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By Heribert F. Broicher, Arne Volland

The application of remote sensing techniques combined with fluorescence spectroscopy is realised in analytical devices called LIF Analysers. The analysis of laser-induced fluorescence facilitates non-destructive, non-contact, on-line and real-time rock identification and quality control of bulk solids in transport. LKAB of Sweden was the first company to test LIF Analysers in the Kiruna Mine for bulk sorting of run-of-mine ores depending on the phosphorus content. Other applications tested in Germany so far are quality control of limestone (iron and/or dolomite content) and rock identification in lignite mining. Of special interest also is rock identification in diamond mines for dilution control. The paper summarises the present state of the application of LIF Analysers.

Jan 1, 2003

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By Andrew B. Cecala

As deeper seams are continually mined, methane liberation will continue to increase and must be monitored effectively. To effectively monitor and develop appropriate control technology, methane-liberation patterns must be known. The Bureau of Mines recently completed a study to identify specific patterns of face methane liberation during long- wall mining. Both of the longwall faces surveyed had high methane liberation rates. At one longwall face, most of the methane was liberated during cutting of coal by the shearer mining machine. At the second face, a significant portion of methane was emitted from the face and floor. An effective methane-monitoring system would be different for each longwall panel because of the differences in how the gas is released along the face.

Jan 1, 1985

By J. W. Shield

Refractory sulfide flotation or gravity gold concentrates are coated onto a sized support matrix and placed in a heap configuration for biooxidation. The surface coating is typically less than 0.05 in. thick and the support matrix is preferably composed of 0.375 to 0.75 in. diameter material. The exposed thin coating of sulfides reduces biooxidation rate limitations due to oxygen mass transfer. The large spaces between matrix particles reduce resistance to fluid percolation and aeration in the heap. The capital and operating costs for this biooxidation configuration are significantly less than for concentrate biooxidation in stirred tanks. After 30 to 90 days of biooxidation, sub- sequent gold recoveries exceed those seen in whole ore heap biooxidation and are comparable to recoveries obtained from stirred tank biooxidation processes. Results from laboratory and pilot testing indicate that this technology is a viable alternative for pretreating sulfide refractory gold ores.

Jan 1, 1997

By W. Kasprzak

Modern light metals processing technologies are very complex and involve a diverse set of variables that must be quantitatively evaluated. The most effective way to design new casting processes that deliver specified metallurgical and mechanical properties is to develop a method of simulating the "real-time" process within a test sample of sufficient size. The results can then be analyzed and the required optimizations can be performed. This paper presents a novel method of simulating the industrial casting processes in a laboratory environment using an experimental apparatus based on the principle of high frequency induction heating. The applicability and accuracy of the proposed analytical method is demonstrated, for example, by simulation of the solidification and heat treatment of a test sample composed of two dissimilar materials. The simulation can be used to develop a stress model for an engine block made from an aluminum based alloy with iron cylinder liner inserts.

Jan 1, 2002

By G. Kazonich

The high costs and environmental problems associated with making iron and steel in the United states is driving the development of new technologies to replace the blast furnace. A prototype reactor incorporating rocket technology was designed and built. This rapid rate reactor was operated successfully and consistently made iron metal. Minus 32s-mesh magnetite particles could be reduced to iron metal in less than 50 ms in a high temperature flow through reactor. Iron product was recovered inside the reactor and in a downstream cyclonic separator. The results of typical operation and how parametric changes affected the reduction of iron ore concentrates are discussed.

Jan 1, 1993

Gold rooms represent a high security area and preventing theft is a challenging task. Where gravity concentrates or high value unit intermediate products are present, particular and specific security procedures must be put in place. This paper describes the development and implementation which reflects best practice in gold room security. Procedures involving key holder systems, key locks, swipe cards and double locks preventing any one person having access to the gold room, including specific procedures for gravity gold concentrators, will be addressed. The use of monitoring and how to deal with alarms and potential hold ups will be reviewed. The use of cameras and archival DVD recorders is common in gold rooms. The use of electronic surveillance, movement detectors, seismic monitors and the two person policy and gold room entry procedures are described, including how to deal with visitors. The importance of confidentiality regarding smelting and gold pick-up days, plus strategies employed to minimise storing large quantities of gold on site will be presented. The role of metallurgical accounting in providing quality auditable information and the minimum standards of record keeping required is discussed. The role of the Gold Squad will be outlined. Regular auditing and risk analysis and several case studies are cited where security was deficient or improved.

