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By B. W. Steele

"Dofasco began operations in 1912 as a steel foundry located in Hamilton, Ontario. Today, Dofasco is a fully integrated mill that manufactures hot rolled, cold rolled, galvanized and tinplate steels. Customers include the automotive, construction, tubular, manufacturing, appliance, packaging and steel ser-vice centre industries. Raw steel production and purchased semi-finished steel processed in1994 was 3.5 million net tonnes. Dofasco employs 7300 people at its Hamilton facility.Environmental management at Dofasco is guided by its environment policy and associated commitments. This paper discusses Dofasco’s responsibility for its products as it relates to these commitments. Dofasco is com-mitted to:n the principles of sustainable development that require that activities be conducted in a manner that provides for the present without compromising the ability of future generations to meet their needs. These principles will be integrated into product design, manufacturing and business planning;n managing renewable and non-renewable resources through the responsible application of reduce, reuse, and recycle principles;n minimizing any potential impact of its operations and products on the environment, employees, customers and the community;n continuous improvement of the effectiveness and integrity of our environmental management systems;n developing understanding among all employees about their responsibilities, and assigning the necessary authority; andn meeting the standards set by relevant legislation and international agreements through participation with governments and the diligent application of economically feasible and scientifically sound methods and technologies."

Jan 1, 1996

Electrochemical behaviors of synthetic and natural enargite in buffer solutions have been investigated using open circuit potential, stationary polarization and cyclic voltammetry as functions of solution pH, scan direction, scan range, scan rate and dissolved O2. The results indicate that the electrochemical behaviors of synthetic and natural enargite are very similar; solution pH, scan direction, scan range and scan rate have remarkable effects on the electrochemical behavior of enargite while dissolved O2 has little effect on the electrochemical behavior of enargite. The potential range in which enargite possesses the ability of passivation is from ?0.9 V to + 0.83 V vs. SCE. Enargite is most stable in neutral and alkaline solution around potential ?0.2 V vs. SCE. The main oxidation products on enargite surface in alkaline solution are Cu(OH)2 while the potential imposed on it is within the range of ?0.2 V to 0.33 V vs. SCE and Cu(OH)2 + S0while the potential applied is higher than 0.52 V vs. SCE.

Jan 1, 2014

By S. Goto, S. Yamashita, K. Hata

"The average consumption of zinc dust for purification of zinc leaching solution is more than 25 kg per tonne of electrolytic zinc. Authors proposed to remove impurities in zinc leaching solution by electrolysis instead of cementation by zinc dust. The effects of copper and arsenic on electrodeposition of cobalt in zinc sulfate solution were examined fundamentally using a potentiostat. It is observed that cobalt is easily deposited on a cathode at potentials under -480mV with arsenic. Mesh cathodes of stainless steel and lead anodes were used in a small electrolytic cell and the electrolyte was circulated through 'the electrodes during the electrolysis. The effect of electrolyte circulating rate , pH, cell temperature, current density, and concentration of copper and arsenious ions on removal of cobalt were studied. Removal of Cd and Ni are also examined.IntroductionCobalt is difficult to remove from a zinc leaching solution by a simple cementation reaction using zinc dust. However, it is easily precipitated by zinc dust with co-addition of arsenious or stibinous oxide and copper ion in practical operations(I), (2), (3). The consumption of zinc dust for purification is 16-152 kg per tonne of electrolytic zinc and 65% of this zinc dust consumption is used for cobalt purification. The average retention time for purification of cobalt is 4.5 hours (1). A more economical process for purification is desired instead of zinc dust. The mechanism of this acceleration effect of copper and arsenious oxide on removal of cobalt are explained by the authorsas follows; a galvanic cell is formed between zinc dust and copper which is precipitated firstly, and cobalt is reduced on copper as Co-As alloy by this galvanic current(2). This assumption was confirmed in experiments using a galvanic cell with a membrane( 4). The following galvanic reactions occur between zinc dust and copper precipitate; on copper cathode,2H+ + 2e -= Hz(g)2Coz+ + 2HAs02 + 6H ++ 10e -= 2CoAs + 4HzOand on zinc anode,Zn = Zn = 2+ 2e –This galvanic current becomes almost zero in a zinc sulfate solution which includes only cobalt and no arsenious oxide, and cobalt is weakly deposited on a copper cathode. Cobalt deposition requiers a high degree of cathodic polarization. However, the galvanic current flows almost constantly in an electrolyte, which includes arsenious oxide, and the cathode potential is kept at about -500mV. Cobalt is precipitated as Co-As on the cathode.The authors assumed that cobalt may be removed by electrolysis at a very low current density instead of zinc dust and the following experiments were carried out. In the first part of this paper, the fundamental experiments using a potentiostat on the behaviour of cobalt in zinc sulfate solution are described. In the second part, the results of the electrolysis are reported. Cobalt is removed by a new type of an electrolytic cell, which was desigoed to <Iccelerate the rate of deposition of cobalt. The removal of cadmium and nickel in a solution which includes cobalt and arsenic are also examined."

