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By C. L. Peng, F. F. Min, S. X. Song

"Using a parameter representing the degree of hydration of particles in a liquid called hydration index I, which we derived based on Einstein’s viscosity equation, we evaluated the degree of hydration of fine montmorillonite particles in different aqueous solutions by measuring the viscosities of the montmorillonite dispersions and plotting relative viscosity against volume fraction of dry montmorillonite particles in the dispersions. We investigated the effects on the hydration of montmorillonite in aqueous solutions of (1) the type and (2) the concentration of electrolytes in the solutions and (3) pH. For the same concentration of electrolytes, the hydration index I of montmorillonite was found to increase in the order of Na+ > K+ for monovalent cations and Mg2+ > Ca2+ for divalent cations, and to decrease with increasing valence of cations in the order of Na+ > Ca2+ > Al3+. For both Na+ and Ca2+, the hydration index I first increased with increasing concentration of electrolytes and then decreased after a certain concentration. The hydration index I increased with increasing pH. IntroductionClay minerals have the distinctive ability to adsorb water molecules and hydrated cations in aqueous solutions, resulting in hydration on their outer surfaces and in their interlayer spaces. Many investigators (Jurinak, 1963; Anderson and Tice, 1971; Costanzo et al., 1982; Israelachvili, 1992) had found evidence of ice-like structures of water on clay minerals.This phenomenon of hydration plays an important role in the dispersion and sedimentation of clay minerals in aqueous solutions. To understand clay hydration, numerous experimental and simulation studies have been carried out since 1933, including the recent ones of Hawkins and Egelstaff (1980), Skipper et al. (1995), Karaborni et al. (1996), Salles et al. (2013) and Morrow et al. (2013). Among the factors that can influence a clay mineral’s hydration characteristics are chemical composition, type and degree of isomorphous replacement in its structure, and number and nature of associated exchangeable cations."

Jan 1, 2015

By V. Songmene, A. Tahan, J. P. Michaud

The machining of thin wall parts, often used in the aeronautical industry still creates a number of problems, including panel deformation. Quality and productivity are often affected. This study seeks to determine the optimal conditions for cutting in order to guarantee a competitive fabrication of parts while still maintaining quality and delivery deadlines. The studied model (Spar) is a typical structural part used in the assembly of airplane wings. The main objective of this study was to improve two performance aspects: surface quality finish (quality criteria) and the rate of cutting by stock removal (economic criteria). To achieve this objective, we used an evaluation process of the geometrical error issuing from the machine-tool. We also determined the stability zones of the machine-tool's dynamic system. Finally, a series of high-speed machining tests (finishing cuts) were conducted using an experimental structured approach (16 000 - 24 000 rpm). Profile measures of surface roughness and cycle times registered during trials allowed us to establish optimal cutting conditions. Surface roughness improved as well as cutting by stock removal. Four parameters were taken into consideration: axial depth of cut, chip load, spindle speed, and cutting fluid. Finally, the influence of the type of cutting fluid was evaluated to show that it did not significantly affect machining results.

Jan 1, 2006

By P. Zhang

A 1989 FIPR characterization study of the future phosphate resources in Florida showed that MgO would be a problem with both the pebble and concentrate as phosphate mining moves deeper. Since the ratio of concentrate to pebble will become higher and higher in the future, reducing Mg content in the concentrate by a small margin would allow blending of a large portion of the high-dolomite pebble. This research was conducted based on that logic. The following six approaches were tested for reducing MgO content in the flotation concentrate: (1) Adding a dolomite depressant in the rougher flotation step; (2) Dolomite flotation on the rougher concentrate with and without grinding; (3) Dolomite flotation on the cleaner concentrate with and without grinding; (4) Scrubbing the flotation feed; (5) Scrubbing the rougher concentrate; (6) Scrubbing the cleaner concentrate. Successful methods include adding a dolomite depressant in the rougher flotation, dolomite flotation on the cleaner concentrate with grinding, and scrubbing the cleaner concentrate in quartz sand. These techniques could reduce MgO content in the final concentrate by 20-40%. The flotation process could achieve a concentrate with the lowest MgO content, but it is the most expensive approach. Adding a dolomite is inexpensive and easy, but the effect is limited. Overall, scrubbing may be the most promising technology for this purpose.

