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By Jian-guang Yang, Lei Jie, Si-yao Peng, Jian-ying Yang

A new membrane electrolysis process for bismuth recovery from bismuthinite concentrate was introduced. Under the conditions of temperature 70 degrees C, acidity 3 mol/L, solid liquid ratio 1:4 and 1.1 times stoichiometry sodium chlorate dosage for 1.5 h oxidation leaching, more than 98.5% bismuth can be leached from bismuthinite concentrate. The resultant leach solution was subjected to membrane electrolysis. Under the conditions of NaCl concentration 300 g/L and pH 7 in anolyte, bismuth ions concentration 80 g/L and HCl concentration 3 mol/L in catholyte, heteropole distance 6 cm, temperature 40 degrees C and current density 200 A/m2, a flat deposited bismuth plate can be obtained after 24 h electrolysis, and the bismuth purity was more than 99%. The current efficiency of cathode was 97.88%. Chemical component analysis results showed that the average convert efficiency of the sodium chlorate was 52.77% and the average oxidizing efficiency of chloride ion was 69.78%, and the resultant anolyte generated in anode compartment could be fully reused as oxidant for leaching bismuthinite concentrate again.

Mar 1, 2017

The Morning Star diorite dyke has been subjected to two periods of mineralization. The earlier, genetically related to the dyke magma, gave rise to a weak chalcopyrite-pyrrhotite-pentlandite-gold mineralization in a narrow zone, up to 25 cm. wide, which parallelsthe nearby western (hanging) wall of the dyke. Subsequently a set of conjugate shears formed in the dyke as a result of tectonic movements. Gold-quartz veins formed in these shears giving rise to the classical "ladder veins" of the Morning Star mine. On either side of the veins ("floors") the diorite has been bleached for up to 3 ft. This involved introduction of much CO. and some K"O, and S with abstraction of SiO. and FeO, giving rise to carbonates, sericite, zoisite and pyrite. The veins consist of quartz with minor amounts of albite and carbonate, together with pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, tetrahedrite, galena, bournonite, boulangerite and gold. Spectrographic analyses of gold show that the suite of trace elements is consistent throughout the mine.INTRODUCTIONThe gold-quartz veins of the Morning Star Gold Mine, at Wood's Point, Victoria, are a classic example of the "ladder vein" type of deposit. The structure of this series of repeating quartz veins or "floors", some barren and some productive, occurring in a set of conjugate shears which transect a "dyke bulge" of diorite (Fig. 1), has been described on numerous occasions as mining has progressed and figures in the textbooks (Whitelaw, 1905; 1916; Junner, 1920; Lindgren, 1933; McKinstry, 1935; 1942; 1949; Kenny, 1949; Hills, 1952; Clappison, 1953) ; but there has been no study of the mineralization apart from that in Junner's (1920) general study of the Walhalla-Wood's Point Goldfield, made at a time when mining had not developed below the 400 ft. level,. and the mine was dormant.

Jan 1, 1958

By Subhash Bhagwat

The definition of high sulfur coal varies from plant to plant and is subject to changes over time as the environmental regulations change. In plants constructed after September 1978 hardly any domestic coal can currently be burned without the use of Flue Gas Desulfurization (FGD) because a 70 percent reduction in potential S02 emission is mandatory even when the potential emission is less than 0.6 lbs. S02/106 Btu heat input. On the other hand older power plants may in many cases be legally emitting up to 6 lbs. S02/106 Btu or more under some State Implementation Plans (SIP). The Clean Air Act requires, however, that in the long run all stationary sources of S02 pollution must abide by the ceiling of 1.2 lbs S02/10 Btu heat input.. Coals with a potential to exceed this limit must, therefore, be considered as high sulfur coals. Such a definition would be unrealistic because many SIP's aim at an emission level of 1.8 to 2.0 lbs. SO2/106 Btu for existing plants and a stricter limit does not appear to be enforceable in the next 5 to 10 years. As a result, coals with an emission potential of greater than 2.0 lbs of S02 per 10 Btu heat input are considered high sulfur coals for the purpose of this investigation. Based on this definition and the 1984 actual consumption of coals by U.S. electric utilities (table 1) only 7 out of the 24 coal producing states could be categorized as low sulfur states. The actual S02 pollution, however, depends on total tonnage of a type of coal as well as the sulfur content of the coal. Table 1 also indicates that only 6 states--Kentucky, Illinois, West Virginia, Ohio, Pennsylvania and Indiana-account for nearly 77 percent of S02 pollution potential in the United States. These 6 states have therefore been chosen for this investigation.

