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By R. T. Moolick, John E. Neill, O&apos

In selecting a particular stripping method the ultimate aim is the removal of material at the least possible cost. Accomplishment of this goal requires the careful consideration of many factors including geologic and topographic information, proximity of the stripping operation to waste disposal areas, possible problems of land reclamation, types of suitable equipment available, and auxiliary equipment requirements. 4.2-1. Selection of Stripping Methods. The size of an orebody and the distribution of values within that orebody normally will limit the variety of economical stripping methods which need to be considered. Much may depend upon the selectivity required in the mining due to the relationship between ore and overburden, as well as the character of the overburden itself. The following factors concerning the geologic nature and environment of an orebody, as well as the production requirements, must be determined before any selection of equipment is made: 1. The size of the orebody and distribution of the values within that orebody. Is the ore massive or scattered, bedded or disseminated, thick or thin? 2. The nature of the overburden to be removed. Is it a hard dense rock, bedded rock (thick or thin), friable material, earth, sand, elay, marsh, etc.? 3. The character and significance of geologic structures (fractures, faults, shear zones, etc.) associated with the ore occurrence. Are there water bearing formations with resulting water disposal problems? 4. In considering the nature of the overburden, including its alteration products, the physical or chemical conditions which, when combined with anticipated climatic conditions, may render certain equipment inoperable during unfavorable seasons.

Jan 1, 1968

By E. S. Tankins

The main purpose of this work was to study the effect of gold on the activity coefficient of oxygen in the liquid Fe-Au alloy and to determine how copper and silver change the activity coefficient of oxygen. A preliminary investigation has been made of equilibrium in the reaction of hydrogen with oxygen in some of the liquid gold alloys. The experimental method, which has been described in detail elsewhere,' consisted of bubbling accurately known H-A-water vapor mixtures through the Fe-Au alloys contained in alumina crucibles within a vertical closed furnace. When equilibrium was reached, the samples were quenched by rapidly lowering the crucible under an atmosphere of argon to a water cooled brass fixture at the bottom of the furnace tube. The melts were found to freeze from the top in less than 4 sec. The heats were carefully prepared for oxygen analysis. The oxygen content was determined by vacuum fusion analysis.' Only high purity electrolytic materials were used in this investigation. The activity and free energy of oxygen in the liquid iron alloys were studied by means of the reaction; The data for the 80 Fe-Au alloys, obtained as a function of temperature, are summarized in Table I and presented in Fig. 1, where log is plotted against . The results can be expressed by: The data were obtained using water vapor-hydrogen ratios between 0.04 and 0.30, and a 25 pct H2-75 pct A mixture. An oxygen content between 0.030 and 0.060

Jan 1, 1970

By William Wiehagen

This trainer?s guide is designed as a reference manual. The purpose is to offer information and examples to skills trainers to assist them in structuring training for new operators of Walk-Thru roof bolting machines. Trainers can use this manual as a resource for helping trainees learn, understand, and apply knowledge and skills. In this sense, the guide is not prescriptive. It is designed to offer information and trigger ideas on what might be done to accelerate learning to those who are new to the roof-bolting task. On-site trainers can modify this guide to fit their conditions, machines and equipment, and work procedures. They can integrate roof control plans, company policies and procedures, and operators? manuals from the manufacturers of the original equipment into this guide. Every trainee is different and will come to the job with varying levels of relevant knowledge and skills. The trainer?s decisions on where to start, how to organize the on-the-job and classroom training portions, and when and how to offer different aspects of the training will be based on (1) a pretraining assessment of the trainee?s knowledge and skills and (2) the trainer?s experience in conducting skills training. The ?Skill Check? section might be useful for deciding where training should start among miners who have underground experience but limited knowledge of roof-bolting techniques. Every job carries a learning curve and likely has a number of ?teachable moments? where significantly new knowledge and skills can be learned.