Feb 23, 2014

By Moris Fresko, Julia Sun, Charles C. Golembewski, Vytas Svalbonas

"A history of mill strain gaging at Metso is presented. The output of these strain-gaging programs is compared with calculated stress ranges from different finite element solutions. These comparisons expose the amount of approximation that exists in the analytical solutions, starting from geometry, and material properties, and ending with different forms of internal load models. The influence of strain gaging results on mill design and analysis practices is also discussed. While these instrumentation programs are valuable in identifying areas of high stress in mills, and locations of stress concentration factors, they are by no means extensive or comprehensive enough to verify general internal load models. The vast majority of the programs were aimed at getting additional data about potential failure points, rather than describing overall mill stress behavior. This is especially true since the more recent gaging programs have not included the difficult task of gaging the mill rotating structure interior. This paper tries to avoid the novice path of leaping to general conclusions on the basis of insufficient data."

Jan 1, 2014

By Sridhar Seetharuman

Sulfur and oxygen dissolved in nickel and cupronickel melts can be removed as gaseous oxides of sulfur by a vacuum treatment. Presented in this paper is a new matched thermochemical diagram that permits direct evaluation of the equilibrium partial pressure of SO, as a function of temperature over an alloy of specified composition. The matched thermochemical diagram consists of a central plot which shows the integral Gibbs' energy of mixing for the binary system S-O2, at different temperatures. The central plot is flanked on either side by terminal plots of the chemical potentials of oxygen and sulfur, as functions of temperature, for different alloy compositions. By projecting the chemical potentials of oxygen and sulfur from the terminal plots on to the central diagram, the equilibrium pressure of SO2,can be directly read on the nomograms on the central plot at different temperatures. The matched thermochemical diaerams are - useful in assuring the efficiency of vacuum refining.

Jan 1, 1993

By Wei Luo

Nickeliferous laterites were characterized by particle size analysis, X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDX), Fourier transform infrared (FTIR) spectroscopy and thermal analysis. Results showed that the laterites consist mainly of nickel-substituted lizardite with cobble-like morphology and traces amounts of magnetite and phlogopite. As fluoride ions can react with silicon in the lizardite crystal structure and form metal-fluoride complexes, as well as increase the equilibrium constant of the lizardite dissolution in acid solution dramatically, the addition of minor fluoride salts (0.2wt.% NaF) gave a markedly enhanced metal extraction rate (Ni 81.7% and Co 52.3%) under the experi-mental conditions of particle size d50= 25 µm, 10% (v/v) H2SO4, reaction time 2 h, reaction temperature 90°C, liquid-to-solid ratio 3 mL g-1 and stirring at 500 rpm compared with H2SO4 alone (Ni 69.6% and Co 30.8%).

Jan 1, 2010

By Harold L. Hinds

The refining of precious metals from steel wool cathoodes is completed by one of two methods: 1) By direct fire smelting or: 2) Acid treatment of the cathodes to dissolve the steel wool and then followed by fire smelting. To further the refining of the cathodes, the Miller Process and the Wohlwill Process are used.

Jan 1, 1981

By Paul Van Negan

During the last decade, MHO has continued to diversify the feed. of its Hoboken smelter. The range of feed materials including larger proportions of precious metals has been extended and the production of minor metals has been developed. These diversifications have required further improvements at the smelter. Attention has been particularly focussed on an increase of productivity, compliance with emission standards and achievement of the highest recoveries of valuable elements. The assaying and sampling facilities have been considerably expanded and the different processing steps of the smelter are now also systematically controlled and managed by simulation models. The charge preparation at the sinter plant, returns handling, sinter conditioning and corresponding ventilation systems have been completely renewed. The annual smelting requirement is now achieved with two blast furnaces instead of three. This is the result of rebuilding and enlarging one of the furnaces and, of a completely new concept of the charge proportioning and charging systems, together with oxygen enrichment and blast air preheat. Ventilation capacity has also been drastically increased. A 7 MVA electric furnace for cleaning the slag from both blast furnaces. contributes to improving the overall metal recovery.

