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An important problem in mine operations is the classification of material as waste, low-grade stockpile, and ore. This classification must often be made with blasthole data that are widely spaced and that have sampling errors. Geo-statistical simulation techniques combined with basic economic principles allows a procedure for classification that maximizes expected profit. Geostatistical simulation methods (Gaussian, indicator, or annealing-based) allow the integration of hard and soft data in the creation of alternative, equally-probable, realizations of the mineral grade(s). At each location, for each realization, we calculate the "profit" if the block were to be classified as ore or waste The optimal classification is the one that maximizes expected profit (a Maximum Profit Se-lection (MPS) procedure). We discuss the theoretical justification of the method and implementation details. The use of blasthole data from different types of mineral deposits, that is, different levels of continuity, is considered. We also show the efficacy of the procedure with different levels of sampling error. The increased revenue due to the MPS procedure and improved sampling is shown. We show the geostatistical simulation procedure and the uncertainty in block grades that result from incomplete and imperfect sampling. The optimal classification is presented. Optimal block classifications are transferred to realizable dig-limits by hand-drawing polygonal boundaries. We compare the results of the proposed method to classification based on kriging. Limitations and areas of future work are identified.

Jan 1, 1999

By C. R. Powell, W. H. Maher

"This paper presents a short history of the development of milling at Buchans, Newfoundland, and a description of the operation.History and DevelopmentTHE original ore discovery was made at Buchans in 1905 by Matty Mitchell, a Micmac Indian who was prospecting for The Anglo Newfoundland Development Company, which company was then preparing to build a paper mill at Grand Falls, some 50 miles east of Buchans. A development program, initiated in 1906, was terminated in 1911 because of metallurgical difficulties. Intermittent testing was carried out by The American Smelting and Refining Company, and in 1925 a satisfactory method of concentration by flotation was found. Following this, intensive geophysical reconnaisasnce, succeeded by diamond drilling, uncovered two additional orebodies similar to the original discovery at Buchans River."

Jan 1, 1966

By T. Karlkvist, H. R. Kota, F. Andreas, B. I. Pålsson

"Separation of different calcium minerals have long been an interesting and challenging problem. In this investigation calcium mineral separation is examined by: microflotation, zeta potential measurement and adsorption, using novel collectors having two functional groups instead of one. In theory, by varying the distance between the functional groups, it could be possible to preferentially target one calcium mineral by matching the spatial distance between the sites on the mineral surface. In this investigation two new surfactants have been tested to estimate their ability to float apatite and/or calcite. Preliminary findings show that an increase in distance between the functional groups favors one mineral over the other, and this might be due to differences in the mineral surface structure. INTRODUCTION Apatite is a strategically important mineral which has both great value for industrial use as a precursor to phosphoric acid; and in the agricultural industry as an important source of phosphorous in fertilizers. This has led both the European Union and the United States to recognize it as an important resource for the future. Currently there is no lack of apatite in the world, but it is important to develop the beneficiation to ensure future supply. A common problem in apatite flotation is the selectivity towards calcite, which it is commonly associated with. Although calcite is an important industrial mineral its abundance makes it not usually worth to extract from apatite ores unless it is easy to separate1,2. Both apatite and calcite are semi soluble minerals with calcium as one of their constituents. The most common way to separate apatite and calcite is to use flotation. A process that involves making the mineral particles to extract from the system hydrophobic by adsorbing a collector on the mineral surface. One way to study collector adsorption on a mineral surface is by zeta potential measurements. The zeta potential is the charge at a slip plane a short distance from the surface. By measuring the zeta potential with and without the presence of collector it is possible to investigate if the collector is present at the surface or not, a change is indicative of collector adsorption. The zeta potential of fluorite, apatite and calcite without collector can be seen in Figure 1. The small difference in zeta potential between apatite and calcite shows the similarity in their surface properties and gives an indication of their separation difficulty. One additional problem with semi soluble minerals is their tendency to slightly dissolve in the pulp and thereby change the ionic composition of the solution. This makes separation and research problematic as the freed ions may readsorb on the mineral surface and interfere with the collector adsorption on the mineral surfaces3–5."

