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By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By Frank L. Hess

BERYLLIUM is demanding more of the limelight, and the output of beryllium copper (containing 2% to~ 3 per cent of beryllium) seems to have grown 60 per cent above that of 1936, which was double that of 1935. There is increasing interest in beryllium-aluminum alloys and small quantities are being marketed at $50 per lb. for the contained beryllium. Other alloys also can be produced. Further price decreases for beryllium copper (now $23 per lb. for the contained beryllium) seem , possible and desirable. No difficulty has been experienced in obtaining beryl and a 'reserve stock has been built up. One supplier heretofore found reliable has offered to furnish 200 tons per month. Supplies during 1937 have come from the Black Hills in South Dakota, Colorado. India, and South America

Jan 1, 1938

By Clyde E. Williams

DESPITE the confusion resulting from the depression and the beginnings of recovery, important progress in all branches of iron and steel metallurgy has been accomplished during the year 1933. Research work has been intensive and highly technical, with increasing attention paid to fundamentals. Plant application of research developments has been rapid. Highly specialized laboratory methods were used for the study of iron-ore concentration methods. More attention has been given by the blast-furnace operator to the sizing of ore and the elimination of fines from the charge by the use of sinter. Combustion in the open-hearth has been placed under better control and the insulation of open-hearth furnaces has spread rapidly, with resultant higher fuel efficiency and better control of the melting and refining operations. Control of iron oxide content in the slag and the determination of iron oxide and other inclusions in steel received great attention during the year.

Jan 1, 1934

By AIME AIME

The 102d meeting of the Institute was held at the Institute headquarters in the Engineering Societies Building, New York, N. Y., on Feb. 19, 20 and 21, 1912. A Bureau of Information, in charge. of Mr. George Buckman, was maintained during the meeting. The proceedings opened with an informal social meeting on Monday evening, Feb. 19, in Assembly-Room No. 1, on the

Mar 1, 1912

By Ananda Moreira Vaz Ourique de Avila

High and intermediate temperature fuel cells (FC) are power generators characterized by high efficiency and their use in cogeneration systems. The single fuel cells are connected in series by the use of interconnects to form a fuel cell stack. Ferritic stainless steels have been used in the making of high and intermediate temperature operation solid oxide fuel cells interconnects. However, at high temperatures, on the order of 700-8500C, these steels can present significant oxidation and degradation processes, promoting increased electrical resistivity and corrosion losses that result in contamination of the electrodes and reducing the performance and the useful life of the FC. Intensive R&D activities have been made to minimize these problems and the use of composite coatings on metallic substrate has been considered. This paper evaluates the use of coatings of copper and nickel, with particles of La2O3, Y2O3, CeO2, LaCrO3 and doped chromites applied on ferritic stainless steels AISI 430, AISI 441 and Crofer22APU produced by electrodeposition. The produced samples were evaluated by microscopy techniques, gravimetric analysis and by electrothermal characterization. The most significant results were obtained with chromites coatings (LaCrO3 pure, mono- and multiple-doped) showing the combination of the best features of metal coatings, substrates and ceramic particles with semiconductor properties.

Aug 7, 2018

By Chad B. Donovan

There is a strong need in North America and other major steel producing markets where major capital investment in new equipment has been minimal over the past several years to make improvements to existing casting machines. In many cases, very cost effective improvements can be made to existing equipment in order to maximize the efficiency and production of an older designed continuous caster, a classic caster. SMS Group and its predecessor companies have been maintaining continuous casting molds for over forty years. This experience has allowed SMS Group to intimately understand the advantages and disadvantages of each design. The most vital component of the continuous caster is the mold copper design, as it has the most influence over the ability to cast a quality product. Updating to a modern copper design is less complicated than most steel producers think and the benefits are significant. Premium mold coatings such as UniGuard® and NanoGuard® allow casters to guard against exposed copper and wear while producing quality products for record campaign lengths.

Oct 30, 2017

By David H. Sanders, Ramin Motamed, Fahim M. Bhuiyan, Raj V. Siddharthan

Large-diameter drilled shafts (DS) are a critical part of a seismic-resistant system, and therefore it is important to be able to accurately model lateral resistance. To undertake the lateral load analysis of largediameter DS, a finite-difference p-y analysis program, NVShaft, is being developed at the University of Nevada Reno. Validation of the new program involved numerous p-y analyses using commercially available programs. Subsequent comparisons suggested the program's ability to yield reasonable predictions for typical diameter DS. Based on the I-15/US 95 load test program carried out in Las Vegas, NV, this study presents the evaluation of NVShaft in Nevada’s subsurface condition. Lateral load analyses of a 2 ft and an 8 ft diameter DS were attempted using NVShaft. The location of the applied lateral loads and the presence of cemented soil-layers were incorporated in the modeling. A good agreement between NVShaft prediction and the measured response was found for the 2 ft diameter DS. For the 8 ft diameter DS, a stiffer response was predicted. The inspections of the moment-curvature characteristics at different load levels suggested cracked response of the concrete due to prior axial load testing may be one of the reasons behind the deviation.

