Search Documents

By T. A. Larssen

The efficiency in production of manganese ferroalloys is dependent on the gaseous reduction of the higher manganese oxides in the ores used as raw materials. The materials, descending in the furnace, will meet the furnace gas that contains significant amounts of CO(g) and reduce in subsequent steps, the last step being reduction of Mn3O4 to MnO. This step may to varying extent occur at temperatures exceeding 800 °C, i.e. in the active region of the Boudouard reaction. The gas reduction of Assmang and Comilog manganese ores were investigated in CO-CO2-atmosphere at temperatures up to 1000 °C. It was seen that decreasing ore size correlates to a lower reduction temperature and increasing reduction rate. Similar effect was observed with increasing CO-content in the gas atmosphere. Further, it was found that Comilog ore obtained a complete prereduction at 600 °C, whereas reduction of Assmang ore was not complete at 800 °C for the majority of the experiments.

By Ihsan B. Tulu, Keith A. Heasley, Aanand Nandula

"The objective of this paper is to present the development of a software tool that will assist in an area calculation of the Analysis of Roof Bolting Systems (ARBS) support intensity while incorporating more detailed geology, stress, and intersection span input. In this area ARBS tool, a detailed CMRR distribution can be determined from the available geologic database at the mine. In addition, the overburden and multiple-seam stresses, as obtained from the boundary-element program LaModel, can be converted to a “pseudo-depth” which is then used as the depth input to the area ARBS calculation. Finally, the section-specific intersection spans can be determined from the mine design for input to the calculation. All this detailed area input information for ARBS is handled by the latest version of the Stability Mapping (StabMap) program, which now outputs an area ARBS suggested support density given the required input parameters. This final ARBS grid can be plotted, analyzed and overlaid on the mine map for optimum use in support design and for presentation to production personnel.INTRODUCTIONSince the inception of roof bolts in the 1940s, there has been a lack of a universally accepted roof bolting design method (Mark, 2002; Mark and Pappas, 2012). To address this situation, the National Institute of Occupational Safety and Hazard (NIOSH) developed roof support design guidelines, which were incorporated into a computer program called the Analysis of Roof Bolting Systems (ARBS). These guidelines were based on the effects of roof quality, stress, and mine geometry (Mark, Molinda and Dolinar, 2001). The roof rock quality in ARBS is represented by the Coal Mine Roof Rating (CMRR), the depth is used as a surrogate for the stress, and the intersection span serves to represent the mine geometry (Mark, Molinda and Dolinar, 2001). These three input parameters are used in the fundamental, empirically derived equation of ARBS to calculate a required support density factor, called ARBS, (Mark, Molinda and Dolinar, 2001):"

Jan 1, 2018

By T. F. Deems

The nature, usage and comparatively rare occurrence of ball clay is described. The importance of these white firing plastic clays in ceramics, particularly in the production of industrial sanitary ware and tiles, is emphasized. The US deposits are briefly discussed. What is known about relevant deposits in Brazil, Argentina, Colombia and Venezuela (the four largest ceramic producers in South America) is also described. The ceramic plants have been sited near the centers of population rather than the plastic clay deposits. At present, extraction is probably concentrated on surface residual deposits and lenses which require minimum investment. Native plastic clays are used exclusively in the tile plants, but in sanitary ware, they are often used as extenders of imported ball clays.

