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By Akira Yazawa

The similarities and differences in copper, nickel and lead smelting processes are discussed based on the sulfur-oxygen chemical potential diagrams and the free energy minimization assessments using a thermodynamic software. The prominent features of copper smelting are ascribable to the fact that copper has a strong affinity for sulfur but weak for oxygen and the liquid phase immiscibility between Cu and Cu2S. During the oxidation of sulfides, nickel metal is not stable except at temperatures higher than 1500°C, well miscible with its sulfide, and is oxidized more easily than copper. Metallic lead looks as stable as copper during the oxidation of the concentrate but Pb and PbS. are much more miscible with each other and the vaporization loss is considerable. In the reductive smelting of oxides, the effects of oxygen potential and temperature on the copper contents in slag are not significant due to the monovalent character of copper and the reduction of copper content in slag is not easy in practice. The effect of the slag compositions on the oxidic metal contents of slag is much more significant for lead than either copper or nickel. Due to the immiscible nature between Pb and Fe, high grade lead bullion is easily obtained and lead is more tolerant to impurities.

Jan 1, 1998

By Douglas A. Grieg

THE EXCUSE for producing still another paper dealing with the oilfields of the Middle East is the overwhelming importance of this area to everyone, both inside and out of the oil industry. Figure 1 shows the area defined as the Middle East for the purpose of this paper. No description of what constitutes the Middle East is generally acceptable to everyone and, in fact, in many parts of the world it is referred to as "Western Asia". At the time ?the writer went to work as a geologist in the Middle East -this was in 1926 -there were just three known oilfields, namely, Hurghada in Egypt, Naft Khaneh in the Transferred Territories of Iraq, and Masjid-i-Sulai-man in Persia. Their combined producing rate at that time was around 100,000 barrels per day. Toda y, just thirty years later, some forty-two fields have been proven to exist, and a recent discovery in Syria -if commercial -may add one more to the list. Producing rates at the end of last year ( 1956) were approaching four million barrels per day. This sizable figure re presents nearly 23 per cent of the total Free World's production. What is more important still, something over 70 per cent of the Free World's proven oil reserves are known to exist in the subsoil of the Middle East.

Jan 1, 1957

By G. K. Derby

The Bureau of Mines studied the problems caused by airborne contaminants from welding exhaust in surface mining operations and investigated equipment designed to reduce existing hazards. Four commercially available welding-fume exhaust units were tested to determine their effectiveness. Results indicated that the four units had the capability of controlling airborne particulate concentrations and bringing them to within allowable exposure limits.

Jan 1, 1981

By C. Liu, G. Zhu, Y. Liao

"The effect of particle size on the flotation kinetics of a low-rank coal was compared using air bubbles and oily bubbles. Five kinetic models were applied to the data from the tests to derive the relationships between the flotation rate constant, the ultimate recovery, and the particle size fraction. The results show that oily bubble flotation (OBF) resulted in a lower ash content and higher combustible recovery than air bubble flotation (ABF), especially for the -125 ??m size fraction. It was found that the flotation of a low-rank coal in individual size fractions using air bubbles and oily bubbles can be best described by a first-order model with rectangular distribution of tendency to float and the classical first-order model respectively. OBF yielded higher ultimate combustible and ultimate ash recoveries. The flotation rate constants for OBF were higher in all the models except for the fully mixed reactor model. The ultimate recovery values and modified rate constants first increased and then decreased as the size fraction decreased. The trend of the flotation rate constants as a function of the size fraction was similar in all the models except for the fully mixed reactor model. IntroductionFroth flotation is a physical-chemical separation method that is widely used in coal beneficiation for the separation of fine coal particles from associated minerals in water slurries. Since the cumulative recovery of a component in the concentrate is proportional to flotation time, the flotation process can be considered as a time-rate recovery process (Emad, Mohammad, and Bahram, 2010). Therefore, the general mathematical flotation models that incorporate both a recovery and a rate function can describe flotation time recovery profiles.The kinetics of coal flotation, as a measure of coal recovery as a function of time, have been studied in detail by many researchers. Different kinetic models have been proposed and published in the literature. The order and the rate constant are strongly dependent on the flotation conditions, such as the particle size and size distribution, the bubble concentration, the reagent concentrations, and the operating parameters (Zhang et al., 2013). The particle size has been reported to affect the flotation kinetics to a great extent (Yoon, Luttrell, and Asmatulu, 2002; Ntengwe and Witika, 2011). Numerous researchers have studied the aspects of flotation kinetics while paying special attention to particle size (Meftuni and Ibrahim, 1997; Rubinstein and Samygin, 1998; Graeme, 2012). However, the effect of particle size on the flotation kinetics of a low-rank coal has been relatively little discussed."