By Antonio Marinucci, Robin Mao

The new Hangzhou West Railway Station, which is currently in the early stages of construction, will be located in the city of Hangzhou, China. To accomplish the ambitious goals of the project, the construction work and station building was divided into three project areas. The original design utilizes 1,580 drilled shafts with diameters of either 800 mm or 1000 mm (32 or 40 inch) to support the new Station and its various ancillary structures. The drilled shafts will be tipped into the moderately weathered argillaceous siltstone a distance between 5 and 15 m (16.5 and 49 ft), resulting in an effective pile length ranging from 35 to 43 m (115 to 141 ft), respectively. For the first phase, approximately 550 production drilled shafts will be installed. Eight (8) sacrificial drilled shafts each with a diameter of 1000 mm (40 inch) were installed to a depth ranging from 50 to 57 m (164 to 187 ft), and were tested to confirm the design parameters used for the first phase, to evaluate the contractor’s installation means-and-methods, and to provide guidance whether redesign is warranted for the subsequent two phases. Bi-directional static load testing was performed using a donut-shaped Super Cell to apply unidirectional axial loads up to 13,200 kN (2,970 kip). This paper will describe the bi-directional testing and select results obtained therefrom. The axial compressive and uplift resistances determined from the testing verified that the available axial resistance of a single drilled shaft exceeded the minimum design requirements.

By Thiago Rangel Bittencourt

Com a tendência de aumento da complexidade geométrica dos painéis de cobertura dos automóveis, aumento de resistência mecânica e diminuição da espessura dos materiais, a estampagem dessas peças tem tornado cada vez mais difícil. Neste contexto, dois graus de aços que exibem elevada resistência mecânica e boa conformabilidade, têm sido ofertados pela siderurgia à indústria automotiva, o Bake Hardenable (BH) e o Interstitial Free High Strength Steel (IFHSS). O presente estudo teve como objetivo avaliar aços BH e IFHSS, em termos de propriedades mecânicas, de conformabilidade, de ganho de resistência em função da deformação, envelhecimento e de resistência à indentação, em escala laboratorial. Desse modo, visou-se avaliar sob quais condições de estampagem deve ser decidido o uso do BH ou do IFHSS em aplicações de painéis automotivos. Os aços avaliados, de um modo geral, apresentaram desempenho similar em termos de conformabilidade. O aço BH foi superior ao IFHSS em relação à resistência à indentação. Portanto, o aço BH aparece como uma solução técnica atrativa, comparativamente ao aço IFHSS, quando aplicado em painéis externos (capôs, portas e paralamas) que requerem maior exigência quanto à resistência à indentação.

Aug 7, 2018

By Eddy Dierckx

Modernization of flat rolling plants is essential to sustainably fulfill increasing market demands and to improve competitiveness. Intelligent modernizations ensure getting maximum prime yield of existing mills, even if they have gone through half a century of operation. Existing mills were designed based on former production, consumption and quality targets. Ever increasing requirements such as increase of productivity, change of product mix (e.g. new steel grades), reduction of energy consumption and improvement of product quality lead to the necessity to adapt the existing equipment to the new target. SMS group provides, besides the reliable equipment and automation solutions to successful upgrades of existing mills, also a systematic approach to develop technical and economical solutions together with our customers (conceptual engineering). This paper describes the SMS group approach to modernizations / upgrades, introduces powerful performance modules and provides a number of successful examples that have been implemented recently.

Aug 17, 2017

By J. B. See

Emeritus Professor David Robertson of the Missouri University of Science and Technology was born in Dublin Ireland on 29 December 1941. His father was a merchant navy Captain who served during WWII and during David’s early years his family lived in Dublin and Donegal where David went to the local elementary school. In 1954 he moved to London with his parents and attended Highgate School before commencing metallurgy at the Royal School of Mines, Imperial College, London in 1960.