Jan 1, 1997

By Chen Jianhua, Shen Zhenchang, Zhang Ming, Chen Feifei

"With flotation cells scale-up, the performance of flotation cells is increasingly variated for short-coming and dead zones existing. The residence time distribution which shows the movement of tracers can assess the unexpected flows such as short circuit and dead zone in a flotation cell. In this paper, the residence time distribution of pilot flotation cell is investigated with CFD simulation. Based on the theoretical model, the short-coming probability and dead zone probability are quantitative. The ideal average residence time is similar with the actual average residence time. The mixing effect of the flotation cell approaches the ideal continuous stirred tank reactor. The operating parameters such as speed and feed velocity have complicated influence on residence time distribution. The research would be helpful to understanding flow in flotation cell and improving performances of flotation cell.INTRODUCTION Froth flotation is a method which purifies minerals according to difference of physical and chemical surface characters of different mineral particles (Shen, Z., Chen J, 2012). Flotation cell is a key equipment for froth flotation method. The flotation cell performances have great influences on flotation index.It is difficult to evaluate flotation cell how to improve flotation procedure to complexity. The main flotation cell performances are aeration volume, air dispersion, solid suspension and residence time distribution, etc (Shen, Z., Lu, S., 2008). Residence time distribution is an important fluid hydrodynamics which could reveal the flow of pulp, mixing of particles and air bubbles. In the flotation cell, the ideal average residence time of pulp could obtain easily. But the fluid differential units would be different flow paths. The residence time of the fluid differential units is variation and would be longer or less than the average residence time. The residence time distribution would reveal the mixing effect and predict the not ideal flow in the flotation cell such as shorting cutting, dead zone, etc. As we know, the shorting cutting and dead zone would be decreased the real flotation time and it is disadvantage to better flotation effect, especially for large flotation cell. It is impossible to eliminate the not ideal flow totally. It is very important to reveal and decrease the shorting cutting and dead zone probability in the flotation cell."

Jan 1, 2018

By K. Trapani

"The study undertaken aims to investigate an ice stope heating and cooling system for its potential to be implemented in sub-arctic mines, as a low carbon alternative to conventional natural gas and refrigeration chiller systems. Its performance was simulated for a years’ worth of data, taking into consideration hourly temperature data. Results showed that to supply the required heating and cooling loads, the ice stope system had to supplement its heating with natural heating. The techno-economic performance of this system was compared to that of a conventional heating and cooling system in a mine, with the ice stope thermal storage system hawing the lowest annuitized cost and significantly lower carbon emissions.INTRODUCTIONConventional heating and cooling, in a mine is implemented using natural gas heaters and chiller refrigeration systems respectively. This results in a significant portion of energy consumption in underground mines attributable to ventilation (De Souza, 2015), including the conditioning of the air to ensure that temperatures do not exceed work comfort standards (ACGIH, 2011). Especially at depth where heat could become a significant issue. An ice stope thermal storage, using ice as the storage medium is being proposed as an alternative to provide the heating and cooling—with the ice creation resulting in heating and the ice melting providing the cooling required. A techno-economic investigation of the two systems is undertaken to identify the capital and operating costs for the two systems, and to assess the ice stope’s potential to be considered a low cost and carbon solution for heating and cooling of mines in sub-arctic climates.NATURAL STORAGE SYSTEM – CONCEPT DEVELOPMENTThe concept for the natural storage system is developed from the ice stope at Frood-Stobie Mine, ON, Canada (Stachulak, 1991). The ice stope was developed for mine air heating, with the heating occurring by spraying warm return service water onto the cold intake air—resulting in the air temperature increasing and ice being created in the stope. In summer this ice was melted by passing warm air on top of it, resulting in slight cooling of the air but no significant temperature difference which could allow effective cooling. A schematic of the Frood-Stobie Mine ice stope is provided in Figure 1."

Jan 1, 2019

By J. P. Downey, T. Salisbury, M. Berlin, E. Rosenberg, G. Pinson, R. Christianson, K. Gleason, W. Gleason, S. Davis

