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By Xue Sun, Dengfu Chen, Yuting Chen, Mujun Long, Song Xu, Helin Fan

In order to seek an effective extraction process for vanadium, the recovery of vanadium from a high Ca/V ratio vanadium slag was studied by sodium roasting and ammonia leaching. In the present paper, the oxidation and leaching process of vanadium slag was investigated by X-ray diffraction (XRD), scanning electron microscopy and energy dispersive X-ray spectrometry (SEM/EDS) techniques. The effects of ammonium carbonate concentration, leaching temperature and leaching time on the leaching ratio of vanadium were discussed. As indicated in the experimental result, the optimal (NH4)2CO3 concentration was 120g/L, leaching temperature was 60°C and leaching time was 20 min. Approximately 92% of the vanadium was recovered under the optimal conditions. Furthermore, by means of X-ray diffraction analysis, the phase transformations of the vanadium slag during roasting and leaching processes were analyzed and discussed.

Jan 1, 2014

By Lin Yang, Yuanbo Zhang, Zhuoxuan Li, Guanghui Li, Jinghua Zeng, Tao Jiang

A technique has been proposed for recovering iron from hematite-rich diasporic-type bauxite ore in this study. Direct reduction roasting followed by low intensity wet magnetic separation process was carried out. The parameters including reduction temperature and time, sodium salts, grinding conditions and magnetic field intensity for separation of iron were determined. The optimum process parameters as follows: roasting temperature of 1050 oC, time of 60 min, sodium salts involving sodium sulfate, borax, sodium carbonate with dosages of 10 wt%, 2 wt%, 35 wt% respectively, and magnetic field intensity of 1000 Gs with fineness of pulp reached 92.75% passing -0.074mm. Under the optimal conditions, an iron concentrate containing 88.17% total iron grade and iron recovery of 92.51% was obtained, 4.55% total iron grade in tailings. This novel technique provide a potential route for utilizing hematiterich diasporic bauxite ore, recovering iron resource firstly, and extracting alumina from magnetic separation tailings further.

Jan 1, 2015

By Itavahn Alves da Silva, Jose Dimas de Arruda, Amanda Aparecida Fátima Arruda, da Silva de Souza, Carlos Antonio da Silva, Varadarajan Seshadri, Samuel

The knowledge of the flow field inside a continuous casting mold is essential to improve operational efficiency of the process and also to achieve better inclusion control. Physical modeling, PIV technique and CFD have been employed to assess the velocity distribution in the metal- slag interface region in a slab mold. The analysis of results shows how higher casting velocity and lower immersion depth of submerged nozzle can lead to higher turbulence in the slag-metal interface. The effects of density difference between slag and metal and interfacial tension between the phases have been highlighted.

Jan 1, 2016

By Youn-Bae Kang, Jong-Jin Pak, Min-Kyu Paek

The critical evaluation and thermodynamic optimization of Mn-Si-C and its sub-binary systems have been carried out over the whole composition range from room temperature to above the liquidus temperature. The solution properties of the liquid systems have not been clearly described because the liquid solution exhibits a high degree of short-range-ordering. In order to predict the thermodynamics of the liquid solution, the liquid phases were optimized by the modified quasichemical model. The model parameters of the solid phases were also optimized by the compound energy formalism to best reproduce the phase diagram and important thermodynamic properties in Mn-Si-C system. Using the model parameters, various thermodynamic calculations were carried out. The present database will be a part of larger thermodynamic database for the ferromanganese alloy database.

