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By Valeh Aghazadeh, Shima Barakan, Mina Soleymani, Ehsan Bidari, Morovvat Faridazad

Molybdenite is the most important molybdenum concentrate, which is mainly recovered as a by-product from porphyry copper deposits. Due to the low efficiency of purification processes such as flotation in the reduction of copper content of molybdenum concentrate to a standard level (i.e., less than 0.5 wt.%), further purification by a hydrometallurgical method is required. Although different types of chemical reagents were found to be effective in the leaching of copper minerals from molybdenum concentrate, the mechanisms of these processes remain largely unexplored. In this study, optimal conditions for maximum copper leaching (> 99%) were obtained at the concentration of HCl = 1 M, FeCl3 = 0.5 M, CuCl2 = 0.05 M, CaCl2 = 0.5 M at 75 °C, 500 rpm, and S:L = 1:10 during 60 min. CuCl2 was identified as the most effective leaching reagent for copper dissolution in agreement with Visual MINTEQ model results due to the formation of various types of copper chloride complexes. Furthermore, the electrochemical behaviors of FeCl3, CuCl2, and CaCl2 reagents before and after the leaching process were investigated by the cyclic voltammetry technique. The results of cyclic voltammograms at different scan rates verified the presence of copper chloride complexes, and ferric ions as the oxidizing reagents for better dissolution of copper sulfides. Based on kinetic study results of shrinking core models, both chemical and diffusion reactions controlled the copper leaching process with an obtained activation energy of 33.56 kJ/mol. For recovery of the leached copper, the precipitation process was done by the addition of Na2S at 45 °C, S/Cu = 1, and pH = 9.

Dec 26, 2022

By Amar Prakash, V. M. S. R. Murthy, Ajoy Kumar Singh, Avinash Paul, John Loui Porathur

Weak, layered, and fragile rock mass formation, if not supported properly, is subject to roof failure thereby affecting safety and productivity in underground coal mines. Though Central Mining Research Institute – Indian School of Mines Rock Mass Rating (CMRI-ISM RMR) based well-defined support design guidelines are established, still occurrence of roof failures in underground coal mines is a real matter of concern for mining engineers and researchers. Numerical modeling techniques are successfully used by several researchers by simulating rock mass condition for stability assessment of mine openings. The analysis becomes crucial in case of weak and fragile rock formation. The present research envelops the determination of 31 cases of rock load by CMRI-ISM RMR under different geo-mining conditions followed by the development of modified Rock Mass Rating (RMR), i.e., rock mass rating dynamic ( RMRdyn) by incorporating P-wave velocity as a new parameter. The rock load determined using RMRdyn and numerical models was correlated and found in close agreement. In addition, the deviation in rock load determined by all the three approaches, i.e., CMRI-ISM RMR, numerical modeling, and RMRdyn, was compared with the actual field data. The percentage deviation obtained in RMRdyn and numerical modeling is less compared to CMRI-ISM RMR.

Sep 1, 2023

By T. M. Garland

A nomographical approach is proposed as a fast, easy-to-use, and reason- ably accurate method for estimating expected discounted cash flow (DCF) rate of return and payout time for onshore development drilling and oil production. All costs pertaining to drilling, completing, and equipping development wells, annual expenses of operation, maintenance, and taxes incurred in producing properties, and crude oil prices were considered in developing the nomographs. This report briefly outlines the origin, derivation, and use of the nomographs.

Jan 1, 1973

By Thierry Bernard

It was in the 1980s that USBM published one of the first regulations to protect constructions from the effects of vibrations caused by mine blasts. Several countries have made their own regulations or recommendations since then with vibration limits that are often lower. However, on many sites, operators choose vibration limits that are lower than those of the existing standards, in order to limit the number of complaints received. The real question is how can we know what level of vibration is susceptible to create or worsen an existing crack in a construction. MCM, to the north of Quebec, is working a deposit on the periphery of the town of Malartic. Within the scope of its environmental monitoring programme, together with the joint monitoring committee, MCM has equipped four sample houses for over 18 months, in order to learn if there is a relationship between the evolution of damage to existing constructions and the seismic levels of vibrations created by mine blasts. The publication presents the results of this unique study that has analyzed millions of measurements (seismic, extensometric, and temperature) to define what relationship exists between the levels of vibration and the movement of cracks. Some surprising results versus some published previously (see ref) might change our perception of the subject.

