Search Documents

By H. L. Retcofsky

Carbon-13 nuclear magnetic resonance (18CNMR) spectra of nine 2-substituted pyridines, seven 3 -substituted pyridines, and nine 4-substituted pyridines have been obtained and analyzed. Substituents included both electron-releasing groups and electron-with hawing groups. Substituent effects on the magnetic shieldings of the ring carbons, except for those in the 2-positions of 2-substituted pyridines, were found to be quite similar to the effects reported for the monosubstituted benzenes, Thus, at least to a first approximation, the two classes of compounds have similar shielding mechanisms. Shieldings of the carbon atoms in the 5-positions of 2-substituted pyridines and those in the 6-positions of 3-substituted pyridines were found to reflect electron release or withdrawal by substituent groups, The pyridinium cation and the compounds 2,2'-dipyridyl and benzonitrile were also investigated.

Jan 1, 1969

By B. Fagerberg

Crushing and grinding practice in Sweden follows largely the international pattern. Certain special circumstances, however, have had an influence on the development. Most mines are worked underground in either quite small or in very large units. To utilize small sulphide ores, custom milling is rather common. Apart from the cement industry, the rock species treated are hard and abrasive. Another important factor is the increasingly strict requirements placed on the mechanical condition of different products, especially lump ores and coarse iron ore concentrates. A significant feature in the design and development of Swedish crushing and grinding practice has also been close cooperation between machinery manufacturers and the users. An account of these conditions and an outline of the crushing and grinding techniques employed in Sweden are presented in this paper with emphasis on the mining industry. For background purposes it may be mentioned that crude ore production in Sweden last year included 45 mill. tonsx) of iron ore, of which some 20 mill. tons from Kiruna alone, and 4 mill. tons of sulphide ore from 22 other mines, fig. 1. In addition 8 mill. tons of limestone were quarried for cement production and several million tons of stone and sand for roads, aerated concrete, etc.

Jan 1, 1968

By R. D. Berkenkotter

This report describes a weighted method for evaluating the mean and variance of assay data from samples of different length . The method , which produces unbiased estimates from which valid confidence limits can be computed , is appropriate for bedded deposits of variable bed thickness and for vein deposits of variable vein width . Assay data from the bedded Florida phosphate deposit is used to illustrate the procedure .

Jan 1, 1964

By D. J. Donaven, Manuel Gomez, W. S. Landers

Bulk density tests were made on a Western U.S. coke oven plant blend to obtain bulk density control data that would be directly transferable to plant practice . Maximum bulk density values were obtained at zero surface moisture . Increase in surface moisture to about 6 percent decreased the bulk density to a minimum value . Increase in the fine grinding of the blend , at constant surface moisture , decreased the bulk density . The effect of oil on bulk density was observed with five oils at concentrations ranging from 1/8 to 1-1 / 2 gallons per ton . Maximum bulk densities were obtained within the 1 / 2- to 1 - gallon - per - ton range . Essentially the same bulk densities were obtained with petrolatum- and nonpetrolatum- containing oils . Storage effects were observed on samples tested at selected intervals from 0 to 56 days . No significant change in bulk density took place if no surface moisture was lost during storage .

Jan 1, 1964

By Albert L. Toenges

EARLY in 1949, the Economic Cooperation Administration requested the Bureau of Mines to assign a coal-mining engineer to study milling conditions in Greek lignite mines; to make recommendations for the introduction of methods and practices that should increase production and decrease the cost of mining; and, from the results of a geological reconnaissance by geologists of the United States Geological Survey, to suggest plans for the development of mines to supply fuel for a thermal power plant, Albert L. Toenges was assigned to this investigation and arrived in Athens, Greece, March 15, 1949. The study of mining operations and the geological reconnaissance (which was made by W. G. Pierce and X. M. Denson, geologists, United States Geological Survey) Were conducted concurrently. The Geological Survey will publish the results of its investigation separately. Washability studies of lignites from Aliveri and Kimi were made at the Central Experiment Station of the Bureau of -Mines, Pittsburgh, Pa. The lignite fields mentioned in this bulletin are shown in figure 1.

