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By V. A. Zhilina, I. V. Shadrunova, O. E. Gorlova

"The aim of the study is to develop and scientifically justify a new adaptive approach to the separating processes of deep and complex processing technogenic mineral raw materials. Technogenic mineral resources as a waste of mining and processing industry are mostly complex objects that have specific features of material composition and technological properties and make it processing ineffective with traditional schemes of mineral raw materials enrichment. Mineral wastes are regarded in this study as a complex object with a large number of signs in conditions of uncertain environment and object. However, adaptation is regarded as the process management system’ adaptation to the specific the properties of the object and the environment that has several hierarchical levels corresponding to different stages in the management of complex object. An adaptive approach is considered as a methodological basis of multivariate schemes for opening the mineral resources and creating mechanisms that could transfer these potential technogenic resources to the actual that significantly expand the mineral resource base of the country's black, coloured, rare, noble metals and construction materials. In this case, potentially the solution to the most pressing social and environmental problems associated with the adverse effects of past economic activity simultaneously with the commercial objectives. This approach to the wastes mining and related processing manufacturers meets the core idea of sustainable development as the balance of interests of State, society, business, private enterprise and each person in the areas of rational use of resources, economic efficiency and environmental safety. On the example of metal-containing raw materials in the form of slags of ferrous and nonferrous metallurgy, ferrous metallurgy sludge, mature fine tailings, the application of adaptive approach illustrates to the development of technologies of its deep and complex processing as phased, thoughtful movement from a comprehensive study of technogenic raw materials to build optimal topologies of technological schemes for processing the mineral wastes. INTRODUCTION Involving the Russian economy in the system of global economic relations significantly changes the nature of the country's competitiveness in the development of the world market and urgently requires competent management of its own natural and mineral resources. The latter at the present time in real economic processes cease to be a passive material foundation and become the producing basis in the production processes in the status of so-called natural capital. Introduced in the field of economic theory at the end of the 20th century, this term means both the flow of natural services and real natural resources. Consequently, natural objects, which act as natural resources of a certain production, today must necessarily be evaluated in a strategic sense. Modern standards of sustainable development presuppose that the economy should equally be oriented to balance the interests of the state, society, business, individual enterprise and each person in the spheres of rational use of resources, preservation of healthy ecosystems, ensuring well-being, high quality of life and environmental safety of not only the current generation, but also respect for the rights of future generations, that is, intergenerational equality. Most types of minerals are classified as non-renewable resources, therefore resource-saving in the sphere of mineral and raw materials complexes is one of the most important factors-indicators characterizing the degree of approximation to the model of rational subsoil use, and, consequently, sustainable development (State Report, 2017)."

Jan 1, 2018

By Dennis A. Hansen

The solubility of anhydrous aluminum chloride in solutions of titanium tetrachloride and vanadium tetrachloride was determined as part of a re-search project-by the Bureau of Mines to make a homogeneous alloy sponge of titanium, vanadium, and aluminum. Solubility curves were established using an autoclave at 75°, 100°, 125°, and 150° C. The solubility of AJC13 in TiC14 is 0.2 wt pct at 75° C; it increases to 18.3 wt pct at 150° C. The data concur with data from earlier researchers of this bi-nary system for 75° to 125° C. For the VC14-AlC13 binary system the solubility of AlC13 is 0.1 wt pct at 75° C, increasing to 1.6 wt pct at 150° C. For the TiC14-AlClrVC14 ternary system the solubility of AlC13 decreases from the values found with a pure TiC14-AlC13 system to the lower values found with a pure VC14-AlC13 system at the respective temperatures.

Jan 1, 1986

By Aurel Goodwin

I chose the title "Let's Clear the Air" for this afternoon's presentation because it has two meanings, the literal and the figurative. Most of you know what MSHA is. Most of you know what MSHA does. And, for the most part, most of you know why. What I hope to accomplish today is to "clear the air" around our health standards, to clarify for you how MSHA views its congressional mandate under Title I Section 101(a)(6), (7), and (9) of the Mine Safety and Health Act. Asbestos, silica, radiation, noise, welding fumes, carbon monoxide, lead, hydrogen sulfide, nitrogen dioxide - the list of physical and chemical hazards encountered in the metal and nonmetal mining industry is as diversified as the industry itself, possibly even more so. In addition, miners are often exposed to several of these health hazards simultaneously.