Jan 1, 2018

By R. B. Tippin

Great Salt Lake Minerals & Chemicals Corporation (GSL), a subsidiary of Gulf Resources & Chemical Corporation, is located on the east side of the Great Salt Lake, approximately 20 miles from Ogden, Utah. GSL processes brine from the north arm of the lake to produce potash, salt cake, salt and magnesium chloride brine. Potash fertilizer, in the form of K2SO4 is GSL's primary product. The GSL Sulfate of Potash Complex The GSL potash complex (depicted in Figure I) is divided into a solar evaporation pond system and the process plants. The solar,evaporation system consists of a 17,000-acre (68.8 Km2) ponding operation where the various salts deposit during the summer evaporation season, and a harvesting operation which recovers the deposits during the remainder of the year. The harvest is either preconcentrated in the flotation plant or processed directly in the chemical plant where sulfate of potash (SOP) is produced. The chemistry of the lake brine results in a solar deposit con¬taining primarily kainite (KCl-MgSO4.3H20), schoenite (K2SO4?MgSO4^ 6H2O), and halite (NaCI), with some carnallite (KCl.MgCl2.6H20) and epsomite (MgSO4.7H20). Other minor minerals may be deposited, depending upon the weather during the evaporation season. Each year, the solar deposit in the evaporation ponds will greatly depend upon the summer weather conditions, which have in the past proven to be quite unpredictable. Weather may alter both the quantity of the solar deposit and the composition of this deposit. During, a "short" evaporation season, the tonnage deposited decreases, but depending upon the short-term weather, the potash mineral content

Jan 1, 1977

By David A. Newman

In the 1950s, an underground limestone mine in the Camp Nelson Formation was developed from an outcrop exposure. The Camp Nelson Limestone met the requirements for DOT stone and aggregate. The mine ownership changed several times, which resulted in distinct mine designs in Level 1. Based upon the production requirements and an attempt to maximize limestone recovery from a single level, a variety of pillar dimensions and three mining heights (28 feet, 68 feet and 83 feet) were developed. This was sufficient prior to reaching the mineable extent of Level 1. Level 2 introduced previously unknown ground control challenges. These included: ??Pillar spalling and a significant back fall on the Level 1 - Level 2 decline; ??Laminated immediate back and the need to bolt the back on Level 2; ??Delamination of the back adjacent to the Level 1 - Level 2 decline resulting in bolt shearing, and floor heave in isolated areas of Level 2; ??Multiple level interaction, the need to design pillars based upon numerical modeling as columnization between Levels is infeasible: and ??Water inflow as the mine approached river. To meet the challenges, a testing program to determine rock strength and physical properties was implemented along with numerical (LAMODEL and FEM) modeling, and borescope inspections of the immediate back. The efforts to implement rock mechanics were re-focused as Level 2 approached its mineable limit and the initial attempt to drive a decline to Level 3 was unsuccessful. A second decline site was selected based on inter burden stability, a consistent shale parting for the Level 3 back horizon, results from numerical models of the immediate back and multiple level interactions, and the projected low water inflow. The mine is operating on Levels 2 and 3 with long-term planning and ground monitoring for Level 3.

Jan 1, 2014

By Michael J. Beus

The National Institute of Occupational Safety and Health-Spokane Research Laboratory (NIOSH-SRL) have developed a Shaft Conveyance Monitoring System (SCMS). Assessment of current hoisting technology has shown that monitoring wire rope tension and conveyance position and load directly from the skip or cage top offers several significant safety, production, and maintenance advantages. The SCMS consists of conveyance position and guide displacement sensors, a battery power supply and charging system, and a new sensor to measure hoist rope tension. This device provides a warning of the occurrence of ?slack rope? a particularly dangerous condition. A 2.4 GHz radio link transmits data to the hoistroom. A reduced scale hoisting test facility has been constructed to test these components prior to field trials. The advantages of monitoring wire rope tension and conveyance position and load directly from a skip or cage top will be discussed. Field tests are underway in full-size shafts to refine the concept and evaluate long-term reliability and maintenance requirements. Application of this technology may result in decreased maintenance costs as well as safer, more productive hoisting operations.