"Direct digital manufacturing offers promise as a technique for fabricating complex hydrogen purification membrane support structures. Free form fabrication methods can produce parts with complex structures, and sintering parameters can be controlled to adjust the density, pore structure, pore pathways and strength in catalytic substrate constructs. Efforts are underway to define the influence of selected process variables on the chemical and mechanical properties.IntroductionThe Center for Advanced Mineral and Metallurgical Processes (CAMP), in collaboration with the Metallurgical and Materials Engineering Department at Montana Tech and the Chemistry Department at the University of Montana, is engaged in the development of new methods and materials for hydrogen purification membrane production. Because hydrogen readily passes through palladium, a structurally sound palladium-based membrane is capable of separating relatively pure hydrogen from other gases. In order for this technology to succeed, a suitable substrate material must be identified.High purity hydrogen is produced by various means. A common method involves a two-stage process for separating hydrogen from a hydrocarbon gas stream: 1) hydrogen-rich syngas is produced by the catalytic reaction of natural gas or another light hydrocarbon gas with steam, and 2) hydrogen is separated from the other syngas components by pressure swing adsorption (PSA) (US. Energy Information Agency, 2011). In PSA, gases enter a column that is packed with a material that absorbs gases as the chamber is filled and pressurized. As the pressure is slowly relieved, the absorbent material releases hydrogen at a higher pressure than the impurity gases. PSA processes produce 99.99% pure hydrogen at a high recovery rate. These systems typically demand a high capital investment due to the high pressure and multiple stages (columns) needed to attain high hydrogen production rates.Research geared toward reducing hydrogen production cost is focused on the development of improved catalysts and adsorbent materials as well as more effective single-stage separation processes. An interesting method combines hydrogen reduction catalysis and filtration. Nascent hydrogen is separated from other gases as it selectively permeates the filter. Catalyst filters may be made of gold, silver, platinum, palladium or precious metal alloys (Davis, 2009)."

Jan 1, 2012

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016

By C. H. Lee

The world-famous Sang Dong Mine in the Republic of Korea has long been one of the world's greatest tungsten ore deposits. Over the years, the development of the Sang Dong deposit has steadily increased to a point where it now exerts a great influence on the world tungsten market. The mine is located in the mountains of the province of Kang Won Do, approximately 150 miles by road due east of Seoul, the capital of the Republic of Korea. In recent years the transportation system in Korea has greatly improved and the mine is now serviced by an excellent secondary type road from the new railroad line which is 20 miles away. The Sang Dong operation is made up of the underground mining, beneficiation mill, chemical refinery, tungsten metal plant, bismuth refinery, acid plant, foundry and machine shops. The bismuthinite production from the Sang Dong Mine is also of considerable importance, The output accounts for nearly 10 per cent of the world production of bismuth. A small amount of molybdenite concentrate is also recovered from the flotation operation.

Jan 1, 1962

By Shahid Islam, Lucian Bogdan

"The maintenance of infrastructures has been of particular concern to the engineering community. As the world’s infrastructure expands and existing infrastructure ages, monitoring and evaluation of the structures have become more critical than ever. A large number of retaining walls, tie backs, slope stabilizations and piles are designed using pre-stressing steel. Many piles and drilled shafts are designed using reinforcing steel. There are few testing methods available to assess these tension and compressive forces. High cost, complicated equipment and limitation of space often prevent these methods from being implemented. DYWIDAG-Systems International (DSI) has been involved in the development, testing and utilization of DYNA Force® sensors to measure the force in the anchors during construction and at any time during the lifetime of the structure. They can be used for bare, epoxy-coated, galvanized and greased-sheathed steel in the bonded, un-bonded, grouted or un-grouted length of the anchor. The sensor is robust and requires no maintenance. Sensors have received attention in terms of accuracy, performance, ease in installation, durability, and cost effectiveness. This paper describes its application in tie-back and anchor force monitoring of retaining walls and bridge abutment and compression forces in drilled shaft reinforcing steel where the data were collected manually, automated and remotely.INTRODUCTIONOur infrastructure is expanding and the existing infrastructure is aging. Some structures are expensive to maintain and some occasionally fail. There is a large demand for implementing health monitoring of structures. Many tie-backs, retaining walls, dams and other geotechnical structures are post-tensioned and many of them need repair using a post-tensioned system. On many occasions during construction and service life of the structure, it is useful to know the force in the post-tensioning and anchor system. Many piles and drilled shafts are designed using reinforcing steel and the compressive forces in reinforcement are unknown. Although there are many methods to measure the tendon force, most of them are cumbersome, expensive, and the accuracy varies depending on the method used.The elasto-magnetic (EM) technology is a novel approach to monitor forces in steel elements. The DYNA Force sensor is built based on EM technology (See Fig. 1). It is composed of a primary coil and a secondary coil (sensing coil). By passing current through the primary coil, ferromagnetic material is magnetized. The sensing coil picks up induced electromotive force that is proportional to change rate of applied magnetic flux (Faraday's law) and relative permeability. As permeability of core changes, output voltage changes. The output voltage is calibrated to measure the force. A readout unit is designed to magnetically energize the steel through the sensor and measure the response of the steel to the process. The readout unit then converts the response into a direct force reading. The sensor has an embedded thermistor which allows for temperature compensation. Due to the diversity of the magnetic property of steel, calibration is done for each type of steel allowing the sensors to perform at their highest accuracy."