Jan 1, 1997

By J J. Laas, A J. S Spearing

Considering the capital outlay, running costs and inherent difficulties of backfilling operations at depth the benefits need to be clearly established, quantified and then exploited. Expansion of Vaal Reefs Exploration and Mining Company towards even deeper, highly faulted ground, and the process of establishing codes of practice for the management of rockfalls and rockbursts, required that a sound support strategy be formulated. This paper describes the derivation of an overall backfilling strategy on Vaal Reefs. Use was made of experience gained over some 12 years with backfilling. Numerical modelling was used to estimate potential benefits of backfilling the deepest mining areas still to be extracted. In exploiting a probably unique opportunity, two contiguous mining areas bounded by the same major geological structures, were compared. One was extensively backfilled and the other not at all. Shaft sinking through a backfilled stope added another dimension to the database.

Jan 1, 1998

By David M. Hopstock

To help assure an adequate supply of minerals to meet the Nation&apos;s economic and strategic needs, the Bureau of Mines is conducting bench-and pilot-scale research using wet high-intensity magnetic (WHIM) separation to recover iron from oxidized taconites of the. Lake Superior region. The advantages and disadvantages of WHIM separation in relation to other separation methods, the most recent innovations in WHIM flowsheet design, and the role of mathematical models in process optimization are discussed.

Jan 1, 1979

By Dale S. Preece, Ruilin Yang

Shock wave physics is an important part of air-deck behavior since the bulk explosives in the column impart a shock into the air-deck where the air shock then passes through the air-deck at a rapidly attenuating velocity. Through both high-fidelity modeling and shock physics theory it is shown that the resulting pressure in the air-deck is two orders of magnitude less than the detonation pressure of the explosive. The induced air blast reflects from the bottom of the borehole and this reflected pressure, even though doubled, is still approximately two orders of magnitude less than the detonation pressure. Air-shocks will ring back and forth in the air-deck for a few tens of milliseconds while the adjacent explosive column(s) are detonating. Transmission of the initial shock through the air along with reflections is an intensive energy consuming process. Energy balance results in shock heating of the air and a temperature increase. However, the increased temperature of the air is also orders of magnitude less than that of the explosive detonation products immediately behind the detonation front. Replacing high energy explosives with zero energy air-decks in a blasthole will always have a negative impact on the adjacent rock fragmentation and movement.

Jan 1, 2016

By E. N. Mounsey

Ausmelt Technology was selected by Bindura Nickel Corporation (BNC) as the basis for a new copper circuit to process nickel plant copper leach residue to blister, anode and finally cathode copper and recover PGM values at the Bindura Smelter Refinery (BSR). The process selected, based on Ausmelt Technology to smelt and convert the residue to matte and blister copper and produce a discard slag, is novel incorporating smelting, converting and slag reduction process steps in a single Ausmelt vessel. The process demands a high quality blister copper product with low levels of arsenic and nickel. This paper reviews the project and the initial operational results to the end of 1997 of the Ausmelt Top Submerged Lancing (TSL) smelter and discusses the implications for the wider TSL converter market.

