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By C. S. Duncan, S. Scuro, D. R. Muss

Work is vepurted which was aimed at accentuating the pec14liar attributes of the GaAs laser diode, namely its sutzull size and its high efficiency. This has been done by reducing- transport losses in the bulk p and n regions of the diode and combining many of. these diodes into series stacks with common optical cazlities. The result of this effort is a nearly monochromati source at about 8450A With a luminous areu 0.05 by The GaAs laser diode is an attractive pulsed light source in the near ir because of its ability to emit very large pulse powers and its small size. In addition to this, the device is efficient; and the higher the 0.05 cm emitting peak pulse po we rs at greater than 300 LC at repetition rates below 200 pps into a cone about 0.01 steradians when operated at 77°K. The results of nzeasuvetnents of peak optical power and spectra frorr~ these stacks are reported and some conclusions are drawn about the vole the individual diodes play in the stacked operation. peak output power, the more efficient it is. The limit for the amount of power that these diodes can emit is the transient and average dissipation associated with the pumping pulse. This power dissipation arises primarily from transport across the bulk regions of the diode; this fact, along with the relatively low thermal conductivity of the GaAs, led us to the conclusion that higher power

Jan 1, 1968

By K Biegaj

The paper describes challenges the author has encountered on Australian underground gold and nickel mines over the last eight years, when recovering high-grade gold/nickel bearing mine floor material with a mobile supersucker/giant vacuum cleaner and other equipment. Whilst for a number of years the mine floor vacuuming and other mine floor clean-down technologies have been accepted/adopted and are working well in other parts of the world and on the South Australian opal mines, regrettably, they have not yet gained acceptance of mining executives and mine managers of gold and metal mines in Australia, who still elect to leave the never to be recovered gold/metal behind or to put it plainly - waste it.For reporting purposes during the mining process, the portion of gold/metal included in calculation of ore reserves prior to obtaining capital funds for their development, continues to be camouflaged in various reconciliation and call factors. This approach, ie wasting of capitally developed and already broken ore stocks should be viewed by the shareholders as totally inappropriate to say the least, especially with the current gold and other metals prices.The author attempts to provide answers as to why the technology referred to above has not yet been accepted on Australian gold and metal mines and outlines the way forward.CITATION:Biegaj, K, 2012. Why do shareholders and mining executives allow mine managers to leave behind high-grade broken ore underground?, in Proceedings Narrow Vein Mining 2012 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Schofield D

The problem of production scheduling is sufficiently complex to negate the use of many conventional optimising techniques as there are numerous and diverse factors that must be considered when trying to produce an optimal schedule. These factors include: grade distribution, orebody geometry, production rate capacity, processing constraints and market price of the minerals amongst a variety of others. In addition it may be observed that many of these factors incorporate a degree of uncertainty and any schedule produced must inevitably consider risk as a primary consideration. The very nature of the problem has limited the use of conventional optimisers. Genetic algorithms use methods based upon evolution and natural selection to produce `optimal' solutions to complex system problems. They are extremely flexible and robust in their nature and it is these characteristics that are important in this particular problem domain. A particular strength of the genetic optimisation approach is the ability to handle the multiple and non-linear constraints that are typically encountered in mine scheduling problems. This paper concentrates on the development of a prototype application of a genetic algorithm to the problem of scheduling the output from multiple production points in an underground mining operation. In particular it.describes a system (GO-SCHED) that can be customised to handle a wide variety of underground scheduling problems. GO-SCHED, a Windows-based system, can interface with a variety of databases and spreadsheets for data input and output and provides a simple intuitive approach to the solution of the scheduling problem.

Jan 1, 1995

By Clinton M. Young

The experiments herein described were carried on in 1908-9 by- the State Geological Survey of Kansas. Some months before taking up work on black powder the Survey had resumed work on an interrupted investigation of explosions in coalmines, a subject which is engaging the attention of numerous investigators. An unusual number of serious disasters has directed to the subject a study which discloses the disquieting fact that, in the United States, the ratio of lives lost per ton of coal mined has been 011 the increase. Methods of coal-mining have changed to some extent with the great increase of output, attained in comparatively recent years. These changes involve the working of very extensive mines, with increased difficulty of ventilation, increased accumulation of coal-dust, and a very great increase in the amount of explosive used. This last point assumes truly startling proportions when it is carefully observed. In the fields of the Middle West it is not now uncommon for a miner to use six kegs (150 lb.) of black powder in a " pay" of two weeks, while within the memory of men still active, one keg (25 Ib.) would last two men for a " pay." So great has the use of explosives become in some fields that the skilled coal-miner is hard to find, and the coal is not mined, but blasted. A preliminary study of the subject of explosions in coalmines has led to the belief that the use of large quantities of explosives, in some cases by slightly-trained men, had riot been