Jan 1, 2017

By Junji Shibata

Heavier rare earth, which is contained in a small amount in ores such as bastnesite and monazite, has been accumulated as a heavier rare earth residue without doing separation and purification due to the lack of suitable methods. The heavier rare earth residue includes seven rare earth elements such as Tb, Dy, Ho, Y, Er, Tm and Yb. Separation and recovery process of Dy, Y, Tm and Yb from leached solution of the heavier rare earth residue was investigated by using a column method with solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organophosphorous extractant whose trade name is PC-88A into a macro porous resin, Amberlite XAD-7. It was almost impossible to separate them in simple adosorption and elution steps. However, we attained to individually separate Dy, Y, Tm and Yb from the leached solution first by changing eluent concentration gradually from pH2 to 0.02kmol/m3 HC1 in the elution step, and secondly by using a development column and changing eluerit concentration in the elution step. The separation process flow was proposed for a heavier rare earth residue by using the solvent impregnated resin method.

Jan 1, 1998

By H. -S. Yoon, C. -J. Kim, K. W. Chung

"With the final goal of ultrasonic application to ion exchange in a resin-in-pulp (RIP) system, the feasibility of an indirect ultrasonic application with a submersed ultrasonic probe was investigated first for the enhancement of ion exchange in the following resin-in-solution (RIS) system: Lewatit MonoPlus MP 600XL in an artificial solution with 106 ppm uranium. Ultrasonic radiation enhanced the ion exchange efficiency without mechanical degradation of resin. For 3.6 g/L of resin, the enhancement was 79 percent after 10 min of ion exchange and it gradually decreased to 11 percent at 60 min. In addition, a preliminary test of the mechanical stability of the resin in the RIP system showed little mechanical fracture of the resin due to ultrasound, which indicates that indirect ultrasonic application by a submersed ultrasonic probe is applicable for RIP systems. IntroductionIn uranium ore processing, the ion exchange process has been used on a commercial scale for preconcentration and purification (Gonzalez-Luque and Streat, 1984). The ion exchange process is divided into two processes: (1) a resin-in-column process with the uranium-bearing solutions passed through columns containing resins and (2) a resin-in-pulp (RIP) process with the leached ore pulp exposed to resins. The latter does not require the separation process of leach liquor and ore solids, which reduces process costs. This process, which has been developed commercially since 1955, has a certain drawback. The adsorption rate and efficiency in the RIP process are relatively low, so numerous contacts between resins and leached ore pulp are needed, which adds to the cost (Merritt, 1971). It is necessary to study methods to reduce process costs.Ultrasound can intensify mass transfer, increase the rate of chemical reactions, and change reaction pathways (Thompson and Doraiswamy, 1999; Luque de Castro and Priego-Capotem, 2007; Adewuyi, 2001; Luque-Garcia and Luque de Castro, 2003). It has great potential in chemistry and is especially considered to be a promising method for enhancing mass-transfer-limited processes, such as ion exchange. Enterzari and Tahmasbi (2009) reported the effect of ultrasound on water softening by ion exchange. Band et al. (1997) proposed a modulated ultrasound application to water desalination with ion-exchange hollow fibers. These reports revealed that ion exchange kinetics could be enhanced by the application of ultrasound. As for hydrometallurgy, Feng and Aldrich (2000) reported that the elution of an ion exchange resin was enhanced by the use of ultrasonication."