May 1, 2001

By C. C. Merrill

Columbium, tantalum, titanium, and zirconium are present in solid waste products generated by the chlorination of rutile used for production of titanium tetrachloride (TiC14). The columbium and tantalum were separated from titanium and zirconium by liquid-liquid extraction techniques using a secondary amine. Salts of these elements are in a leach liquor produced by water leaching of mineral waste from the chlorination of rutile. This waste, produced at the rate of approximately 50,000 tons per year, is about 40 wt pct water soluble. Leach liquors, separated by filtration, were further separated into a solid fraction and a liquid fraction by pressure hydrolysis, The solid fraction containing Cb, Ta, Ti, and Zr was dissolved in HC1-HF and used as a feed solution. Columbium and tantalum were removed from the organic extractant with 1 [N] HC1. A miniature 10-stage reactor showed that the columbium and tantalum present in solution could be separated with a continuous flow.

Jan 1, 1972

By Hazel Lyman Nickel

Daring to try where others had failed, Herbert and Lou Henry Hoover translated from the Latin the principal (and first) textbook on the mining and metallurgical profession, De Re Metallica, 1556, which had been in use for two centuries and then had lain dormant for 350 years in a language unreadable except by a chosen few. Thus the Hoovers enriched the English tongue with a vitally important contribution to history in the fields of mining, metallurgy, and chemistry. To them it was a joint hobby, because they were actively interested in the beginnings of the mining profession in which they had both been trained. Illuminating the years of toil to perfect this translation shone their ideal of service to humanity, since, in the Preface, they refer to their task as "a labour of love", which had to find the moments for its execution in night hours, weekends, and holidays, extending over a period of about five years. And they add: "If the work serves to strengthen the traditions of one of the most important and least recognized of the world's professions, we shall be amply repaid". While a student at Stanford University, during the years of 1891-95, Herbert Hoover had become familiar with a copy of this Latin mineralogy classic, De Re Metallica, a rare book in the private library of Dr. John C. Branner, at that time head of the department of geology and mining. Another Stanford student in geology was also examining and studying the ponderous volume of twelve 'books'. She was Miss Lou Henry, of Monterey, who graduated in 1898, and the following year became Mrs. Herbert Hoover. Interwoven through the tapestry of their life experiences gleamed the silver thread of their interest in this mediaeval Latin textbook. Just nine years lacer, the Hoovers had commenced their translation, while they were in temporary residence in London after the seething years in China under the shadow of the Boxer rebellion.

Jan 1, 1949

By R. G. Reddy

Solid state reduction of roast movat chromite ore with carbon was carried out as a function of C/FeO ratio and temperature in the range 800°C to 900°C by thermogravimetry analysis (TGA). A two stage mechanism, (1) the reduction of FeO present in Roast Movat with carbon monoxide; and (2) the regeneration of CO by the oxidation of carbon with CO2 was proposed. The rate controlling step is the carbon oxidation reaction. A kinetic equation, that of random nucleation, was proposed. The activation energy for the reduction was determined to be 55800 J/mole and is compared to those activation energies determined for other chromite ores.

Jan 1, 1998

By R Zavadil, S Kuyucak, F Fazeli

Proton exchange membrane (PEM) fuel cells generate electricity by reacting hydrogen and oxygen. A thin, bipolar electrode material provides a medium for electron exchange with the electrolyte, alternately serving as anode at the hydrogen-rich side and cathode at the oxygen-rich side. Stainless steels have sufficient corrosion resistance to qualify as bipolar plate materials. However, the protective chromite layer increases the contact resistance, the battery’s internal resistance; and thus, decreases the electrical efficiency of the fuel cell. A heat-treatment is proposed and investigated via simulation by ThermoCalc / Dictra and experimentally, to generate a sufficient quantity of conducting surface carbides that breach the protective layer. Once carbide growth is arrested, a subsequent heat-treatment is also needed at a higher temperature to restore the corrosion resistance by filling-in the Cr-depleted layer (sensitization) around the carbide particles.