Jan 1, 2016

By John Nagy

Limited experiments in the laboratory with specimens of mine rock from a Virginia bituminous coal mine indicate that natural gas-air mixtures can be ignited by sparks generated by rubbing friction of sandstone against sand-stone, shale against sandstone, sandstone against (roof-bolt) steel, and shale against steel. Such sparks, generated during a roof fall, may have initiated a recent gas explosion in this Virginia mine, although this cannot be stated with certainty. No ignitions of gas were produced by sparks or heat generated by impact friction between mine rocks or steel, during tension breaks of roof bolts, or by pull tests of roof bolts through their washers and roof plate. However, this negative result of limited experiments does not preclude the possibility of gas being ignited by these conditions.

Jan 1, 1960

By M. P. Hoffman

The U.S. Bureau of Mines is developing a roof bolter with a computer-controlled drill head that will increase the safety of roof bolting in underground coal mines by allowing miners to be relocated to a safe area. To ensure secure anchorage, acceleration and strain data are broadcast from an instrumented drill steel to a data acquisition system. These data are analyzed, correlated, and transformed to pro-vide information about roof strata, then are sent to a supervisory computer executing National Institute of Standards and Technology's real-time control software. The supervisory computer sends setpoint commands to proportional-integral-derivative control loops to control drill thrust, position, revolutions per minute, and torque.

Jan 1, 1994

By Donald Bruce, Alex Reeb, George Filz, Wesley Schmutzler, Mitsuo Nozu

"One million seven-hundred thousand cubic yards of deep mixing were installed to support an elevation raise of an earthen levee known as LPV 111, which is located in east New Orleans. The deep mixing was done by two contractors using somewhat different technologies, but producing elements of the same size. As part of the quality control and quality assurance program, 507 deep-mixed elements were cored and 5,082 specimens were strength tested in unconfined compression. This paper presents data from the coring and testing program. Very high percentages of the core run lengths were recovered, except during one period for one mixing technology. The coring methods are described, and reasons for the isolated episode of low recovery are discussed. The strength data show that the specification acceptance criteria were satisfied. Statistical parameters of the strength data are provided, and trends between strength and the following factors are discussed: depth, soil type, binder factor, and project-specific experience. Photographs of longitudinal cuts of core specimens are presented. Important lessons learned from this unusually large project are described.INTRODUCTIONThe Lake Pontchartrain and Vicinity Hurricane Protection system included a project known as LPV 111, which is an approximately 5-mile long segment of levee and floodwall located in east New Orleans along the Gulf Intracoastal Waterway and adjacent to Bayou Sauvage National Wildlife Refuge (Cali et al. 2012). The majority of the project consisted of a raise of an existing earthen levee from an existing crest elevation of about 18 ft to a new crest elevation of about 28 ft. The underlying soils were weak and compressible, providing inadequate support for the raised levee. Ground improvement in the form of deep mixing was selected to provide the necessary stability and settlement control for the raised levee.The US Army Corps of Engineers (USACE), New Orleans District, was the governmental agency in responsible charge of the project, including approval of design, construction, and payment. The lead designer was URS Corporation, and the general contractor was Archer-Western-Alberici (AWA), working in alliance with TREVIICOS South (Trevi), who, together with Fudo Construction (Fudo), performed the deep mixing.As part of the quality control and quality assurance program, over 500 production deep-mixed elements were cored, the cores were carefully logged, and over 5,000 unconfined compression tests were performed. In addition, selected specimens were carefully photographed before and after longitudinal saw cuts to expose the interior of the specimens. This paper provides a summary of the coring and testing performed on the production deep-mixed elements."

Jan 1, 2015

By S. Kelebek, E. Yalcin

This paper reports bulk flotation characteristics of a pyritic gold ore sample from the Barry District, Quebec using isopropyl and amyl xanthates. The ore sample was highly floatable with particles showing tendencies for self-aggregation that was most apparent in the first stage of flotation. A possible reason for this is discussed. The gold concentrate grade-recovery performance with respect to the particle size is presented for the rougher-scavengers as well as for the cleaners. The effects of copper sulphate as an activator, fuel oil and NaSH as a sulphidising agent are discussed along with the recovery by size behaviour.

