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By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

By G Bournival, Y Saavedra Moreno, S Ata

Flotation frothers are heteropolar molecules that are preferentially adsorbed at the bubble interface to enhance the flotation performance by promoting the formation of small and stable bubbles. Frothers have different characteristics that can be used to classify them. A classification framework has been recently presented by Saavedra Moreno et al (2022) to classify non-ionic frothers by conducting a principal component analysis (PCA) and a hierarchical clustering analysis (HCA). However, for the purpose of the present research, only five frother characteristics, including molecular weight (MW), hydrophile–lipophile balance (HLB), critical coalescence concentration (CCC), the minimum Sauter mean diameter (DL), and foam stability index (DFI) were used in the PCA and HCA. All those characteristics were evaluated for a two-phase system in the absence of particles. Realising the important role that particles play in froth stability and behaviour, the effect of hydrophobic particles on the presented frother classification framework was investigated in this study. Four frothers with different characteristics, methyl isobutyl carbinol (MIBC), 1-pentanol, tri (propylene glycol) (TPG), and tri (propylene glycol) methyl ether (TPM), were chosen. The experiments were carried out in the presence and absence of silica particles esterified with 1-pentanol. It was evident that the results for 1-pentanol, TPM, MIBC, and TPG in the three-phase system agreed well with the frother classification presented for the two-phase system as frothers were clustered in the same groups. The findings from this research support the use of the frother classification system presented in two-phase system to select a specific frother for a particular application without the necessity of conducting laborious experiments in a three-phase system.

Aug 24, 2022

By S K. Michelic, M Schickbichler, A Kharicha, E Karimi-Sibaki

The requirements for the controllability of metallurgical processes are increasingly becoming the focus of both industry and research. Advances in this field of research not only impact the stability of processes but often also influence the quality of the final product. One important way to examine processes in-depth, and thus show potential for improvement, is to describe them using physicsdriven models. In metallurgy, thermodynamic and kinetic descriptions of interactions between individual components of a system are often used to describe and analyse important metallurgical phenomena across the entire process. However, for the creation of physics-based models, boundary conditions and process variables must be implemented to enable a description that is as realistic as possible. The collection and generalisation of boundary conditions and process variables is, therefore, an important step towards functional models. The focus of this study is the determination of mass transfer coefficients between all components in a steel/slag/refractory system. For this purpose, experimental and theoretical methods are applied. Laboratory scale experiments are carried out in an induction furnace, and the mass transfer coefficients of the defined steel/slag/refractory system are calculated from changes in the chemical composition of the various components. Additionally, a calculation of the mass transfer coefficients based on dimensionless quantities is carried out. By comparing the values of the mass transfer coefficients determined theoretically and those determined experimentally in the trials, the suitability of the calculation is examined. The collection of mass transfer coefficients provides essential findings for future kinetic descriptions of inclusion modification based on the effective equilibrium reaction zone (EERZ) approach.

Aug 21, 2024

By Q Shu, T Deng, B Yan, B Song, D Wang

In view of the lack of phase equilibria data of vanadium-bearing oxide system and the desirability of them for design or optimisation of vanadium extraction process, the phase equilibria relationships of V2O3-FeO-SiO2-CaO(15 mass per cent) system were determined experimentally and then an isothermal section phase diagram of this system was constructed. Totally, 81 samples of different composition were equilibrated at 1623 K for 48 hours in iron crucible under Ar atmosphere. The equilibrated samples were quenched quickly in cold water, and then the phase constituents of all the samples were identified by X-ray diffraction (XRD) combined with electron probe microanalysis (EPMA) measurements.

Aug 21, 2024

By D. Lynn Gordon, Larry B. Weston, Michael W. Manhart, Patrick R. Bowden, Michael W. Redmond

Study of confinement effects on detonation characteristics and subsequent fitting form development as a function of confiner strength and thickness.

Feb 1, 2020

By Chris L. Powell, Russell J. Denny.