Jan 1, 1911

By Norman J. Sather

LOCATION AND HISTORY The Bunker Hill Mine is situated on the south side of the Coeur d’Alene River in Shoshone County of Northern Idaho near the City of Kellogg. Kellogg, the largest in the Coeur d’Alene District cities, is at an elevation of 2,300 feet and has a population of approximately 7,000 people. It can be reached by air, railway or highway. The history of the Bunker Hill Mine dates back to August 26, 1885, when Noah S . Kellogg found the outcrop of the Bunker Hill ore body on the hillside above the present town of Wardner, Idaho, in Milo Gulch. A small concentrator was erected in 1886. Before the railroad came, the mine output was transported by mule teams to the head of navigation on Coeur d’Alene Lake. After ten years of production, an interest was purchased in the Tacoma Smelter at Tacoma, Washington, to which the entire output was shipped. In 1916 and 1917 a modern lead smelting plant and refinery was erected and in 1927 and 1928, a modern Electrolytic Zinc Reduction Plant was built and put into operation by the Sullivan Mining Company which was 50% owned and now totally owned by The Bunker Hill Company. GEOLOGY AND MINERALOGY The Bunker Hill ore bodies are found in gray and greenish gray quartzite and argillaceous quartzite of Precambrian age and are known as the Revett and St. Regis formations. Most of the ore bodies are found in the St. Regis formation.

Jan 1, 1970

By J. Roth

"While not taking issue with the general thesis expressed in Dr. Ridge's analysis of the role of genetic concepts versus observational data in ore exploration (Ridge, 1983), the criticism could be offered that the author tends to slight the importance of conceptual (i.e. theoretical) models in mineral exploration.As a general rule, observational data in science lacks significance and utility without a theoretical construct to organize those observations. Theory in turn dictates what observations are made-and which ones are judged important. Thus, for example, prior to the elaboration-and acceptance- of the current model for volcanogenic base metal deposits, the structural aspect s of these deposits were most closely observed and studied by explorationists. The nature of the enclosing rocks and any attendant alteration was given minimal attention, and certainly didn't figure prominently as an exploration guide.Similarly, the importance of alteration features to exploration for porphyry copper-molybdenum deposits was only perceived when a theoretical model was developed to account for these aspects. Indeed, many of these porphyry copper deposits were regarded as epigenetic vein deposits by geologists of an earlier era observing and examining on a different physical scale-and with a different theoretical bias.In constructing and evaluating such conceptual models, explorationists primarily rely on observation data and proximate associations; speculative thoughts as to ultimate provenance or crustal evolution clearly play a subordinate role, as Dr. Ridge argues. This, however, should not obscure the fact that concepts and theories do indeed exert a major influence in mineral exploration."

Jan 1, 1983

By Nilmani M, Fountain CR

Injection of gases into slag-melt mixtures produces various zones as a result of bubble formation and disintegration within the melt. The extent of these zones depends on the type of reactor used. When compared with ferrous processes, non ferrous processes are character- ised by large bubbles formed adjacent to the tuyeres, low flowrates and shallow tuyere sub- mergence. These features can result in a greater proportion of reaction occurring above the bath, more refractory wear and tuyere blockage with more splashing. The large bubble zone adjacent to the tuyeres has been investigated using the tech- niques of physical modelling, mathematical modelling and plant trials. Large bubble form- ation in physical models was recorded using a high speed camera and a rapid response pressure transducer coupled to an oscilloscope and data recorder. It was found that the bubble volume (Vb) could be correlated at low flowrates using the single bubble model Vb = 1.378 Q6/5 g-3/5 Deviations from this correlation occurred with increasing gas jet momentum. Plant trials were carried out on a copper converter at Mount Isa Mines during five different charges. Pressure measurements were made through the tuyeres during the slag blow and commencement of the copper blow. The power spectrum density showed that the dominant pulse amplitude occurred at a frequency of approximately 3 pulses/sec. Plant data from this and other converters were correlated using the same relationship as for physical modelling. De- viations occurred due to the state of the re- fractory, bath composition or bath circulation effects.