Jan 1, 2017

Although mining, particularly of gold and coal, played a significant role in the development of New Zealand, from the time of the spectacular gold rushes of the 1860s its economic importance to the country as a whole has decreased substantially since that time. Gold, coal and non-metallic agricultural and industrial minerals have been found in economically significant quantities, however, the search for base metals has not been successful.

Jan 1, 1982

By S. D. Thompson

Several discrete-event simulation models have been developed for designing the conveying system capacities of underground coal mines. Most of these models require the use of a step-function approach to mimic the loading process at each conveyor loading point. Over the years, practitioners have generally employed one of three versions of the step-function approach. An important issue is how these three versions compare to each other in terms of simulated capacity requirements for belt conveyors. Another is-sue is how they compare to peak capacity design. This paper addresses these issues by statistically and quantitatively comparing their simulation results. The consequences and problems associated with using each version are also discussed and summarized.

Jan 1, 1997

By D. M. Watson

Mineral discoveries and subsequent extraction have led to the establishment of many small communities, some major towns and a few cities . In Canada, such developments have essentially occurred without benefit of long-range regional or local planning. In the past, this was not a cause for concern. Now, however, rising expectations and reorientation of social values have placed increasing responsibility on government and industry to ensure the long-term viability of communities and regions. Such responsibility means large investments by government in infrastructure and by industry in extractive and processing plants. Uncertainty in the interpretation of ore reserve estimates becomes a critical factor. The traditional methods of reporting reserves - "proven", "probable" , "possible" - may be useful in individual mine production planning, but they are inadequate for planning industrial and public infrastructure, The need for a better information base is critical, with clear and precise definitions of what is being reported, but we are a long way from achieving it. The challenge is therefore to develop a closer professional relationship between government and industry and to tie mineral development to long-range regional strategies.

Jan 1, 1977

By A. C. Gagnon, H. Saroglou

"The focus of this paper is on the analysis of geometrical discontinuity properties for the rock mass located within an open pit mine located in Western Africa. Discontinuity data were collected using various techniques including oriented core logging, borehole televiewer surveys, surface pit wall mapping and photogrammetry. The geological setting was initially studied prior to the data analysis to produce threedimensional ground models of the regional and mine site geology along with block diagrams illustrating predicted fracture patterns. Stereographic and statistical discontinuity data analysis of the geometrical properties of the rock mass was subsequently performed to identify unique structural domains throughout the open pit area. The discontinuity data collected throughout the studied open pit area were primarily discontinuity orientation, frequency and spacing and the investigation focused on the reasons for observed differences between the various data collection techniques. Stereographic analysis was used to assess the preferred geometry of discontinuities filtered by lithology, data collection technique, borehole, discontinuity type and pit wall (footwall or hanging wall). The observed fracture pattern is explained adequately by the geological setting. The need for accurate ground models for the design of open pit slopes is highlighted.INTRODUCTIONThe Tasiast Mine is an open pit operation located in north-western Mauritania, approximately 300 kilometres north of the capital Nouakchott. The Tasiast mine, which is owned and operated by Kinross Gold Corporation (Kinross), began commercial operations in 2008. The Tasiast mine is located in an area characterized by flat desert terrain within the western reaches of the Sahara Desert region. The current mine site includes mill buildings, shop facilities, waste dumps, tailings facilities and two main open pit operations (Piment and West Branch). The West Branch pit is the focus of this paper. The current open pit plan for West Branch indicates a final pit measuring approximately 2.5 km long by 1.4 km wide and 510 m deep."