"The remotely located Cockatoo Island iron ore mine off the Kimberly coast in Western Australia, which has been in operation since 1951, was recently expanded up to 50m below sea-level using staged construction of a rock-filled seawall around the open cut mining operation. The most recent stage of the seawall expansion required a seepage reducing cut-off barrier to be installed through the seawall into underlying seabed sediments. A line of grout holes at 1m centres was proposed to form the seepage barrier, with grouting extending 17m below the top of the seawall. Top hammer drilling techniques were used to penetrate the 12m deep rockfill to seabed level, and permeation grouting carried out within the rockfill to fill voids and stabilise material around grout holes. The local 10m tides meant that tidal washout of fines and grout would be a major risk, and so a combination of cementitious and chemical grout was used to create rapid gel times. Following permeation grouting, holes were re-opened to allow jet grouting to hydraulically mix and grout permeable seabed sediments below the seawall. Using the duplex jet grout system in a single pass to 17m below platform level, the jet grouting was extended upwards into the seawall fill itself to overlap with the earlier permeation grouting. Finally a soil/cement mixed capping trench was installed using slurry trenching techniques with soil/cement/bentonite mixed backfill in order to complete the grout treatment. The approach taken allowed considerable onsite flexibility in technique. An automated slurry batching plant allowed adjustment of mixes to suit the varying subsurface conditions which were encountered during the works.IntroductionLate in 2013 Wagstaff Piling was engaged to install a seepage barrier through a rockfilled seawall built to allow expansion of sub-sea iron ore mining operations on Cockatoo Island off the remote Kimberley coast in the North West of Western Australia. Earlier stages of seawall construction had used a variety of different construction techniques with varied success, and the history of sub-sea mining on the island had been plagued with failures, including failures in the slope of the seawall itself, hanging wall failure underneath and inside the seawall, and footwall failures as the ore was mined leaving the rock face inclined at 55 degrees, parallel to the bedding. The current expansion, known as the Stage 4 expansion, was more tightly constrained by the pit geometry and available materials than previous seawall expansion stages that adopted clay core and sheet pile seepage barrier solutions. In Stage 4, an innovative grout curtain seepage barrier solution was selected to ultimately provide the necessary cut-off to allow access to high grade ore, while protecting the mine from inundation by the sea."

Jan 1, 2016

By Cheng Lin, Guoming Lin

"This paper presents a case history for the design, construction and long-term performance monitoring of a driven prestressed concrete (PSC) piled foundation supporting a large liquefied natural gas (LNG) tank in Savannah, Georgia, USA. Following a geotechnical investigation, a design stage pile test program was performed with three objectives: to study the densification effect from pile driving on the liquefaction resistance, to test axial and lateral pile capacities, and pile behavior under lateral loads. The test program comprised five piles driven on a test pad constructed adjacent to the tank foundation. Cone penetration testing (CPT) was performed before and after pile installation to test soil densification effects from the pile driving and liquefaction potential was re-evaluated based on the soil densities after pile installation. The axial load tests involved static load testing, high strain dynamic testing, and Statnamic testing. This paper presents the findings of the densification effects, compares results from different axial testing methods and discusses the procedures to use the load test results in the pile design. The paper also comments on the construction issues and presents performance data with 10 years of monitoring.1. IntroductionThe project site is located at the Kinder Morgan’s Elba Island LNG Terminal on the Savannah River which is three miles downstream of the downtown Savannah, Georgia. This LNG terminal was initially developed in the 1970s as an LNG import terminal. The facility includes five LNG storage tanks with two larger tanks which were constructed in 2003 and 2006, respectively. The terminal is currently being converted into a liquefaction and export facility. This paper discusses pile foundations for Tank D4 which is a double walled insulated steel tank built to hold one million barrels of LNG in 2003. This tank has an outer tank diameter of 258 feet, an inner diameter of 252 feet, and liquid height of 113 feet. A number of geotechnical challenges were present in the foundation design and construction.??The site is a typical coastal deposit site featuring a thick layer of very soft under-consolidated clay (up to 40 feet in thickness);??The bedrock is a couple of thousand feet deep;??There is a sand layer that is liquefiable under a high seismic design category (0.5% possibility of exceedance in 50 years)."

Jan 1, 1900

The introduction of a new mining method to Australia is not without its risks and challenges. This paper discusses the processes of planning a new operation, with particular emphasis on block caving and its Northparkes adaptation. As well as applying advanced technologies, here also is the opportunity to develop the art and science of block caving for its application to a wider range of geotechnical conditions than previously Envisaged.