Aug 1, 2010

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By Francis F. Pitard

The presence of elements, minerals, or chemical compounds in materials at very low concentrations is becoming a constantly increasing concern for several segments of the Industry. Some trace elements or chemical compounds may be considered as hazardous, some are simply considered as undesirable In complex processes where they could be constantly recycled and end up as the major factor of decreasing quality for some valuable products. In some other cases, the presence of a trace element or mineral may be highly desirable because of its economical value: precious metals are falling into this category, they probably were the first trace elements to draw our attention. Tremendous quantity of money is spent for analysis at the trace level, also the analytical "tool" has been considerably improved during recent years, but still the sampling aspect of the problem remains obscur for many, and because of it, large quantity of analytical efforts become meaningless. Not only the absence of sampling strategies is badly affecting the representativeness of a large majority of samples, but furthermore for the same reasons, many laboratories are failing In their endeavor to prepare reliable standard reference materials. The reason of this failure has its roots in the unability to estimate effectively the sampling characteristics of the element, mineral, or compound of interest, not to mention the unability to perform precise and accurate complete analysis, so essential for the instrumental analyst (1). In this paper a strategy to perform a better sampling operation is recommended. SELECTION OF A PROBABILISTIC APPROACH AS SOON AS PRACTICALLY POSSIBLE It Is essential to differentiate probabilistic sampling from non-probabilistic sampling. As Illustrated in Figure 1, the sampling operation Is a selection process which could be performed In two different ways: I. A probabilistic selection process according to which all elements of a lot of material to be sampled are submitted to the selection with a same probability of being selected. 2. A non-probabilistic selection process according to which all elements of a lot of material to be sampled are submitted to the selection with different probabilities of being selected.

Jan 1, 1986

By Y. Ide, K. Kishitake

It is expected that an Al-Cr-N composite nitride film may have a higher resistance to oxidation at elevated temperatures than the well-known Ti-Al-N films. The formation conditions of Al-Cr-N films by a de reactive sputtering method and their properties were studied in this study. The films characterized with respect to their high temperature properties such as chemical composition, crystal structure, microhardness, wear and· friction. The crystal structure of the Al-Cr-N films changed from hexagonal phase to cubic phase with an increase in Cr content in the films. The resistivity to thermal oxidation of the Al-Cr-N films is superior to that of usual TI-Al-N films. A half of the friction coefficient in the Al-Cr-N film was obtained comparing with that in the ordinary TI-Al-N film at room temperature and the wear rate of Al-Cr-N film was 2 order smaller than that of TI-Al-N film. The Al-Cr-N films show a small friction coefficient at 500°C and then they are recognized to have good tribological characteristics.

Jan 1, 2000

By X. J. Lu

Purified Na-montmorillonite samples were used as the starting materials to prepare organically modified montmorillonites (OM), and a series of OM samples were prepared by intercalation of al-kyl quaternary ammoniums with different alkyl chain length. The interlayer spacing (d001) of the OM was determined by small angle X-ray diffraction and its gelating performance was characterized by measuring the viscosity of OM/dimethylbenzene mixture. The effects of alkyl chain length, dosage of alkyl ammonium, intercalation duration and layer charge of the starting material on the OM structure and gelating properties were investigated. According to the results, the adsorption quantity of the alkyl ammonium is dependent on the hydrocarbon chain length, the dosage of the alkyl ammonium and the retention time. The adsorption quantity of the alkyl ammonium increases with the chain length and the dosage, and extra adsorption more than the CEC of the montmorillonite sample was observed under the dosages of more than 1.3 CEC. The interlayer spacing (d001) of the OM shows a dynamic variation with the dosage and the retention time, and super interlayer spacings greater than the length of the alkyl ammonium were observed under larger dosages and shorter retention times. However, the gelating performance of OM does not follow the variations of the adsorption quantity of alkyl ammonium, an optimum viscosity value of OM/ dimethylbenzene gel was observed with the moderate adsorption of the alkyl ammoniums. Furthermore, the layer charge plays an important role on the gelating performance of OM. The OM synthesized by the starting material with lower layer charge shows better gelating performance in the dimethylbenzene solution.