Jan 1, 1986

By Omid Asghari, Amin Mousavi, Arshad Ranjbar

Geometallurgical modeling of the production benches is an attempt to estimate the geometallurgical variables of the different ore domains, which leads to a better understanding of the ore and its properties. Having geometallurgical variables results in a more accurate prediction of ore characteristics, an improved drilling and blasting operation, and better efficiency of the processing plant. In this research, the geometallurgical variables required for the geometallurgical modeling of the extraction benches are discussed. Then, the relations between Bond work index (BWi), as one of the most important geometallurgical variables and the primary grindability index, and rock geomechanical properties are investigated based on the previously published studies. The BWi is the main parameter for measuring the resistance to the grinding of ore minerals. It represents the energy required for processing (e.g., crushing, grinding) ore rocks in the beneficiation plant. As a real case study, BWi of a production bench in Sungun Copper Mine, located in East Azarbaijan province, Iran, was estimated. The rock’s geomechanical properties were measured using laboratory tests, including uniaxial compressive strength, Brazilian tensile strength, point load strength, and hardness. Then, BWi was estimated using the proposed formulas in the literature and the results of the rock’s geomechanical properties. The selected bench consists of three ore zones and two dyke domains. The laboratory tests revealed that the first ore zone has a slightly higher compressive strength than the other two zones, while the compressive strength of the waste rocks is larger than the ore domains. Using the proposed equations in the literature, the predicted values of the BWi for the samples in ore zones are in the range of 6.36 – 14.44 (kWh/t), and therefore this wide range must be considered when the short-term production schedule is planned. In addition, variations are observed in the samples within a specific zone and between the ore zones, demonstrating heterogeneity in the selected bench. Finally, wide-open results obtained by different equations show a necessity to perform a geometallurgical program specifically for the Sungun mine.

Oct 28, 2021

By H. C. Fowler

Hydrogen sulphide associated with the gasps and vapors from certain crude oils now produced in the United States has forced a serious health and safety problem upon the petroleum industry. Although the presence of hydrogen sulphide in or occurring with Mexican crudes has been known for some time, it was not until recently that crude oils which give off poisonous amounts of hydrogen sulphide have been produced to any extent in the United State. The injurious effects of this poisonous gas were first recognized by the refiners along; the Atlantic and Gulf Coasts upon receiving shipments of crude petroleum from Mexico. The problem of combating the hazards of the gases and vapors given off by this petroleum become more important as the use of Mexican crude increased. In 1925, the Bureau of Mines and Public Health Service under cooperative agreement with the American Petroleum Institute, studied the causes rend effects of hydrogen sulphide poisoning. Bureau of Mines Bulletin 2312 is report of this investigation, and although written with special reference to refineries, it nevertheless contains much information that is of value to the producer of petroleum.