Jan 1, 2015

By T. P. McNulty

During the last decade, many exhaustive studies have been made of process energy requirements for the production of various metals and materials. Some excellent technical papers and text books have resulted, and some of these are included in the bibliography of this paper. These studies were, of course, prompted by the economic pressures which resulted from the beginning of the "Energy Crisis" in 1973. Our intensified consciousness of the cost of energy led, then, to a greatly improved understanding of the energy consumption attributable to individual mining, processing, and refining steps. It is worth noting, however, that an awareness of the cost of energy is not new and that efforts to minimize this cost were an important part of sound mine and plant management practice throughout the earlier days of our industry. One only has to read a few accounts of mining operations around the beginning of this century to develop an appreciation for the cost of supplying wood, coal, fuel oil, or electric power to remote locations.

Jan 1, 1983

By S Schwarz, D Alexander

The mining industry, and in fact the world, has undergone significant changes in the past five to ten years, ranging from the metals boom, the global financial crisis and the rise and fall of national economies, to name just a few. There has been a focus on sustainable development for projects and operations in the mining industry, mainly pushed onto the industry by communities, governments and other agencies. While sustainable development and operation is a worthy priority for mining operations, discussions with mining industry personnel (with a strong slant on the mineral processing perspective) have shown other issues have surpassed the typical issues of water resources, energy availability and the environment. These include staff turnover and skills shortages, extracting metal from more complex orebodies and the uptake of new step-change technology.A number of key operating mineral processing personnel were interviewed to determine their perspective on the current issues facing the mining industry. This paper details the findings of this survey and highlights some of the topics that have been identified as the top issues from a mineral processing perspective.CITATION:Schwarz, S and Alexander, D, 2012. Current issues in the mining industry - From the operational mineral processorÆs perspective, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 369-372 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By E. Yigit

Hydrometallurgical production of zinc from concentrates is generally carried out by H2SO4 leaching. For the smooth operation of this process, some harmful components must be removed from the leach solution before the electrolysis stage; MgO is one of these compounds. Zinc concentrate samples from the Mount Isa mines were used in leaching tests. Leaching tests with an aqueous solution of H2SO4 and SO2 gas were carried out at various temperatures, pH levels and leaching durations. While duration and the pH value of the solution were effective parameters in H2SO4 leaching, temperature and pH were more effective in SO2 leaching for the removal of MgCO3 and CaCO3. Removal of MgCO3 and CaCO3 was generally achieved at low pH values. The results show that SO2 gas can be a good alternative to sulfuric acid in the leaching of MgCO3 and CaCO3

Jan 1, 2010

By James B. Pfeiffer

TETRA Technologies, Inc., has applied its HDS? metals precipitation system to control a mine drainage problem. The effluent from the mine contains primarily zinc, manganese and iron, plus varying small amounts of cadmium, copper and lead. The flow from the mine averages 350 gpm, and varies considerably depending on season and weather conditions. The plant was designed to treat 1000 gpm of the water and generate a dense sludge suitable for recycling. The HDS? system contains a number of reactors, followed by post filtration and meets stringent metals discharge criteria as specified by New Source Performance Standards.

Jan 1, 1994

By T. A. Griffin

Gentlemen: The subject of this paper is: ADVANCED APPLICATIONS OF BUCKET WHEEL EXCAVATORS AND RECLAIMERS. Against an urgent world wide energy crisis, the role of bucket wheel excavators and reclaimers in the surface mining of fossil fuels and other ores has been raised to new prominence. This paper will review the reasons for the expanded application of bucket wheel technology, its unique contributions, and other factors relative to volume, cost, versatility, and efficiency. Today, surface mining is faced with the twin challenge of (1), accelerating the rate of removal of massive quantities of overburden and ore, and (2), replacing comparable high volumes of overburden back into the mined-out portion of the pit. Optimum quantitites for - a single electrical power plant now range from 5 to 15 million tons of coal per year. The use of bucket wheels offers the best method for meeting this challenge at lowest possible cost. For example, an advanced application that also satisfies environmental concerns involves the simultaneous functioning of two bucket wheel excavators during surface mining operations. Working at spaced intervals and different levels in conjunction with a transfer conveyor and stacker, one excavator removes the ore while the other one transfers overburden to a stacker that replaces it back into the open pit. The result of this continuously operating cycle is: (1) removal of ore and replacement of overburden back into the pit in massive quantities, (2) at accelerated volume and extreme low cost that cannot be matched by conventional loading machines of any size, and (3) fulfills a basic environmental requirement which is to