Jan 1, 2014

By George H. K. Schenck

Diminishing returns in management's fight to lower manufacturing expenses have added luster to savings that can be achieved in delivered costs through creative management of the distribution function. This is especially true for companies engaged in the production of bulk commodities, for which transport costs may represent 25 to 50% or more of total delivered price, A. E. Cascino, vice president of International Minerals and Chemical Corporation, recently gave an example of why top management in his firm is concerned with distribution: "The price of a ton of phosphate rock, f.o.b. mine, is about $7. The cost of warehousing, freight, and handling frequently totals an additional $11 . . . . If one of our competitors . . . discovers a way in which he can cut his distribution costs by $3, we're dead! Even if we wanted to offset our competitor's more efficient means of shipping with reduced f.o.b. price for our product-we don't have that much profit margin . . . ." In a special report on the revolution now occurring in transportation of goods, Business Week stated in its September 24 issue: "Moving and storing goods on their way from mine and mill through various sub-assemblies to their final markets costs anywhere from $50 billion to $75 billion a year- $100 billion if paperwork costs are included.

Jan 1, 1967

By R. Hogg, S. Chander

"The distribution of the wettability of coals of different rank was determined by measurements of contact angles for individual particles. The contact angle was estimated from the equilibrium partitioning of a particle at the water/air interface. Using this technique contact angles were determined for a larger number of particles from a given sample and a frequency distribution of contact angle was obtained. The contact angle distribution was broad for all the coals tested with included an anthracite, a hvA bituminous and a sub-bituminous coal. In comparison, spherical particles of polymethylmethacrylaie gave a much narrower distribution. The distribution for irregular polyethylene particles was somewhat broader than that for the polymethylmethacrylate spheres but broader than that for the polymethylmethacrylate spheres but considerably narrower than that for coal. The broader wetting distribution for coal was attributed to differences in surface chemical properties.INTRODUCTIONA knowledge of the wetting properties of coals is very useful in coal cleaning by flotation and other processes in which separations are based on differential surface properties. The various methods available for measuring wetting characteristics include: contact angle, 1-2 time, time, 3-5 bubble attachment, 6 film flotation,7 displacement pressure, 8-9 penetration rate, 10-11 bubble pick-up, 12 induction time, 13 imbibition time, 14 and calorimetry. 15-16 Of all these methods, however, the measure¬ment of contact angle by the sessile drop and captive bubble techniques have been most widely used. Brady and Gauger"" demonstrated through the use of the contact angle method that the natural hydrophobicity of coal varied greatly from sample to sample. Subsequent experiments showed that this difference correlated well with rank, the larger contact angles generally being associated with the higher rank coals. 18-19 More recent studies by Aplan and co-workers' show that the wettability of various ranks of coals as determined by sessile drop and captive bubble methods is a more complex function of rank. The hydrophobicity of coal usually increases with rank up to about 80% fixed carbon (dmmf) and then decreases."

Mar 1, 1992

By A. Ashrafi

The electrochemical deposition of polypyrrole coating on different pretreated aluminum-alloy 7075 substrates was carried out using cyclic voltammetry, The pretreatment of specimens consisted of mechanical polishing and/or electrochemical etching, In the latter case, an aqueous solution of phosphoric acid and ethanol was used, The electrodeposition solution was 0,25 M pyrrole and 0,1 M oxalic acid in double-distilled water, The cyclic voltammetry scan rate used was 700mv/s, Morphology of the coatings was examined using scanning electron microscope (SEM), Using the Tafel experiment, corrosion resistance of the coated substrates was investigated in 0.1 M NaC1 solutions, Results obtained revealed that electropolymerization of polypyrrole on 7075 aluminum alloy would increase the resistance against corrosion in 0,1M NaC1 solution, Also it was observed that, compared with mechanical polishing, electroetching pretreatment would be more effective.

Jan 1, 2005

By Sandeep Upadhya, Marc Morgan, Baljinder Bassi, James Fletcher, Mike Deevy, Nishant Nayan

"In order to protect public safety in the event of a deliberate fire attack, underground rail authorities are increasingly considering the need to design for arson-initiated fire scenarios. Where typical design fires for modern rolling stock mean a peak fire size is reached after 12 minutes, an arson-initiated fire reaches its peak within 2-3 minutes. We present the innovations required to successfully incorporate this requirement on a recent design-build project. In stations 3D modelling is used to optimise smoke reservoir designs, smoke chimneys, station boxes and tunnel geometry to allow coordination with structural requirements. In tunnels, novel coupling of one dimensional network modelling and 3D Computational Fluid Dynamics (CFD) is used to improve assessment of complex fire scenarios. Finally, the impact on tunnel structures is assessed through comparison with standard time-temperature curves and risk of explosive spalling. INTRODUCTION An increasing regulatory environment and the appreciable influence that terrorist incidents have had on public safety policy have motivated the need to protect against large arson fires, especially in civil structures and public transport systems. With a greater reliance of a growing urban population on underground subway systems, design of such infrastructure is continually being reassessed and developed worldwide. Underground rail authorities are paying increased consideration to the design of fires - with properties beyond the upper regions of growth and intensity - amongst arson fire studies. Use of fire hardened materials on modern rolling stock means fires caused accidentally can be expected to develop relative slowly. However, recent experiments involving large initiating fires (as would result from an arson attack) have shown rapid fire growth rates and flashover leading to greater maximum heat release rates, Hadjisophocleous (2012), White (2010), and Lönnermark, et al. (2015). This paper describes the challenges and innovations required to complete a detailed design to control smoke from such aggressive super-fast growing fires. Computational modelling is used to demonstrate the required smoke control design by configuring the mechanical exhaust system combined with careful coordination with the architectural and structural design. The design objectives are to provide tenable egress paths in accordance with NFPA 130 (2014) and fire-fighting access. Finally, analysis of the design fire is used to inform the tunnel lining design, reducing the risk of explosive spalling, protecting the asset in the event of a severe fire."