Jan 1, 1927

By J. D. Davis

The carbonizing properties of No. 2-bed coal from the Bartoy mine and No. 5- or Miller-bed coal from the Wilkeson-Miller mine, both at Wilkeson, Pierce County, Wash., were determined by the Bureau of Mines-American Gas Association (BM-AGA) method. Tests were made in the 13-inch retort at 500°, 600°, and 700° C. and in the 18¬inch retort at 800°, 900°, and 1,000° C. Fischer low-temperature and United States Steel Corporation high-temperature assays were made and the results compared with those of the BM-AGA tests at corresponding temperatures. Agglutinating and plastic properties were determined, and chemical and petrographic analyses were made. The No. 2 bed is 58.5 to 88.0 inches thick at three points sampled in the Bartoy mine. The coal is 98 percent bright and contains only a trace of fusain. A composite of three mine samples contained 13.8 percent ash. The washed sample, which was used in the tests described herein, contained 11.4 percent ash, 2.2 percent moisture, and 0.6 percent sulfur upon the as-carbonized basis and 68.4 percent fixed carbon upon the dry, mineral-matter-free basis. The heating value was 15,183 B. t.u. per pound upon the moist, mineral-matter-free basis. No. 2 therefore ranks as a high-volatile A coal and is very high in that, rank. The ash softens at 2,910° F. Except for its ash content, which is higher than the limit of 9.0 percent specified by the American Society for Testing Materials, No. 2 coal fulfills the requirements of a coking coal. It also is classed as extremely friable, the friability being 88.0 percent. The agglutinating index (7.6 for the 15 : 1 ratio of silicon carbide to coal) is high, and the plasticity as indicated by the Gieseler test (60 divisions per minute) is low for a high-volatile A coal.

Jan 1, 1942

By Michael E. Henderson

The U.S. Bureau of Mines (BOM) constructed the Hydraulic Transport Research Facility (HTRF) to investigate the hydraulic parameters relating to the transport of coarse coal. To achieve these goals in a timely and efficient manner, the Bureau contracted to Boeing Services International, Inc. (BSI) the responsibility of operating the HTRF and providing technical support. This data report is a summary of the testing and data results for the period from 16 September to 1 November 1983. The testing covered herein is for coarse 2-in by a (minus 50 mm) Pittsburgh Seam coal in a 12-in (3 00 mm) pipeline, at velocities ranging from 5 to 18 ft/s (1.5 to 5.5 m/s) and at concentrations ranging from 15 to 55 pct.

Jan 1, 1985

By S Hapugoda, J R. Manuel, M J. Peterson, A Poliakov, E Donskoi

The occurrence and deportment of manganese in a number of ferromanganese and Mn-bearing iron ore samples from supergene-upgraded deposits, as well as from magnetite banded iron formation (BIF) and magnetite skarn deposits, was characterised in order to provide a basis for improved understanding of the processing characteristics of different ore types and investigate the potential for development of a robust geometallurgical classification for Mn-oxide ores. An understanding of the Mn mineralogy in mixed Fe-Mn deposits is necessary to inform any attempt to separate the Fe and Mn during beneficiation and to understand and predict the behaviour of lump and fine ore products during processing.A suite of analytical techniques was utilised, including hand sorting of lump ore particles, optical microscopy, X-ray fluorescence (XRF)/inductively-coupled plasma mass spectrometry (ICP-MS) chemistry, X-ray diffraction (XRD), scanning electron microscopy (SEM)/electron probe microanalysis (EPMA) and gas and solid phase pycnometry, in order to elucidate manganese mineralogy, mineral chemistry and mineral textures. Manganomelane group minerals (eg cryptomelane, hollandite), pyrolusite and lithiophorite were the most common manganese oxides in the samples examined. From the microprobe work, there was evidence of probable substitution of Mn, as well as Al and Si, into the structures of goethite and hematite. Manganomelane minerals were often intimately associated with goethite, in particular, and a clarification of this association and the associated Si and Al impurities is fundamental for improved understanding of beneficiation and sintering behaviour of Mn-oxide ores. Due to the poor or very fine crystallinity of some supergene manganese deposits and of some Mn oxide minerals, in particular the extent of overlapping peaks and their variable mineral chemistry, XRD was a problematic technique to equivocally determine Mn mineralogy.For lower-grade, earthy, poorly microcrystalline ores the mineralogical and textural association between mixed Mn, Fe and Al (¦ Si) phases was also critical. The deportment and potential separation of these elements in these deposits, especially Al, was complex, as they were characterised by forms of æhydrousÆ cryptomelane with higher levels of Fe-Al-Si substitution, as well as intimate intergrowths of ochreous-earthy goethite (probably aluminous in part) with cryptomelane, lithiophorite and/or kaolinite.Trace amounts of alkali elements in ferromanganese deposits were considered likely to be preferentially structurally associated with Mn oxides, while lateritic deposits with significant amounts of lithiophorite could contain elevated levels of deleterious impurities; Co and Ni in particular.A combination of solid and gas phase pycnometry proved to be a useful technique for broadly discriminating hematitic, goethitic and mixed Mn oxide-goethite lump particles based upon differences in their envelope and apparent densities. Based upon these preliminary results and ongoing Raman spectroscopy work on manganese deposits sensu stricto, Raman spectroscopy is a technique considered to have promise during targeted research to better link the optical and compositional properties of ferromanganese ore particles. CT-scan (computed tomography scan) analysis could also be combined with Raman spectroscopy and pycnometry to link mineral composition, mineral texture, ore particle textures and particle porosity/permeability to the high-temperature processing behaviour of lump and fines products.CITATION:Peterson, M J, Hapugoda, S, Manuel, J R, Donskoi, E and Poliakov, A, 2013. Textural characterisation of manganese minerals to improve the geometallurgical characterisation of ferromanganese and iron ores, in Proceedings Iron Ore 2013 , pp 281-300 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By F. J. Wiebelt