Jan 1, 2011

By Jiang Su, Alan Bloodworth

"Composite sprayed concrete lining (SCL), consisting of two layers of permanent sprayed concrete separated by a layer of spray-applied waterproofing membrane, represents the latest development in SCL tunneling, but presents several challenges to designers. This paper aims to address the following issues: (1) how to simulate composite action, (2) behavior of a composite SCL tunnel, and (3) how to utilize composite action to achieve lining thickness efficiency. It firstly sets out the background to the composite SCL concept, and then presents a strategy for numerical investigation. The main part of the paper is the presentation and discussion of the simulation results, focusing on the lining deformation, load sharing and the safety margin of both linings. Interface stresses are also examined. It is found that significant secondary lining thickness reduction may be achieved by utilizing composite action. Challenges for the design of composite SCL tunnels are briefly discussed at the end. INTRODUCTION Sprayed concrete lined (SCL) tunnelling has seen rapid development over the last twenty years in the UK (Su 2013). One of these developments has been the replacement of traditional sheet membrane and cast in situ secondary lining with innovative spray applied waterproofing membrane and sprayed secondary lining system, which has been adopted in recent major projects, such as Crossrail (Pickett 2013), and brings many benefits to the construction (Dimmock et al. 2013). The combination of sprayed primary lining, spray applied waterproofing membrane and sprayed secondary lining is perceived to provide a structurally efficient lining system that outperforms the traditional lining system, which consists of sacrificial primary lining, sheet waterproofing membrane and cast in situ secondary lining. The claimed benefits in structural performance arises from the composite action between the sprayed primary and secondary linings via the spray applied waterproofing membrane, which produces a much stiffer cross-section and therefore a more efficient use of materials. Early investigations on the design of composite SCL tunnels were carried out without (1) definite and reliable long-term interface parameters, (2) a verified numerical modelling technique, or (3) consideration of different stress histories between primary and secondary linings (Thomas and Pickett 2011, Marcher et al. 2011). This paper reports the findings from a numerical parametric study on a typical composite SCL tunnel with varied secondary lining thickness. The results show that the true benefit of composite lining arises from the optimisation of the lining thickness (stiffness) ratio between the primary and secondary linings to achieve secondary lining safety and thickness efficiency at the same time."

Jan 1, 2016

By J. A. Barsin

Stationary air pollutant sources established prior to the New Source Performance Standard (NSPS) are not, at present, subject to federal emissions regulations. However, proposed legislation could require many existing stationary sources to reduce emissions. This paper will report upon the laboratory work undertaken to date by B&W to commercialize a limestone system for sulfur capture both in pulverized coal and cyclone coal-fired utility boilers. Updates will be provided on the US EPA/State of Ohio/Ohio Edison/B&W sponsored pulverized coal full-scale limestone injection demonstration, and on the EPRI/Baltimore Gas 8 Electric, Atlantic Electric/B&W sponsored laboratory-scale cyclone coal limestone injection investigations.

Jan 1, 1986

By Matthew Clay, Colin Chambers, Susan Hookham

Opencast (quarries) and underground mines around the world use blasting methods to mine valuable ore. Traditional blasting systems use technologies such as electric delay detonator systems (developed in the 1950s) and non-electric detonator systems (developed in the 1970s) to initiate a detonation train to blast rock more effectively, and so retrieve valuable product more efficiently. However, the lack of precise control over blast timings with these approaches can result in undesirable outcomes such as significant flyrock, excessive ground vibration, uneven grade of rock and misfires (in which sections of the blast can remain unfired). The development of Electronic Initiation Systems (EIS), first used in the 1990s, introduced a higher level of control over the blast. These systems greatly reduce the negative issues associated with blasting. However, this precision introduces complexity, and with this complexity comes difficulty in demonstrating the predictability, safety and reliability of such systems.

Jan 1, 2017

By A. Broussaud

An original methodology has been developed for steady state simulation of selective grinding and mineral liberation in rod and ball mills. Three fundamental aspects of the methodology are presented successively : modeling ore texture, modeling grinding and its selectivity, and modeling mineral liberation. The methodology for modeling ore texture includes the conversion of 2D data into 3D reconstructed information and the use of the BILCO coherent material balance software. The models for grinding Simulation are classified into three levels, corresponding to three levels of available experimental data. All models account for grinding selectivity and for variations of engineering para-meters and operating conditions. An algorithm has been introduced to forecast mineral liberation, compatible with accurate simulation of selective grinding, which generates reasonable results.