Jan 1, 1995

By A. A. Bakke

"The Fort Knox gold deposit is hosted within the Fort Knox Pluton, a Cretaceous multiphase granitic body that intrudes the Fairbanks schist. Gold occurs along the margins of stockwork veins and veinlets, quartz-filled shear zones, and along fractures within the granite. The mineralization is generally sulphide-poor and closely associated with trace amounts of bismuth, tellurium and to a lesser extent with molybdenum and tungsten. At present, proven/probable reserve estimates, based on a cutoff grade of 0.39 g/t Au, are 158.3 million tonnes grading 0.83 g/t Au.The Fairbanks schist comprises the bulk of the country rock. The dominant lithologies present include muscovite-quartz schist and micaceous quartzite. Immediately north and south of the main orebody, mixed metamorphic lithologies of the Cleary sequence, a subunit of the Fairbanks schist, have been mapped. Development of local zones of weakness, most likely due to a broad regional warping event, resulted in brittle-ductile deformation and activation of a northwest-southeast shear couple between contrasting lithologies.The Fort Knox Pluton consists of at least three phases based primarily on textural differences. Intrusion of a fine-grained granite was followed by a medium-grained porphyritic granite. The youngest intrusive phase is a coarse-grained, seriate porphyritic granite, the Vogt Stock. The Vogt Stock forms an elongate dome with the axis in the east-west direction. Structures displayed in the overlying units, believed to be the result of doming, include tension fiSSUres and longitudinal fractures.Premineralization fractures, the result of the magmatic doming, provided conduits for initial stockwork quartz vein development and quartz enrichment in shear zones. Weak development of vein-controlled phyl/ic, potassic, albitic, and argillic alteration styles are present. Evidence of a late thermal event resulting in a low-temperature alteration assemblage of calcite + zeolite (stilbite) + chalcedony + clay occupies breccia zones, joint surfaces, and fractures within the granite."

Jan 1, 1995

By Rick Coleman, Chelvan (Chevy) Veloo

"P.T. Freeport Indonesia's lrian Jaya Operation has been producing copper concentrate continuously since 1972. Numerous ore discoveries and five mill expansion programs have seen the initial milling rate of 7,200 MTPD escalate to the present rate of 125,000 MTPD, producing 2.5 million pounds of copper and 3,500 troy ounces of gold per day. The latest expansion, commissioned in February 1995, incorporates a 34 foot Semi- Autogenous Grinding (SAG) Mill, two 20'x30' Ball Mills, conventional roughing, cleaner column flotation, and attendant upgrades to the existing concentrate pumping and dewatering facilities. This paper will describe the SAG Plant flowsheet, and focus on the key training issues which contributed to a successful plant start-up.IntroductionP.T. Freeport Indonesia's operations in the Ertsberg mining district are located in the Jayawijaya Mountains of Irian Jaya, the easternmost province of the Republic of Indonesia. P.T. Freeport Indonesia (PTFI), the operator, is owned by Freeport MacMoRan Copper and Gold (81.3%), the Government of Indonesia (9.4%), and private Indonesian investors (9.4%). Geographical location, and sailing distances are provided on the attached location map.The operation stretches over 7 4 miles ( 114 km) from the dewatering and concentrate shipping facility at the Port of Amamapare on the Arafura Sea to the Grasberg open pit located at 3400m. The regional geology is covered in detail by Van Nort et al (1991 ), with current proven and probable reserves estimated at 1.13 billion metric tonnes grading 1.30% Copper, 1.42 ppm Gold, and 4.06 ppm Silver. The Grasberg open pit mining operation provides 92% of the mill feed, and is described in detail by Hickson (1991). The remainder of the mill feed is derived from several underground block caving operations. Current production rates provide a mine life in excess of 25 years. However, very favorable geology in the area leads to expectations that additional reserves will extend the life of the operation considerably."

Jan 1, 1996

By M. Giralico

Optimized mixer settler designs will now handle flows of over 25,000 GPM. The size and expense of the equipment hamper experimental settler optimization efforts. Computational Fluid Dynamics (CFD) is a timely and predictable tool for settler design development. In the past, CFD has been used to evaluate only the flow field in pumped and auxiliary tanks. A similar numerical analysis is used to evaluate settler flow and phase separation. Phase separation is analyzed using multiple species for the aqueous and organic phase. Experimental validation shows good agreement between the computational and experimental solutions in both flow field and phase separation. The computational model is used to show performance differences between various choices of settler geometry, liquid depth, with variable flow rates. Understanding the differences allows the development of optimized settler designs. System improvements are predicted to lower entrainment levels further and/or allow new smaller footprint designs. This paper focuses on the major design components of the settler and how future technological advances will lead to further improvements in their design. LIGHTNIN?s new designs will handle tomorrow?s production requirements, while maximizing profits.

Jan 1, 2003

By M. A. Nagle

Various strategic projects were carried out in 2002 to increase the capacity of Teck Cominco's integrated zinc-lead smelter at the Trail operations site in British Columbia, Canada. The lead smelter treats the iron residue from the zinc plant and optimizes the overall zinc recovery. This paper summarizes two options that were considered to reduce the zinc content in the leaching iron residue. The first option involved increasing the capacity of an existing hot acid leach circuit up to the iron loading constraints of the circuit. The second sought to maximize the hot acid leach capability by separating the ferrite-rich solids, followed by aggressive hot acid leaching (>100°C) and subsequent iron precipitation. Different forms of iron precipitation were reviewed in order to determine the most effective and economical approach. Among these, was a novel high temperature ferrite conversion process. The technical results and selection criteria are presented together with possible ways to integrate the process concepts into the current sulphide leaching plant circuit. The first option was selected for implementation and is currently being operated successfully.