Production of small tonnages of asbestos has been reported from 18 California counties; 16 additional counties have occurrences of asbestos. The counties in the northern part of California that have had a recorded production are: Alameda, Amador, Calaveras, Contra Costa, E1 Dorado, Napa, Nevada, Placer, Shasta, Siskiyou, Trinity, and Tuolumne. No deposit in the State has maintained consistent production. Serpentinized peridotites (potential chrysotile-bearing rocks) are widely distributed in the coast ranges, Klamath Mountains, and western foothills of the Sierra Nevada.

Jan 1, 1958

By Michael E. Henderson

The U.S. Bureau of Mines (BOM) constructed the Hydraulic Transport Research Facility (HTRF) to investigate the hydraulic parameters relating to the transport of coarse coal. To achieve these goals in a timely and efficient manner, the Bureau contracted to Boeing Services International (BSI) the responsibility of operating the HTRF and providing technical support. This data report is a summary of the testing and data results for the period 22 November to 10 December 1982. The testing covered herein is for coarse 2-in by 0 (minus 50 mm) Pittsburgh Seam coal in a 6-in (150 mm) pipeline, at velocities ranging from 5 to 20 ft/s (1.5 to 6.1 m/s) and at concentrations ranging from 15 to 45 pct by weight.

Jan 1, 1986

By T. R. A. Davey

A Survey of current and recent research and developmental work is supplemented by predictions for processes which should be developed over the reminder of this century.

Jan 1, 1970

By M. A. Schellhardt, E. J. Dewees, R. Vincent Smith

"INTRODUCTION Abnormal material requirements of the nation at war impose an intensive demand upon many irreplaceable natural resources. Natural-3as reserves) for example, are being subjected at the present time to extensive depletion by large-scale withdrawals of gas to supply unprecedented demands for fuel and raw materials for the synthesis of strategic products. Fluids produced from many so-called gas-condensate type reservoirs have become an important source of hydrocarbons vital to the war effort.Development of gas-condensate type reservoirs in Arkansas, Louisiana, and Texas in recent years created many problems not common to ordinary gas-producing operations. Early in the development of condensate-type gas fields, general practices were evolved and applied to insure efficient re¬covery of the hydrocarbons existing in the gas phase under initial reservoir pressures and temperatures, put often the practices were predicted mainlyregardingupon generalized theory regarding the behavior of the fluids and were not always the most efficient, because field and laboratory procedure for testing these hydrocarbons had not progressed as rapidly or as far as field development. Specific information regarding the composition and properties of fluids ultimately recoverable from many gas-condensate reservoirs, especially, is lacking."

