Search Documents

By Run-sheng xu, Hai-yang WANG, Di ZHAO, Teng-fei SONG, Jian-Liang Zhang

This paper was mainly focused on the different semi-cokes and charcoal which could be new fuels for blast furnace injection. Through the comparative study with bituminous coal and anthracite coal, the properties of semi-cokes and charcoal were presented in this research. 10 indexes of different fuels were obtained by different standard experiment, including proximate analysis, ultimate analysis, igniting point, explosivity, transportation characteristic, ash properties, grindability, calorific value, combustibility and reactivity with CO2. According to the data analysis, it provided a theoretical basis for rational utilization of various blast furnace fuels, and helped to broaden the scope of the blast furnace injection fuels. This research could contribute to energy conservation, emissions reduction, and sustainable development of iron and steel enterprises.

Jan 1, 2015

By Dietmar Eifler, Marcus Klein, Hendrik Kramer

Conventional methods to characterize the fatigue behavior of metallic materials are very time and cost consuming. That is why the new short-time procedure PHYBALCHT was developed at the Institute of Materials Science and Engineering at the University of Kaiserslautern. This innovative method requires only a planar material surface to perform cyclic force-controlled hardness indentation tests. To characterize the cyclic elastic-plastic behavior of the test material the change of the force-indentation-depth-hysteresis is plotted versus the number of indentation cycles. In accordance to the plastic strain amplitude the indentation-depth width of the hysteresis loop is measured at half minimum force and is called plastic indentation-depth amplitude. Its change as a function of the number of cycles of indentation can be described by power-laws. One of these power-laws contains the hardening-exponentCHT eII, which correlates very well with the amount of cyclic hardening in conventional constant amplitude fatigue tests. To identify heat-treatment-parameters and SAE 52100 TRIP-alloys with high hardening rates as well as their damage tolerance the PHYBALCHT- and PHYBALLIT-method were used. One modified SAE 52100 TRIP-alloy was investigated in detail. The fatigue behavior and the cyclic hardening of the selected SAE 52100 TRIP-alloy was investigated and compared with conventional SAE 52100. Conventional stress-controlled fatigue tests were performed on a servo-hydraulic test system with a frequency of 5 Hz and a load ratio of R = -1. Different rates of cyclic hardening were identified. The size of the nonmetallic inclusions leading to crack initiation and the number of cycles to failure were used to evaluate differences in the damage tolerance capability.

Jan 1, 2015

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020

By J. A. Brown, F. P. Kerr, M. A. Archer

Extensive testwork on Global Atomic’s Dasa Project in Niger has been conducted at SGS Minerals laboratory in Lakefield, Ontario. Much of this testwork has focused on a two-stage counter-current leach as a means of improving leach efficiency and decreasing reagent consumption. The ore contains uranium mineralization requiring relatively high sulphuric acid concentrations during leaching to achieve acceptably high extractions. Excess free acidity in the leach solution may be utilized by recycling the high acid solution and contacting it with fresh ground ore. The resulting pregnant leach solution (PLS), now higher in uranium concentration and depleted in free acid, is forwarded on to uranium recovery by solvent extraction. The first stage residue proceeds to the second stage leach where fresh acid and oxidant are provided to leach the remaining uranium. This paper presents the results of the testwork conducted on both a Master Composite and Variability samples.