Jan 1, 1980

By William H. Dresher

A study has been made of the reaction mechanisms occurring during the salt-roast process to form water-soluble sodium vanadate compounds from the vanadium oxide compounds present in vanadium-bearing ores and concentrates. Two reactions have been identified, either of which lead to water-soluble compounds--oxidation of sodium chloride by water vapor and. oxidation of sodium chloride by oxygen. The former reaction has been found to be predominant in the salt-roast process. A kinetic treatment of the data has shown that for the formation of sodium metavanadate the rate-controlling step in the reaction, in which sodium chloride is oxidized by water vapor is the decomposition of a species containing water and sodiumm chloride, on the surface at the gas-solid interface. For the formation of sodium pyrovanadate, the rate-controlling step is the decomposition of a species containing water and sodium metavaradate on the surface. The transportation of water through the system, perhaps as a sodium chloride-water complex or a sodium metavanadate-water complex, and the actual chemical reaction are relatively fast compared to the initial surface decomposition step. A similar treatment on the data for the oxidation, of sodium chloride by oxygen has shown that the rate-controlling step, is the actual transportation of oxygen from the gas-solid interface to the reactive site. This transportation is by a sequence of two diffusion processes. Transportation during the early stages of the reaction is by the diffusion of oxygen through a continuous layer of reaction product. After, the first few minutes of reaction time a second diffusion process begins and is continuous for the remainder of the reaction. This second diffusion process involves the diffusion of oxygen, through a layer of reaction product that has developed voids around which the oxygen must diffuse. The hindering, nature of this latter process causes the rate of transportation of oxygen to the reaction site to be considerably slower than by the simple diffusion mechanism initially followed. A thermodynamic treatment of the data has shown that the energy of activation for the decomposition of the water-sodium chloride species on the surface is -12.1 Kcal. per mole. For the decomposition of the water-sodium metavanadate species on the surface' the energy of activation is -15.1 Kcal. per mole. The results of this study indicate the limiting mechanisms of the basic reactions occurring during the salt-roast process. These results suggest what variables should be examined in applying this information to actual plant operations.

Jan 1, 1961

By N. E. Hanna

To be approved for use in underground coal mines in the United States, explosives and blasting devices must pass certain safety tests prescribed by the Federal Bureau of Mines. These tests are described in Schedule 1-G4/ (explosives) and Schedule 26A5/ (blasting devices). An explosive or blasting device that passes the appropriate tests is placed on the active permissible list. As this list is subject to continuous revision, it has been the practice of the Bureau of Mines to publish periodically the names of explosives and blasting devices that have been added to the active list, as well as those that have been transferred to the inactive list; changes in brand names also are reported. The present circular gives all explosives and blasting devices on the active permissible list as of December 31, 1957, and shows all changes, additions, and transfers in that list between December 31, 1951,6/ and December 31, 1957.

Jan 1, 1958

By Mauritz Kotze, Jason Furtney, Ewan Sellers, Sandy Etchells, Tom Szendrei

The development of a simple model for gas flow and burden movement has driven the need to improve our understanding of burden breakage mechanisms for single hole blasts and the interaction between multiple holes in solid and jointed rock masses. Conventional analytical understandings of the burden breakout using the elastic-tensile fracture model were studied and found to provide a breakout angle that is independent of burden in contradiction to experimental data. By considering rock fracture in terms of Mohr-Coulomb plasticity using analytical expressions from the field of cavity expansion analysis an improved relationship between breakout angle and burden is derived until the point of critical breakout at which the angle of breakout suddenly changes from between 90 degree and 100 degrees to zero. This suggests that the critical burden occurs at about 0.6 times the radial fracture zone calculated from the analytical solutions.

Jan 1, 2013

By C. C. Shale

Current-voltage relationships for air at high temperature in negative corona are compared with relationships predicted by theory. Deviations are discussed. Eased on the latest theoretical concept of electron detachment from negative ions and recent findings in basic research on free electron gases, results of applied research show the existence of free electrons in air at high temperature and high field strength-to-pressure ratios.

Jan 1, 1967

By R. L. Morse

The thermodynamic program is similar to previous mine ventilation programs but has been expanded to consider the compressibility of air. The thermodynamic program does consider: 1) air density variations, 2) humidity changes, 3) intake, exhaust, and underground fans, 4) heat transfer between rock and air, 5) refrigeration of heating plants, both surface and underground, and 6) heat generated by equipment, both diesel and electric. 110st of the compressibility factors are handled in the branch calculations. The field survey necessary to supply-data for this program is quite similar to the basic base and leap-frog pair of stations method used with most incompressible mine ventilation programs. The thermodynamic program is a complete package of ventilation network analysis which can provide mine management with good operational control and planning of mine ventilation systems.