Oct 1, 1944

By Richard G. Almes

Since the failure of a major coal refuse disposal embankment and impoundment in the Buffalo Creek watershed near Man, West Virginia in early 1972, there have been extensive changes in the design and construction requirements for coal refuse disposal facilities located throughout the United States. The primary emphasis has been on improving the safety of these facilities, particularly for impoundments which are capable of storing millions of gallons of process water and storm runoff. The Mine Safety and Health Administration (MSHA) of the U.S. Department of Labor (formerly the Mining Enforcement and Safety Administration, U.S. Department of interior) has been the lead federal agency in promulgating regulations pertaining to coal waste disposal. In 1974 and 1975, studies were undertaken by our firm under contract to the Mining Enforcement and Safety Administration to prepare a comprehensive engineering and design manual to be used by operators and engineers in the planning and design of coal refuse disposal facilities with the intent ion of avoiding any more Buffalo Creek failures. The resultant 800-page document addresses major subjects such as safety, environmental controls, and cost. Specific topics include characterization of coal refuse, classification of disposal facilities, project planning, geotechnical investigations, testing and design requirements, hydraulic and hydrologic design, environmental factors, operations, and monitoring, instrumentation, and maintenance.

Jan 1, 1980

By P. R. Taylor

This investigation (Bowles, 1990) involves consideration of technology utilized by three separate fields of metallurgy and materials science: 1) The recovery of metals employing the use of solvent extraction, 2) The fabrication of materials using powder metallurgy, and 3) The use of composite materials in fabrication of engineering materials. The research considers each of the processes in order to realize the benefits of each. In light of the fact that materials have an intended use -it does seem plausible to simplify the process required between "mother earth" and final use. For instance, a primary copper producer that already employs a solvent extraction and electrowinning process could produce value added products directly. Part of the existing extractant flow could be diverted into a pressurized hydrogen stripping process in order to produce specialty composite powders. Innumerable methods have been employed for the recovery of metals; solvent extraction, the one considered in this study, was used due to the possibility of it providing a pure powdered metal. The use of solvent extraction in the recovery of metals has gained wide acceptance and its use proves beneficial in many applications (Ritchey and Ashbrook, 1984). Pressure hydrogen stripping of solvent extractants may provide the benefit of flowsheet simplification compared to conventional solvent extraction followed by electrowinning. It may also provide the benefit of direct production of high purity metal powder (Demopoulos and Distin, 1985).

Jan 1, 1992

By E. P. Youngman

This paper presents one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative, to the rights of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the mining laws of British Guiana has been prepared from the best available sources in Washington and is, released subject to amplification and correction, if necessary, by United States foreign-service officials. INTRODUCTION The sources of information available in the preparation of this paper are the following: 1. The Crown lands ordinance, No. 32 of 1903, September 26, 1903.

Jan 1, 1934

By D. R. Nagaraj

Depression of copper sulfides followed by MoS2 flotation is the most commonly practiced technique for Cu-MO separation. Although numerous organic depressants have been developed in the past, a majority of the currently used copper depressants are inorganic compounds (ex. NaHS, Nokes reagent, etc.). A unique advantage of organic depressants over the inorganic compounds is the potential versatility for design of the organic molecule to suit many requirements. The present study was initiated to systematically investigate the structure- activity relationships for a large number of organic complexing agents in comparison with the commonly used inorganic depressants that are often inefficient and hazardous. The results obtained in this study are discussed in light of the useful correlation obtained between practical solution redox potential and depressant activity. Several requirements, such as the presence of an active -SH and hydrophilic -OH or -COOH in the organic molecule, are identified for a reagent to be a satisfactory depressant. Some preliminary results on the desorbability (or destruction) of collector coating on the sulfide surfaces in the non-xanthate collector systems are also discussed.