Jan 1, 2020

By B Armstrong

The Proterozoic poly-metallic Trilogy deposit was discovered in 1997, and until recently, mining evaluation was stalled due to poor metallurgical performance. Unlocking the substantial economic value of the deposit required a coming together of geologists, mineralogists, metallurgists and mining engineers, who by working collaboratively, uncovered the detail necessary to allow the required metallurgical breakthroughs to occur. The deposit itself is described as a sedimentary exhalative (SEDEX), with an enriched lead-zinc-silver core surrounded by a broader envelope of copper-gold mineralisation. The geological domains were defined in broad terms based on the style of mineralisation, assay values and lithology. These domains, while adequate for the resource estimation process, failed to translate into representative metallurgical domains. Additional work with new techniques defined regions in the deposit with altered processing properties which could not be recognised by conventional geological logging. Such additional complexities could not be appreciated at the outset of the metallurgical test work program.These regions were defined by applying the EDTA analysis method for recognition of where the valuable sulfides, particularly galena, had been partially modified by oxidising conditions. Hence, the flotation response of the valuable sulfide minerals was diminished and the increased amount of heavy metal cations available in the system significantly reduced selectivity in the flotation process.Understanding the detail of this complexity was essential in determining representative metallurgical domains, which was the first step in the long road of development.

Sep 5, 2011

By A. Kobzhanov, S. Saparova, S. Brochot, D. A. Mango

KATCO (an ORANO Mining and Kazatomprom joint venture) is the largest in-situ leach uranium mining operation in the world, exploiting the Muyunkum and Tortkuduk uranium deposits in southern Kazakhstan. After extraction from the deposits, uranium is then transported via a hydraulic network to be purified in three processing plants located near these deposits. Within KATCO, with the support of ORANO Mining and CASPEO, in 2018 and 2019, a large project that had as its main objective to improve the uranium accounting system was implemented. The objective of this paper is to describe this project and all the changes that it entailed. At KATCO plants, a black-box approach was previously used for uranium accounting. However, it is recommended to use all the available measurements and to deploy a data reconciliation model (between well-fields and plant) as the reconciliation uncertainty is overall lower and it provides a more accurate uranium balance. During the deployment of this project, the rules and algorithms to generate the uranium accounting report, the associated flow diagrams (for uranium accounting), the streams, units of operation, stocks, reporting and Key Performance Indicators calculation rules were re-defined.

Jan 1, 2020

By Taghi Sherizadeh, Paul Brooks, Dogukan Guner, Samuel Nowak

Large excavations are well known to result in rock mass deformations which can present challenging situations for mine personnel. Most of the currently available ground movement monitoring devices fail to adequately provide mine operators with highly accurate and meaningful insights into rock mass deformation or displacement. The use of distributed fiber optic sensors (DFOS) in industries such as oil and gas and civil engineering has shown the potential of these sensors to deliver real-time, highly accurate, and long-range distributed strain measurements with great success. However, the use of these sensors in underground mining is limited to a few case studies.

By C J. Greet

Oil can enter a flotation circuit from a number of sources (for example, from mining equipment, oil leaks from the grinding equipment and coatings on the grinding media, but to name a few). Folklore generally states that any oil that contaminates the ore entering the flotation circuit is considered to have a negative impact on flotation. That is, a loss in concentrate grade and recovery.This represents a dilemma for some grinding media suppliers, who use a variety of quenching medium (air, polymer, oil or water) to achieve the desired physical properties of the ball. In the case of high chrome grinding media it is necessary, in some instances, to quench in oil to give the ball the right degree of toughness, which invariably leads to these balls having a thin film of oil on their surface. Once the grinding media arrives on site and site personnel recognise that the balls are “covered” in oil, they generally insist that the oil will have a deleterious impact on flotation performance.Obviously, any supplier “worth their salt” would take remedial action at the point of manufacture to minimise this problem. However, does quenching oil actually present a significant “threat” to the flotation process? This paper provides both laboratory and plant data describing the effect quenching oil has on the flotation of copper sulphide ore, with surprising results!

