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By S. Fitzel

The Betts process for electrorefining of lead has been in operation since 1902 in the Trail Operations Metallurgical complex. The Betts process allows production of high purity lead in a single electrochemical step. Process improvements and plant expansions have taken place over the many decades of operation of this process which has proven to be robust, flexible, and capable of successfully treating a large range of anode bullion compositions. This paper reviews the history of the Betts lead electrorefining process, the innovations and quick industrial adoption of new discoveries that took place at the end of the nineteenth century. The process was first implemented in Trail Operations and integrated very well with metallurgical needs then and now.

By Andrew Rietz, Yu Bao, Steven Halewski

"HP-Pile foundations are the most favorable type of foundations for bridges because of their constructability, versatility with regard to subsoil conditions, and settlement controllability. For many years, bridge engineers have puzzled over the most economical way to orient HP-Piles: Should the strong axis be oriented in the longitudinal direction or in the transverse direction? The accurate design of foundations may considerably reduce construction costs. In order to answer this question, 3-D finite element models will be set up to analyze the effects of pile orientation on bridge behavior. Because seismic loading usually controls the structural design in seismic zones, it is important to investigate the effects of pile orientation under such loading. HP-Piles are designed conservatively due to the uncertainty of the dynamic soil-structure interaction during earthquakes. For the bridge substructure, the soil’s stiffness plays an important role in load distribution as the soil and piles act as a combined system to resist the seismic loading. The dynamic soil-structure interaction mechanisms of bridges in both the longitudinal and the transverse directions will be investigated through the use of 3-D finite element models. The numerical models will realistically simulate the soil-pileabutment- wingwall-superstructure system subjected to seismic loads. Nonlinear soil springs will be employed to model the non-elastic soil behavior. The analysis will provide theoretical support to the design practice.IntroductionAs sustainability has asserted itself in the public’s eye, bridge professionals have rushed to develop criteria for sustainable bridges. The three main categories that define and distinguish sustainable bridges are: lower energy input, increased durability, and simplified deconstruction. By optimizing the structural members, the engineer is able to reduce the material quantities for the bridge, effectively reducing the energy input for the bridge (Hunt; Whittemore). A deeper understanding of soilfoundation- structure mechanism will facilitate sustainable bridge design by lowering energy input and increasing the service life of bridges (Rietz et al.)."

Jan 1, 2017

By Fumito Tanaka

In the Mitsubishi Continuous Copper Smelting & Converting Process, the heat for the dissolution of scraps is effectively supplied from the melts strongly stirred by top injection. Various kinds of shape of scraps not only powder but also lump, sheet, cube and so on can be treated without any emission of dust and fugitive gas, and no additional furnaces for scrap processing is necessary. Therefore, this process is much suitable for recycling. The authors have investigated the melting rate of ice sphere into a water bath equipped with top blowing lances as a basic study for the dissolution of scrap. Hydrodynamic experiments were carried out, and mathematical models were applied to the results. The results show that the melting rate of ice sphere strongly depends on the standing waves at the bath surface.

Jan 1, 2001

By A. Pearson, F. A. Auld, S. O. Colbeck

"""The theory of buckling of shafts and Steel tunnel-linings"" was published by E. Amstutz in 1970 and commented on by S. Jacobsen in 1974. The authors have revised and enhanced Amstutz’s work to address Jacobsen's comments on its limitations and to extend its validity over a wider range of pipe/shaft geometries, including those commonly found in deep mine access shafts. The author has looked at Amstutz’s assessment of strengthening with flexible shear anchorages and adapted the theory of non-linear shear deformation response of bolts to develop a method of assessing increased buckling capacity utilising the full plastic shear capacity of studs. INTRODUCTION “Amstutz Buckling” refers to the buckling of pipe embedded in concrete under external uniform pressure. In terms of a mining environment, this relates directly to the design of a watertight shaft. This load case will commonly occur where a main shaft is cast against a geostatically stable primary liner and the only load applied to the final shaft is that of a uniform ground water load. Ernst Amstutz wrote his first paper on buckling of pressure-shaft steel linings in 1950 and subsequently improved his theory (Amstutz, 1970), which was then widely adopted for use within the industry. Years later, an alternative approach (Jacobsen, 1974) was proposed. Within his paper Jacobsen critiques Amstutz work, identifying some mathematical inconsistencies and highlighting limitations of the theory imposed by approximations adopted by Amstutz. Despite these limitations Amstutz work has still been used as the favoured design theory for use in the mining industry. In reviewing this body of work the author realised that with the advent of readily available computing software it was possible to adopt an iterative approach using Amstutz approximate formulae to find a solution to the original precise formulae, thus eliminating the limitations highlighted by Jacobsen The shear deformation to load characteristics of bolts has long been established (Crawford & Kulak 1968) and used for the plastic design of bolted connections in shear. This relationship is directly transferable to the design of shear studs, typical properties are well known, and actual values easily established in simple lab tests. The author has taken this relationship and modified Amstutz theory (Amstutz, 1970) for shear anchored strengthened liner buckling, to give a more efficient solution, using readily available material properties."