Jan 1, 1983

By H. N. Dunning

A comprehensive production research program, now in progress at the Petroleum Experiment Station of the Bureau of Mines at Bartlesville, Okla., includes studies of the displacement of petroleum from sand by detergent solutions. An earlier report (12)2/ presented the results of an extensive research program to determine the value of detergents as floodwater additives. This report presents later results of the detergent-testing program (13, 17). Although water-flooding methods and controls are constantly being improved to increase the production of oil from secondary-recovery operations, considerable crude oil commonly remains.in place after a water flood has been terminated. Therefore, the possibility of improving the efficiency of a waterflood by the use of detergents is of increasing interest. The effects of many substances on the efficiency of water flooding have been investigated in laboratory studies (5, 11, 13, 17, 19, 24). Of the various sub-stances tested, only surface-active agents were consistently effective in removing oil from sand. Results of laboratory studies presented in earlier reports (9, 11, 12, 13) show that many detergent solutions effectively displace petroleum from sand surfaces under varying conditions encountered in centrifuging, manual and mechanical agitation, ultrasonic vibration, and imbibition.

Jan 1, 1957

By O. M. Schaus

This paper is one of a series, prepared by the Bureau of Mines and deals with the Montreal mine, one of only two active properties in Wisconsin on the Penokee-Gogebic range. The purpose of this paper is to describe the conditions of occurrence of iron ore in a particular property and to present sufficient details of equipment and production methods to convey to the unacquainted operator a correct idea of the mining practice.

Jan 1, 1930

By Everett P. Partridge, J. E. Conley

Available statistics show that the demands of the American chemical industry for sodium sulphate have been increasing slightly in recent years. The supply from domestic sources, particularly in the form of byproduct salt cake from the acid manufacturers, has been tending to decrease this to the growing manufacture of synthetic acid. Both hydrochloric and nitric acids are being synthesized from their elements. The natural result has been that a smaller amount of salt cake is available. Simultaneously, the expansion of the kraft-paper industry, especially in the South, has brought about greater demand for sodium sulphate in that section. This demand is being met by domestic byproduct salt cake, by imported German sodium sulphate made from potash waste liquors, and by favorably situated domestic deposits of Glauber salts and the anhydrous salt, thenardite. No shortage of natural sodium sulphate exists in the United States, but usually such deposits occur in semiarid regions far removed from transportation facilities and from markets. Moreover, the major portion of the natural deposits is Glauber salt or mirabilite (Na2 504 • 10H20), which must be dried or dehydrated in order to meet consumer requirements. The water of hydration represents, roughly, 55 percent of the total weight of the crude salts and therefore has a very important influence on transportation costs, in many instances the cost of getting even the dehydrated product to market is the deciding economic factor. Therefore, the recovery of production of anhydrous sodium sulphate from plant-waste liquors or from natural brines of suitable composition might be economically feasible.

Mar 1, 1936

By Frank Parrish

THIS REPORT by the Federal Bureau of Mines presents data on water-supply wells used by waterflood operators in North Texas and shows the distribution of permeable source sediments. Averages of well characteristics, including static fluid levels, working fluid levels, net thicknesses, producing rates, and depths, are presented and discussed. Essentially all water used in waterflooding is mineralized water from consolidated sediments. This study is concerned with the geology and distribution of these mineralized source sediments, whereas previous work in this area was predominantly a study of shallow sources of potable water. Tables, isopachous maps, and electric-log cross sections are included to describe the several source aquifers. In general, water-producing capacity increases with depth of the sediments. Wells completed in Cretaceous sediments 82 to 600 feet deep yield 50 to 600 barrels of water daily, whereas those completed in Pennsylvanian sediments 360 to 4,110 feet deep yield 100 to 7,000 barrels daily. Although deeper formations are used where oil and water are produced conjunctively and where large withdrawal rates are required, insufficient well data prevented mapping of deeper formations.

Jan 1, 1961