Jan 1, 2014

By D. N. Esfahani, K. Khazen, M. Mohammadi

Electrowinning is one of the nickel recovery processes from solutions obtained from the leaching of nickel sources. Every year significant amounts of nickel products are used in various industrial processes and daily life, such as catalysts or batteries, which are a valuable source of nickel for recovery. Nickel purity is also very important in the electrowinning process, because the amount of impurities in nickel such as sulphur, if greater than 100 ppm, make it unsuitable for use in catalysts and plating. Because sulfur is intrinsic to the sulphate electrowinning system, we needed to investigate parameters that can affect the quality and purity of nickel. In this regard, experiments were performed in static and circulating electrowinning processes. A monitoring and circulation system was designed and built to measure voltage, current and temperature as well as to circulate the solution in the system at a specified rate. It was then observed that nickel ion concentration, pH, using the circulation system and additives, were factors affecting the purity and quality of nickel, and in the best case the amount of sulphur in nickel was below 100 ppm. Keywords: Nickel, electrowinning, sulphur impurity

Jan 1, 2020

By А. V. Aksenov, S. G. Rybkin, А. Y. Senchenko

Recovered activated carbon fines result from processing of ore and concentrates via cyanide leaching and sorption of valuable metals on carbon at gold-mining plants. This intermediate product is characterised by the particles sized smaller than 0.6 mm and gold grade up to 300-500 g/t. Processing of carbon fines with recovery of valuable metals is not available at many plants due to the lack of optimal technology. The paper describes the testwork and development of an efficient technology to process carbon fines with the recovery of valuable metals into the target gold alloy. This innovative technology involves pelletising of fine activated carbon particles using an organic binder, drying and further firing of pellets in a grate fired furnace at 800-900 °С. The produced ash is subject to sintering with sodium nitrate and hydroxide at 600-700°С. The sintered ash is then leached in water. The insoluble residue containing gold and silver is removed by filtration, dried and smelted to produce gold alloy. Water solution containing sulphur and arsenic is subject to detoxification. Processing of recovered carbon fines according to the developed technology implies the use of standard full-scale equipment. The offered method to treat gold-bearing carbon fines was patented by the Eurasian Patent Office. Key words: Fine activated carbon particles, valuable metals, pelletizing, firing, ash, sintering, leaching, smelting

Jan 1, 2020

By Jose Carlos D'Abreu

O presente trabalho se refere a um programa de pesquisa cooperativa Universidade- Empresa, que objetivou analisar a metalização de briquetes autorredutores quando submetidos à redução sólida e quando adicionados a um banho de aço fundido, atendidas as similaridades impostas pelos processos industriais. Focando principalmente a recuperação dos resíduos particulados gerados pela siderurgia integrada, foram formulados sete tipos de aglomerados autorredutores. O presente trabalho considerou duas rotas experimentais: primeiramente, a que realizou a autorredução em fase sólida numa atmosfera de nitrogênio, e a monitoração da conversão reacional resultante através da análise dos gases de exaustão gerados. Em segundo lugar, a que promoveu a autorredução via a imersão dos briquetes num banho de aço carbono, e a realização posterior das monitorações das variações de composição do aço fundido e de sua temperatura, visando comparar o “potencial refrigerante” dos briquetes e das sucatas. Este trabalho apresenta os resultados experimentais relativos a seis briquetes, no caso da rota de autorredução sólida, e de um briquete (tipo A), no caso da segunda rota. Finalmente, com base nos resultados laboratoriais, foi possível concluir pela viabilidade técnica preliminar das duas rotas de reciclagem.

Aug 16, 2017

By Alim Ullah

The paper discusses the necessity of upgrading low-iron containing ores, giving as an example, NML-Tata Steel Project in the Quebec-Labrador region of Canada. As cooling of pellets is generally a bottle-neck in most pelletizing plants, examples are given of the methods used to improve cooling in the existing plants and a simple, low-cost alternative, tested on a pot-grate system, is presented. The procedure described is applicable to sinter plants also. The trends in iron and steel production worldwide are then given, as well as the reasons for the increase in steel production by the Electric Arc Furnace (EAF) route. The stoichiometric and thermodynamic requirements for producing iron, irrespective of the process, are explained. The different ironmaking processes, especially the Direct Reduction (DR) ones are briefly discussed, outlining recent improvements made to some of them. The pros and cons of producing cooled DRI and Hot-Briquetted Iron (HBI) are given with predictions made for their future growth. An alternative to cold-briquetting of DRI fines is also discussed. Highlights of an ironmaking processes which is at the laboratory/pilot plant stage are given.