Jan 1, 2015

By M. Kim, M. Ha

"The effect of red mud on the melting behavior of ferronickel slag was investigated by a laboratory-scale horizontal tube furnace. Melting and softening of slag samples fluxed with different amount of red mud was examined by in-situ visualization technique at temperature range from 1400 to 1550°C. FactSageTM 7.0 was used for the thermodynamic calculation of multi component system of ferronickel slag and red mud. Liquid phase area was extended to lower temperature by adding red mud indicating its suitability as a flux material. X-ray diffraction analysis confirmed the dependency of the phase changes on the red mud content. Microscopic observation by scanning electron microscope (SEM / EDX) clarified the phase transformations from olivine to spinel along with red mud additions.INTRODUCTION Ferronickel smelting by submerged arc furnace (SAF) is an energy intensive process performed at high temperature range 1500–1600°C. During the smelting process of saprolitic nickel laterite ore with a nickel content of 2.2–2.3 pct, a large quantity of ferronickel slag is being produced that account for 97 pct of ore charged. To achieve ferronickel grade of 15–20 pct Ni, electrical energy of 80 to 85 MW is used for the melting and reduction of nickel oxide (NiO) and iron oxide (FeO) in the ore (Rodd et al., 2010). Unreduced components, mostly MgO, SiO2 and partly FeO are removed from the furnace in a liquid slag form by a tapping operation. Due to the high melting temperature, forsterite (Mg2SiO4) based slag containing approximately 10 pct FeO requires typical process temperature of 1600°C. Flux in metallurgical process is a medium that decreases melting and operating temperatures while it increases fluidity of the liquid slags. Calcite and fluorite are examples of flux materials used for the ironmaking, steel refining and continuous casting process. Oxide systems based on CaO - CaF2 - SiO2 - Al2O3 - MgO cover most of the slag composition in ferrous metallurgy accordingly. Crucial operating factors for ironmaking and steelmaking slags are basicity (typically CaO/SiO2 ratio), viscosity and impurity levels. These are extensively controlled by the fluxes. General metallurgical fluxes such as limestone, dolomite and calcium fluoride are abundant in nature and supplied to steel mills at low prices. Meanwhile, in copper flash smelting process, silica is supplied with copper concentrate to remove iron oxide (FeO) generated from sulfide oxidation. FeO - SiO2 binary system formulates eutectic area at 25–38 pct of silica that has low melting temperature below 1205°C. Fayalitic system (Fe2SiO4) that has low viscosity (0.1 Pa·s) (Park et al., 2011) facilitates easy separation of slags from molten sulfide mattes. Recently, copper plants actively utilize recycled raw materials as a flux. Various recycled glasses are ground and fed to copper smelting process as a partial replacement of silica ore. Applying industrial wastes to smelting processes is advantageous since the operators can reduce the production cost remarkably. Not to mention the consumption of recycled materials can ultimately minimize the environmental risks and the waste management costs. The authors, therefore, investigated the reasonable waste materials that can be effectively used for ferronickel smelting process. Prerequisites for potential fluxing materials are non-recyclable property, low transportation cost and excellent performance as a flux."

Jan 1, 2017

By J. C. Murray

Introductory: In dealing with a topic so large, one that involves such a multiplicity of details, and that also has certain controversial aspects, it is quite impracticable within the limits of this article to touch upon many most interesting phases and incidents. Also, to bring out the actual truth, it is necessary to make certain categorical statements. The writer believes that all such statements made here-under are supported by facts. Again, however, it is out of the question to cite all the proof. The writer, therefore, will gladly answer any pertinent criticisms or questions and thus supplement the unavoidable brevity of this paper. Controversial points will take care of themselves. Historical: For present purposes the history of gold mining in Nova Scotia may best be summed up in a very few paragraphs, in some of which the writer quotes freely from recent reports compiled by himself. The first material discovery of gold was made in the year 1860. As this and rapidly succeeding discoveries were looked upon as bonanzas, the claims were fixed at a size of 20 by 50 feet, and a yearly rental of $20 was charged. Later the claims (areas) were increased in size to 50 by 150 feet. In the year 1866 a temporarily successful company, so we are informed by a contemporary writer, owned a mill and mining plant worth $6,000. As this fact is cited with admiration, it is apparent that most of the mining and milling must have been done in a very primitive manner indeed.

Jan 1, 1926

By P. Huang

Chitosan was tested as a depressant in the differential flotation separation of chalcopyrite and galena. The micro-flotation results showed that chitosan selectively depressed chalcopyrite while galena was floated by potassium ethyl xanthate in acidic solutions. With the addition of 0.67 mg/L chitosan (CT) in the slurry of chalcopyrite-galena mixtures at pH 4, the recovery of galena was 95% while that of chalcopyrite was 30%, indicating that chitosan could potentially be used in differential Cu-Pb sulfide separation. Furthermore, the study of chitosan with either low (LCT) or high molecular weight (HCT) in the differential flotation indicated that better separation was achieved by the chitosan with lower molecular weight (LCT). ToF-SIMS was employed to study the distribution of CT on the surface of chalcopyrite-galena mixtures by ion mass spectra analysis and surface imaging, which showed that CT adsorbed heavily on chalcopyrite but barely adsorbed on galena. The positive ion ToF-SIMS spectra provided information on the surface composition of chalcopyrite-galena mixtures after CT treatment. It appears that the selective adsorption of CT on chalcopyrite was originated from the strong interaction between NH3+ and Cu. Keywords: differential flotation, micro-flotation