Aug 1, 2006

From the cold Pacific waters in June rolls a blanket of white clouds that tucks up around the mountains at around 8000 or 9000 ft. This is the way it happens in southern Peru and so the mining operations and daily living at Toquepala have an ethereal quality not often encountered. Besides looking down on the clouds from the brightly sunlit mountain tops, one can discern the trace of a different era in the brown barren mountain slopes. This trace is like a delicate net laid over the surface of the earth-a criss-crossing of innumerable trails that are so omnipresent, yet faint, that the local people have long since ceased to notice them. It is difficult at first to ask about them because no one understands what you are talking about. It finally comes out though, that the markings are indeed trails, but fossil trails made by animals in times when they were in abundance in a countryside that was green in some bygone century. In a way Toquepala is still pristine, it is the way the engineers planned it-from the ground up. There are no additions or expansions- those tackings-on that spoil the symmetry of design while increasing the profit. This does not deny that annual production has gone up over the years. Daily mill throughput has been increased from 30,000 to 42,000 tpd. Initial design of the concentrator was for 30,000 tpd but in 1964-65 milling capacity was increased to 36,000 tpd at a cost of $3 million.

Jan 11, 1969

By Tim Robinson, Michael S. Moats, William G. Davenport, Andreas Filzwieser, Andreas Siegmund, Shijie Wang

This survey continues the long tradition of providing a snapshot of operating data from industrial electrorefineries. It is a supplement to previous surveys that were performed in 1987, 1991, 1995, 1999, 2001, 2003, 2007, 2010, 2013 and 2016. Analyses of current data and historical trends are presented. Examples of innovations to reduce costs, improve productivity, and improve quality are provided. In general, refineries continue to increase productivity while treating anodes with more impurities. INTRODUCTION This manuscript analyzes global survey data provided by operating copper electrorefineries. This paper continues a series of surveys of copper refining tankhouses that started in 1987 (Schloen, 1987, 1991; Schloen & Davemport, 1995; Davenport et al., 1999; Robinson et al., 2003; Moats et al., 2007, 2013, 2016). In this installment, data collected from 2015 and 2018 will be presented and analyzed. The 2015 survey data were presented at Copper 2016 in Kobe, Japan. This survey will continue the analysis of previous data to illustrate long term trends in copper electrorefining, which were originally presented at the Davenport Symposium in October, 2014 (Moats, Robinson, & Wang, 2014). Refineries who supplied surveys are listed in Table 1. Cathode production data from 2015 and 2017/18 (from surveys presented in 2016 and 2019) are provided to indicate which plants provided surveys and when. This manuscript presents operating data for ~6.5 million tonnes of copper production, which represents 30–35% of the world’s copper electrorefining production. The detailed survey results are available upon request from the corresponding author.

Jan 1, 2019

By J. Tikka, E. Bäcklund, N. -O. Lindfors

Tornados are the most violent weather events in the world, and we have all seen the forces and phenomena created by tornados in nature. Airgrinder AB has been working with a material treatment technology, which most easily could be described as an artificial tornado. The process consists principally of one air fan providing a high-velocity airstream that enters a mechanical cyclone. When the gas enters the cyclone, an outer vortex is created. This outer vortex rotates next to the cyclone wall, and at the bottom of the cyclone funnel the gas stream is turned and an inner vortex is created. The control of the air flow is tuned by a special device on top of the cyclone. The gas outlet is at the top of the cyclone and the material outlet at the bottom. The material is fed through a feeding device into the air stream channel prior to the inlet into the cyclone. The process is basically an improved grinding and dehydrating system, which is very efficient and environmentally friendly and can even be employed with very sticky materials. Also due to its rotating comminution, the material particles become rounded during grinding, hence more free flowing and easier to handle. MEFOS has already tested more than 30 different applications in the pilot equipment. The materials tested range from metallurgical slags containing 2?3% moisture to sludges with up to70% moisture. This technology has a potentially strong impact on mineral beneficiation, including the drying of sticky fine-grained materials, improved and selective gas scrubbing and the manufacture of free flowing powders.

Jan 1, 2007

IN NOVEMBER 1933 I had the pleasure of receiving an autographed copy of a small brochure entitled "Birth of the Porphyry Coppers." The author, James Colquhoun, a distinguished British mining engineer, had been the dominant figure in the Arizona Copper Company, Limited, which, until its acquisition by the Phelps Dodge Corporation in 1921, had been the principal producer of copper in the Morenci district. In addition to the highly productive Humboldt and Longfellow mines it owned the Clay property, which, of course, has now become Arizona's No. 1 copper mine. Except for Utah Copper it is the premier Porphyry copper enterprise in the United States. Mr. Colquhoun's little volume was inspired by THE PORPHYRY COPPERS which had appeared early that year. In a most courteous and friendly way he adduces data to show that "we (Arizona Copper Company Limited) were successfully treating low-grade porphyry ores in quantity for at least four years (1901 to 19W) before the Utah Copper Company did anything at all." This last remark is based on the figures in THE PORPHYRY COPPERS showing that Utah's first production came from the Copperton pilot plant in 1905. Mr. Colquhoun traces the story of Morenci beginning in 1883 when he first arrived there. He tells how the rich self-fluxing ores (containing lime- stone, silica, and iron in proportion to permit direct smelting to produce black copper) were gradually exhausted. High-grade siliceous ore could be mixed in limited quantity with the self-fluxing ores; and oxidized ores were leached to contribute substantially to the production of the district. But