Aug 1, 2018

By Marjorie Benegra

This study aims to compare the wear resistance assessed in rubber wheel abrasion test of nickel aluminide coatings deposited by for Plasma Transferred Arc (PTA) and High Velocity Oxigen Fuel (HVOF) manufacturing, using the same raw material. A nickel aluminide powder was atomized and deposited on 316L steel plate substrate. After deposition, some specimens were submitted to a heat treating (1200 °C for 24 h followed by 760°C for 24 h). The coatings deposited using PTA developed different microstructures due to the incorporation of substrate elements, its performance was better than the HVOF coatings, although their Vickers hardness was similar. After heat treating, a significant variation in hardness and wear resistance was observed. For PTA specimens, there were decrease in hardness of 35%, while for HVOF ones this drop was approximately 20%. Nonetheless, the effect of thermal exposure in wear resistance was quite different: an increase of 21% was observed for HVOF coatings, while a reduction of 20% occurred in PTA ones. Microstructures modifications in PTA coatings were significant for their wear resistance. On the other hand, the reduction of porosity and sintering were responsible for a better performance of heat-treated HVOF coatings.

Jul 31, 2018

By Delvaux Carlos de Miranda Sobrinho, Hegler Zurick Arantes Assunção, Marco Venicio Mendonça de Souza, Luciano Toledo Ribeiro

This paper aims to present the development of a 600mm U-Pile that was done in Gerdau’s Ouro Branco Heavy Section Mill in order to feed the local market with a product.The focus of this study is to show the developmental process the Mill went through until it was prepared for hot trials. All roll pass and guide designs were developed by our own team. Analytical tools like Finite Element Analysis and reduced scale lead trials will be shown and how these tools impacted on the development timeframe and accuracy of the final results on steel.

Oct 1, 2019

By Ivan César Lopes Diniz

Stretcher Reducing Mill (SRM) is a mill used in production of tubes. It is composed with a set 24 of stands responsible to define the final outside diameter (OD) of tubes. External appearance is critical in this process even though this requirement has no effect on mechanical properties. For this reason, an investigation of external longitudinal marks mechanism is in progress using 6 Sigma methodology. This paper is a part of the investigation with focus on the rolls and its mechanical properties. Destructive tests were performed in the rolls and compared with the project. After a detailed investigation, it was concluded that rolls were out of hardness specification and the project was poor of information. A new supplier was developed (internal market) based on the new project and all requirements were achieved as demonstrated in this paper. A monopolistic market for this product in VSB (Vallourec Soluções Tubulares do Brasil) was eliminated. Concerning the effect on the external longitudinal marks, the new rolls developed within hardness range minimized the mechanism of wear on rolls surface and consequently on tubes surface. A collateral effect has been faced, but still better than external longitudinal marks on tubes surface. The quenched and tempered rolls are more sensitive for process variation, mainly linked with cooling system and temperature of tubes (mechanical resistance for deformation). Nevertheless, a new material has been aimed focusing on reduction of rolls breakage with good tenacity and affordable cost.

Oct 4, 2019

By M. G. Schulz

Mining of molybdenum at Questa, New Mexico has been accomplished by block cave methods since August, 1983. As caving progresses, a periodic geologic evaluation is made of the rock-types present in finger raises on the Grizzly Level of the mine. The production maturity of the cave can be monitored by relating this data to geologic cross-sections through the ore body. The draw point mapping program is a simple and effective tool that is used in making draw control decisions at Questa.