Jan 1, 2006

By T. T. Chen

The iron- and elemental sulphur-rich residues generated during batch and continuous pressure oxidative leaching of Inco Limited's Voisey's Bay nickel sulphide concentrate at 150°C in sulphate-chloride media have been characterized by X-ray diffraction analysis and scanning electron microscopy. The residues produced during the continuous leaching of the pentlandite- and pyrrhotite-rich concentrate consisted predominantly of hematite and elemental sulphur, with minor amounts of goethite. Although the iron species generated in the batch leaching tests were similar to those formed during continuous leaching, the morphologies of the hematite and goethite particles were significantly different. In addition to the tiny spheroids and bubble-like particles, the hematite and goethite generated during batch leaching occurred as larger "hollow" shell-like particles that contained residual pentlandite or sulphur cores. Although the leach solution from which the iron oxides had precipitated contained 5-15 g/L sodium, sodium jarosite was detected only in trace amounts in a few of the leach residues.

Jan 1, 2006

By K. Narayana Swamy

Experimental results of 3-phase mixing in a physical model of a CCRL for metals refining, at high levels of bottom gas injection (up to a superfIcial gas velocity (Us) of 12.5 cm/min), are presented. A thermal tracer technique was used to elucidate both longitudinal mixing and interphase heat transfer. The results indicate that even under conditions of significant bottom gas injection, it should be possible to maintain acceptably low longitudinal mixing (D. < 20 cm2/s and D/uL < 0.1) in the CCRL. Interphase mass-transfer coefficients of the order of 0.02 cm/s and higher, are predicted from the measured interphase heat transfer coefficients using the mass and heat transfer analogy. Adequate performance is likely to be possible for an industrial CCRL, based on extrapolation of these results to full-scale conditions.

Jan 1, 1996

By D. W. Lawler

Prior to the manufacture of sulphuric acid in metallurgical plants, the SO2 rich gas from the smelter, roaster, or furnace must be cleaned to removed particulates, volatile contaminants, SO3, and water. Cleaning is accomplished by contacting the. gas with cooled weak acid. The system is designed so that all the contaminants, originally in the gas are captured in the weak acid, which then becomes an effluent from the plant. Historically, the entire weak acid effluent stream has been treated for disposal, with no attempt to recycle or recover any part if it. This is becoming increasingly environmentally unacceptable, and operators must consider better methods of treatment and recovery. In this paper, Kvaerner Chemetics discuss a number of options that allow the contaminants to &apos;be separated from the acid&apos; value. This will result in an acid byproduct that can be sold or used elsewhere, and will minimize the volume of hazardous byproducts that must be discharged.

Jan 1, 1998

By Schaap W

A test on Taylor&apos;s rule of mine life using published data on open pit porphyry copper mines confirmed that mine life is, on average proportional to the fourth root of reserve tonnage. Deviations from this rule-of-thumb occur to a large extent as variations between regions that are qualitatively explained in terms of differences in grade, infrastructural needs or special taxation effects.

Jan 1, 1984

By Ivan Malinsky, Gérard Castonguay

"On a développé un procédé qui donne une fonte (2,3% C, 0,07% V) du V2O5 (99%) et un rutile synthétique (94% TiO2) à partir d&apos;un minerai, dont les réserves au Québec sont importantes. Le procédé comprend les opérations suivantes: 1) la concentration magnétique du minerai (30% Fe, 9% TiO2 et 0,65% V2O5) pour produire un concentré (65% Fe, 7% TiO2 et 1,6% V2O5); 2) le smeltage du concentré aggloméré dans un four à arc, sans fondant, pour produire une fonte et une scorie (30% FeO, 40% TiO2 et 8,0% V2O5) qui contient plus de 95% du vanadium et du titane présents dans le concentré; 3) le grillage alcalin (37% Na2CO3) de la scorie suivi d&apos;une lixiviation à l&apos;eau et de la précipitation de l&apos;hexavanadate d&apos;ammonium à partir du filtrat; 4) la lixiviation du résidu par l&apos;acide sulfurique pur ou usagé pour produire un rutile synthétique. Un estimé préliminaire de la valeur économique du projet laisse croire à sa rentabilité à la condition que l&apos;investissement pour le smeltage soit inférieur à environ 400$/tonne de fer.IntroductionLes gisements de magnétites titanifères sont nombreux dans le monde. Ils consistent en une magnétite étroitement liée a l&apos;ilménite, La teneur trop élevée en TiO2 empêche l&apos;exploitation de ces gisements pour la production de fer. Cependant, dans certains cas, la magnétite a une teneur intéressante en vanadium qui peut rendre l&apos;exploitation de ces gisements rentable. Aujourd&apos;hui, les magnétites titanifères constituent la plus importante source de production de vanadium. On estime qu&apos;environ 70% du vanadium produit provient de ces sources."