Jan 1, 1984

By Albert J. Phillips

As early as 1824, Haidinger' described crystals of native copper that were, according to Dana,2 " probably twinned parallel to the octahedral plane and normal to this axis." In 1837, Rose3 very clearly demonstrated that native copper crystals were commonly twinned on the octahedral plane. Lasaulx,4 in 1882, described polysynthetic octahedral twins and stated that enclosed twinning lamellae were observed. Even on crystals formed artificially by electrolysis, twinning was observed as early as 1886, by Brown.5 Many other descriptions of twinning in native copper and in gold and silver are to be found in the literature, and in every case with which we are acquainted the twinning is conformable to the spinel law; i. e., the octahedral plane is both twinning and composition plane. Metallurgists have long been familiar with the straight-sided bars or bands that commonly occur within the irregularly outlined grains of metallic crystalline aggregates. They are certainly found in nearly all metals of the face-centered cubic type after cold working and annealing. If a specimen showing these bands is rotated, keeping the angle of incidence of the illuminating beam constant, they usually exchange color contrast periodically with their respective matrix crystals. Also slip lines, when produced in these specimens, nearly always show a change in direction upon passing through the bands, giving rise to the "stairway" effect often illustrated in metallurgical textbooks. Apparently the only quantitative observations on bands of this sort were made by Osmond and Cartaud6 on austenitic steel. They selected,

By Ben L. Seegmiller

Introduction The profitability of an open pit operation depends to a large extent on the use of the steepest pit slopes possible, provided they do not fail during the life of the mine Optimum pit slopes can be designed by using rock mechanics technology. Such technology includes gathering and analyzing pertinent data prior to pit design, rigorous application of rock mechanics principles during the design process, remedial actions to improve slope stability, and monitoring slopes during the life of the mine. Ignoring rock mechanics technology in pit design may place the entire mining enter- prise in jeopardy Disruption of mining operations and safety hazards caused by slope instability can be severe. A classic case in point is the major slope failure (Seegmiller, 1972) that occurred at a southwestern US copper mining operation in 1970-1971 Minor slope stability problems initially amounted to no more than a nuisance, but in time, the unstable zones became larger, causing greater disruption of production and threatening safety Mining at or near the slide toe had continued throughout the period of slope failure, aggravating the already unstable condition The original plan for this pit called for mining the overall pit slope to 37.5" Mine operators were forced to lessen the back- slope angle in the hope that the failing rock mass would stabilize. However, stabilization did not take place, and when mining in the area of failure was completed, the overall slope had been reduced to approximately 27" Mining had been successful in removing only a small portion of the ore body at a high stripping ratio.

Jan 1, 1979

By L. H. Marshall

MALLEABLE-IRON castings frequently are made brittle by hot-dip galvanizing. The castings may be and usually are perfectly normal before the hot-dip treatment, in that they will stand a remarkable amount of distortion and punishment before fracturing, yet, after galvanizing, a single blow with a hammer will often cause a break. One such casting broke when accidentally dropped on a concrete floor. Such weakness causes galvanizers to view malleable cast iron with misgivings, and, in turn, is a source of worry to the manufacturer of the castings. It is felt, therefore, that a practical method of overcoming this embrittlement, a method that has already been used on several thousand tons of castings, will be of general interest. The purpose of this paper is to describe this immunizing process. DEVELOPMENT OF THE PROBLEM In the early days the trade was not much concerned with the finish of the castings and in most cases the only protection given to the parts placed in service was a coat of paint. It was soon found that this form of protection was inadequate and the user demanded a better type of rustproofing. In compliance with this demand, the use of zinc for coating gradually spread until it became general practice. More than half of all the zinc produced today is used for coating iron and steel, and, in spite of the recent use of cadmium and chromium, zinc coatings are still recognized as among the best general rust inhibitors for atmospheric exposure.