Jan 1, 1990

By William C. Ellis

Underground water is part of a continuing hydrologic cycle, which involves all elements of water occurrence. All groundwater of economic importance is in process of movement through a porous rock stratum from a place of intake or recharge to a place of disposal. Groundwater moves and is contained in fractures in the rock and/or in intergranular spaces of porous formations. Where there have been no water developments by man, groundwater is in a state of approximate equilibrium and the forces of replenishment and discharge are in balance. Thus, groundwater, unlike other mineral resources, is constantly being replenished in most areas at a rate which is measurable and which is important in the planning of its utilization. As illustrated by Figure 1, replenishment of groundwater supplies results from the direct penetration of rainfall through the soil to the water table, by seepage from surface streams or ponds, and/or by subsurface movement from an adjacent groundwater body. Under natural discharge conditions, water is commonly consumed by transpiration of trees and other types of vegetation, by flows from springs, by evaporation from shallow depths below the surface, and seepage into streams that traverse the area.

Jan 1, 1964

By Mario E. Rossi

Geostatistical conditional simulations are becoming increasingly popular as tools that provide models of uncertainty at different stages of a mining project. They have been used as grade control tools in daily operations, to assess the uncertainty of minable reserves at the project?s feasibility stage, and to assess mineralization potential in certain settings. Other applications include assessment of recoverable reserves, resource and reserve classification, and drill hole spacing optimization studies. All large-scale applications of conditional simulations intend to benefit from the ?correct? (or ?accurate?) characterization of uncertainty, adequately describing the variability observed from the data and its impact on the final objective. The objective of this paper is to compare the ad-hoc ?uncertainty model? provided by a traditional classification scheme with the probability intervals resulting from a conditional simulation model. It is argued that the uncertainty model derived from the use of classification schemes is of little practical use to the mining company or operation. The paper emphasizes differences in uncertainty based on the size of the mining unit considered and the extraction method, and local geological differences. Most importantly, it discusses confidence intervals for these mining units, as compared to the relative precision envisioned by a typical classification scheme. The application described in this paper is taken from a medium-sized Cu open and underground mine in northern Chile, and it demonstrates the impact of several variables on the resulting conditional simulation models. It also compares a more ?traditional? resource classification scheme applied, and the wide difference in local confidence intervals for each mining unit.

May 1, 2001

By Shu Yamaguchi

The behavior of halide impurities in pyrometallurgical processes such as Wealtz kiln and MF process has been discussed based on the thermochemical data and the reported data of PbO activity in PbCl2-PbO melts. The role of PbCl(g) has been estimated to be significant in the chloridization evaporation reaction. From reported data on the PbO activity in PbC12-PbO melts, activity of PbCl2 has been calculated by the numerical integration of Gibbs-Duhem equation, and the stability domains and the composition of the liquid phase as well as the vapor pressure of PbCl2 have been estimated as functions of log P2HCI/PH2O and temperature. From the discussion of the path during cooling process on the log P2 HCI . PH2O vs. temperature diagram, the authors proposed a possible dechioridization process that utilize water vapor as a dechloridizer for the direct precipitation of PbO from gas phase.

Jan 1, 2003

By G M. Jeffress, D C. Arne

There are two discrete aspects to collecting portable X-ray fluorescence (pXRF) data to obtain reliable results and to comply with reporting requirements under the 2012 edition of the JORC Code (JORC, 2012) – sampling method and quality assurance. A robust sampling program is required to obtain representative material for analysis. The appropriate method should be established for a particular project using a small orientation study. A variety of approaches to sampling soils, drill cuttings, rock faces and diamond drill core are discussed. These include using multiple spot analyses, scanning using a single operating beam and the collection of cutting saw pulps. The operator must also be aware of the attenuating effects of analysing through sample bags of different material types for various elements as well as the limitations of current pXRF instruments in reporting reliable data for certain elements. The analysis of the samples must also be accompanied by a quality assurance program in order to generate data that are ‘fit for purpose’. This includes recording X-ray tube resolution on a routine basis, using matrix-appropriate standards for which total elemental concentrations are available, using silica blanks, capturing sufficient duplicate analyses to constrain data precision and obtaining check assays to calibrate pXRF data against laboratory data. Examples of quality control approaches and data are presented. Table 1 of the 2012 JORC Code also recommends that information on instrument make and model, reading times and calibration be provided in any reporting of pXRF data. To this should be added information on operating mode and temperature, software version and moisture content of the samples. A robust sampling methodology with a suitable quality assurance/quality control program should produce pXRF data of sufficient quality for public reporting purposes, provided that the data are presented using appropriate cautionary language and adequate supporting information.CITATION:Arne, D C and Jeffress, G M, 2014. Sampling and analysis for public reporting of portable x-ray fluorescence data under the 2012 edition of the JORC Code, in Proceedings Sampling 2014 , pp 57–64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By Z. H. Xu