Aug 8, 2011

By V. E. Housman

EPA's Mining Waste Section within the Office of Solid Waste is continuing to collect and analyze information on mining waste management practices. Starting in 1991, the Mining Waste Section has continued to conduct site visits and prepare case study reports on the waste generation and management practices of operating mines. In choosing sites to study, a reasonable attempt was made to provide diversity in mining commodity types, geographic regions, geology, climate, and environment. To date, EPA has visited the following mines: Asarco Troy (copper) in Montana, Newmont Rain in Nevada (gold), Cyprus Thompson Creek (molybdenum) in Idaho, LTV Steel (iron) in Minnesota, Phelps Dodge Morenci (copper) in Arizona, Doe Run Fletcher (lead) in Missouri, Brewer (gold) in South Carolina, IMC Four Corners (phosphate) .in Florida, Pennzoil Culberson (sulfur) in Texas, Nerco Cripple Creek (gold) in Colorado, Copper Range White Pine (copper) in Michigan, Magma San Manuel (copper) in Arizona, Colosseum (gold) in California, and several gold placer mines in Alaska, including the Valdez Creek Mine. EPA has prepared a case study report on each facility. The mine operators were provided an opportunity to comment on their respective site visit report and their comments have been included in' each respective report. These site visit reports have in turn been incorporated into technical resource documents which provide a detailed description of each mining sector. EPA is currently reviewing the technical resource documents and plans to release the documents in the Spring of 1994.

Jan 1, 1994

By Ronaldo Câmara Cozza

Iron aluminide alloy; Ball-cratering wear testing; Rolling abrasion; Wear volume; Coefficient of friction

Jul 31, 2018

By Alex Matheson, Nick W. D. Massey, Peter T. Bobrowsky

Crowing pressures on aggregate resources include diminishing reserves, high transportation costs, sterilization and land use conflicts. In the absence of detailed resource knowledge for a particular region, aggregate resource potential maps provide the best "first approximation" regarding the surficial distribution of sand and gravel. The 1:50 000 scale Level Ill aggregate potential map integrates several important factors which influence the management of sand and gravel. Data used to generate this type of thematic map is readily available in most areas, fieldwork required is minimal, there is a logical quantitative evaluation of the data layers and integration is easily accomplished on a desktop PC-based platform. Also the aggregate potential map, with its focus on identifying areas of potential future aggregate exploitation as well as present inventory, provides a useful tool for the aggregate explorationist.

Jan 1, 2001

By Denis Yaychuk, Gary Billingsley

The economic eva luation of a mineral property or mining venture should include the quantification of ri k as part of the analy is. The re ults of such an analysis provide the decision-makers not only with the most likely financial outcome and the probability of achieving that or any other outcome. but al o with a ranki ng of the relative impact of all the ri sk factors. These type of resu lts offer more complete information for investment and technical deci ions than the traditional cash flow/ ensitivity analysis. In addi tion. by attempting to quantify ri sk. the personnel providing the va ri able input are forced to take a much clo e r look at the data involved, and are fo rced to work together. the reby increa ing substantially the awa reness of the impact their work and others· work has on th e outcome of the analysis.

Jan 1, 1986

By Kyle A. Perry, Ethan A. Steward

The mining of underground coal presents several hazards for miners, including the risk of an explosion fueled by methane gas and coal dust. Methane gas, produced during coal formation, can continuously leak into old workings and build up through its lower explosive limit. Underground coal mines are required to maintain safe conditions, either by ventilating old workings or sealing them off using approved methods. Seals must be designed to withstand instantaneous pressures for a minimum of four seconds. A design strength of at least 50 pounds per square inch (psi) is required for atmospheres monitored and maintained inert, 120 psi for non-inert or not monitored, and greater than 120 psi for special cases. Due to the high cost and testing environment availability, most mine seals are designed through calculations and computer modeling and not subjected to full-scale testing in a representative environment. High pressure is not the only threat that mine seals may be exposed to. During an underground explosion, pressure waves and gas expansion may propel common mine items and objects to a high velocity, generating enough energy to damage mine seals and reduce their strength. Damaged mine seals may fail to contain their rated pressure, allow high pressure gas and fumes to vent through the seal during an explosion, or allow gasses to leak through the seal later after an explosion has occurred. This paper examines the effects of high velocity impacts of common mine materials and items on a reinforced mine seal rated to 120 psi.