Jan 1, 2019

By Charlene Gokhale

Geopolymerisation has emerged during the last few years as an industrial and ecological approach to construction and waste management. By utilizing waste materials and their reactive properties, it is now possible to create geopolymers systems that not only mechanically durable enough to be used as construction materials but are also potential stable immobilisation systems for toxic waste. Previous studies by Van Jaarsveld et al. (1997) and Van Jaarsveld et al. (1998) have reported on the numerous applications of geopolymers in the immobilisation of toxic metals. Research into the possible utilisation of geopolymers as an encapsulation media for organic waste has however been rare. This paper therefore provides an insight into the possible utilisation of geopolymers as a binder for hazardous organic materials.

Jan 1, 2003

By M. C. Flemings, S. B. Brown

"Metallurgy, as all of material science and engineering, rests on the intellectual foundations of processing-structure-property-performance relationships. Today it is widely recognized that processing has been too long neglected and presents exciting opportunities for exploitation. New processes, many of them already in the laboratory, will be exploited in the year 2000 and beyond, for near net shape forming and for achieving-new metallurgical structures and composite structures. Process modelling will alter the way we think about process and product design. Processes themselves will increasingly be automated and controlled by computers, altering the nature of the workplace and the tasks of the metallurgical engineer of the future. IntroductionInnovations in metal processing is hardly a new phenomenon, with the field thousands of years old. Nonetheless, the next few decades offer particularly important opportunities to improve our ability to process these materials. We appreciate today the variety of processing paths available to us, including vapor-, plasma- and electro-deposition, multiple phase and casting technologies, and non-equilibrium processes, and how these affect structure at the atomic level and at higher levels of aggregation. We understand the basic physical mechanisms involved far better than even before and have remarkable new abilities to predict, control, and simulate the kinetics underlying processes, and the processes themselves.The following sections describe these new opportunities in greater detail. First, we examine developments in the modelling of metal processing. We then consider some implications associated with process control and automation. Finally we present what we consider to be particularly promising metal processing technologies, and conclude with a few summary comments."

Jan 1, 1988

By G. A. Eltringham, A. F. Sarofim, A. A. Shook, M. P. Heap, B. R. Adams, K. A. Davis

This paper discusses the use of a reacting CFD model to determine chalcopyrite kinetics in a drop tube furnace and to predict the reaction of a chalcopyrite concentrate in the reaction shaft of an industrial smelter. Reacting CFD codes can be applied to determine the consequences of the interaction of gas with particles and therefore improve the ability to derive kinetic parameters that take into account the different temperature and oxidation histories that different particles will see. This paper describes the application of such a model to derive improved kinetic parameters for the pyrolysis and oxidation of chalcopyrite. The improved kinetic parameters derived from the drop tube studies are used to simulate chalcopyrite concentrate reactions in the reaction shaft of an industrial smelter. The reaction shaft model includes the effects of turbulent fluid mechanics, entrained flow mixing, turbulent particle dispersion, heterogeneous particle reactions, radiative and convective heat transfer, and surface and bath deposition rates. Particle reaction and composition characteristics are predicted as a function of particle trajectory and deposition and are used to aid in evaluating shaft performance.

Jan 1, 1999

By Ragnhild Aune

In fire refining of copper, the affinities of various impurity elements on dissolved oxygen is of great significance. Further, in the design of oxygen probes in liquid copper, the influence of solute interactions on the activity of oxygen need to be considered in order to evaluate the oxygen concentration in molten copper. The present paper presents a series of measurements of the activities of oxygen in liquid Cu-M-o alloys (where M stands for Mn, Zn, As, Se or Te) carried out by the present group employing the solid electrolyte galvanic cell technique. Extreme care was taken to control the oxygen potentials in the inert gas atmosphere, and to keep the oxygen levels very low in the molten metal. The oxygen content was determined by analysis of the samples taken out from the melt. The results obtained showed that Mn has a strong negative influence on the activity coefficient of oxygen in liquid copper. A similar, but less prominent effect was observed in the case of Zn. Arsenic had no influence on the activity of oxygen in Cu (liq.). Se and Te had slight negative effect on oxygen activities in copper at XO > 10-5, while at lower oxygen levels the interaction coefficients were found to be positive. The results obtained were compared with empirical models for the calculation of interaction coefficients available in literature.