Jan 2, 1926

By F. F. Frick, Frederick Laist

In a leaching process, having obtained the copper in solution, the choice of the precipitation method is influenced by the following factors: 1. Availability of precipitant. 2. Adaptability to the leaching process. 3. Final product desired. 4. Regeneration of leaching solutions. 5. Fouling of solutions. There are three general classes of precipitation methods: 1. The use of iron, scrap or sponge. 2. Electrolytic deposition. 3. The use of some gas or reagent by which the copper is obtained, usually in the form of an intermediate precipitate which requires further treatment. For example, the precipitation of, the copper as Cu2Cl2 from chloride solutions; with SO2 gas. The use of iron is adapted to almost any process. It has the great advantage of extreme simplicity, and the recovery of the copper and any values present in a highly concentrated, easily treatable form. The disadvantages are the cost in isolated places, the uncertainty of the scrap-iron market, and the fouling of the leaching solutions. The latter is a serious factor, when a reagent such as salt is used in them, which makes necessary their re-use. Where applicable, electrolytic deposition is very attractive. The copper is obtained in a form directly marketable, there is a regeneration of acid and no fouling of solutions. Unfortunately, chloride solutions do not lend themselves to electrolysis. An entirely satisfactory anode material has not yet been discovered, although magnetite, apart from being rather brittle, seems to answer the requirements fairly well. The use of a method of the. third class is involved in many special

Jan 1, 1915

By Ben L. Seegmiller

Artificial support of rock slopes in mining applications may consist of rock anchors with and without auxiliary support systems, but- tresses or shotcrete. The use of artificial support systems is not applicable in all cases of slope instability. Some pit slope problems simply cannot be cured with a support system. In other cases, a sup- port system which would solve the problem would be uneconomical. Rock anchor design may be undertaken using an active or tensioned system or a passive or untensioned system. Failure problems to which artificial support systems are most commonly applied include planar, wedge, rotational and toppling failures. Design of auxiliary support systems and rock anchor peripheral items may be initially estimated using analytical concepts, but field trials are commonly used to determine final requirements. Field procedures usually require a close coordination between mining personnel and the support installation team. Great care must be exercised during installation to prevent numerous potential problems including poor anchorage, excess bearing and corrosion. Displacement monitoring of the completed system is a must if the effectiveness is to be closely judged by means other than total slope and/or support system failure. The cost of a support system is relatively high when compared to other remedial measures that may be taken to solve a slope instability problem. Therefore, the system costs play a vital role in determining whether or not artificial support should be considered beyond the initial assessment stage. Case histories are few, but do include examples of each type of support system.

Jan 1, 1983

By A. R. Troiano, W. J. Barnett

IN recent years the demands of space limitations and increased loads, particularly in the aircraft industry, have accelerated the trend toward utilization of ultra-high strength steels. The increased application of such steels has focused attention on the phenomenon of delayed failure or static fatigue. Parts subjected to a static load, after successfully sustaining the load for an extended period of time, may fail in a brittle manner. Subsequent examination of such failed parts by conventional laboratory tests in many cases reveals no apparent signs of embrittle-ment. That is, the material exhibits good ductility and impact resistance. Furthermore, consideration of the service conditions (environment and temperature) under which this brittle failure occurred eliminates its classification as a stress-corrosion or creep type of failure. Recently this unique time dependent fracture process has been the subject of numerous investigations. The most significant result of these studies was the recognition of hydrogen as the source of embrittlement. While the effect of numerous variables on the occurrence of static fatigue failure has been defined, an adequate explanation of these behaviors is lacking. The occurrence of this phenomenon in steels generally has been limited to strength levels in excess of 180,000 lb per sq in. Although steels at high hardness levels have exhibited delayed failure in the absence of hydrogen introduction after heat treat-ment,'.' this behavior was most prevalent when the material in processing had been subjected to an environment conducive to the absorption of hydrogen. Delayed failures have been produced in high strength steels by the introduction of hydrogen

Jan 1, 1958

By John Sasadi, Karl Heinz Zepter, Leonard Sugin, Roger L. Hulette

Mt. Newman Mining Co. is now completing an expansion program, begun even before initial construction was complete, which will result in the ability to ship up to 35 million tpy of iron ore by early 1973. Located in the Pilbara region of Western Australia, the mine at Mt. Whaleback is about 700 road miles north of Perth and 265 railroad miles south of the port facilities at Port Hedland. Development of the tertiary crushing and screening facilities best illustrates the orderly, but rapid, sequence through which the capacity of the port loading terminal has been expanded. When the present program is completed, crushing and shiploading capability will reach - - 35 million tpy. Operations commenced in 1969 with 3 crusher lines in service; and despite the 5-million annual ton rating, 6.46 million tons of ore were shipped during the first full year of operation. With continuing increase in ore sales, expansion to an annual capacity of 12 million tons was authorized, and installation of two more crusher lines was begun. As a part of this program, provision for installation of a sixth crusher at some future date was included in the planning; but before construction was completed, new ore sales contracts demanded further expansion to an annual rate of 20 million tons, and the sixth crusher line was authorized. The distributing and collecting conveyors had been designed for extension in length and increase in capacity, therefore, conveyor service was provided for the additional crushers with additional belting and hardware only.