Sep 1, 2012

By J Kwak

Driving sustainability concepts and practices into the heart of the design process is the key to achieving a successful, sustainable plant design. Engineering design practices, tools, systems and methodologies should be prepared around true eco-efficiency parameters, adopt wholesystems-thinking and consider life-cycle impacts for the design task. Experience dictates that the application of sustainable plant design practices is most likely to succeed if: The principles are well documented and explained. All stakeholders agree on what sustainability means. Sustainable plant design is treated as a core process. The principals of sustainable plant design are equally applicable in brownfield and Greenfield environments. Although brownfield situations provide the designer with less latitude for change, these types of projects do allow easier measurement and demonstration of relative impacts. This paper further develops the above points by drawing on case studies from HatchÆs repertoire.

Jan 1, 2004

By Kaioeng Wang, Qi Liu, Yahui Xiang

"In the differential metal sulfide ore flotation it is desirable to replace the toxic inorganic depressants with environmentally benign chemicals. Chitosan, as a natural and non-toxic polymer, has been proven to be an efficient depressant for chalcopyrite while allowing galena to be floated by xanthate collectors. However, the poor solubility of chitosan limits its potential applications as the flotation could only be carried out at about pH 4 where chitosan is soluble. A carboxymethyl derivative of chitosan, named N-carboxymethyl chitosan (N-CMC), was synthesized by substituting the amino groups of chitosan with carboxymethyl groups. The substitution significantly improved the solubility of chitosan. The structure of N-CMC was studied and compared with chitosan via Fourier transform infrared spectroscopy (FTIR). Flotation tests were performed on single minerals and mineral mixtures (with weight ratio of 1:1) with the addition of appropriate amount of potassium ethyl xanthate (KEX) and N-CMC. The solution pH was varied from neutral to alkaline. The flotation concentrates and tailings were collected and analysed for the contents of copper and lead. FTIR measurements showed that new peaks of C=O stretching of -COOH and N-H deformation of -NH- appeared in N-CMC, which indicated that the carboxymethyl groups were introduced and the amino groups were the sites for the substitution. Flotation results indicated that N-CMC could depress either chalcopyrite or galena depending on the pH. The results were not affected by the sequence of KEX and N-CMC addition. Therefore, N-CMC is potentially useful in Cu-Pb sulfide separation following a bulk Cu-Pb flotation. The N-CMC was also found to have surface cleaning functions, and was able to remove contaminating copper ions from galena surfaces. Therefore, its application in sulfide ore flotation is expected to be more robust than the original chitosan."

Jan 1, 2014

By J E. Powalisz

"The application of automated sampling techniques can help to provide a representative sample of process fluids and slurries that provide data for controlling process, custody transfer and quality assurance and quality control purposes.The automation of sampling provides a more consistent and reliable sampling process and eliminates many of the human-induced errors. Automated sampling can also provide a higher degree of safety in the plant/processing environment as well as better bottom-line results.Automated, fixed volume samplers can provide a very representative sample by integrating many small ‘grabs’ of sample from a process. Automated samplers can be controlled in a variety of ways to optimise the sampling process, including:cycle ratedwell timetotal volume.Properly selected and applied, an automated sampler can effectively isolate the operator from the process fluid during sampling and, to a great degree, during sample container collection.A variety of materials of construction, including seals, are available to handle demanding mining applications. Alloy 625, alloy 2205, AL6XN® and even certain plastics are used successfully in mining slurry applications.This paper explores the application of automated, fixed volume, batch style samplers in copper/nickel and gold processing, specifically pregnant leach solution and extraction fluids.Several specific field applications are discussed, including process installation details, hardware and operation.CITATION:Powalisz, J E, 2014. The application of automated samplers in copper/nickel processing, in Proceedings Sampling 2014, pp 35–42 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 29, 2014

By R. Hurman Eric

The electrode in a slag-resistance electric furnace is the central factor in the design and operation of the furnace by its role of conveying the smelting power, i.e. heat needed for the operation. The control parameters are the size and positioning in the slag bath which are defined by slag resistivity, furnace resistance, cell constant and power input sequence all of which are closely interrelated. The flow of heat generated by the electrode current determines the energy distributions and thus the furnace dimensions. Heat flow models concerning vertical, horizontal and combined two-dimensional flows are discussed. All these considerations are based on the experimentally determined slag properties such as its resistivity.