Jan 1, 2003

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

By A. G. Jackson, Mark D. Benedict, Steven R. LeClair, Yang Cao, David M. Conrad

"Electronic Prototyping (EP) represents a new and powerful medium that many in science and technology view as the research paradigm of the future. Actually, EP has many handles, sometimes referred to as simulation-based design involving more long term objectives such as virtual reality, but regardless of the 'spin', the direction of EP is an enhanced visual paradigm to enable a new set of tools for engineers and scientists alike. Tools to not only automate, visualize and compute otherwise intractable problems but to enable augmentations of our ability to perceive that which is interesting and new -""a virtual version of a process"" [1] prodding us on the pathways of materials and process discovery.IntroductionActually there are many reasons to apply sensors to materials, such as smart or adaptive materials/structures, and new materials synthesis/processing [1], only some of which are motivated by improved product quality and/or productivity. Although U.S. Air Force applications of sensors to materials processing represent but one of many perspectives, hopefully it is a perspective which will engender new ideas and insights in addressing future challenges in materials research. To provide context and establish need for future sensor applications in materials processing, we will utilize on one of several Air Force vistas or '21st-Century' objectives."

Jan 1, 1997

By B. R. Westphal

The Integral Fast Reactor (IFR) concept being developed by Argonne National Laboratory is based on the pyrometallurgical processing of spent nuclear metallic fuel with subsequent fabrication into new reactor fuel by an injection casting process. During fabrication, a dilute scrap stream containing uranium alloy fines and broken quartz (Vycor) molds is produced. Waste characterization of this stream, developed by using present operating data and chemical analysis, was used to evaluate different uranium recovery methods and possible process variations for the return of the recovered metal. Two methods, comminution with size separation and electrostatic separation, have been tested and can successfully recover over 94% of the metal. Recycling the recovered metal to the injection casting process was evaluated for the different economic and process impacts. The physical waste parameters and the important separation process variables are discussed relative to their effects on the viability of recycling the material. A discussion of the criteria that is being used to establish the acceptable operating limits is also presented.

Jan 1, 1992

By R. M. Reyes, D. Negrete, G. Herrera

First Majestic Silver Corp’s La Encantada Silver Mine is a producing mine with a capacity of 3,000 tonnes per day. The La Encantada team is currently constructing two small-scale caving mines, including the San Javier breccia caving mine. The new mine is constructed within a mineralized breccia body composed of clasts of varying sizes and with very poor rock quality. Due to this poor rock quality, primary and secondary supports are required to support both the development and production stages. Since the proximity of the new mining levels to existing old workings, correct selection of the support system and proper production controls, instrumentation, and monitoring are very critical to maintain the stability of the pillars and fortification elements. An increased ground deformation due to the load transfer during the production stage is expected. This report reviews the primary and secondary support elements used in the different stages of mining, the monitoring of ground deformation, and the steps taken to analyze and visualize the collected data in order to enable the geotechnical team to manage caving stress and maintain pillar stability. INTRODUCTION First Majestic Silver Corp. (“First Majestic”) is a Canadian mining company focused on silver production in Mexico that operates six producing silver mines, including La Encantada Silver Mine (“La Encantada”). First Majestic acquired La Encantada in 2006. La Encantada is located in the northwestern portion of the state of Coahuila, in northern Mexico, in the municipality of Villa de Ocampo. The mine lies in the northern part of the Sierra Madre Oriental physiographic province. The mine location is shown in Figure 1. La Encantada is a producing mine, with a mill processing capacity of 3,000 tpd, and a 4,000 tpd capacity cyanidation leaching circuit equipped to process fresh underground ore and old tailings amenable to be reprocessed. The mine is currently employing several mining methods, including overhand cut and fill for narrow veins, small mantos, and other minor deposits. A subset of caving methods are applied on the larger, but weak, mineral deposits, such as at the San Javier breccia and La Prieta breccia. La Encantada consists of vein, manto, breccia pipe, and chimney deposits with concentrations of silver, lead, iron, and zinc in oxidized mineralization enclosed by calcareous sedimentary formations of Cretaceous age. At deeper levels, there is sulphide mineralization in skarn with zinc and silver concentrations associated with a granodiorite intrusion.