Jan 1, 1974

By Jeramy B. Decker, Paul H. Madsen

"During the excavation of the north bound tunnel of the Devil’s Slide Tunnel project, deformation (convergence) was measured after passing through Fault Zone B. The tunnel convergence was not symmetrical, but was larger on the left side of the profile. It was determined that a shear zone nearly parallel with the tunnel drive was contributing to the uneven deformation. This paper will discuss how it was determined that the shear zone existed and how multi-point borehole Extensometers (MPBX) were used to verify that a significant amount of the deformation was occurring due to movement along the shear zone as the excavation was advanced. In addition, performance of the shotcrete liner in the area of the convergence will be examined. Finally, the paper will consider the means and methods that were utilized to ultimately control and stabilize the deformation. INTRODUCTION The Devil’s Slide Tunnel Project consisted of excavating two 1,250 meter tunnels each with a profile of 80 m2 utilizing the New Austrian Tunneling Method (NATM) or otherwise known as the Sequential Excavation Method (SEM). The tunnels are part of the California Coastal Highway south of Pacifica, CA, a suburb of San Francisco. The tunnels were opened to traffic in March of 2013. Geological Setting The tunnels run north-south through the San Pedro Mountain ridge, which is part of the Santa Cruz Mountains. The tunnel lies within the San Andreas Fault system and is 7.2 km west of the surface trace of the San Andreas Fault and 2.8 km east of the surface trace of the San Gregorio Fault. The 10 km strip between these two faults is referred to as the La Honda structural and terrain block (Decker et al. 2010; Amini et al. 2005; Earth Mechanics Inc. 2003). Locally, the tunnel passes through three blocks representing different geological conditions: South Block, Central Block, and North Block (Figure 1) (Decker et al. 2010; HNTB Corporation et al. 2005). The South Block consists of Mesozoic aged granodiorite and quartz diorite. The South Block also contains many local shear zones and a low angle thrust fault (Fault A). The South Block ends at Fault B, which is the southern border of the Central Block."

Jan 1, 2016

By W. A. Cole

As the mines get older and the active workings get Farther and farther away from the original mine openings, it becomes increasingly difficult and expensive to ventilate most coal-mines properly. At the same time, the avenues of escape for those employed underground have become so extended' as often to make it impossible for them to make their way out of the mine in the event of a fire, mine explosion, or other emergency. Where such Conditions exist, the only satisfactory solution is to make new ventilation and emergency-escape openings near the active mine workings. At most mines this would necessitate sinking shafts, which is often slow and expensive.

Jan 1, 1945

By A. D. Misener, L. G. D. Thompson

"IntroductionIt was shown by work previously reported that reliable geothermal gradients representative of various regions of the earth's, surface could he obtained from extended surveys of the rock temperatures in operating mines. These surveys showed the presence of anomalies in the isothermal levels and the existence of regions of regular behaviour. Below about 3,000 feet the temperature gradients became quite regular over the areas stud1ed. It is these regular gradients which are taken as representative of the region, wherever possible.The present paper describes the extension of this work which was undertaken to obtain further temperature gradients with a view to correlating them to other geophysical properties determined for the same regions. The additional data obtained have indicated possible reasons for the temperature anomalies. The experimental procedure was similar to that already described and was again made possible through the wholehearted co-operation of the management and the assistance of the personnel of the mines concerned. The research was entirely supported by a grant from the Research Council of Ontario.The equipment was a distinct improvement over that previously used and made it possible to take many more accurate temperature readings in a given time. Thermistor resistance thermometers were used, encased in silver sheaths and protected against damage by heavy copper casings. These were calibrated with a standard platinum resistance thermometer.The bridge used with these thermometers was one of a number designed and built by the Meteorological Service and designated M.S.C. Thermometer Indicator Type C-3. This very convenient and portable instrument operated from batteries in the instrument case. Multiple thermometer connections were provided so that rapid readings• of a number of thermometers was possible to accuracy of the order of 0.1°F. All electrical connections on the panel are covered with Dow-Corning ignition compound to prevent; electrical leakage due to moisture condensation. This, together with the high resistance of the thermometers and components of the bridge, gave much more reliable results than previously obtainable."