Jan 1, 2014

By Frederic Dewey

(New York Meeting, February, 1913) This old and well-known method of determining, silver is, in bullion work, so far superior to the furnace-assay that it is looked upon with reverential awe by many, if not by most, users, and its-ease of execution, with proper equipment, commends it highly where much commercial bullion work on silver is required. The method is so thoroughly well known that a, description of it here may seem to be unnecessary, but many thousands of determinations are annually made by it in the U. S. Mint Service and its practice is there reduced to an art. This is necessary both for the sake of economy of time, acid because high-grade work with it requires constant practice. It is useless for a person who uses it only occasionally to expect to attain high accuracy with it, without spending more time upon a determination than is warranted in a busy commercial laboratory. It is always employed in the Mint service whenever possible, but its chief field is in the determination of silver in standard silver (ingots and coin), which is 900 fine in silver and 100 fine in copper, and I shall first briefly outline its use on this metal and then take up various points in detail, especially as related to the accuracy of the results obtained.

Jan 4, 1913

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992

By Matthew D. Marks

"The Sacramento Area Flood Control Agency initiated the Natomas Levee Improvement Program in 2006 which would bring the entire 42 mile Natomas Basin perimeter levee system into compliance with applicable Federal and State standards for levee protecting urban areas. The soil-bentonite slurry cutoff has been utilized as the primary construction method for addressing the under seepage deficiencies. To date, a combined total of over 4,500,000 square feet of slurry cutoff wall have been constructed utilizing excavation methods to a maximum depth of 75 feet and deep soil mixing methods to a depth of 90 feet. The construction of these cutoff walls has required the use of newly designed and custom built long boom and stick attachments for large hydraulic excavators and additional resource will be required to complete future phases. Key components of the NLIP program have included advancements in the development of soil-bentonite backfill mix designs, specified ranges on the soil backfill gradation to address concerns of long term consolidation of the backfill material, evaluation of the trench slurry filtrate loss with regard to cutoff wall acceptance, maintenance high slurry densities to provide greater trench stability, and continued development of backfill mixing procedures.IntroductionThe Natomas Levee Improvement Program (NLIP) was initiated by the Sacramento Flood Control Agency (SAFCA) in 2006. The long term objective of the NLIP is to provide 200-year level flood protection to the basin. To date, approximately 21 of the 42 mile Natomas Basin perimeter levee system has been completed, totaling over $100,000,000 in construction contracts, of which slurry cutoff walls make up approximately $25,000,000. Other construction elements include excavation and removal of unsuitable levee materials, raising or widening existing levees, construction of landside seepage berms, drainage canals, and miscellaneous structures.Although each construction phase of the NLIP includes various construction elements of levee restoration program, the slurry cutoff wall is the primary construction element for addressing the under seepage deficiencies. To date, approximately 4,500,000 square feet of slurry cutoff walls have been installed using excavation and deep soil mixing (DSM) methods. This includes approximately 2,000,000 square feet of slurry cutoff wall along 5 miles of the NCC South Levee and 2,500,000 square feet of slurry cutoff wall along 16 miles of the Sacramento River East Levee (SREL). The work has been completed under 8 separate contracts, through SAFCA, and performed between September 2007 and December 2012. A summary of the contract phases and associated cutoff wall square footage is provided in Table 1. Most of the work has been performed within the seasonal dry weather period in the Sacramento valley, which occurs between April and October. This has required much of the work to be performed on an aggressive construction schedule, year after year."

Jan 1, 2017

By R. Pandher, R. Schonewille

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGETH METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011

By Ray Everson, Henry Kasaini

"We carried out adsorption experiments in chloride media to study the adsorption characteristics of Pd (II) anions on the surface of activated carbon. Throughout the experiments, we used commercial activated carbon pellets (0.8 Norit). The adsorption process was interpreted by using the ionisation and adsorption model. This implies that palladium anions were adsorbed physically on a protonated surface of activated carbon either as anionic complex species (PdCl4 -2) or aqua chloro-complex species [PdCl3(H2O)-] in acidic media. Furthermore, we established that adsorption of Pd (II) species was reversible at high chloride [Cl-1] concentration. The maximum adsorption capacity (Qsat) of Pd (II) anions averaged 27 mg/g. The Toth adsorption isotherms fairly predicted the equilibrium adsorption of Pd (II) species and the associated surface coverage.The effect of temperature and acid strength of the feed solution on the adsorption of Pd (II) ions were quantified. The adsorption kinetics was limited by external mass transfer since the effect of pore diffusion on the overall rate constant was negligibly small. A pseudo first-order kinetics model was used to describe the adsorption kinetics."