Jan 1, 2019

By Stephen G. Mlot

The evaluation of mineral projects involves the identification, mitigation and management of significant uncertainty. Benchmarking is an essential and effective way of increasing confidence and reducing uncertainty associated with input parameters and assumptions. Comprehensive and detailed benchmarking will ensure ?best practice? technologies, methods and systems have been considered and that the appropriate practices can be identified and incorporated into the project. In conjunction with the involvement of experienced industry practitioners, benchmarking is best employed throughout project evaluation to enable early identification of ?errors?, producing more accurate and predictable outcomes. Considerable time and effort is required to gather data and information, which should be benchmarked by the project evaluation team. There is a history of mining projects underperforming, on production, on costs and on return to the investors. The quality of mine plans and feasibility studies, and the quality of the input data is being questioned in many ways. Benchmarking assists sound project evaluation practices, by providing a database of actual results, to validate project inputs and outcomes, ensuring they are realistic and achievable. Benchmarking also provides unbiased, statistical support as the basis for sound investment decision making and ensures well considered decisions are made resulting in a more efficient study process. The evaluation of the quality of projects which are the subject of transactions also benefits from the use of real data obtained from a benchmarking database. Vendors are quick to highlight the benefits of their projects, and conceal the flaws, inflating the value. Buyers will want to quantify the potential of a project through the due diligence process relying on actual results from benchmarking. For the reasons broadly outlined above, benchmarking should be considered as an essential component of effective Project Evaluation.

Aug 1, 2013

By Jessica M. Wempen

Differential Interferometric Synthetic Aperture Radar (DInSAR), a satellite-based remote sensing technique, has been demonstrated as a potentially practical method for measuring mining induced surface subsidence. Unlike traditional methods of subsidence monitoring, DInSAR has the capacity to generate subsidence data on a regional mining scale with a relatively high data density. Using DInSAR to evaluate subsidence over large regions with relatively long time scales has the potential to help quantify the impact of subsidence in the mining region, and provide a means for validating whole-mine geotechnical models. In this study, nine pairs of interferometric data from the Japanese Advance Land Observing Satellite (ALOS) were processed using DInSAR to generate displacement maps for a group of trona mines in southwest Wyoming. The data cover a time span from December 2007 to March 2011. The maximum subsidence for one of the mines totaled 1.3 meters for this period. Cumulative DInSAR displacement maps show the development of subsidence over time. In this mining region, surface subsidence is generated primarily by extraction of trona using retreating longwalls. Additionally, trona is extracted by solution mining, which also generates measurable surface subsidence.

Jan 1, 2014

By Harold V. Fairbanks

This investigation included a study of three different methods for the acoustic drying of ultrafine coals. Ultrafine coal being defined as coal which passes through a 100 mesh sieve. The first method employed stationary drying of small coal samples in sound fields having frequencies of 12,000 cps and 20,000 cps. Sound intensities up to 150 db were used. The second method employed the use of rotary drying kilns. The effect of such variables as temperature, sound intensity, coal feed rate, air flow rate, and initial moisture content were studied. The third method employed the use of a multi-tiered, vibrating screen dryer. The effect of initial moisture content and residence time were studied.

Jan 1, 1970

By G. R. Addie

While the cost of transporting raw phosphate matrix from a pit to a processing plant via slurry pipelines is more efficient than it could be by rail cars, conventional trucks or belt conveyors, it still amounts to many millions of dollars, and in many areas there still exists much room for improvement. By taking advantage of pipeline test data on different slurries, it is possible to reduce costs by optimizing pipeline diameters, operating velocities and slurry concentrations. Better wearing, more efficient pump designs are now available which, if applied correctly, can lead to significant savings. The authors discuss what benefits are possible in relation to the electrical operating and wear maintenance costs and go into some of the factors associated with taking advantage of these benefits, identifying what they see as being practically possible.

Jan 1, 1998

By W. D. Cho

The slag chemistry in steel processing plays an important role in terms of the removal of impurities including alumina particles. In the present study, the dissolution of solid alumina particles in CaO-based fluxes at the temperatures between 1450 and 1550 °C has been investigated to determine dissolution kinetics and mechanism. Alumina particles were added directly in the slags and the size of alumina particles was measured as a function of time using optical and scaru;ling electron microscopes. The dissolution rate has also been obtained as a function of Si02, CaF2, MgO and MnO contents in the slags. The diffusion boundary layer between alumina and bulk slag phase has been observed and analyzed using SEM and EDX. In addition, some experiments have been performed for the dissolution of alumina in BaO-based fluxes.