Jan 1, 1951

By Howard S. Avery

The wear resistance of an alloy in heavy mill liner sections may be quite different from that of the same alloy in small balls and other light sections. This fact was established by means of a well standardized laboratory test that was validated for ball mill service. The salient properties of mill liner alloys, including austenitic manganese steels, medium alloy hardenable steels, and abrasion resistance cast irons are described, critically compared, and quantitatively ranked in terms of mill liner service. Where they are tough enough the high-chromium and other martensitic cast irons (e.g. Ni-Hard) promise maximum economy, but their section sensitivity is a limitation. To overcome this an extensive research program studied over a hundred experimental alloys, ranking them for heavy section abrasion resistance by means of the laboratory test. Computer analysis of the results provided a parabolic formula in terms of composition, the apexes of the parabolas providing optimum wear resistance. From the extensive family of parabolas one apex was selected for intensive study in experimental liners, pilot plant production, development of quality controls, and finally full scale production. This is a 19% chromium iron critically alloyed with nickel and molybdenum and hardened by heat treatment. It has excellent resistance to various types of abrasion, but its chief advantage is in heavy mill liner sections, where it has about 25% better abrasion resistance than the best of the quality controlled chilled Ni-Hards. It is also tougher. After production problems were solved, a number of ball and rod mill tests were arranged on a guaranteed performance basis. Two of these, representing about 138,000 pounds of mill liner castings, have recently confirmed in service the superiority that was predicted by the laboratory tests.

Jan 1, 1969

By K. L. Paciorek

The primary objective of this final phase of Contract No. H0133004 was to provide a description of all experimental assemblies and procedures used throughout this project in such a detail as to permit duplication of the tests in any other laboratory. A further objective was to summarize and evaluate all results generated throughout the duration of this program and to tabulate all the materials and data in such a manner as to allow this report to be used as a reference index for specific compositions or groups of compositions regarding potential hazards arising from their use .in underground coal mining operations. The report also contains an updated survey of the literature on thermal oxidative degradation of compositions investigated under this contract.

Jan 1, 1978

By C. M. Campbell

In his report on the Coal Resources of Southern Vancouver Island, Mr. J. D. MacKenzie stated that: "For various reasons it has been imagined that the coal deposits of Vancouver Island are extremely large and readily available." "Unfortunately," he added, "neither of these assumptions is correct." The chief disability under which the Island mines now labor does not concern the extent of the deposits. There is ample coal for the present demand. It does, however, concern the availability of the coal. If it were readily available the fuel-oil competition would not be serious and there would be no competition with Alberta, American, Welsh, or Australian coal along the Pacific Coast, for Vancouver Island coal could be produced at a price that would cut out all competition. The outstanding operating difficulty common to all Island mines is the extreme irregularity of the coal seams. To most people a coal seam is synonymous with uniformity, and in most coal seams a condition found at one point will be repeated at other points in the same seam throughout the basin. The accompanying drawings show how very far this is from being true in the Cassidy mine, which, in many respects, is typical of Vancouver Island mines. Figure I is a plan covering about 160 acres of the Douglas seam, the only workable seam in this part of the district. The area shown represents what has been the best producing part of the mine and indicates the very large percentage of the seam where the coal is either entirely lacking or so small in amount that it cannot be profitably recovered.

Jan 1, 1924

By A. B. Hooker

All State mining laws require that flame safety lamps be used in gassy mines; the laws of some States require that safety lamps be kept for emergencies at every coal mine, whether gassy or nongassy. The use of the flame safety lamp has been widespread because it is the only defice readily available for detecting both the presence of methane and deficiency of oxygen. This paper reports the results of an investigation by the Electrical Section, in cooperation with the Gas Section, of the Pittsburgh Experiment Sta¬tion relative to the behavior of permissible flame safety lamps in mine atmospheres deficient in oxygen and the effects of methane5 on the detection of Oxygen deficiency.