Jan 1, 1987

By J. Sachweh

The last few years have shown a significant increase in the demands for fine products, which means everything under 10µm. There are more and more applications requesting extremely fine ground powders leading to the development of several milling machines which are better adapted to the new products. Cost saving machinery is important for the worldwide competition. Especially the energy consumption is extremely important for any fine ground product. A worthwhile field for mechanical engineering companies is the dry milling machinery as there are not as many solutions available compared with wet milling applications. In many cases wet mil-ling is the only solution to reach the requested quality, but there are also a lot of applications which can be performed in a dry way on the premise that the right mill and classifier are available. Dry milling permits to save energy and allows to influence the particle size distribution more easily, as a classifier can be used in that case. This will significantly reduce production costs and can enable the production of new products with better properties. The Tower Mill is well-known already in the field of wet grinding. Recent research work and end user reports have shown clearly that this mill has a lot of advantages compared to a ball mill. Up to now this advantage is limited to wet grinding as only few mills have been used for dry grinding. There is no doubt about the efficiency of dry grinding, but new and improved feeding and discharg-ing systems have to be developed in order to enable the full range of its advantages. Especially the high production capacities are a challenge for mill and classifier designers. The Tower Mill with its special grinding mechanism allows to cope with very high feed rates, because machines with more than 1 MW are available. Improved grinding efficiency will decrease the circulation load through the classifier and also lead to smaller classifier sizes. Together with im-proved mills the classifier can work more efficiently because the feed material is finer. Results of a test center plant production will be shown together with a comparison between stan-dard machinery and the MaxxMill®. Preferential applications for each mill will be explained.

Jan 1, 2014

By Dean Treweek, Anthony Harding

"Creating stable, safe, constructible and cost effective support to openings in segmental linings is often an important component of successful delivery of a tunnel project. The many constraints on successful implementation include operational, spatial, geotechnical, structural, and constructability. Failure to address these adequately can lead to significant impacts on cost, schedule, and safety. With reference to past project experiences, this paper provides a guide to the most commonly deployed solutions and their pros and cons to help designers quickly identify the most appropriate solutions for a particular project, or act as a starting point for developing new and/or project specific solutions. It highlights the challenges that designers and contractors must address together for successful support of tunnel openings, and the constraints that arise. It then describes the common structural forms of support, and how each form can mitigate the constraints, allowing an effective opening support system to be implemented. INTRODUCTION While only a small portion of the total excavated volume of a typical tunnel, cross passages are often one of the most complex elements of a bored tunnel to construct. Cross passages in soft ground typically involve ground improvement, groundwater control, and multiple temporary support measures to ensure safe construction in ground that has been overstressed due to the construction of the running tunnels. Permanent lining construction requires careful detailing of waterproofing and reinforcement to support both long term ground and water loads and support the broken out rings of the main lining. While there is not a great deal of literature specific to cross passage construction, the main issues are discussed in some detail by Lawrence and Taylor (2011). However, the temporary support of the running tunnel segmental linings during cross passage construction is not always given the attention it deserves. The authors have been unable to find much literature on the design of such systems, much less the considerations that have led to a particular solution. Lawrence and Taylor only mention two potential methods of support. It may be easy to dismiss the opening support as an inconsequential item, but selection of the wrong support type can have significant impacts on both cost and schedule."

Jan 1, 2016

By A Jewbali, R Perry, R Inglis, L Allen

"The use of conditional simulation to characterise mine plan uncertainty is increasing for the assessment of risk in mining projects. While the development of grade uncertainty profiles is relatively straightforward and can be validated using standard geostatistical techniques, the addition of geological uncertainty to evaluate total risk remains problematic. Some of the problems associated with geological uncertainty methods include the clustering of data in favourable geologic units, difficulty in training image definition and the inability to address change of support issues for categorical variables. Despite these obstacles, the importance of geological uncertainty as a contributor to total uncertainty has prompted Newmont to explore and evaluate the use of various techniques (and combinations of techniques) on different deposit types.Two orogenic deposits of different geological complexity were selected for the study: Subika, a shear zone-hosted deposit, and Merian, a deposit containing gold mineralisation associated with quartz vein zones and stockwork within which are found higher-grade quartz breccia zones. Newmont trialled various categorical simulation approaches to determine the applicability of these methods for each deposit type and the effect of parameter choice on the width of the uncertainty interval. Some of the techniques that were trialled include multiple point statistics methods, sequential indicator simulation using local probabilities as well as variations of these methodologies.The goals of this study included: gaining an understanding of which techniques may work best in which deposit types gaining an understanding of the intricacies of each method gaining an understanding of the effect that each method has on total uncertainty analysis.This paper presents a comparison of the various techniques and makes recommendations for their use in uncertainty analysis.CITATION:Jewbali, A, Perry, R, Allen, L and Inglis, R, 2014. Applicability of categorical simulation methods for assessment of mine plan risk, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014, pp 85–98 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 24, 2014