Jan 1, 1957

By Frank Drake

Manganese-ores are known to exist in the Caucasus in a number of localities, viz., in the government of Kutais, near the village of Chiaturi; in the same goverilment near the Choruk river, southward from Batum; and in the governments of Erivan and Tiflis. In smaller quantities they are found in various other places also. The first-mentioned deposits are by far the most important; the others being not only less extensive, but remote from present means of communication, and, from their character, expensive to work, although in some cases the ore is of a superior quality. All the manganese-ore now known in the market as a Caucasian " ore comes from Chiaturi, no other deposits in the Caucasus having been worked commercially; movements have been made, however, towards the exploitat,ion of some of those on the Choruk river. The Manganese-Ore District of Chiaturi. General Remarks, Statistics, Etc.—No other known deposit of manganese-ore can approach that of Chiaturi in capacity for producing large quantities of high-grade ore at a low cost. The deposit is said to have been discovered in 1848, by the geologist Abich, but the first shipments were not made until 1879, when 871 tons* were produced. Since that time, the production has steadily increased, until now the world relies on this deposit for about one-half its supply of manganese-ore. The industry is also of great importance locally, and aftords a livelihood to a considerable proportion of the population of the district in which the deposit is situated.

Jan 1, 1899

By Leroy A. Palmer

All the domestic production of magnesite during 1925 came from two states, California and Washington. Of a total of 120,660 tons of crude ore, 64,600 tons, or 54 per cent., were produced in California.' Of this quantity California produced about 99 per cent. of the caustic calcined, but only 10 per cent. of the dead-burned. The largest producer was C. S. Maltby, of San Francisco, who operated the Red Mountain mine, in Santa Clara County, and the Sampson mine, in San Benito County, under lease. These two mines have been studied by the author, and offer interesting comparisons as to mining and treatment methods and final products. Geology The general geology of the magnesite deposits of California has been described by Hess,2 Bain3 and others4 and although a detailed discussion is not necessary here, a brief summary will assist in understanding mining conditions. California magnesite, when comparatively pure, is usually a white, fine-grained rock, with a conchoidal fracture, occurring in veins and lense-like masses in serpentine. The veins vary considerably in width, and usually occur in a series of more or less parallel veins intersected by other series or systems of veins, probably following original or secondary fissures in the enclosing serpentine. The most generally accepted theory of origin is that the magnesite was formed by the action of surface waters charged with CO2 percolating downward through fissures and changing the magnesium silicates of the serpentine into magnesium carbonate.

Jan 1, 1927

By B. H. Caudle, M. D. Witte

In predicting the performance of a pattern injection operation, the engineer needs to know both the amount of oil to be recovered and the rate at which the recovcry will take place. This paper- describes fluid flow model studies on the effect of mobility ratio on the rate of oil recovery in a five-spot. The results show the change in fluid conductivity (total flow rate/pressure drop) as the sweep-ont pattern increases for mobility ratios between 0.1 (and 10. There data, when cornbitted with a knowledge of reservoir permeabilities and sweep-orit pattern efficiencies, cata he used to predict the cLrmulntivr oil production as a function of time for homogeneous five-spot injection systems. INTRODUCTION The flow potential in a pattern flood element is a function of the mobility ratio and how far the injected flood front has gone.1,2 For a waterflood project having a mobility ratio of one, the conductance—which is the flow rate per unit pressure drop (q/Ap)—-will remain the same throughout the life of the flood. If the mobility ratio is favorable ( < I), the conductance of the project will drop continuously throughout the operation. If, on the other hand, the mobility ratio is unfavorahlc. the conductance ratio will increase continuously. Therefore, if the reservoir engineer wishes to predict either the rate at a specified pressure or the pressure at some rate for a secondary recovery project, he must know how the conductance will vary during the flood. Other investigators have studied this problem using potentiometric models&apos; or analytical solution&apos;. The