Jan 6, 1972

By D. Sager

Middleburg Ferrochrome (MFC), a company in Samancor Chrome, commissioned a new ferrochrome smelter in March 2009. This is a 60 MW DC-arc furnace with a DC power supply for the smelting of Transvaal chromite ore fines. With the benefit of 12 years' experience with this technology while operating a 44 MW DC-arc furnace, MFC mitigated all known challenges and considered up-scaling risk in the new plant, which had a rapid ramp-up to full power in 02 of 2009. Good operating practices, as made possible by robust equipment selection, including a thyristor rectifier set of proven technology, and operation with optimal slag chemistry, leads to a safe and effective plant operation. With the optimized furnace design and a correctly sized power conditioning system, using only standard (static) harmonic filters and a correctly sized smoothing reactor, the arc furnace is not a 'dirty load' for the utility, staying well within IEC limits for power quality. A patented arc compensation system is installed and allows for full arc position control (to compensate for magnetic field induced arc deflection) so that a symmetrical crucible is maintained, significantly benefiting refractory life. The principal benefits gained from the MFC process is the fact that ore fines are processed, without metallurgical coke, and higher chrome recoveries are achieved compared to other smelting technologies when using a DC open arc for smelting. Keywords Samancor Chrome, Middelburg Ferrochrome, ABB, smelting, DC arc furnace, arc compensation, power factor correction, anode, harmonics, thyristor, reactor, maintenance, refractory, ores, reductants.

Jan 1, 2010

The Mississippi river was discovered by French explorers that came southwestward, by way of the Great Lakes, from eastern Canada. Vignan, Joliet, De Champlain, and others of the French pioneers in the first half of the seventeenth century, dreamed of a short cut to China by means of the great waterways they explored. In a geographical book published in London in 1726 by Daniel Coxe an account is given of "a new and curious discovery and relation betwixt the river Meschachebe [Mississippi] and the South Sea, which separates America from China, by means of several large rivers and lakes". Louis Joliet, a fur-trader, and Jacques Marquette, a Jesuit missionary, reached the Mississippi and paddled their canoes on its broad waters on June 17, 1673.* They descended the river as far as the entry of the Arkansas tributary, and then returned overland to Canada, being deterred from going farther south by reason of Indian hostility. Several years later Robert de La Salle, a French trader, starting from Quebec, went westward to Lake Michigan and thence to the Illinois river, which he and his comrades descended in their canoes to the junction with the Mississippi, and then followed it to the sea. They reached the Gulf of Mexico on April 9, 1682. Thus the great central waterway of North America was made known. These French-Canadian voyageurs, or boatmen, traded with the Indians for furs in the Upper Mississippi valley, and when in need of bullets they noticed the outcrops of lead ore, from which, probably in the last decade of the seventeenth

Jan 1, 1932

By H. Reginald Hardy, Y. P. Chugh, Robert Stefanko

Many materials including rocks, ice, metals and their alloys, wood, etc., emit transient vibrations in the audible and subaudible range when stressed. In rocks, this phenomenon is referred to as "microseismic activity, " "rock noise, " or " seismo-acoustical activity. " In metals this phenomenon is often termed "acoustic emission." Each individual microseismic disturbance is generally referred to as a "microseismim" or an "elastic shock." The terms "microseismic activity" and "microseismim" will be employed exclusively in this chapter. Microseismic activity has been observed in many rocks loaded experimentally in the laboratory.1 The form of a group of typical microseismims is shown in Fig. 1. Quantitatively, the microseismic activity in rock under stress is most commonly described by the number of microseismims observed per unit time. This is commonly known as the "noise rate." The noise rate in general increases with increasing stress level and rises sharply just prior to failure of the material.2 The origin of microseismims is not well understood, but it appears to be related to processes of deformation and failure which are accompanied by a sudden release of strain energy. In a polycrystalline material, microseismims may originate at the micro-level as a result of dislocations or at the macro-level by twinning, grain boundary movement, or initiation and propagation of fractures through and between the grains. It is assumed that the sudden release of stored elastic strain energy accompanying these processes generates a stress wave which travels from the point of origin, within the material, to a boundary where it is observed as a