Flotation as a versatile multiphase separation technology has been practiced for more than 100 years in coal and mineral processing. Although effective over a wide particle size range, flotation for mineral separation has been largely understood as an art rather than a science, treating the flotation system as a black box. With rapid progresses in microscopic technologies coupled with high speed video recording and imaging analysis, ingénue design of visualization systems has made it possible to understand fundamentals of flotation by visualization. In this presentation, the state of the art where visualization plays a key role in advancing our fundamental knowledge of flotation will be reviewed. The areas to be covered include characterization of bubbles (shape, size, velocity and sol-ids loading) in a running flotation system, either column or mechanical cell, bubble-solid attachment, hydrodynamic cavitation in fine particle aggregation and flotation, froth imaging, particle-particle interactions by zeta potential distribution measurements, and heterogeneous gas nucleation by atomic force microscope imaging. With these capabilities, critical roles, good or bad, of ore proper-ties, solution chemistry, slurry hydrodynamics, and operation variables in flotation systems as applied to mineral, coal and oil sands processing were clearly elucidated.

Jan 1, 2014

By W. W. Atkinson

This paper describes some concepts developed in a geologic data recording system at the Victoria, Nevada breccia pipe-skarn copper mine. The recording system is not fundamentally new, but represents expansion of earlier ideas. The paper is based on the philosophy that a high quality geologic data base is necessary and that it should be complete, clear, standardized, neat, quantitative, and readily useable. It may be multi-colored or simply black and white. Graphic, descriptive and quantitative recording of data is essential. A format for core logging is presented and discussed and as well as a multiple overlay system for recording data gathered in surface mapping.

Jan 1, 1983

By C M. Standen

The SAG mill at Rasp Mine has undergone a number of liner design modifications since commissioning in 2012, making liner wear and failure difficult to predict from historical data. During 2017, several instances of liner failure or near failure were experienced resulting in unplanned downtime for emergency relines or to patch liners in the lead up to a planned shutdown. The strategy for relining mills is often to minimise the frequency of relines (and subsequent shutdown costs) by extending liner life, achieved through design modifications. However, it was observed that as the Rasp SAG mill liners wear, mill performance declined with power draw increasing and throughput declining. Opportunity and inefficiency costs start to erode the revenue per additional tonne milled for a given set of liners, and in turn the benefit of delaying relines. As such, optimising the frequency of relines becomes a trade-off between reline costs and opportunity/inefficiency costs in delaying relines. The aim of this paper is to demonstrate a frame work for analysing costs using a marginal economic analysis with the assumption that the Law of Diminishing Returns can be applied to the life of mill liners. The SAG mill operating variables can be modelled to determine their impact on costs and an optimal reline point can be defined where the total costs are minimised. This prevents unexpected failures due to accelerated wear by providing justification to reline earlier and thereby allowing efforts to be focused on sustaining milling performance.CITATION:Standen, C M, 2018. An economic approach to optimising mill reline frequency – a case study of SAG mill relines at Rasp mine, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 197–206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Wei Yin, Yu Wu, Xiexing Miao