Jun 2, 2023

By Jorge Armstrong, Sean Warren, JOSEF BOURGEOIS

The application of statistical analysis software programs has proven useful for the investigation of rockfall runout distance along a designed slope. Rockfall modeling programs are continually being upgraded with more sophisticated analysis tools, such as the use of the rigid body versus lump mass models. Engineers at mine sites utilizing the software may have varied experience related to these models, their associated input parameters, and how to interpret the generated results. To address this concern, researchers at the Spokane Mining Research Division (SMRD) of the US National Institute for Occupational Safety and Health (NIOSH) investigated the influence of slope height, slope angle, slope material, and rock size for both rigid body and lump mass models in a 2-D statistical analysis program. Based on a literature search and industry input, specific ranges common to that of an open pit mining environment were chosen for each of the input parameters to determine 90% rock runout distance as well as their sensitivity to change. Data collected from this numerical analysis and simulation will be compared to empirical rockfall data gathered through the duration of the Highwall Safety project conducted by NIOSH from 2022–2026.

Jun 18, 2023

By Qingguo Xue, Jingsong Wang, Guang Wang, Yuanyuan Zhang

Due to complicated structure and composition of high-phosphorus iron ore, pure substances were used to simulate the chemical composition of high-phosphorus iron ore to study the reaction of fluorapatite at different temperatures and effect of additives. The gasification process of P during carbothermic reduction process was investigated using a quadrupole mass spectrometer gas analysis. It is found fluorapatite was reduced to phosphorus which diffused into iron and gas phase. From the gas analysis, it was observed that PO and P gas species were vaporized around 800 °C. As the reduction temperature increased, the diffusion of phosphorus into iron was enhanced. The presence of Ca(OH)2 as additives not only promoted the reduction of iron oxide, but also decreased the degree of fluorapatite reaction to inhibit P into iron.

Mar 1, 2018

By Zhi Yang, Ahmad Ghahreman, Farzaneh Sadri

Impurity removal is a very important stage of the hydrometallurgical treatment of rare earth elements (REE) processing circuit, which is performed after water leaching of the acid baked REE concentrate. Lime neutralization has a high efficiency in removal of impurities and is the preferred process due to its economic advantage; however, the process has its own problems, such as the production of large volumes of gypsum and co-precipitation of REE with gypsum, i.e. REE loss. This work deals with the effect of several additives (cetryltrimethylammonium bromide (CTAB), polyvinylsulfonic acid (PVS) and polyacrylic acid (PAA)) on the uptake of REE by gypsum from synthesized acidic solutions. The main purpose of this study is to investigate the changes in the crystalline morphology of gypsum precipitated by the addition of crystal habit modifiers and to determine the crystal changes’ effects on the uptake of REE by gypsum. In this regard, different concentrations (0.2, 2 and 5 g L−1) of above-mentioned additives were studied at room temperature.

Mar 1, 2018

By Jeffrey Oke D.S.H. Oke, Craig J. Archibald, Anna P. Perry

Underground mining at the Diavik Diamond Mine (Northwest Territories, Canada) commenced in 2003 and has targeted four kimberlite pipe orebodies. The A154 North (A154N) pipe was mined using longhole open stoping with cemented and uncemented rock fill. During the later stages of mining, unique geotechnical challenges developed in the upper portion of the orebody, resulting in difficult ground conditions during secondary stoping. The two uppermost stoping horizons in A154N (A- and B-blocks) were located within the widest portion of the kimberlite pipe and were mined using a multi-panel retreat, overhand primary–secondary extraction sequence. Primary stopes were commonly advanced to near the top of each block prior to the initiation of secondary stoping. Ore development was excavated to full stope width, and secondary development initiated at the base of the block adjacent to mined-out primary stopes resulted in the formation of tall, slender hanging pendant pillars—locally up to 100 m high—laterally supported by frictional contact with adjacent cemented rockfill pillars. Beginning in 2015, differential vertical movements across the ore-waste contact of A154N pendant stope pillars were identified, and the extent and rates of movements increased significantly as secondary stoping progressed through to 2025. These conditions created significant challenges for the safe extraction of remaining stopes and raised concerns for deeper mining blocks if similar methods were maintained. This case study describes the factors contributing to the observed ground behaviour and outlines the strategic mine design modifications and tactical risk mitigation measures implemented to manage geotechnical risk in the remaining A- and B-blocks and to prevent recurrence in lower A154N mining horizons.