By William Kelly, Frederick Laist

The slow, tedious and costly method of reducing copper matte to metallic copper in the reverberatory furnace, commonly known as the Welsh process, was displaced by the rapid and inexpensive converter process about fifty years ago. The art of refining copper was for many generations a carefully guarded secret among the Welsh furnacemen and was handed down among them from father to son. An attempt was made to apply it at Butte when the smelting of copper ore first started there but it proved too difficult and expensive under local conditions, and until the introduction of the converter process the entire output of copper was shipped to Swansea in the form of high-grade (60 per cent) matte. Before the construction of the Manhes converter, attempts had been made to reduce copper matte in the bessemer steel converter, but these failed, chiefly because the air was blown through the bottom of the vessel. The air holes became clogged with chilled copper as soon as the reduction started. Manhes partially overcame this difficulty by placing the tuyeres in the side of the vessel, some, distance above the bottom, thus allowing space beneath them for the copper to accumulate. Nevertheless the first attempts to operate such a converter at Butte were not successful, as no means had been provided for clearing away obstructions, which formed to some extent in front of the tuyeres. This difficulty was overcome by drilling holes in the outside wall of the air chamber directly opposite the holes in the shell and lining, so that these could be punched

Jan 1, 1934

By E. S. Bardwell

THE reverberatory copper-refining furnaces at the Great Falls Reduction Dept. of the Anaconda Copper Mining Co. have used successively, as fuel, lump coal on grates, pulverized coal, oil and natural gas. In no other plant, so far as can be ascertained, has such a variety of fuels been used. This fact affords a unique opportunity for comparing the relative efficiency obtained with these several fuels under nearly identical conditions. FURNACES The present furnace refinery at Great Falls was placed in operation in April, 1916. The original installation consisted of two furnaces, each with hearths 36 by 14 ft. and provided with fire boxes 10 by 12 ft. for firing lump coal on grates. These furnaces had air-cooled sand bottoms and chrome-brick side walls both above and below the metal line. The roofs were of 12-in. silica brick. Each furnace was provided with a waste-heat boiler of approximately 400 boiler-hp. capacity. We soon found that chrome brick was very unsatisfactory as sidewall material because of its excessive spalling. At the first opportunity the furnaces were rebuilt, using magnesite brick below the metal line and silica brick from the metal line to the roof. At the same time the thickness of the side walls was increased, thus decreasing the width of the hearth to 13 ft. At about this time also, the thickness of the furnace roofs was increased from 12 to 15 in. No further changes occurred in furnace design until 1922, when the use of lump coal on grates was abandoned in favor of pulverized coal.

Jan 1, 1932

By Jed H. Mosgrave

One of the most interesting of all the subjects required of persons studying the different facets of coal mining is coal mine gases. Some mine gases have been a real problem since the very beginning of underground mining and in the early days there was insufficient knowledge to really cope with them. The history of mining shows that until the last 50 years, work was done primarily by the hand methods which are primitive by today&apos;s standards. Miners had to contend with gases without the aid of enclosed lighting, permissible mine machinery, sophisticated testing devices, and high pressure ventilating fans. In early days the miners were not educated as to the different mine gases nor did they have the technical equipment to determine the actual composition of the deadly atmospheres they encountered. They simply applied a descriptive term to each gas or mixture of gases depending on its effect on a person or the surrounding atmosphere. The gases or mixtures of gases were then referred to as "damps" which was probably derived from the German word "dampf," meaning vapors or gases. The more common damps encountered were as follows: Blackdamp A condition of the atmosphere where a miner&apos;s light would be extinguished and in which breathing would be difficult, sometimes even resulting in suffocation. An atmosphere deficient in oxygen and which could contain a combination of any of the mine gases. Firedamp Flammable mixtures of methane and air which would either burn or explode when ignited. White Damp A mixture of gases containing carbon monoxide.