Jan 1, 2016

By Robert Vidal

A model of the homogeneous chemistry and transport processes within the separator of a chrome-alum electrowinning cell is introduced, discussed, and compared to experiment. The influence of diffusion, electromigration, and convection are included; it is found that convection was the dominant mode of transport for the experimental conditions. Simulation results explain experimental observations concerning an apparent disappearance of dichromate ions produced at the cell anode. The relation between potential drop across the diaphragm and the current and fluid flow is also illustrated. The model is used to recommend future experimental and theoretical work.

Jan 1, 1994

By P. R. Hervey

Quartz is the second most widely used electronic material, with approximately 3,000 tons of single crystals used each year. Virtually all of this material is synthetic; grown with a technique called hydrothermal growth. We will review the basics of hydrothermal growth, the feedstocks for these crystals, and the challenges to improving the growth process. We will also review the processing of these crystals, the markets and applications where they are used, and the global outlook for these markets.

Jan 1, 1999

By H. J. Heinen

The Bureau of Milts studied repetitive batch electrowinning of molybdenum from molybdic oxide ) to determine the effects upon the electrolyte life, purity of metal product , and overall cell performance. The electrolyte consisted of 54.0 weight-percent sodium tetraborate (Na2B407), 23.6 weight-percent sodium chloride (NaC1), 14.9 weight-percent sodium fluoride (NaF), and 7.5 weight-percent Mo03. The feed materials were pure and technical-grade Mo03. Electrolysis was conducted at l,000° C in a graphite cell in an atmosphere of air and carbon oxides. Electrolyte degradation did not occur during repetitive winning of molybdenum from pure Mo03 in an 8-day (5,400-ampere-hour) period of operation. Electrowon metal contained <0.1 percent total impurities. The electrode configuration is a key factor in the direct conversion of technical-grade Mo03 to metal by repetitive cyclic electrolysis. The best configuration found was a cathodic crucible and a central anode. Metal purity of 99.8 percent and a current efficiency of 91 percent were maintained until the combined impurity buildup the electrolyte reached 4.7 percent silicon, l.0 percent aluminum, and 0.6 percent iron. One pound of molybdenum was produced per 1.5 pounds of solvent salts employed. About 25 percent of the initial NaCl and NaF contents of the electrolyte were lost owing to volatilization and crucible penetration.

Jan 1, 1966

By K. Kim

A site characterization strategy formulated for the probabilistic design of underground structures is presented, which takes into account the variability of rock properties and the stochastic nature of the rock failure process. It entails determining probability distributions of rock properties by utilizing the theory of extremes and Monte Carlo simulation. Laboratory and field test data are analyzed and presented to illustrate the methodology. The results indicate that the distributive characteristics of rock mass properties can be estimated using empirical relationships currently available. This results of analyses can be incorporated into the design of underground structures, and then, the relative uncertainties of the failure probability of the structures can be assessed.

Jan 1, 1995

By Ross W. Smith

Many studies have been made of the microflotation of quartz (1,2,3,4,5,6) and alumina (3,5,6, 7,8) using various anionic and cationic hetero- polar hydrocarbon surfactants as collectors. A few studies have been made on these minerals using amphoteric hydrocarbon collectors ( 9,10, 11,12) and only a few studies have been made on the use of fluorocarbon surfactants as flotation collectors (13,14). The present investigation compares microflotation response of the two minerals in hydocarbon and fluorocarbon collector systems of the anionic, cationic and amphoteric types. An attempt is made to relate flotation response of the minerals to their electrokinetic behavior and the pKa values of the collectors.

Jan 1, 1979