"For engineering problems of “three under” coal (coal trapped under buildings, waters-bodies and railways) exploitation, environment protection and gangue separation from raw coal underground exist in Tangshan Coal Colliery. By analyzing concrete technical problems, a technical approach of closed cycle “coal mining-gangue washing-backfilling-coal mining”, i.e. integration of coal mining, gangue separation and solid backfilling, is put forward with key technologies including gangue transportation with great depth, gangue separation from raw coal underground and integration of coal mining and backfilling. Based on the specific geological conditions of Tangshan Coal Colliery, 591m vertical feeding transportation system with great depth is designed; meanwhile, for efficient gangue transportation, ancillary wear-resisting pipe size and buffer equipment are optimized. Underground gangue separation system is created to be joined with the existing production system and backfilling system; besides, as per separation characteristics of coal and gangue, buddle jig is adopted for gangue roughing of raw coal underground. By cooperation of backfilling hydraulic support and other key equipment, the designed stope backfilling system completely realizes integration of coal mining and backfilling. Engineering practice shows that, through the research and implementation of the above key technologies, integration of coal exploitation, gangue separation and solid backfilling is successfully implemented in Tangshan Coal Colliery; moreover, it completely solves the three major engineering problems and realizes waste disposal, underground washing and separation, and ground surface subsidence control.INTRODUCTIONSo far, “three under” coal (coal trapped under buildings, watersbodies and railways) and key state-owned coal resources trapped under villages in China have reached 13.7 billion t and 5.22 billion t, respectively. With the development of coal enterprises, China currently has more than 1,600 gangue dumps (Miao et al., 2010a) with accumulated stack amount of 4.5 billion t, occupying a land area of 150,000 km2; moreover, surface subsidence caused by mining activities has damaged the environments of industry, agriculture, transportation and living, while new environmental pollution sources formed by coal related industries also result in damage to ecological environment (Huang et al., 2011a). On the one hand, due to large scale coal mining, some coal collieries suffering from resource exhaustion are faced with survival problems; on the other hand, coal mining has caused and been faced with increasingly prominent environmental problems, such as “three under” coal exploitation, waste disposal and ground surface subsidence control (Miao et al., 2010b; Zhang et al., 2009)."

Jan 1, 2015

By Narasimha Mangadoddy, Teja Reddy Vakamalla

"Vertical hydrocyclones are very common in most of the comminution circuits. Inclined cyclones are also found for specific mineral processing applications. In this work, Computational Fluid Dynamics (CFD) technique and experiments are used to find the reasons behind the inclinations effect on hydrocyclone performance characteristics. The water and silica slurry experiments are conducted with 75 mm hydrocyclone at different inclined positions (0-600) to the vertical plane. Corresponding two-phase numerical simulations are performed with Volume of Fluid (VOF) model coupled with Large Eddy Simulation (LES) turbulence model. Multiphase simulations are carried out with Algebraic Slip Mixture model modified with lift, drag forces and Newtonian rheology model corrected with fines for various feed solids concentration. A raise in the under flow solids percentage, cut diameter and a reduction in the water split is observed with the inclination. Electrical Resistance Tomography (ERT) and High Speed Video (HSV) data is used to cross validate the inclined cyclone’s CFD air-core and solids concentration data. Predicted efficiency curves are found in a close agreement with experiments for all the inclinations. Comparison of experimental and predicted flow data clearly follows trend with the literature. Key words: Hydrocyclone, CFD, ERT, inclination, water splitINTRODUCTIONHydrocyclones are devices used to separate or classify particles based on particle size difference in the water medium. Their usage is very wide in chemical, petroleum, mineral and bio industries due to its structural simplicity, high throughput, small volume, low cost and maintenance. Cyclone mainly consists of a cylindrical section followed by a conical section attached to a single feed inlet and two product outlets named vortex finder and spigot. It works on the principle of centrifugal sedimentation. The slurry is fed tangentially to the hydrocyclone, in which larger particles are moved towards the wall and separated by centrifugal forces to the underflow. Smaller size particles follow liquid due to drag forces to the overflow. With its simple structure, the flow behavior inside the hydrocyclone is quite complex. Vertical cyclones are common in practice in most of the comminution circuits. Horizontal cyclones can be found in extreme cases which are for installation convenience rather than for process reasons. Inclined cyclones are also present for specific mineral processing applications. In coal preparation plants, dense medium cyclones are operated near to horizontal inclination of 20 degrees to allow large spigot sizes for sinks removal, self-drain of contents during shutdown. In the phosphate removal, dense medium cyclones are inclined with an angle between 0-90 degrees for better separation of ore and tailings (Liu Feng et al., 2006). Even in the clusters, hydrocyclones are mounted with an inclination around the feed distributor for uniform distribution of slurry and under flow collection. It is believed in mineral processing industry that inclined cyclones would fetch the benefit in number of ways while classifying the material by size. Gravity influences the cyclone performance through the air core size and position variations in large cyclones. It also favours the cyclone operation at coarser cut points without varying any other design and operating parameters. Minimizing fines misplacement to underflow can be achieved with inclination."