Jan 1, 1998

By Mitsuru Tanahashi

In order to develop an effective process for the production of from metallurgical-grade one (MG-Si), the oxidation removal of boron from molten MG-Si was investigated at a solar-grade silicon (SOG-Si) 1773K by the following two CaO-saturated CaO-CaF2 flux treatment processes. I) Boron removal by flux addition onto the molten M6-8 followed by oxygen gas injection into the melt (Two-stage connecting process). II) Boron removal by simultaneous injection of flux powders and oxygen gas into the molten MG-Si (Simultaneous injection process). These processes can establish the special condition of both high basicity of the flux and the high oxygen partial pressure at the boron removal reaction sites. Through these processes, especially by the simultaneous injection Process using a flux powder injection equipment, the boron content in MG-Si can be efficiently reduced. The obtained results clarified that both processes should be conducted for a time period as short as possible by using as much flux as possible. By repeating the simultaneous injection process for 60 s three times under the optimum operating conditions determined in the present study, the boron content in MG-Si can be reduced from 14 to 4.7 mass ppm.

Jan 1, 2003

By Dolf Vos

The balling section of the pelletizing plant at Hoogovens IJmuiden consists of 7 balling drums. Each with an average capacity of 100 tons of green pellets per hour. The balling drums are equipped with rotating scrapers and water-spraying systems. The scrapers are installed in order to restrict the growth of the race to a certain thickness. The spraying system is used to adjust the desired value of the moisture-content of the rewetted ground ore, the pellets and the race. The desired value is the value by which the balling- process is stable, good pellets are formed and surge occurs within certain limits. In October 1980 the construction of one of the balling drums has been modified. The rotating scraper was removed and the inner wall of the drum was supplied with a rubber-lining. In 1982 a second balling drum has been rubber- lined. At the same time the Tyler vibrating screen of this balling circuit has been replaced by a roller(bed)screen. By the end of 1983 all 7 balling circuits will be equipped with rubber-lined drums in combination with roller(bed)screens. The combination of these two modifications will improve the quality and the screen analysis of the green pellets, moreover resulting in savings on energy- and maintenance costs. This paper describes the influence of a rubber- lining on the balling process and the green pellet quality by carrying out in-plant testruns in November/December 1980. The testrun results have been compared with the results of a not modified balling drum.

Jan 1, 1983

By E. James Quinn

Solvent extraction technology using EHEHPA (2-ethylhexyl phosphonic acid, 2-ethyhexyl mono ester) is the norm for industrial separations of rare earth elements. This process has some shortcomings, including a large number of stages compared to most SX processes and high acid requirement for stripping of the heavy rare earths. In this work, we examine a number of alternative mixed solvent extraction systems: (i) Mixtures of organophosphonic and phosphinic acids such as EHEHPA/Cyanex 272 or Cyanex 572; (ii) Ionic liquid mixtures of EHEHPA with quaternary ammonium chloride (Aliquat 336); and (iii) Mixtures of carboxylic acids for yttrium/lanthanide separations. We discuss and compare the efficacy of these systems with reference to the Nd/Sm separation, which is of industrial significance. Based on the extraction chemistry and the use of modelling tools to define the counter-current solvent extraction circuit, we present a techno-economic analysis of a separation plant and discuss the impact of various solvent systems on the capital expenditure (CAPEX) and operating costs (OPEX).

By David M. Parkes

Geology is frequently complicated, hence only more regular deposits are mined. Coal is generally thick, often steeply pitching and usually soft or well-cleated. Due to competition from open-pit mines, only two underground mines are operating, McIntyre and B.C. Coal. Several other mines are being planned, the method being evenly divided between hydraulic, longwall, and room and pillar. McIntyre mines in the flat part of their formation (up to 20 degrees) uses continuous miners and shuttle cars in the 3m and 6m seams. This company is considering a retreating longwall face. B.C. Coal operates a hydraulic mine in a 16m thick seam dipping at 10 to 55 degrees with a productivity of about 20 tonnes per manshift.