Jan 1, 1937

By Helen Ahnberg

The scope of the present paper is limited to report the experimental evidence and not for describing the analytical assumptions. However, the idea behind the experimental program is that the deterioration may be caused by the leaching of Ca from the treated soil to surrounding soil or water driven by the difference in the Ca ion concentration. As a consequence of Ca leaching, it may be natural to expect the expansion of micro void space within the treated soil. In a saturated condition, the water inflow into the treated soil may accompany the leaching phenomenon. We measured the water content within the treated soil. But there is not much difference in water content within the soil.

Feb 10, 2003

By C. J. Milam

Oil shale may not produce the same excitement of the gold rush days, but presently there is an "oil shale fever" among mining men. Such exotic equipment as 800-ton haul units, 75 ft. boring machines, and huge fully automatic multi-purpose jumbo drill units are only a few of the topics of conversation in the oil shale groups. I am dreaming, perhaps, but this type of exotic thinking will exuberate the advancement in mining technology and will only be tempered by the practicality and the availability of today's equipment.

Jan 1, 1975

By A. B. Hooker

All state mining laws require that flame safety lamps be used in gassy mines; the laws of some States require that safety lamps be kept for emergencies at every coal mine, whether gassy or nongassy. The use of the flame safety lamp has been widespread because it is the only defice readily available for detecting both the presence of methane and deficiency of oxygen. This paper reports the results of an investigation by the Electrical Section, in cooperation with the Gas Section, of the Pittsburgh Experiment station relative to the behavior of permissible flame Safety lamps in mine atmospheres deficient in oxygen and the effects of methan5/ on the detection of oxygen deficiency.

Jan 1, 1937

By N. Ahmed

This paper is concerned with the drainage behaviour of gangue mineral in the froth phase. Experiments were carried out in a continuous laboratory flotation cell in which froth depth and bubble size could be changed independently. The fraction of solids returning from the froth to the pulp zone was expressed using a rate constant. A mixture of hydrophilic solids (silica) and floatable particles (glass ballotini) was used as a flotation feed. Samples of glass ballotini of different hydrophobicities were obtained, using controlled silanation. Three samples, with contact angles of 50, 66, 82 degrees, were used. The effect of the initial bubble size (pulp bubble size), concentration of gangue mineral in the froth zone, and froth depth on the drainage of silica, were investigated. The drainage rate of the entrained solids increases with an increase in the degree of hydrophobicity of the floatable particles. Concerning the effect of pulp bubble size on the drainage rate of entrained solids, larger bubbles always give higher drainage rates due to formation of relatively loose froth structures which allow gangue particles to easily move down to the pulp zone. Conversely, smaller bubbles exhibit lower drainage rate constants, in particular at shallow froth depths.

Jan 1, 2003

By WILLIAM E. NEWNAM

THE molding and loading of pig lead has, in the past, been accomplished mainly by the strong arm method and, as the pigs are usually loaded directly into the cars, it has been a hot and laborious task. Of late years it has been difficult to obtain men willing to perform such labor and the need has been felt for loading and molding machinery which would eliminate all manual handling of the hot pigs and which would be sufficiently compact to permit of installation in existing plants with little or no

Jan 1, 1924

By Nico Sutmoller, Rich Palladino

Underground voids present a unique geotechnical engineering challenge. This paper will address materials and transportation mediums that are typically used for backfilling underground voids with native material. After reviewing traditional backfill and transportation methods, this paper will explore the advancing technology of foam transportation and the advantages of using this technology for transporting fill materials into underground voids to backfill them with Liquid-Sand. The paper will also review the benefits that Liquid-Sand brings to these applications and highlight specific case studies in which foam transportation has proven effective and provided cost-effective, environmental benefits.