Jan 1, 2016

By M. D. Carver

This investigation was undertaken by the Bureau of Nines to determine the effects of impurity levels on the mechanical properties of columbium at low temperatures. High-purity, electron-bombardment-melted columbium was purchased and used as a basis material. Variations in impurity levels were obtained by arc-melting charges containing definite amounts of added impurities. Tensile tests were conducted at low temperatures. Results showed the almost pure basis metal to be ductile at minus 194° C., the lower limit of the range used, Ductility of less pure columbium appeared to depend on interstitial element content. The ductile-to-brittle transition temperature appeared to be raised by increasing carbon content in the range of 50 to 730 parts per million, nitrogen content in the range of 50 to 200 parts per million, or total interstitial element content in the range of 240 to 1,380 parts per million. Some evidence was obtained indicating that decreasing cold work also raised the transition temperature, but recrystallization appeared to have no effect on it. Variations in interstitial element levels appeared to have little or no effect on ultimate strength of columbim in the range of room temperature to minus 194° C, Physical metallurgy studies of massive arc-melted and electron-bombardment- melted columbium were included in the columbium-tantalum research work assigned to the Albany Metallurgy Research Center in fiscal year 1959.

Jan 1, 1961

By J. D. Campbell

"Coal is one of Alberta's major fuel resources, but its distribution, especially in the flat plains region, has been somewhat obscured by surficial deposits. After a period of neglect, easily strippable plains coal is presently approaching a position of dominance in electrical power production, a position it is likely to retain for a number of decades in the face of strong competition from hydro and nuclear power. Accordingly, the Research Council of Alberta has undertaken an inventory survey of the province's supplies of this resource.In the southern part of the province and in the north-central forest-fringe area, some strippable coal is found in the Belly River Formation and its equivalents, but major strippable coal reserves in large areas of central Alberta occur within the Edmonton Formation. The survey is planned on a reconnaissance scale, drilling test holes at 2-mile intervals in selected large areas. It appears to show that, in well-settled regions, large reserves of strippable coal are only to be expected where they have long been known; major presently unknown bodies of coal must be sought in unsettled regions or at depths too great for strip mining. However, such bodies might still be economically competitive with hydro and nuclear power in the production of electric power for some time to come."

Jan 1, 1967

By David Tisdale, Phillip Mackey, Nagendra Tripathi, Matthew Kreuh, Pascal Coursol

Xstrata Nickel’s Sudbury smelter operation is based on fluid bed roasting of Ni-Cu sulphide concentrate, followed by electric furnace reductive smelting and Peirce-Smith converting to produce a Bessemer matte for electro refining, along with sulphuric acid produced from smelter gas. While the site dates back to the 1930s, the present smelter configuration has been operational since 1978, and currently has a nominal capacity of about 67,000 tpy of contained nickel and is investigating options to expand in future up to 85,000 tpy. As part of a review of plant capacity options, a new metallurgical model of the plant was developed in order to examine a number of processing alternatives. Based on the METSIM™ platform, the present model includes the ability to examine the impact of a number of plant parameters on potential plant performance including; for example, the following: percent of sulphur elimination in roasting, matte grade, degree of matte metallization, temperature, coke requirements, sulphuric acid production, CO2 emissions and overall energy requirements. The process model also includes a number of special features adopted; for example, approaches to effectively model the complex Ni-Cu-Co-Fe-S-O matte system. This paper provides a description of the model and gives an overview of the results. As well as presenting the results of the present study, the applicability of this modeling approach to pyrometallurgical systems in general is also briefly discussed in the paper.

Jan 1, 2009