Jan 1, 1982

By W. A. McKinney

In conventional dump leaching of porphyry mine strip wastes, many years are required to extract up to 20 percent of the copper from the contained sulfide minerals. Furthermore, none of the molybdenum, gold, or silver in the strip wastes is recovered by current leaching practices. Because mineralization occurs predominately along fracture planes, breaking of the rock during mining operations liberates and concentrates some of the metal values in the fines. Research shows that upgraded fines can be screened from mine wastes and froth floated for early recovery of copper, molybdenum, gold, and silver. For example, screening a dump sample assaying 0.35 percent copper as chalcopyrite removed about 20 percent of the copper as minus 1/4-inch material that analyzed 0.6 percent copper. About 35 percent of the molybdenum and 20 percent of the gold and silver also reported in the fines. Crushing the mine dump sample to minus 3 inch before screening increased the distribution of copper and molybdenum in the minus 1/4-inch screen fraction to 28 and 50 percent, respectively. Similar results were obtained by screening fines from two other large samples of mine waste dump materials. Flotation studies established that the enriched minus 1/4-inch fines from the three dump samples could be effectively concentrated. Comparative testing revealed that the combination of froth flotation of fines and acid-ferric sulfate leaching of the coarser fraction enabled doubling the recovery of copper over direct leaching of the samples. In addition, significant amounts of molybdenum, gold, arid silver were recovered by flotation.

Jan 1, 1970

By L. M. Demers, D. C. Kuhn, N. El-Ayouby, C. F. Stanley

"Oxygenated metabolites of arachidonic acid (MJ are produced by the alveolar macrophage (AM) and have been shown to mediate inflammatory reactions. We therefore assessed the production of eicosanoids by AM harvested from the lungs of rats ex· posed to a bituminous coal dust for 2 wk in an inhalation chamber in order to determine if AA metabolism was altered in a manner that may promote an inflammatory response in the lung. Exposure to coal dust resulted in a 66% increase in the number of AM harvested, an increase in thromboxane A2 (TxA;i) and leukotriene 84 (LTB,j) production to 222% and 181% of control values, respectively, and a decrease in prostaglandin E2 (PGE:i) production to '62% of control values. In AM harvested from rats allowed to breath clean air for 2 wk following coal dust exposure, PGE2 production returned to control levels but TxA2 and LTB4 production remained elevated. The TxA2 synthesis inhibitor UK 38,485 reduced TxA2 production in dust-exposed AM both immediately and 2 wk following exposure. Thus, exposure of rats to coal dust significantly alters the metabolism of AA in AM, with potentially important aspects of AA metabolism remaining altered even after a 2-wk recovery period. Based on the established role of eicosanoids in inflammatory and fibrotic processes, these results suggest that the alteration of AM eicosanoid production as a result of the inhalation of coal mine dust may be an important factor in the pathophysiology of coal workers' pneumoconiosis.The authors are grateful to Joan Greenwood and Barbara Scheetz for their excellent technical assistance and to Brenda Pavone for the preparation of the manuscript. This research was supported by the U.S. Department of The Interior's Mineral Institute Program administered through the Generic Mineral Technology Center for Respirable Dust under grant 1135142.Request for reprints should be sent to Douglas C. Kuhn, Ph.D., Department of Pathology, The M.S. Hershey Medical Center, Hershey, PA 17033.INTRODUCTIONPulmonary alveolar macrophages (AM) are activated by foreign particles and microorganisms that enter the small airways (Kass et al., 1966; Herscowitz, 1985). This defensive reaction involves phagocytosis, lysosomal enzyme release, and the generation of reactive oxygen species by the AM (Snella, 1986; Rich et al., 1987). A number of agents, including phorbol esters, zymosan, adenosine diphosphate, organic hydroperoxides, and calcium ionophore, have been shown to activate the AM in vitro (Badger, 1986; Marshall and Lands, 1986; Snella, 1986). The AM response to these activators appears to be mediated in part by the oxygenated metabolites of arachidonic acid (AA) (Bertram et al., 1988; Demers et al., 1987; Mcleish et al., 1987).The AM may metabolize AA through cyclooxygenase- and lipoxygenase- catalyzed pathways to produce a variety of eicosanoids including prostaglandin (PG) E2, thromboxane (Tx) A2, leukotriene (LT) B4, LTC4, LTD4, and several hydroxyeicosatetraenoic acid derivatives (HETEs) (Willis, 1970; Camp et al., 1983; Poubelle et al., 1986). The production of these eicosanoids may enhance the. defensive ability of the challenged lung since they stimulate chemotactic cell recruitment to the site of invasion, enhance extravasation of circulating immune cells, and promote local vasodilatation. However, continued stimulation of the AM population, with the consequent production of proinflammatory eicosanoids, may ultimately enhance the disease process by contributing to chronic bronchoconstriction, fibrosis, and the persistent release of toxic oxygen species."