Jan 1, 2014

By Ihsan Berk Tulu, Ted Klemetti, Deniz Tuncay, Cicek Sena, Zhao Haochen

"Analysis of Longwall Pillar Stability (ALPS) and Analysis of Retreat Mine Pillar Stability (ARMPS) treat the pillar as a passive structure that is designed to carry overburden dead-weight. This dead-weight is calculated by simple rules based on the geometry of the mining, such as “tributary area theory,” “pressure arch theory,” and “abutment angle theory.” Although the pressure arch loading approach indirectly accounts for the generally stiffer overburden response of narrow and deep panels, it does not include the effect of specific geology of the overburden in load calculations. The relationship between successful pillar layouts and overburden geology can be incorporated into the load calculation by using the Ground Response Curve (GRC) approach.This paper introduces the GRC modeling methodology to investigate the effect of overburden geology and excavation geometry on load transfer mechanisms using seven field measurement case studies from four U.S. mines. It was also shown that the modeling methodology used to derive GRC in this study approximates mining-induced stresses and deformations within 5% of the values measured in the field.INTRODUCTIONFrith and Reed (2017) stated that current state-of-the-art pillar design methods ignore the overburden mechanics and use estimated dead-weight of overburden to compute pillar sizes. In the United States and around the world, overburden loading is typically estimated by simple geometric rules, generally with the tributary area theory (TAT). The specific overburden mechanics, structural competence of the overburden strata, geology, in situ stresses, and overburden/pillar interactions are typically ignored. However, these important mechanical responses affect the stability of the mine pillars and openings; therefore, they also affect the safety of the mine workers.Research conducted by the National Institute for Occupational Safety and Health (NIOSH) after the Crandall Canyon mine disaster (Esterhuizen, Mark, and Murphy, 2010) showed that small panel width-to-depth ratios and stiff-strong overburden result in a reduction of the observed pillar loads, much smaller than the TAT estimate. In fact, as a response to the Crandall Canyon disaster, Mark (2010) implemented a pressure arch loading approach into the latest ARMPS program to recognize the inherently greater stability of narrow panels at depth. The pressure arch approach is a first logical step to introducing non-tributary area loading into the practical ARMPS program. Although the pressure arch loading indirectly accounts for the generally stiffer overburden response of narrow and deep panels, it does not include the effect of specific geology and mechanical response of overburden in the load calculations."

Jan 1, 2019

By L. N. Hill

The classifiers on the primary grinding circuit at Cyprus Sierrita have been upgraded from 0.66 m (26 in) diameter hydrocyclones to 0.84 m (33 in) diameter hydrocyclones. This has resulted in a 4.3 % (11 t/h) (12 standard tons/hour) increase in mill throughput while producing a flotation feed which contains 4.8% less +300 micron (48 mesh Tyler screen size) material. This reduction in flotation feed particle size has increased copper (CU) recovery by 0.8 %. Various grinding circuit relationships were evaluated. These relationships include circulating load versus throughput, horizontal versus vertical cyclone configuration, and the effect of cyclone components on performance. We conclude that the improvements achieved are due to a shift in the overflow size distribution created by a cyclone diameter more suited to our operation, and by eliminating the cyclone capacity constraint in the grinding circuit.

Jan 1, 1994

By Mu Chen, Ye-Shuang Xu, Dong-Wei Hou, Shui-Long Shen, Huai-Na Wu

"This paper presents a laboratory investigation on the mechanical behaviors of the cement-clay admixture improved by polypropylene fiber. Cement can significantly improve the clay admixture. The fiber additive also improves the strength and ductility of the improved clay. The Unconfined Compression Strength (UCS) of the polypropylene fiber-reinforced cement-clay presents an overall trend to grow with the increase of fiber length. The improved clay reached its peak strength at the fiber content of 0.5%. Then the UCS of the improved clay will slowly reverse if the fiber content continues to rise. For study of curing time, improved clay behaves better in its early strength, but an inhibition will be brought about if fibers are excessive.INTRODUCTIONGround improvement technology is essential for construction of structures in soft ground. Some traditional techniques often cost much but result in little. For instance, along the coastal region of China, soft ground is often improved by backfill with high quality sandy soil transported far away, leading to high additional haulage costs and long construction period. Reutilizing the excavated soil as backfill or subgrade after treatment, by contrast, will be more economical and effective (Hufenus et al., 2006). Many researches have been conducted to improve the compression strength of soft soil, among which, the method of mixing the soft soil with cement and fly ash is one of the most common ways (Kolias et al., 2005; Horpibulsuk et al., 2009; Porcino et al., 2012). It is known that soil resists well against compression and shear force but behaves poorly in resistance to tension. Therefore, utilizing tensile elements such as fibers and strips to improve the tensile strength will be effective because of its strength isotropy, better durability and cost effective (Haeri et al., 2000; Kaniraj and Havanagi, 2001; Consoli et al., 2010)."