Jan 1, 1985

By Olgac Kangal, Ali Guney, Gulay Bulut, Guven Onal, Ayhan A. Sirkeci

This paper presents the results of pilot scale column flotation applications in the two different copper concentrators in Turkey. The Kure Copper Plant is located in the Black Sea Region of Turkey. In Kure, a very fine grinding requirement for an adequate level of liberation makes a successful flotation difficult and consequently the final concentrate can hardly assay above 16% Cu Column flotation tests were conducted at the plant site using two different column types The experiments proved that the grade of the concentrate could be increased from about 14% Cu to 25-26% Cu. Murgul Cakmakkaya Copper Concentrator is the largest copper concentrator in Turkey. Although concentrate production capacity is around 170,000 tons annually with 22-23% Cu content, this figure tends to be much lower than that. In Murgul a Turbo Column of Multotec Company of South Africa was employed. As a result of systematic column flotation tests, the grade of the concentrate was increased from 20.3% Cu to 28.7% Cu.

Jan 1, 2003

By R A. Pakhomov, L V. Krupnov, P V. Malakhov, I M. Dymov

The article presents results of thermodynamic calculations and laboratory studies, focusing on the cobalt behaviour during oxidative smelting of copper-nickel mattes. The compositions of the studied solutions are related to the products formed during the second stage of the converting process of copper-nickel matte at the Nadezhdinsky Metallurgical Plant (NMP) of MMC Norilsk Nickel company. These sulfide products typically contain from 1.5 to 12 wt per cent of iron. The obtained experimental results and thermodynamic calculations indicate that adjusting the CaO ratio to increase the proportion of CaO or complete replacement of SiO2 with fluxes containing CaO leads to a significant increase in cobalt recovery rates in the matte phase (with an iron concentration of 2.5 wt per cent) raising them from 30 per cent to 45 per cent. Meanwhile, the recovery rates of copper and nickel remain constant.

Aug 21, 2024

By D Bruce, D Cox

The main access decline at Carrapateena mine was excavated through two different underground aquifers. In these areas of decline, pressurised water finds the path of least resistance through the rock and into the excavation. In some locations the ground water would upwell underneath the roadway resulting in rapid deterioration of the running surface. The deterioration of the road was so rapid that the two areas of decline required significant roadworks every single shift or it would become impassable by mine traffic. With a full fleet of underground trucks hauling to the surface, managing these sections of roadway was impractical and unproductive. The site team resolved this issue by installing Roller Compacted Concrete (RCC) to the affected sections of decline. RCC is a specialist concrete product that is delivered to the site near dry and is installed using a grader and roller similar to road base. This product can be installed quickly and be trafficked within hours of installation, making it ideal for mines with single access declines and unfavourable road conditions. RCC roadways were successfully installed at Carrapateena mine in conjunction with under-road drainage. These roadways have proved to be a very effective solution which requires minimal maintenance and are resistant to water ingress from the aquifer. This paper discusses the technical aspects of the RCC, as well as the practical implementation of the solution as a whole.

Mar 15, 2021

By Chuanyu Feng

In this paper, a load-based micro-indentation technique suitable for field applications was developed. This technique bears the same theoretical background as traditional load-depth sensing indentation, and does not need any direct measurement of indentation depth or contact area. The removal of this requirement will reduce much of the cost associated with traditional instrumented indentation. To demonstrate the feasibility, a portable indentation system suitable for online material characterization was developed. Design issues of the portable unit were discussed and preliminary results using the portable unit were also presented.