Jan 1, 1990

By Raymond S. Shrode

Transportation is one of several important increments in the total market cost of most commodities. On a national average it has been reported that transportation accounts for about 25% of the total cost of a product at the market place. And industrial minerals are no exception. In fact, the proportionate cost frequently exceeds the 25% average. Further, it may actually determine the economic value of a deposit. Transportation may possibly be thought of as a specialized subject of concern only to a traffic manager and of only nominal interest to the mining engineer, the geologist or other technically oriented member of mineral producers&apos; staff. However, in the industrial minerals field, interest is not commonly confined to exploration, development, production or marketing, but is in contrast an overlapping one. In a very real sense this broad area of interest in the total economics of the business is the specialty of the industrial minerals man. And transportation is a vital part of the total picture. Comments in this paper deal with rail transportation.

Jan 1, 1969

By W. R. Bull

This paper examines water-only cyclone performance for the cleaning of fine coal, and the effects of changes in feed flow rate, feed pulp density, and vortex finder diameter. A model is presented for performance simulation which can be used to predict products obtained based on feed washability data.

Jan 1, 1987

By J. Jung, W. Keller, A. Zucht

"The agitator design for nickel high pressure acid leach autoclaves (HPAL) is critical with regard to the process result, i.e., the recovery rate. Further considerations during the design phase are the avoidance of acid hot spots which reduce the lifetime, due to corrosion of the wetted parts, including components manufactured from titanium. Besides the process knowledge to design HPAL autoclaves, tools such as, Computational Fluid Dynamics (CFD) supplemented by lab testing allow the design of optimized agitation systems. This paper describes the effect that different feed point locations have on instantaneous blending of the reactants. Furthermore, experiments and CFD show where abrasion issues might occur and how to obtain information about the static and dynamic forces acting on internals. We show how simulations can be validated by lab testing to ensure that the CFD models are applied in an appropriate way.INTRODUCTIONAgitated systems in hydrometallurgical processes have to comply with multiple process tasks and in many cases have to withstand extreme operation conditions such as pressure up to 50 bar, elevated temperatures of up to 250°C and exposure to very acidic or alkaline environments and abrasive ores. The process tasks range from instantaneous mixing of reactants, homogeneous suspensions of up to 65% wt. solids with coarse and heavy particles, enhancing the solid-liquid mass transfer for leaching, dispersing large volumes of reactants (gas-liquid, liquid-liquid mass transfer) and moreover to transport generated heat e.g., from exothermic reactions through the vessel walls or internal heat exchangers if required. For economies of scale, agitator systems have reached sizes of 5000 m³ for large open leach tanks with impeller diameters of approx. 6 m, while autoclaves nowadays have exceeded 5.5 meters in diameter with a power demand for a single compartment drive between 300 - 400 kW. In parallel all process industries require a more efficient use of resources, to generate less by-products and higher yields, while ore-bodies tend to be less qualitative and new process routes (e.g. direct leach) are developed. Besides all these facts the mixing solution must be robust and economic. In this paper we want to address our approach in the development and designing of HPAL agitation equipment."