Jan 1, 1977

By Larry Hopkins

The molten metal circulation pump has become a staple for melting aluminum in reverberatory furnaces. The forced convection that is created in the melt efficiently provides circulation while dramatically improving melt rates, lowering fuel consumption, extending refractory life, and providing metallurgical homogeneity. Two metallurgical guidelines that are important to many casthouses are molten metal inclusion levels and hydrogen gas content. In order to improve molten metal quality, furnace and casting practices must 'manage these molten metal defects, Today specialized in-line degassing and filtration equipment is used downstream of the furnace to accomplish these tasks. In contrast, the molten metal gas injection pump has metallurgical contact time in the process for hours during the charging/homogenization cycle. The qualitative benefits of employing a gas injection pump to "pre-clean" are outlined and discussed against historical empirical information obtained with alternate methods. Further, a recent study quantifies the merits of this gas injection technique as an effective molten metal quality improvement tool. Specifically, the effects on inclusion level as determined by PoDFA?, gas content as determined by A1SCAN? sampling and alkali metal content as determined by spectrographic analysis are examined in relationship to various gas feed compositions and flow rates.

Jan 1, 1995

By Dalene Joalet Steenkamp

Excavation of industrial-scale furnaces allows for the systematic study of reaction sequences by identifying the different reaction zones within the furnace. In 2013, Transalloys excavated a 48 MVA submerged arc furnace that was used for silicomanganese production using the ore-based route. The excavation method was reported elsewhere as was observations made in terms of refractory wear and modes of electrical energy dissipation prior to excavation. The paper presented here, reports on the process reaction zones observed during the excavation and subsequent phase chemical analyses of a number of process samples obtained during the excavation. The zones identified were a loose burden zone, a dry coke-bed zone, a wet coke-bed zone, a hard build-up zone, and an alloy zone. The results are compared to observations made in the excavation of an industrial-scale SAF and a pilot-scale SAF in Norway. The presence of the hard build-up zone below one of the electrodes and absence of a slag zone below all three electrodes are unique features of the SAF excavated at Transalloys.

By T. A. E. Breen

A new high intensity grinding technology has been developed and is now being commercialized by Hicom International of Australia. This has led to the development and manufacture of Hicom 120 grinding mills which are now being sold internationally for a range of mining industry applications. The first commercial process application has been for the diamond sector, where the ability of the mill to remove host kimberlite rock by attritioning, with no damage to the thereby liberated diamonds, is seen to be a most beneficial attribute. There are, however, many other mineral industry applications for this mill.

Jan 1, 1999

By W. J. Kuit

Since closure in 1968, the Wedge Mine, situated adjacent to the Nepisiguit River in New Brunswick, has been flooding with acidic water containing toxic levels of heavy metals. Cominco Ltd. has undertaken a series of pollution control measures to mitigate the threat posed to the river quality. Included has been a successful treatment campaign in 1976 which discharged in excess of 30 million gallons of high-quality effluent from the accumulated volume of mine water. The sources of contamination have been identified as actively leaching waste dumps. A comprehensive program of permanent corrective measures has been prepared which will culminate in mine backfilling. Once completed, the unacceptable burden of water treatment in perpetuity at a non-producing property will be removed.

Jan 1, 1977

By Richard H. Olson

Talc is currently mined in the U.S. in six major districts. The size and depth of the ore bodies and their mineralogy dictate the types of products manufactured and the mining and processing methods which must be employed. The geology of the major deposits is well known and will be but briefly discussed The major emphasis will be placed upon the past history of the districts, the size and depth and configurations of the ore bodies, the ore mineralogy, and how all of these factors govern the types of mining and processing operations which may be employed in each of the districts.

Jan 1, 1984

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By Y. M. Shneerson, E. E. Zhmarin, E. M. Vigdorchik

One of the Gipronickel Institute activities is research and development of customized leaching technologies. The work is performed in several steps. Leaching kinetics are studied on a lab-scale according to a special procedure. Experimental data are processed using mathematical models of batch and continuous processes. Reliability of kinetic data and preliminary calculations is verified experimentally in laboratory reactors of various capacities. If necessary, certain parameters of the mathematical model are adjusted after pilot plant tests in continuous mode ( 4-reactor train, each with 25 L capacity). The specified kinetic characteristics along with the mathematical model are used for further development of industrial leaching technology.

Jan 1, 2005

By R. Rodgers

The Pinto Valley Concentrator of BHP Copper Inc. restarted its sulphide mining operations in September 2007 to produce copper and moly concentrates. During the plant production ramp up, the copper/moly circuit quickly reached the copper grade and recovery targets, but the production and quality of the moly concentrate continued to be a challenge. Even though several improvements in the moly circuit were completed, the final moly concentrate did not meet contractual specifications. After reviewing several options to improve grade and reduce contaminants, the installation of three flotation columns was chosen. The column design and construction were done utilizing in-house craftsmen and engineers. Ten days after commissioning, the columns successfully reached a steady operation and began producing moly concentrate to the required specifications, that is, high moly tenors and low copper and iron content. In this paper, the operating parameters, mass balance, design, installation, commissioning and operation of the new flotation columns will be discussed.