Jan 1, 2009

By Shawn P. Coughlin, Michael A. Schimmenti, Juan Leonardo Tello del Pino

"PROJECT OVERVIEWThe Sistema de Potabilización Área Norte project (Northern Area Purification System) was a major expansion of the potable water system in Buenos Aires Province, Argentina. The aim of the project was to transport and purify raw water from the Paraná River to provide potable water for five communities in the northern part of the province, benefitting up to two million inhabitants. The project was constructed by a joint venture of four South American contractors (“the JV”), and consisted of the following key components:• Treatment Plant: A 16 hectare area was cleared for the construction of a treatment plant to purify 900,000 m3/day of raw water from the Paraná River and distribute it to the surrounding communities.• Bored Tunnel: Nearly 15 km of 3.6 m inner diameter tunnel, ranging from 18 to 22 m below grade, was bored with two EPB tunnel boring machines to draw the raw water from the river. The TBMs started from a central launch shaft and proceeded in opposite directions: Cristina advanced northbound to the Paraná River Intake System, and Liliana advanced southbound to the new treatment plant.• Access & Ventilation Shafts: Five access shafts and eight ventilation shafts were installed along the length of the tunnel. The access shafts were designed to provide entry points for inspection and maintenance of the final tunnel. The five shafts consisted of: one central launch shaft in the middle of the tunnel alignment, one retrieval shaft at each end of the tunnel (Intake and Treatment Plant, respectively), and two intermediate shafts. The intermediate shafts were installed before the TBM passed, with a final liner to be installed afterwards. Access Shaft 3, the intermediate shaft located between the launch shaft and the treatment plant, experienced persistent leaks during initial excavation attempts."

Jan 1, 2016

By S. Kelebek, Gerhard W. Heinrich, Peter F. Wells

"The review and optimization of process stages is an integral part of the program to improve the metallurgical performance of the Strathcona Mill. Improved primary grind size distributions, streamlining of rougher-scavenger circuits and increased platinum recoveries were the target of plant and laboratory scale tests. The results can be summarized as follows:• Decreasing the primary grinding cyclone vortex finder diameter for nickel/copper ore gave significant increases in overall copper recovery and improved rougher flotation selectivity.• The scavenger flotation stage in the circuit treating copper ore was found to contribute little to this circuit's copper recoveries -yet to be essential for acceptable recoveries of nickel, platinum and gold. The elimination of this stage by re-routing the tailings from the copper ore rougher into the nickel/copper ore rougher feed has lead to lower gangue recoveries to the nickel concentrate and to improved copper-nickel separation, while reducing equipment operating costs.• Surface aging effects such as oxidation are known to decrease flotation recoveries of platinum minerals such as sperrylite. The conditioning of an intermediate non-magnetic process stream with copper sulphate prior to thickening increased the platinum recoveries in the subsequent flotation stage by approximately 10%."

Jan 1, 1996

By Rick Deschamps

A reoccurring problem with support of excavations in urban areas involves the placement of external support components like anchors or nails in right-a-ways, subway and utility setbacks, in areas occupied by adjacent structures, and within the property of non cooperative neighbors. Such a situation occurred for a project in Arlington, Virginia, which ultimately resulted in the preliminary design of a large footing supported cantilever retaining wall that was extremely costly and impractical to build. An innovative design alternate consisting of a series of vertical concrete elements (VCEs) supported by post tensioned tiedowns was proposed to the General Contractor and accepted by the owner. The VCEs were designed to serve as the main structural elements for both the temporary support of excavation system and the permanent wall. The VCE?s were constructed using single bite diaphragm wall panels oriented perpendicular to the excavation face including a rebar cage and tremie concrete. Threaded inserts were placed within the rebar cage to attach the cast in place exterior wall. Overall stability and lateral movement of the VCEs were controlled by high capacity vertical anchors embedded within the VCE. A detailed instrumentation program was installed to monitor the movements of the VCEs with relation to the excavation depth. The paper present the project case history by discussing the design concepts of the VCE, the construction approaches used to install them, the construction challenges encountered, and the performance of the unique system.

Jan 1, 2008

The problem of comparison of island arc's andesites in terms of petrochemical data is exa- mined. It is definitely established that only two main factors exist controlling the petroche- mical variety of the Kurile arc's andesites.Ori final multivariate statistical technique and computer software are used to extract these fac- tors. It is shown as well that the chemical com- position of igneous rocks depends on the type and structure of the Earth's crust. The follo- ~cing interpretation is proposed for the two factors describing petrochemistry of andesites: the first one is the depth to the Benioff seis- mofocal zone and the second one is supposed to indicate the position of the peripheral magma chambers. The basic trends of variations in the chemical composition components depending on the changes in the controlling factors are de- Tcnnined.

Jan 1, 1987