Jan 1, 2012

This publication summarizes, for potential contractors and other interested parties, the proposed research, development, and demonstration contract projects programed by the Bureau of Mines for fiscal year 1977 (October 1, 1976-September 30, 1977) under its Advancing Coal Mining Technology program. The objective of these projects is to provide an ordered and sequenced series of advances toward the overall goal of providing the system technology required to increase the productivity of the coal mining process.

Jan 1, 1977

By D. W. Collins

The uptake of gold from halide solutions by activated carbon has been investigated using various techniques. Halide systems typically exhibit combined adsorption-reduction type behavior. In an attempt to gain more information about the nature of these processes, samples of synthetic highly-oriented pyrolytic graphite (HOPG) were contacted with aqueous solutions of gold-iodide. HOPG represents a model structure for activated carbon comprising of basal- plane sites, edge sites, and various defect sites. Two basic instrumental methods were used to examine the uptake of gold by HOPG. The first was standard X-ray photoelectron spectroscopy (XPS). The other involved several scanning probe techniques. XPS clearly indicated a preferred uptake of gold at edge sites. However, iodine appeared to be distributed on both basal-plane and edge sites. At low iodine additions, tapping mode AFM showed that clusters were concentrated along steps and surface defects. At high iodine concentrations, the HOPG surface was uniformly covered by iodine.

Jan 1, 1998

By William G. Doepken

The extensive use of rubber-tired support vehicles as a complement to a fleet of load-haul-dump and drill jumbo units has proved invaluable in maintaining scheduled multilevel/multiheading development drifting advances at the Henderson Mine. Support equipment, whether self-powered or towed, releases primary drill-blast-muck equipment from the supportive functions of ground control, utilities installation, steel and concrete construction and supply handling, thus providing both balance and increased flexibility to an underground, rubber-tired mining system. Experience has indicated that increases in man productivity and improved safety and working conditions coupled with decreases in overall costs and mining cycle times are realized with the inclusion of support vehicles in the mining fleet.

Jan 1, 1976

By Corby G. Anderson, Caelen D. Anderson, Patrick R. Taylor

"The United States contains a variety of domestic rare earth element mineral sources containing such as ancylite, bastnasite, monazite, and xenotime. Research has been performed to investigate the fundamental surface chemistry involved in the froth flotation of these minerals, and apply the knowledge gained to substantiate the results through experimental testwork on a domestically sourced rare earth ore. This paper will outline the fundamentals and literature of rare earth mineral flotation, review its industrial applications and provide some recent research updates.THE RARE EARTH ELEMENTSRare earth elements (REE’s) are a unique family of elements with nearly identical physical and chemical properties. They account for approximately 1/6th of all naturally occurring elements, but the entire group occupies only one position on the periodic table. These 15 elements make up the lanthanide series (atomic numbers 57–71), and all but one (promethium) occur naturally. In addition to these 15 elements, yttrium and scandium are also considered rare earths since they tend to occur in the same deposits as the rare earths and share similar physical and chemical properties as seen in Figure 1. In particular Figure 2 denotes, a cartoon of the subtle differences in each caused by the 4f atomic sub shell (Gschneidner Jr., 1964). These subtle differences result in very difficult challenges in the selective concentration and final separation of each rare earth. (Anderson, 2015, Kronholm, Anderson, Taylor, 2013)Rare earths are separated into two different subsections; the “lights” or LREE’s (lanthanum57 through europium63) and the “heavies” or HREE’s (gadolinium64 through lutetium71). Yttrium is generally considered a heavy rare earth since its ionic radius is close to that of the HREE’s, while scandium is not considered either a light or a heavy."

Jan 1, 2016