Jan 1, 1950

By W. B. Xie

The hardening behaviour and microstructure evolution of Cu-30Ni-30Mn alloys aged at 350 °C has been investigated utilizing optical microscope, scanning electron microscope, transmission electron microscopy and Vickers hardness tester. The results show that the discontinuous precipitation of NiMn phase results in a remarkably hardening effect in Cu-30Ni-30Mn alloy during aging at 350 °C. The maximum hardness (~494HV) is attained in the sample after aged for 48 h. The NiMn precipitates are ordered and have a face-centered tetragonal structure. The coherent orientation relationship between the NiMn precipitates and Cu matrix is (220)Matrix // (220)P, [1-1-2]Matrix // [1-1-2]P. In addition, there is a linear relationship between hardness and volume fraction of the discontinuous precipitation, which indicates that the hardness increment of Cu-Ni-Mn alloys aged at 350 °C is attributed to the microstructure characteristics of discontinuous precipitation. The high strength of discontinuous precipitation colony is caused by the formation of nanoscale NiMn precipitates with a lamellar structure in discontinuous precipitation. INTRODUCTION Cu-Ni-Mn alloys are attractive candidates for oil drilling, aerospace and energy applications due to their high elasticity, high strength and excellent corrosion resistance (Sun et al., 2009; Liu, Yang, Xia, Jiang, & Gui, 2016). The high strength of the Cu-Ni-Mn alloys is mainly attributed to the precipitation of NiMn phase (Shapiro, Tyler, & Lanam, 1974; Xie et al., 2015). The uniformly dispersed nanoprecipitates formed by continuous precipitation can impede dislocation movement, and thereby lead to a significant improvement in strength of traditional precipitation-strengthened alloys. However, it is reported that there are two precipitation types observed in Cu-Ni-Mn alloys, namely, continuous precipitation and discontinuous precipitation (Shapiro et al., 1974). The discontinuous cellular colony with a lamellar structure nucleates at grain boundaries, and progressively grows inward the grain on the process of discontinuous precipitation (Ng, Bettles, & Muddle, 2011). It is found that the discontinuous precipitation can occur in many Cu-based alloys, such as Cu-Ni- Mn alloy (Shapiro et al., 1974), Cu-Be alloy (Monzen, Hasegawa, & Watanabe, 2010) and Cu-Ni-Sn alloy (Zhao, & Notis, 1998). Many studies consider that the discontinuous precipitation results in a detrimental effect on hardness and strength, and the discontinuous precipitation occurring during aging treatment should be suppressed (Markandeya, Nagarjuna, & Sarma, 2004; Semboshi, Sato, Iwase, & Takasugi, 2016). The mechanical properties can also be improved by discontinuous precipitation in AZ91 magnesium alloy (Tamura, Kida, Suzuki, & Soda, 2009) and AM30 magnesium alloy (Saikawa et al., 2012). Jun (2017) found that the reduced interlamellar spacing of precipitate fibers in discontinuous cellular colony leads to a significant increase in hardness. Indeed, the strengthening contribution of discontinuous precipitation is similar to that of continuous precipitation in Cu-20Ni-20Mn alloy. Discontinuous precipitation of NiMn phase can provide a significant strengthening effect in Cu-Ni-Mn alloys.

Jan 1, 2019