May 2, 2026

By P. Somasundaran, D. R. Nagaraj, Tarun Bhambani, P. Patra

Flotation separation and recovery of value minerals from ores containing fibrous silicate minerals are known to be quite challenging. Earlier studies have established that the metallurgical challenges (poor selectivity and recovery, high energy consumption, etc.) arise from the impact of the fibrous minerals (with high aspect ratio) on pulp rheology, which was found be rather complex. The complex rheological behavior of ore suspensions containing particles with high aspect ratio and its influence on flotation outcome are investigated in this study. Flotation tests and rheological measurements were carried out with both ores (containing fibrous minerals) and a model system comprising nylon fibers (chemically inert) added to a copper ore that had no fibrous mineral. These studies allowed the determination of contributions of physical properties of the fiber to pulp rheological behavior. Optical microscopy images of the fiber pulp indicated that the fibers entangled to form two levels of microstructures: two-dimensional (2D) aggregates under semi-dilute (< 20% solids) conditions and three-dimensional (3D) microstructures at concentrations > 30% solids. The yield stress (σ) values determined for the fiber pulp were logarithmically related to the volume fraction of the 2D/3D structures. The relationships developed here for different ARs showed that the yield stress of a flotation pulp changes with respect to shape, size, and the concentrations of the microstructures. Implications to the effects of such entangle networks on selectivity of flotation separation are discussed.

By James Withers, Dongbo An, Jinhong Zhang

A micro-scale investigation was carried out by applying atomic force microscopy (AFM) to study in situ the adsorption of various collectors, i.e., oleic acid, octanohydroxamic acid (HA), and salicylhydroxamic acid (SHA), on bastnaesite in aqueous solutions. The obtained AFM images show that the surface morphology of bastnaesite changes greatly after it comes into contact with the solutions of the collectors, suggesting that all these collectors can effectively adsorb onto bastnaesite. Increasing temperature can facilitate the adsorption of oleic acid onto bastnaesite. Results from attenuated total reflectance–Fourier transform infrared spectrometry (ATR-FTIR) also show that all of these collectors adsorb strongly onto bastnaesite, with strong absorbance spectra being detected. The ATR-FTIR results confirm those obtained by AFM. In general, hydroxamic acid collectors (HA and SHA) adsorb onto bastnaesite mainly in the form of insoluble metal hydroxamate. This specific adsorption mechanism explains that a high selectivity with a moderate collectivity will be achieved with a hydroxamic acid collector for the flotation of bastnaesite.

By Alaina Mallard, Katie Schumacher, Jannette Chorney, Grant C. Wallace, Jerome P. Downey

Commercial ceramic carbide operations require large thermal and mechanical energy inputs in order to produce a powder product. A process that could reduce the energy requirements needed to make these materials would allow for these materials to be implemented in a greater number of industrial applications. In this study, silicon carbide (SiC), tungsten carbide (WC), and molybdenum carbide (Mo2C) were synthesized via the carbothermal reduction of activated carbon loaded with silicate, tungstate, and molybdate anions adsorbed from aqueous solutions. Carburization was carried out under reducing and inert gas atmospheres, at temperatures lower than those utilized by commercial operations. Silicon carbide “whiskers” were synthesized under H2 at 1400 °C, while molybdenum carbide and mixed crystals of WC, W2C, and W were synthesized at temperatures below 1000 °C. X-ray diffraction and scanning electron microscopy were used to characterize the carburization products, and inductively coupled plasma-optical emission spectroscopy (ICP-OES) was used to determine the degree of adsorption onto the activated carbon matrix.

Mar 1, 2018