboratory, and the D-wave and S-wave waveform data are collected. The waveform characteristics are analysed, and the main frequency distribution of the pressure wave is found to be within 1 Hz by using FFT. At the same time, the influence of the propagation distance of the pressure wave on the waveform is analysed. The propagation velocity of D-wave and S-wave are roughly calculated, and they are 279.6 m/s and 397.3 m/s respectively. S-wave is slightly faster than D-wave. Although there are errors and uncertainties in the test, the test verified the feasibility of the existence and collection of pressure waves in the ventilation roadway, and provides a method for the future study of the propagation of pressure waves in the mine ventilation system.

Oct 12, 2022

By J. E. Crawshaw

"The few previous observations of the effect of turbulence on limits of inflammability have been made on a small scale in turbulence produced either by a fan or by movement of the mixture.By a suitable amount of turbulence from a fan the lower limit of methane was 5 per cent as compared with 5 per cent observed for quiescent mixtures in the same vessel.3 With a streaming movement of the gas mixture within the range of speed from 35 to 65 centimeters per second (69 to 128 feet a minute) the lower limit was approximately 5 percent,4 For a quiescent mixture of ethane the lower limit was 3.10 per cent ethane, but with fan running at a moderate speed a 3 per cent mixture exploded.5The object of the tests herein reported was (1) to determine the lower limit of natural gas in a mixture of natural gas and air Which would be ignited and propagate violently when the turbulence was produced by explosives fired from a cannon into the mixture; (2) to observe the behavior when the mixture contained less than this low limit; and (3) to determine how turbulence produced by a fan affects thin limit.Four series of tests were run, three of which were to determine the effect of different sources of ignition: Tests with (1) an electric igniter; (2) 3F black blasting powder stemmed with 2 pounds of dry fire clay stemming used to ignite the mixture, and (3) 40 per cent straight nitroglycerin dynamite unstemmed. The fourth was made to study the effect of turbulence produced by a two-speed electric fan, using an electric igniter as the source of ignition.In both series of tests with explosives, charges of 50 and 200 were used to determine the effect of increased quantity of explosives on the lower limit of natural gas."

Jul 1, 1930

By Xin Zhang, Xu Zhang, Hao Bai, Ning Li

Organic Rankine Cycle (ORC) is an effective technology for low-grade waste heat power generation. In this paper, the thermal-dynamic performance of ORC system, in which low-temperature waste heat (from 40-140oC) is used as heat source, was evaluated with software RefProp8.0. The result indicates that in the range of low temperature, the working fluids like R601, R601a, R600a, R141b, R245fa and R245ca have better thermal performance. Furthermore, pilot-scale experiment using R245fa as working fluid was conducted, which validated the operation of the system for low-grade waste heat recovery. Finally, the economic feasibility of ORC has been analyzed for an ORC system using the waste heat from quenching water of blast furnace slag (80oC). According to the analysis, the project is reasonable in economy because the recovery period of investment is less than 4.2 years and environment-friendly since the CO2 emissions can be reduced by almost 43650.68t annually.

Jan 1, 2016

By C. Kasatuka

Globalization creates investment opportunities for enterprises around the world. Attracting foreign investment has been a key challenge for economic growth in developing countries. Corruption, political instability, armed conflict, and other internal problems affect foreign direct investment (FDI) inflows negatively. A framework of criteria provides a basis for comparing non-commercial risk (NCR) among twenty-three mineral economies. Countries competing for foreign direct investment inflows are ranked from least to most risky. This study compares Inward FDI Performance Index (IND) with NCR ratings in developing countries and shows that risk is increasingly mitigated by means of appropriately structured insurance. Given the option for countries with similar mineral potential, investors will generally invest in the country that offers lower non-commercial risk. Keywords: foreign direct investment, non-commercial risk, developing countries.

Jan 1, 2006

By G.A. Moore, C. E. Sims

In previous publications of the writers4-7 it has been shown that vacuum extraction of steel can be carried as close to quantitative completion as desired provided the steel is in the austenitic state and sufficiellt time is allowed. For precise work, the method claims preference because the equipmelit for holding and heating the sample can be made simple, and because crucibles, boats, and other unnecessary materials can be eliminated and the blanks thus made very small. It is well known that the evolution rate of hydrogen is smaller just above the trans. formation than immediately below, as would be expected from the increase in solubility when passing into the gamma state. Many attempts have been made to obtain analyses by extraction just below the transition, using times of approxi. mately 2 hr. while it is true that the rate of evolution drops nearly to zero under these conditions, it has repeatedly been shown that the process is incomplete since on raising the temperature into the austenitic range, evolution will be resumed, usually after a, considerable induction period. The low-temperature evolution process appears to be useful in some cases for comparative tests where the residual crror may be more or less constant between samples, For general use, however, there is no guarantee that the error caused by incomplete extraction is constant; hence, the more laborious but more reliable high-temPe&apos;atu&apos;e Process must be used. At high temperature, an original flash evolution, similar to that at lower temperature, is first observed. After not more than an hour, the flash subsides and cvolution settles down to a regular first-order reaction rate for which the half-life* is usually of the order of a few hours for the 5/8-in. diam cylinder at 1050°C. The regular evolution may be followed for whatever period appears justified, after which the residual gas may be estimated as equal to that which was evolved in the last observed half-life period. Tests have shown that the composition of the evolved gas does not vary greatly during the progress of evolution; therefore the residual gas may safely be taken to have the same composition as the portion col-

Jan 1, 1949

By C. E. Sims, G. A. Moore

In previous publications of the writers4-7 it has been shown that vacuum extraction of steel can be carried as close to quantitative completion as desired provided the steel is in the austenitic state and sufficiellt time is allowed. For precise work, the method claims preference because the equipmelit for holding and heating the sample can be made simple, and because crucibles, boats, and other unnecessary materials can be eliminated and the blanks thus made very small. It is well known that the evolution rate of hydrogen is smaller just above the trans. formation than immediately below, as would be expected from the increase in solubility when passing into the gamma state. Many attempts have been made to obtain analyses by extraction just below the transition, using times of approxi. mately 2 hr. while it is true that the rate of evolution drops nearly to zero under these conditions, it has repeatedly been shown that the process is incomplete since on raising the temperature into the austenitic range, evolution will be resumed, usually after a, considerable induction period. The low-temperature evolution process appears to be useful in some cases for comparative tests where the residual crror may be more or less constant between samples, For general use, however, there is no guarantee that the error caused by incomplete extraction is constant; hence, the more laborious but more reliable high-temPe&apos;atu&apos;e Process must be used. At high temperature, an original flash evolution, similar to that at lower temperature, is first observed. After not more than an hour, the flash subsides and cvolution settles down to a regular first-order reaction rate for which the half-life* is usually of the order of a few hours for the 5/8-in. diam cylinder at 1050°C. The regular evolution may be followed for whatever period appears justified, after which the residual gas may be estimated as equal to that which was evolved in the last observed half-life period. Tests have shown that the composition of the evolved gas does not vary greatly during the progress of evolution; therefore the residual gas may safely be taken to have the same composition as the portion col-

Jan 1, 1949