Jan 1, 1973

By C. J. Liebenberg

This paper focuses on the application of ion exchange technology for the recovery of copper from a leach solution originating from a heap bioleach in which base metals are leached from a low-grade ore that bears platinum group metals. Screening tests indicated that Dow XUS43605 has high selectivity for copper over the other metals in the solution, namely nickel, iron, cobalt, zinc, manganese, and aluminium. Batch adsorption kinetic experiments showed that copper adsorption equilibrium is attained at a fast rate. The kinetics of adsorption increased as the temperature was increased from 25°C to 60°C due to the decrease in solution viscosity and the subsequent improved intra-particle mass diffusion. Single-component Langmuir and Freundlich isotherm models were fitted to the batch copper adsorption equilibrium data, and a maximum copper capacity of 26 g/l was observed for Dow XUS43605. The effects of flow rate, temperature, pH, and initial metal concentration on the dynamic recovery of copper were investigated in fixed-bed columns, and it was determined that temperature and flow rate had the most significant impacts on the loading of copper on the resin at copper breakthrough. A 36% increase in copper loading at breakthrough was observed when the temperature was increased from 25°C to 60°C. Finally, it was determined that a split elution is possible by using different concentrations of H2S04 to first elute co-loaded nickel from the resin, followed by the elution of copper.

Jan 1, 2013

As part of the U.S. Bureau of Mines (USBM) program to characterize subsidence this combination of software and hardware has been used to remotely monitor overburden response to longwall mining. Background The principle of time domain reflectometry (TDR) is being used by the USBM to monitor strata displacements induced by mining. This capability has been enhanced by the availability of cable testers with serial communication modules that allow users to get TDR records in digital form. Actual field installations involve coaxial cables that arc hundreds of meters long, and the many records obtained when monitoring such long cables on a daily basis motivated development of software to view interactively and compare waveforms and to analyze signature changes. Time domain reflectometry (TDR) was developed in the 1960&apos;s as a method to locate discontinuities in coaxial transmission cables. The concept has been extended to measurement of properties of materials into which probes are embedded, such as water content of soil, and evaluation of coaxial cable dielectric behavior. This technique was adapted by the USBM in 1975 for use in checking the movement of rock during underground mining. Coaxial cables are grouted into a rock mass that is expected to cave, and progressive rock movement causes the cable to deform. Consequently, there is a progressive change in cable electrical properties that produces changes in TDR pulse reflection signatures. TDR technology has been advanced by Northwestern University to the point where it is now possible to distinguish shear deformation from tensile deformation, and to quantify rock mass displacements, by analyzing these changes in TDR signatures.

Jan 1, 1993

Etching solutions containing hexavalent chromium ions (e.g., chromic acid) are used in brass finishing, printed circuit board etching, preparation of plastic for plating, anodizing, and various other industrial surface treatment operations. As the solutions are used, hexavalent chromium ions are reduced to their trivalent state, contaminants accumulate in the solution, and the effective acid concentration is reduced. When the etching rate becomes unsatisfactory for the particular operation, the solutions are discarded. This is a problem because the discarded solutions are pollutants, and because replacing the etching solution is expensive. The Bureau of Mines has developed a process for regenerating these spent solutions and returning them to the surface treatment operation without interrupting the etching process. An electrolysis cell containing anode and cathode compartments that are separated by permeable membranes, is used for regenerating the spent solutions. The spent chromic acid solution is fed to the anode compartment and sui (uric acid is circulated in the cathode compartment. Application of a steady electrical potential of a few volts dc across the electrodes causes the copper ions and other contaminants in the spent solution to migrate through the membrane to the cathode compartment where copper is plated onto the cathode. Zinc and the other contaminants remain in the sulfuric acid. At the same time, the complex, trivalent chromium ions in the spent solution are attracted to the anode where they are oxidized to their original hexavalent state. The regenerated solution in the anode compartment is then recycled back to the plant?s etching operation for reuse.

Jan 1, 1980

By Luis Rudolphy, Pekka Tähkiö

"Flotation plant design, construction and start-up can be challenging tasks, because multiple factors and disciplines have to be combined in an efficient manner, in order to execute a project that meets the technical, financial and timeframe expectations. Key considerations that need to be addressed when designing a flotation plant are process requirements, equipment integrability, automation, and up- and downstream processes/designs. Furthermore, several other lifecycle factors need to be considered, such as servicing and maintainability, operational costs, future expansions and decommissioning, among others. To address these challenges, Outotec has developed a new approach to designing flotation plants that targets eliminating most of the inherent risks that can be found in these types of projects. The new Outotec® plant is a fully modular approach in which the above-mentioned challenges have been taken into consideration in the design phase. As a result, the cPlant concept can give several benefits for new and experienced companies involved in the minerals processing business, such as lower risk investments, fast and cost-efficient flotation plant delivery, faster ramp-up period, easy plant expansions, fully automated processes and operation and maintenance ease. As well, dismantling and transportation of the cPlant to a new location is easy and fast, hence the new cPlant concept makes possible to exploit small, short-lifespan ore deposits and also retreat old tailings ponds that might contain valuable minerals and where the ore quantities are limited. Furthermore, cPlant is easily implemented for brownfields and temporary expansions during bigger expansions."