Feb 1, 2025

By Hazel J. Stratton

IN THE HALF-CENTURY that has passed since the Bureau of Mines was established in July 1910, the research and technologic investigations conducted by the Bureau's scientists, engineers, and other personnel have helped significantly in improving health and safety in the mineral industries and have contributed substantially in conserving the Nation's mineral resources through improved techniques in the mining, treatment, and use of mineral commodities. From Bureau laboratories have come new materials for industry and better methods of extracting and processing minerals and mineral fuels. Bureau safety investigations-complemented by equipment testing and by programs of mine inspection and education-have brought about safer and more healthful working conditions.

Jan 1, 1960

By D. W. MacFarlane

In the formation of Oil and Gas Producing Units lawyer& and engineers are interdependent members of the same team. Management is, there-fore, entitled to expect no less than a total cooperative effort from the members of these professions. The petroleum and natural gas lawyer must diligently inform himself on the implications of engineering evidence. Otherwise he can be of little assistance to his engineering witness in a thorough, systematic and convincing presentation of his technical evidence. Conversely, the engineer must appreciate the concern of counsel that quasijudical hearings, whether technical or otherwise, be con-ducted in such a manner as to pre-serve some semblance of organized judicial procedures in the adjudication of property rights. The principal problems in unitization are the participation formula and the adjustment of investment in unit facilities. The equating of oil to gas, the effect of unit infill drilling, the relative values of producing zones and well productivity have •been controversial factors in several Saskatchewan units to date. Perhaps the most perplexing of these has been well productivity. While preserving current income, it may also preserve an ability to drain adjacent tracts plus an inequitable sharing of .reserves properly attributable to secondary recovery operations. However, inequity may also result in depriving an operator of the benefits accruing to him under competitive operations by virtue of his favourable reservoir position or his use of advanced production techniques. The Saskatchewan Oil and Gas Conservation Act has been construed by the Department of Mineral Resources as •completely negating any benefits inherent in the rule of capture when determining equities under unit operations. Under adjustment of investment provisions, large cash flows between owners of exploited acreage should be avoided upon the creation of a unit. These provisions should not deprive any company of the benefits it may have obtained under competitive operations in producing its fair share of the reservoir at a lower net cost per barrel than its competitors. Unitization should be concerned with physical conservation rather than in equalizing production costs as between operators.

Jan 1, 1960

By Augustus Locke

Jan 1, 1923

By E. R. Bauer

This report presents the results of a cooperative study between BethEnergy Mines Inc., Ebensburg, PA, a central Pennsylvania coal mining company, and the U.S. Bureau of Mines to investigate longwall development entry roof instability. In-mine mapping of geologic and deformational features was conducted to reveal the major ground control problems encountered during gate road development. In addition, mining-induced pillar load monitoring was used to indicate development loading on variously dimensioned gate road pillars and to determine if pillar yielding occurred. Finally, visual observations of a variety of roof control methods were used to determine the most effective support elements for controlling cutter roof failure.

Jan 1, 1992

By H. J. McQueen

Before 1950, hot working was simply deforming above the recrystallization point and gave a soft product compared to cold working. From 1960 onwards, improved testing in compression and torsion (stress, strain rate, temperature, quenching) provided valid specimens for microstructural analysis by polarized optical and transmission electron microscopy (TEM). Indeed, TEM was essential to uncovering the hot working mechanisms because it could distinguish between cold and hot substructures (dynamic recovery) in either initial or new grains (dynamic recrystallization). Over the years, teams at Concordia, McGill and UBC obtained NSERC support for students and equipment. CANMET built up a hot forming group having capabilities from high-rate cam-plastometer compression to rolling of experimental alloy billets; this was combined with latest metallographic instruments for fundamental research. Al alloys of every class (2000, 3000, 5000, 7000, 8000) were studied to understand the effects of solutes, precipitates, dispersoids and composites. The complex flow patterns in extrusion were clarified and modeled by finite element methods. Physical simulations of rolling schedules (up to 20 passes and reductions of 98%) by torsion provided evidence of microstructure development during both the passes and the softening intervals, thus clarifying development of texture in different alloys. The results frequently appeared in proceedings of Light Metals symposia and Canadian Metallurgical Quarterly

Jan 1, 2011