Jan 1, 2015

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By Do-Hyeong Kim, Jong-Jin Pak, Jung-Mock Jang, Min-Kyu Paek

"Thermodynamic relations among Mn, Al and N in liquid iron were studied by measuring the effect of Mn on the solubility product of AlN in liquid Fe-Mn-Al-N alloys in the temperature range from 1773 to 1873 K. The critical Al and N contents for AlN formation were determined by the metal-nitride-gas equilibration technique over wide ranges of melt composition and temperature. The effects of Mn on N solubility in Fe-Mn and Fe-Mn-Al melts containing Mn up to 26 mass% were separately determined in the same temperature range. The experimental results were thermodynamically analyzed using the Wagner's formalism to estimate the critical Al and N contents for the onset of A1N formation. The validity was checked by the observation of inclusion evolution in Fe-20%Mn-1.5%Al-0.6%C-0.3%Si-0.012%N melt during cooling and solidification.IntroductionRecently, high manganese steels such as Twinning Induced Plasticity (TWIP) steels have been developed as next generation steels because of their high formability as well as excellent strength and ductility.[1•2l In these steel grades, a large amount of Mn (15-20 mass%) and Al (1-2 mass%) are added to liquid steels, and such high Mn and Al concentration bring the great challenges to the steelmaking and casting processes. Mn significantly increases the N solubility in liquid iron and the AlN inclusions can be easily formed at such high Al concentrations due to high affinity of Al and Mn with N in liquid steels. Although the AlN inclusion is known to be a dominating and considered as a detrimental phase for the hot ductility of steels,l3l thermodynamics of AlN formation in high Mn-Al alloyed liquid steels was not well known.Moreover, the melting point of these steels decreases down to near 1623 K as increasing Mn content up to 20 mass%. However, most of thermodynamic data has been measured at the steelmaking temperature around 1873 K. Even at steelmaking temperature, there are huge scatters in thermodynamic interactions of Mn and Al on N in liquid iron. The nitrogen solubility in Fe-Mn alloy melts has been measured using the Sieverts' method[4l and the samplinij method[5-7J in the temperature range of 1813 to 1973 K. In the authors' recent study,[8•9 the N solubility in Fe-Al alloy melts was measured using the sampling method in the temperature range of 1823 to 1973 K. However, the simultaneous effect of Mn and Al at high concentrations on Nin liquid Fe-Mn-Al-N alloys is still not known. Also, there remains uncertainty about the temperature dependence of the interaction parameter of Mn on N in liquid Fe-Mn alloys. Therefore, it is worthwhile to check the temperature dependence of this parameter at a low temperature near the melting point of Fe-Mn alloys. There have been few studies on the characterization of non-metallic"

Jan 1, 2014

By E. H. Baker

Vapour pressures of sulphur have been measured over the temperature range 340-1039°C by means of boiling-point measurements, an internally heated pressure vessel being employed with argon as the pressure medium. The results are expressed satisfactorily by a four-term pressure-temperature relation. At the cited critical temperature of 1040°C the calculated critical pressure is 204 atm. From the pressure-temperature relation and available thermal data for the vapour, the approximate composition of the saturated vapour in terms of the various molecular species has been derived for the critical point

Dec 1, 1971

By E. E. Maurer

Kerr-McGee has operated the Ambrosia Lake uranium mill since startup in 1958. Tonnage milled per day has varied from 3500-7000 tons. The mill capacity is currently rated at 7000 tons per day. The process consists of two parallel circuits following crushing and sampling, \\lhich include open circuit rod mill grinding, sulfuric acid leach, cyclone classification, and counter-current washing circuits of sand classifiers and slime thickeners. Pregnant solution is clarified and polished by precoat pressure leaf filters prior to amine solvent extraction. Yellowcake is precipitated from the pregnant strip solution with ammonia, filtered and dried.

Jan 1, 1972

By K. M. Kim, J. B. Kemeny

A case study was conducted with 5 shots with varying pre-blast block sizes and explosive energies. From this case study a site-specific predictive fragmentation model was developed. There are two main innovations in this study. One is using an image analysis program (Split-Desktop 3.0) on the bench face to obtain the pre-blast block size (F80) quickly and consistently. Another innovation is to utilize the Schmidt Hammer Hardness (SHH) to estimate intact rock strength.

Jan 1, 2011

By M. E. Smith

Chile is the world's largest copper producer and as such sets the standard of practice in copper SX/EW design. The authors summarize the liner systems used at many of Chile's major copper producers both operating and planned. The evolution in the state of the art is also discussed, considering both economic factors and Chile's burgeoning environmentalism.

Jan 1, 1994