Jan 1, 1995

By I. D. Reznik

The flowsheets of converter matte production from sulphide copper - nickel and oxide nickel ores on Severonickel and Yuzhuralnickel integrated ,;corks are given. The cobalt behaviour in electrosmelting and autogenous ore smelting, converting and converter slag cleaning is observed. A list of acticles published in the 80 th is given.

Jan 1, 1993

By C. L. Lin

The characterization of rare-earth resources in 3D is now possible using high-resolution X-ray microtomography (HRXMT) to describe ore texture and mineral phase composition. In addition, detailed texture analysis, including grain exposure and mineral association, can be described. Preliminary examination of a sample of Mountain Pass ore is reported to describe the spatial distribution of the mineral phases (calcite, barite and bastnaesite), particularly the grain size distribution of bastnaesite. The examination includes analysis of selected particle size classes to determine the appropriate size for liberation of the rare-earth mineral bastnaesite. Good liberation is expected to be achieved if the material is ground to a top size of -150 µm.

By David, Cole

THE years 1914-15-16 were a pioneering period in mining, milling, and copper metallurgy generally. It was uncertain just what path the crushing, grinding, and concentrating processes would take. This situation was quite embarrassing to the directors of some of our large porphyry properties, then being equipped for production. Inspiration had already made several designs for its proposed 15,000-ton concentrator, incorporating in them the latest devices developed in the art of gravity concentration, only to have the work vitiated by the rapid march of events. In a little improvised plant, built on ground that is now in the crater of subsidence over the Inspiration- Miami orebodies, flotation was being experimentally ' applied to Inspiration ore by Minerals Separation engineers in 1914, with results indicating that this process would be of major importance in the concentration of the sulfides. How best to apply it, and especially how to crush and grind the ore to the very much finer sizes required for the new process, was a serious question, properly to be answered only by doing it, in full- sized machines, under regular 'operating conditions.

Jan 1, 1931

By A. S. Baillie

THE subject of taxes appears to engage our attention altogether too lightly. At least it would seem that, notwithstanding the increase in the cost of government, and its concomitant increased taxation, little constructive work is being done with a view to solving the problem of increased taxes. I believe that the inattention of the public generally to the subject of increased taxation is due largely to the fact that shareholders are not advised of the amount of taxes paid by industry. Were companies to advise their shareholders the amount of monies paid or payable out of each year's earnings for taxes in one form or another, and were such amounts compared with the amounts available for distribution to shareholders, the effect would be a general demand for more equitable taxation methods. While I am not unmindful of the burdens and inequities in taxation confronting industry generally, I believe that the mining industry in this Province does not fully appreciate the burden represented by the costs of taxation. My reason for this belief is based partly upon1the fact that no serious effort has so far been made to devise some means By which the mining industry in British Columbia might protect itself against the ever-increasing burden of taxation. In addition to this fact the widely diverse nature of mining in British Columbia makes the accumulation of comparable data a problem which, so far as I can ascertain, has never been attempted in a manner which would be authoritative. It should not be necessary to cite the effects of this burden upon any one mining company or upon any branch of the mining industry, such as coal mining, placer mining, base-metal mining, or the precious-metal mines. In my opinion, the operation of our mines by large corporations is conducive to the payment of taxes with much less protest than would be the case were the taxes being taken out of the earnings of just a few partners or a very few shareholders. We appear to be too unmindful of the taxes, paid by mining companies, of a kind that are not so prominently brought to our attention as are the taxes which are calculated upon the taxable income of the company at the end of its fiscal year. British Columbian mining companies pay many other taxes besides those which are calculated upon taxable income. Among these are school taxes, property taxes, gasoline taxes, mineral taxes, coal royalty, to say nothing of fuel-oil tax, sales tax, and excise taxes.

Jan 1, 1935

By M. Rieber

The recent history of the mercury market results almost entirely from U.S. Government actions. Its derived demand has been curtailed by U.S.E.P.A. mandates; its supply has been augmented by U.S.D.L.A. controlled stockpile releases. The resultant prices have altered its market structure, impacted mercury mining, refiners and recyclers, and affected international production and markets. From a marketplace product mercury is rapidly becoming a disposal problem. Other minerals may follow in its wake. This paper reviews developments in demand, particularly in relation to environmental constraints. Supply side impacts are considered. The impact of stockpiles, both as a market overhang and as a potential supply is reviewed. Government stockpile disposal activity is emphasized, but the size, estimated disposal rate, and quality of the private stockpiles are considered, as is the potential availability of additional material from shut-in mines.

Jan 1, 1995