Jan 1, 1983

By Márcio Aurélio dos Santos

A Automação Industrial utiliza de forma intensiva os mesmos equipamentos e softwares de TI como servidores, historiadores, switches, firewall, dentre outros. No entanto, são poucas as áreas de automação que aplicam de forma eficaz todos os controles e cuidados que esses ativos requerem. Neste cenário, a garantia de altos níveis de disponibilidade dos sistemas de automação inicia-se pelo ambiente físico no qual tais sistemas estão instalados. É comum a improvisação de ambientes inadequados dentro das áreas industriais ou a instalação em subestações elétricas que não foram construídas com o rigor necessário para receber os ativos de TI Industrial utilizados nos sistemas automação. A solução para manter elevados os índices de disponibilidade destes ativos é, sem dúvida, instalá-los em Data Centers, comumente utilizados nas áreas de TI, o que é facilmente justificável pelo fato de que a indisponibilidade dos ativos de automação representa um impacto maior aos resultados das indústrias ao se comparar com a indisponibilidade dos ativos de “TI Corporativa”. Assim, este trabalho conceitua um ambiente de Data Center, discute as particularidades relacionadas à Automação Industrial (projetos de cabeamento estruturado e as interligações entre os níveis 1 e 2 de Automação) e apresenta as estratégias que a Samarco Mineração está adotando com relação ao tema.

Jul 30, 2018

By A. Fisher

The use of thermal integrity testing to verify the quality of deep foundations has increased significantly in the UK and other world markets over the last 5 years. The introduction of distributed fibre optic sensing to this field has broadened the range of applications in which it can be deployed and the types of foundations which can be tested. This paper presents how fibre optic sensing technology can be successfully deployed in the construction environment the range of foundation techniques to which it can be applied. Alongside developments in the practical aspects of thermal testing, progress has been made in establishing assessment criteria which can be used to evaluate the results. This paper presents recent examples of comparative studies on foundations which include both thermal integrity testing, cross hole sonic logging and intrusive coring. The use of distributed strain measurement during pile load testing presents an alternative means to verify the assessment criteria used for integrity testing. This new approach can achieve comparable results to foundation exhumation or intrusive investigation and at a fraction of the cost. This paper presents the findings of several such studies, highlighting the benefits and opportunities for future improvement of the method.

Oct 1, 2022

By Larissa Rodrigues de Carvalho Rocha, Mauro Vivaldino Fernandes, Beatriz Fausta Gandra

A composição química do gás redutor afeta, de forma marcante, sua difusividade através do leito e a capacidade de redução da carga metálica. Associado a isto, o cenário econômico e ambiental indica a necessidade de se buscar cada vez mais elevada produtividade dos altos-fornos, com baixo consumo de combustível e menor emissão de CO2. Para tanto, as empresas têm buscado operar com elevada taxa de injeção de carvão e, em casos de política favorável, intensificar o uso de gás natural em altos-fornos. Nestes casos, a quantidade de material reduzida via H2, em comparação ao CO, é aumentada. No presente trabalho, são apresentados os resultados de ensaios em amolecimento e fusão (A&F) de dois tipos de granulados, de um tipo de pelota e de um sínter industrial, utilizando-se como redutor um gás com diferentes teores de H2 (0% a 12%). Verificou-se que, para o granulado, não há uma tendência definida. Embora um maior teor de hidrogênio possa favorecer a redução, isto não refletiu em melhor permeabilidade do leito. No caso da pelota estudada, houve leve tendência de melhora nos parâmetros avaliados quando se tem o gás mais rico em hidrogênio. No entanto, seu desempenho em A&F foi muito aquém daquele esperado para este tipo de carga, uma vez que apresentou elevada resistência à permeabilidade associada à baixa redutibilidade até o início do amolecimento. Para o sínter, foi identificada evidente melhora nos aspectos de redução e de permeabilidade do leito.

Oct 1, 2019