Jan 1, 2010

By William I. Weisman

Natural sodium sulfate is obtained from both brines and solid deposits. The brines almost always contain other salts with sodium chloride predominating. They may be obtained from surface occurrences, such as Great Salt Lake or from shallow subterranean deposits. Althought many sodium sulfate minerals are known to exist, only three are of commercial significance. These are thenardite, the anhydrous salt; mirabilite, the decahydrate; and glauberite, the double salt of sodium and calcium sulfate. The reader is referred to Weisman (1983) for details on mineralogy and geology of sodium sulfate minerals. Sodium sulfate deposits, either in the form of brine or solid minerals, are found in many parts of the world. Natural sources, by far, provide the primary supply of commercial grades in Canada, Mexico, Spain, and probably in the U.S.S.R., Chile, Argentina, and Turkey. In the United States, production of natural material and synthetic (including by-product) are about equal in volume and have been for many years.

Jan 1, 1984

By T. Reed Scollon

Before we can attempt to answer the question of what can be expected from coal research, let us examine why research is done in other fields and what others expect for the money they spend on research and development. Up to 1900 almost all organized research was carried out at universities. Most of the support came from the university, and by present standards the amount of research was extremely small. The motivation for university research was basically discovery of new phenomena, with the objective of advancing knowledge. Side by, side with this organized effort was that of individual inventors who were primarily responsible for applying this new-found knowledge to useful purposes. During this period inventors were rarely supported by anyone, and experimentation was carried out either in their spare time or at the expense of earning a living. Men like Edison, I believe, were the first to demonstrate on a large scale that one could systematically apply newly discovered scientific principles to inventions that would serve useful purposes and would return a profit to those engaged in the effort. The tremendous expansion in research therefore began with the realization and demonstration that the scientific discovered could be applied in such a way as to return a' handsome profit to those who invested in it. The motivation of many of the research personnel however, remained the satisfaction associated with new discoveries, The money to support their efforts came from those interested in a return on their investments. Since the First World War and a rapidly accelerating rate since the Second World War another important motive for supporting research has appeared--the needs associated with national defense; this type of research has been supported almost exclusively by the Government.

Jan 1, 1959

By Antonio Zechini, Giuseppe Iorio, Massimo Grisolia

"The new C Line of the Rome Metro runs northwest to southeast across the city center, with 30 new stations and a total length of more than 15.5 mi (25 km). Due to the presence of a dense urban environment, the selected solution for the construction of the stations consists of a cutand- cover excavation, which is retained by multipropped diaphragm walls to minimize settlement and prevent damage to the nearby structures. The bottom of the excavation of the underground stations are about 82 ft to 98 ft (25 m to 30 m) below ground surface, and about 66 ft to 82 ft (20 m to 25 m) below the groundwater table. To ensure dry conditions and to prevent hydraulic base heave instability, deep well systems were designed and used to lower groundwater level and piezometric head during excavation. The dewatering field tests showed how the local stratigraphy strongly affects the dewatering efficiency. Finite element modeling (FEM) of steady state filtration were used to compare the soil permeability with Lefranc in-situ test results and to verify the efficiency of the grouted plugs. The geological sequence along the new C Line consists of a very heterogeneously layered deposit. The base deposit of stiff overconsolidated clay (“APL,” Pliocene age) is overlain by fluvio-palustrine very dense sandy gravels (“SG,” Pleistocene age), which are then overlain by medium stiff clayey silts or dense sandy silts (“AR” or “ST,” Paleotevere units). These deposits are overlain by covered by pyroclastic volcanic soils, tuff, silty sand and sandy silt (Middle to Upper Pleistocene) deriving from the Colli Albani apparatus. A layer of made ground (“R”) of varying thickness covers the stratigraphic sequence and the natural soil profile everywhere.The local hydrogeological framework is very complex and characterized by a double groundwater system. The upper main aquifer is mainly represented by the “pozzolane sequences” (“PR/PN”), while the lower aquifer consists of a deposit of sandy gravel (“SG,” Pleistocene), which is underlain by marine claystone bedrock (“APL,” Pliocene). The pyroclastic deposits (e.g., pozzolane, lithoid and pseudolithoid tuff and clayely tuff) show large variations in permeability due to porosity, compaction processes, sealing and secondary fracturing. Permeability values for each soil type were determined using Lefranc tests at variable head and using pumping tests. The Lefranc tests indicated a wide range of permeability."

Jan 1, 2017

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005