Jan 1, 1972

By D. Van Dyk

Horizontal rotating mills are being used all over the world in different mineral and power generation industries. David Brown South Africa, with over 140 years of experience in gear manufacture and design, has been supplying these industries with innovative designs at exceptional quality. The gearing systems associated with these industries are challenged daily with operating conditions that are not always fully understood. Failures are therefore experienced, over time in the industry, which cannot always be fully explained. David Brown South Africa has developed a gear monitoring system, the Intelligent Gearing System, in association with Transmission Dynamics (UK), in order to monitor and analyse these operating conditions in real time. The system has been designed on the principles of Six Sigma, incorporating Design for Six Sigma. The purpose with this system design is to monitor the operating conditions on the pinion, record the information and analyse the data in relation to the rate of fatigue damage to the girth gear and pinion. This is done in real time and unattended. The output from the Intelligent Gearing System can be fed back into the operating system of the mill user, in order to display an alarm for operating conditions exceeding the design criteria as well as information on the rate of fatigue damage due to these operating conditions. When the mill operating and the effect on the fatigue life of the mill gearing components, conditions are better understood, mill users can forecast critical spare holding levels with an increased accuracy. The Intelligent Gearing System also allows early actions to remove reasons for system overloads.

Jan 1, 2006

By N. A. Tiner, Saara Asunmaa

The early stages of nucleation of vacuunz-deposited gold coatings on electropolished surfaces of pure nickel and binary alloys of Ni-A1 and Ni-Ti have been studied, employing carefully controlled temperature and vacuum conditions. The preferential nucleation of gold on slip-plane edges on the crystal surfaces gave rise to a very pronounced decoration effect which was used in studying the morphology of the pain boundaries, etch pits, and slip planes on crystal faces. Characteristic surface patterns were observed with local dimensional variations. Most pronounced geometric patterns were ohserved in the pain boundaries of nickel and on the crystal faces of Ni-A1 alloy. The nucleation behauior of gold indicates contamination on the Ni-T1 alloy and the getter properties of titanium are presented as a tentative interpretation for the detected contamination. The markings and imperfections on cleavage surfaces of crystals have long been observed by optical microscopy.1,2 Surface-replica techniques are also used to detect the smallest steps and structural details on crystal surfaces by electron microscopy. Recently, Bassett3-5 and Sella, Conjeaud, and Trillat 6 have shown that, when gold is deposited onto a rocksalt cleavage surface, there is preferential nucleation at steps and slip-plane edges on the crystal surface. This gives rise to a very pronounced decoration effect which is invaluable for revealing the lattice steps on a cleavage surface. According to Bassett,3 gold atoms arriving during vacuum evaporation at the crystal surface have a certain mobility on the surface after arrival, particularly at elevated temperature. If a significant

Jan 1, 1964

By D. E. Shanks

The Bureau of Mines investigated the effects of HCI concentration and solution temperature on the solubility and crystal form of the chlorides of Co, Mn, and Ni when sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increasing HCI concentration in solution caused the chlo-rides of Co, Mn, and Ni to crystallize (salt out) because of the common ion effect. The salting-out crystallization was most effective for NiCI2, which had a solubility of 0.7 pct at 20° C and maximum HCI concentration. COCl2 salted out to a minimum solubility of 9.4 pct at 20° C and 22 pct HCI concentration and increased in solubility at greater HCI concentrations because of the formation of chloride complexes. MnCl2 was intermediate in behavior. The effect of temperature on solubility was greatest for CoCl2 and least for NiCI2, 15 and 7 pct change, respectively, over the temperature range of 20° to 60° C. The salted-out chlorides of cobalt and nickel formed the hexahydrates and those of manganese formed the tetrahydrate in saturated metal chlo-ride solutions at 20° C and low concentrations of HCI. Increasing the temperature or the HCI concentration caused a 108s in waters of hydra-tion. At 60° C, the salted-out crystals of NiCl2 formed the tetrahydrate in HCI concentrations up to 18 pct and the dihydrate at higher concentrations, while cobalt and manganese chlorides formed the dihydrates, even in water.

Jan 1, 1985