Jan 1, 2003

By Y. Y. Liu, H. M. Domanus, W. T. Sha

"Casting is fundamental to manufacturing of many types of equipment and products. Although casting is a very old technology that has been in existence for hundreds of years, it remains a highly empirical technology, and production of new castings requires an expensive and time-consuming trial-and-error approach.In recent years, mathematical modeling of casting has received increasing attention; however, a majority of the modeling work has been in the area of heat transfer and solidification. Very little work has been done in modeling fluid flow of the liquid melt. This paper presents a model of fluid flow coupled with heat transfer of a liquid melt for casting processes. The model to be described in this paper is an extension of the COMMIX code and is capable of handling castings with any shape, size, and material. A feature of this model is the ability to track the liquid/gas interface and liquid/solid interface. The flow of liquid melt through the sprue and runners and into the mold cavity is calculated as well as three-dimensional temperature and velocity distributions of the liquid melt throughout the casting process.IntroductionBower et al. (1), in their 1969 review of the evolution of some of the casting techniques, stated that:""The evolution of technology requires alternatives to be available so that choices can be made that lead to changes. The role of solidification science and other disciplines related to casting technology is to develop a better understanding of process and product, so that a wider range of alternatives is possible.Alternatives, whether from science or from invention, must lead to improvements in casting ""utility."" Utility, or economic advantage, must include consideration of total system costs, and final product value. The cost of materials, melt processing and finishing should be optimized with casting costs, since all are part of the production system. It is the favorable relationship between total processing costs and product value that makes a change in casting technology viable, but the best change is not possible unless technology has provided an understanding."""

Jan 1, 1986

By Kazuyoshi Kamimura, Masaya Kawata

"It has been 30 years since the cement deep mixing (CDM) method developed in Japan. CDM method has been applied to many structures. While various technical improvements have been implemented in the meantime, the single-axial and double-axial technologies used at the time of its initial development are still prevalent.In response to the recent trend of reducing construction costs, we developed a triple-axial CDM method called the “Lemni 2/3 Method.” This method uses two lemniscate motions caused by newly developed auxiliary stirring devices and employs a double-axial injection method in which the cement slurry injection takes place only from the outer two axes. In this way, it is possible to create a stabilized body around the three axes. Moreover, this method does not require substantial equipment investment as conventional construction machine and facilities can be used without modification and large volume work is possible.With these technologies, this method can achieve a substantial reduction in the construction period and cost, while ensuring the same level of improvement quality as conventional methods. As a result, this method is being applied to ground improvement work in a variety of places.Lemni 2/3 Method was first put to practical use in 2004. Since then, the method has been used for ten projects. In this paper, we show some application examples of this method.OUTLINE OF TRIPLE-AXIAL CDM METHOD (LEMNI 2/3 METHOD)In the newly developed CDM method (Lemni 2/3 Method), work efficiency is improved by employing triple-axial stirring blades instead of the conventional single- or double-axial type. Existing conventional construction facilities for double-axial type can be used with only minor equipment additions, because the cement slurry injection takes place only from the outer two axes.Construction Machine and Construction MethodThe combination of major construction machines of the Lemni 2/3 Method differs little from the standard specifications of the double-axial type as shown in Fig. 1. Existing work control equipment can be used without modification, which is further evidence of the simplicity, convenience, and economy of the new method. The Fig. 2 photo shows a full view of the construction machine, and the Fig. 3 photo shows the stirring blades and the auxiliary stirring devices. The work procedure for the Lemni 2/3 Method is shown in Fig. 4."

Jan 1, 2015

By R. A. Campbell

Pig iron and silicospiegeleisen were produced experimentally from a very low-grade manganiferous iron ore from Steep Rock, Ontario, by a two-stage electric smelting process. The most favourruble operating conditions were determined for each stage. Cement clinker then was made by calcining the slag from the second stage of smelting, with additional limestone and alumina. (This slag would normally be a waste material). The cement clinker produced had the composition of commercial Portland cement, and met the physical test requirements of the Canadian Standards Association Specification A5-1951 for normal Portland cement as well as could be expected for a material produced on .such a small scale.

Jan 1, 1958