Jan 1, 2003

By U Singh

This paper presents the evolution of the studies and strategic plans to extend the life of operations at the Savage River iron ore project in north-western Tasmania. The current Life-of-Mine (LOM) plan for the Savage River operations is based on a series of open pits. Drilling has confirmed high-grade extensions of the magnetite resource at depths that exceed practical limits for open pit mining. Grange Resources Limited, the owner of the operation, is investigating underground options – not only to extend the LOM plan but also to maintain peak production at a reduced operating cost while reducing greenhouse gas emissions into the future. What makes this project unique is that it requires introducing a productive and cost-effective mining method to exploit a challenging geotechnical and geometrical orebody in an area of high rainfall. To support the study efforts, the development of an exploration decline, underground drilling programs, and an exploratory drive excavated into the orebody for geotechnical investigation was key to providing the necessary data for a pre-feasibility study (PFS). This paper describes the pragmatic approach and processes to developing the underground mining options study through data collection and then integrating these options into the open pit plans to optimise an overall strategic plan for the Savage River operations. The learnings for operators from this experience are how the technical and pragmatic approaches were aligned to develop the strategic plans, and the importance of timely investment in gathering the necessary data.

Mar 29, 2023

By S Liu, N M. Rana, A Take, N Ghahramani, D Clohan, S McDougall, S G. Evans, H J. Chen

Tailings dam breaches have caused significant life loss, social, economic and environmental damage in recent years. The term "tailings-flow" refers to various forms of tailings outflow movement resulting from the breach of a tailings dam. These flows, comprising a mixture of tailings, water and dam materials, can take different forms, ranging from a debris flood to a flowslide, and can travel long distances and impact large areas. The inundation extents depend on the failure mechanism, tailings dam height, total released volume, sediment concentration (associated with the rheological behaviour of the flow) and downstream conditions (including topography, land cover and presence of a water body). Numerical runout modelling of tailings dam breaches is important for predicting the dynamics and extent of tailings-flows, which are crucial steps in tailings dam consequence analysis and risk management. This paper presents a comparison of numerical simulations of the 1994 Merriespruit tailings dam breach using three numerical models: DAN3D, FLO-2D and MADflow3D. Using compiled site condition information and data from the literature and public domain, model performance was evaluated primarily based on comparisons between the observed and simulated inundation extents. The main purpose of this preliminary model benchmarking exercise was to help us evaluate the capabilities and limitations of each model, and to identify opportunities for future model improvements as part of a broader research initiative known as CanBreach. This exercise also highlights the inherent complexity of tailings-flows and the importance of using judgement to interpret model input and results.

Jul 1, 2021

By J. Racinais, P. Vincent

"In September 2011, Menard Oceania (MO) was engaged by Mac Mahon John Holland Joint Venture (MJHJV) to provide ground improvement solution for the $34bn Ichthys LNG development. With close to 400,000m2 of mangrove swampland set to be reclaimed and improved, this project was a great opportunity to showcase the technical, commercial and environmental benefits that Dynamic Replacement (DR) ground Improvement technique can provide. The ground improvement works involved complete design and construction for the Ichthys LNG site located at Blaydin Point on a low lying peninsula in Darwin Harbour. Dynamic replacement and stone columns technique were selected to treat intertidal mangrove mud to achieve required bearing strength, stability and limit settlement to an acceptable levels. The site is underlain by a 3m to 5m thick layer of highly organic mangrove muds with very soft shear strength ranging from 0kPa to 12kPa at depth. The site is exposed to daily sea water level tidal variations of up to 8m, which created significant constructability constraints and slope instability risks. This paper presents the design philosophy, the process involved in the selection of the construction methods, the site constraints encountered during the works and a review of the results achieved, quality control and post constructions performance.INTRODUCTIONInpex Browse, Ltd (Inpex) and its partner Total are developing the Ichthys gas field to pipe gas to onshore facilities at Blaydin Point on the south side of East Arm in Darwin Harbour. The proposed LNG plant consists of gas receiving facilities, 2 x 4.2Mtpa nominal capacity LNG trains, LPG and condensate production facilities, product storage and export facilities, a module offload facility (MOF), a flare pad (FP) and associated off plot facilities.The proposed on-shore facilities are located on extremely soft intertidal mangrove muds, therefore an appropriate ground improvement was required to achieve required strength and stability of site works and limit long term settlement to an acceptable level.Various ground improvement techniques were studied to select the most suitable for the ground conditions and site constraints encountered at the Blaydin point site. Dynamic replacement technique was selected for onshore section to improve soft mangrove mud to depths of 5.5m and Stone Columns (SC) technique was selected for MOF off-shore section to improve intertidal deposits to a depth of 2.5m.This paper presents DR design and construction works performed between December 2012 and August 2013 at Flare Pad Area."

Jan 1, 1900