By Nordau R. Goodman

"IntroductionTHE HISTORY of Nova Scotia's gypsum industry goes back about two hundred years. The extensive deposits found in the Windsor formation, which is Lower Carboniferous, were the first discovered in North America and were known to the earliest .settlers. There has been a steady increase in production from these beds, except for minor setbacks in years of wars and depressions, but at the same time there has been a decrease in the number of operating quarries. This decrease reflects the change from the days of horse-and-cart recovery to the modern, large-scale, highly mechanized operations. In the beginning, almost any outcrop could •supply the tonnage requirements and the most •convenient were selected, but the millions of tons needed to meet present-day needs are not easily found.Despite the size and importance of the Nova Scotian deposits there has been little detailed geological work. Sir Charles Lyell, in 1843 ( 10), established that the beds are Lower Carboniferous and this was confirmed by Sir William Dawson (3) a .few years later. Both Lyell and Dawson agreed the calcium sulphate beds were an original part of a bedded series .but did not consider they resulted from a concentration of sea water. Lyell reached the conclusion that the gypsum was related to volcanic action in the form of heated vapours or hot springs. Dawson believed it was formed by the action •of sulphuric acid on calcium carbonate. The acid, derived from the oxidation •of iron pyrites which was abundant in the older formations, was carried by rivers into basins which were rich in shells."

Jan 1, 1954

Rosebery Mine is situated on the west coast of Tasmania and is AustraliaÆs largest volcanic-hosted base and precious metals deposit (zinc, lead, copper, gold and silver). The milling operation has been producing zinc, lead and copper concentrates continuously for over 100 years. RoseberyÆs long life demonstrates the operation to be high grade, and high margin, capable of operating through several commodity price cycles. Paradoxically, throughout this long history the ælife-of-mineÆ as defined by proven and probable reserves has been short. Zinifex has demonstrated its commitment to discover the future of Rosebery with the growth project æProject HorizonsÆ. The aim of the project is to extend the life of mine beyond 2020, with an additional exploration expenditure of $19 million over three years. Despite the maturity of the deposit, early success has confirmed the potential with the discovery of new resources. Mine planning strategic studies are challenging established paradigms of mine production, throughput rates and metal cut-off grades. Discovering the optimal process rate for Rosebery, by examining the æHill of ValueÆ and underground mine optimisation is proving critical to the best exploitation of RoseberyÆs rich resources. The promise of finding a mine within a mine is being realised, with new lenses being delivered by exploration success and real grade/tonnage options optimised through dynamic mine planning. The future of Rosebery is co-dependent on these two areas of discovery. This ensures capital expenditure decisions are informed, to secure the next 20 years of wealth creation and beyond.

Jan 1, 2008

By G. W. Grove

Coal-mine officials and those who are preparing to become officials should be familiar with the instruments and devices that are employed rather commonly in and around mines and should know how to use them with safety and efficiency. Among these axe instruments and devices used in determining the pressure, velocity, volume, and certain other conditions of ventilation and in detecting the more common mine gases, such as methane, carbon monoxide, and hydrogen sulphide, or a deficiency of that very important agent, oxygen. Water gages, anemometers, barometers, psychrometers, flame safety lamps, lamp-testing boxes, and methane, carbon monoxide, and hydrogen sulphide detectors are described and their use and operation discussed in this paper.