Jan 1, 2015

By R Vleggaar

In addressing a short-term operational need for the relocation of a tailings storage facility reclaim pond, a mine has achieved a host of water management objectives. Through effective planning and adoption of a strategic æwhole of mine lifeÆ approach, the mine has achieved significant environmental, social and economic benefits. A review of all water management aspects across the site identified a host of other interrelated water issues and concerns which, if dealt with individually, would prove too costly for individual operational departments. When considered as a whole, however, the issues became opportunities and provided the stimulus for integration of the site water management system. The development of site water and solute balance models provided the tool by which a number of water management options/strategies could be evaluated. The conceptual design and costing of the proposed water infrastructure further facilitated the evaluation of the multiple benefits to be gained from each option. A business case could then be made to mine management for the preferred option. The recommended water management strategy finally recommended to the mine not only provided a tailings storage facility (TSF) reclaim pond, but also provided for:increased wastewater recovery from the TSF, the capture of all waste rock dump run-off, additional water harvesting from local creeks, increased wastewater reuse, improved environmental water management, infrastructure that could be used by the local community after mine closure, and overall cost savings. This paper illustrates how effective water management planning can provide both short-term economic and environmental benefits, as well as long-term social benefits.

Jan 1, 2006

By John F. Allan

This paper does not pretend to advance any facts or improvements not known to many members of the Institute, but is intended merely to give a few practical hints on preliminary tests, and to call attention to a possible enlarged field for the cyanide process in the treatment of some silver-ores, which merits investigation. Broadly considered, the choice of a process for the treatment of silver-ores in Mexico is confined to the following alternatives: (1) Concentration for treatment by smelting; (2) milling and pan-amalgamation; (3) the patio and Ortega process; [4) chloridizing roast and lixiviation; (5) chloridizing roast and cyaniding; and (6) cyaniding of the crude ore. These methods of treatment may also be combined, and cyaniding or concentration, or both, may be introduced, at what-ever stage it is found to be most advantageous. The characteristics of the ore (especially its gold-content) and local conditions, such as distance from railway, cost of fuel, amount of water available, vary so much that it is impossible to make general comparisons between the different processes, either as to extraction or cost. Concentration and subsequent smelting may be made very expensive by long-distance transportation of concentrates; pan-amalgamation is undoubtedly expensive; and the patio process is barred when the ore contains appreciable amounts of gold, by reason of its poor extraction of that metal; yet there are many ores for which each of these processes is especially adapted, and the expense of treatment is compensated by the results obtained.

Jan 1, 1905

By Larry M. Southwick

The smelting of copper and other non-ferrous metals have made considerable advances over the last 125 years. Many of the ideas and processes currently in use were attempted early in the history of smelting and were unsuccessful. Often the cause was incomplete understanding of the metallurgy involved, inadequate refractories, poor materials of equipment fabrication or trying too many new ideas at once. With time, these problems get solved and the technologies become commercialized .These were processes whose time had not come when originally proposed, but did eventually. On the other hand, there have been some concepts whose time will never come. They were impossible then and they are impossible now. The people that dream these up were either crackpots (they didn&apos;t know what they were doing, but thought they did), or charlatans (they knew they didn&apos;t know what they were doing, but didn&apos;t care). Both rely on bad science to propose metallurgical absurdities. These too have their place in the development of technology, though mostly negative, and several examples will be discussed in this paper. Three from around the turn of the century will be covered, as well as one from this decade. The last demonstrates that the art of creating absurdities has not withered, even after ninety years of scientific sophistication, and some can even be patented. The first three reached field trials due to the gullibility of company management. The last arose from a fortuitous mis-operation of a plant which solved a problem, but the explanation and patent which arose are metallurgically impossible.

Jan 1, 1999