Jan 1, 1938

By M. Fan, Z. Long

"This paper presents some studies on recovering valuable elements from Chinese coal by-products, including coal combustion fly ash, stone coal ash, and coal flotation tailings. Both commercialized technologies and economic potential recovery methods are described in this study. Magnetically stabilized air-dense medium fluidized bed separation, tribo-electrostatic separation, froth flotation, and hydrometallurgical methods are discussed in recovering various valuable elements in Chinese coal by-products from different coalfields. These valuable elements include iron, carbon, aluminum, rare earth elements, lithium, gallium, germanium, uranium, titanium, scandium, silicon, vanadium and phosphorus, etc. The ultimate goal is to fully utilize all valuable elements in coal by-product. Each component within coal by-product should be efficiently segregated to its highest value. INTRODUCTION Coal is mainly composed of energy-producing elements carbon and hydrogen. In addition to these elements, coal usually contains many other valuable elements, including iron, aluminum, silicon, rare earth elements, lithium, gallium, germanium, vanadium, uranium, titanium, scandium, and phosphorus, etc. These coal-associated elements are significantly enriched in coal combustion by-product fly ash because of majority of main components, carbon and hydrogen elements, being removed. Table 1 provides the chemical composition range of the main elements oxides in 12 Chinese fly ash samples collected from coal power plants located in Northeast China, Northwest China, Southwest China, and Southeast China. It can be seen from Table 1 that the major mineral components of different ashes are similar, but the bulk chemistry of different fly ashes may vary widely due to the changes of ratios of the mineral components in different coals. The major mineral components in various Chinese coal combustion fly ash are silicates, iron oxides, and unburned carbon."

Jan 1, 2017

By Wu Jian-tao, LI Guo-wei

"The Cement Mixing Pile (CMP) quality assurance assessment is an important programme in evaluating the efficiency of foundation improvement. Coring is the current specified method of quality assessment in China which has the shortcomings of long cycle, high cost and low efficiency. The field and laboratory test show that the regular cone penetration test can only detect maximum of 4m of effective detection depth in CMP. In contrast, the method of cone penetration test in the reserved hole can detect the quality continuously along the pile at any depth. The tip resistance of reserved hole penetration in the 7th day has good linear relationship with unconfined compressive strength in the 28th day. The slope of linear relationship decreases with the increasing of clay particles content.INTRODUCTIONThe method of Cement Mixing Pile (CMP) is often used to improve soft soil foundation in highway construction, with the major purpose of reducing settlements under embankments (Bruce et al., 2000),which is a form of what is known as the Deep Mixing Method (Bruce et al., 2013). The CMP technology spread quickly in China in the 1980s. CMP quality assurance assessment is an important programme in evaluating the efficiency of foundation improvement. Coring is the current specified method of quality assessment in China (China Academy Of Building Research, 2002). The method of Coring is perceived in some quarters that samples will provide lower strengths given the distress caused to the core during drilling and extraction (Bruce et al., 2002).The cone penetration test CPT can provide continuous measurements of the penetration resistance, sleeve friction at the tip of the probe, which has advantages of simple operation, low cost and high efficiency compared with coring. However, CPT tests have not been established to assess CMP in Sweden because of difficulties in maintaining verticality (Larsson, 2005). In Finland and Norway, however, CPT tests are commonly used (Halkola, 1999). One of the disadvantages of CPT is the tendency of the cone to steer out of the column (Porbaha et al., 2003). Darya Mokrousova (2010) states this tendency to deviate can be overcome by pre-boring and starting the penetration test from the base of the pre-bored hole. Sheng Haiyang (1999) found that probes may be deflected out, sometimes even at small penetration depths, and may not give a complete inspection of the pile. Liu Songyu et al. (2003) suggested that the Standard Penetration Test (SPT) is an effective way to evaluate the strength and quality of stabilized soil-cement columns. In general, Regular CPT can’t test the full length of CMP, and SPT still needed drilling which causes discontinuous detection. From the existing standard of China, core sampling compressive strength test is the main method, evidently, coring displays a longer test cycle, high cost and low efficiency. Therefore, an improvement of CMP quality assessment, by conjuring a fast and reliable detection and evaluation method, is necessary. The aim of this paper is to research the feasibility of using CPT in assessing the quality of CMP and presents an improved CPT method."

Jan 1, 2015

By Joon H. Jang

At a selected pH, hydrothermal oxidation of chalcopyrite was carried out under controlled F+,, at elevated pressures and temperatures (172-200°C) by balancing the rate of oxygen injection against the rate of consumption. Chalcopyrite was converted to covellite (CuS) and digenite (CU1.8S) with rejection of iron and sulfur to the solution. Covellite forms in the first stage, followed by nucleation and growth of digenite in the second stage. The effects of rapid and slow injection of stoichiometric quantities of oxygen are compared. Both the covellite and digenite form a porous layer occupying the same volume as the original chalcopyrite grain. An electrochemical kinetic model is presented to correlate the observed results.

Jan 1, 1993