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By J. S. Ross

OIL-FIELD waters enter into many underground problems with which the petroleum engineer has to deal. Whether the problem is one of infiltration or natural encroachment, it is always desirable to determine the source of the water before commencing repair or remedial work. The usual mechanical tests for determining the source of extraneous water in wells are slow and expensive. An excellent means for the identification of oil-field waters may be afforded by their chemical characteristics when the chemical character of waters from the various sands has been established, by careful sampling and analysis cautiously interpreted. In the Salt Creek field, Wyoming, a fairly high degree of efficiency has been attained in the controlof field operations by utilizing the information afforded by the analysis. All of the operating companies appreciate this means of identifying waters, with the result that water-sampling has become general practice. Most of the chemical work dealing with Salt Creek waters has been done since the laboratories of the Midwest Refining Co. and the U. S. Geological Survey, were established in the field; the former in 1922, the latter in 1924. A spirit of cooperation has existed between the company and the government personnel by which many of the data for this paper were made available.

Jan 1, 1928

(Quality can be defined as that which is acceptable to the market and can be supplied with a predictable degree of uniformity and dependability at a low cost. The market for any mining product is downstream processing, whether it be an alumina refinery, a gold processing plant or a flotation plant. The cost of that downstream process is partly dependent on uniformity of its feed material both in physical and chemical terms. With more operations adopting procedures which require quality assurances in line with International Standards, from their raw material suppliers, miners must look to their grade control processes to provide uniformity and predicability.This is not a new concept. The mining industry has constantly been working with ahighly variable raw material supplied by Mother Nature, from whom we cannot demand quality assurances. Through the processes of exploration, resource and reserve definition, long and short term mine planning and day to day grade control an end product has been supplied which consistently meets our customers requirements, in an economic fashion. When any of these processes fail, then penalties are incurred which can range from increased mineral processing costs to loss of markets and in the ultimate case, failure of a mining operation.

Jan 1, 1992

By W. C. Hittinger, J. McGlassan, J. W. Peterson

THIS paper describes the result of an investigation of the production of thin alloyed layers on a thicker substrate of pure germanium as one step in the manufacture of transistors.' The technique of alloying materials with semiconductors is a means of introducing small amounts of impurity elements in the alloyed regions of the crystal lattice of the semiconductor, the presence of which make possible the junction type transistor.2 Impurity elements are added which will produce regions having differing electrical resistivities and means of carrying current. Impurities are of two types: those which produce an excess of electrons (negative or n-type), and those which produce a deficiency of electrons (positive or p-type) in comparison to the pure semiconductor. The boundary between two such regions is designated a p-n junction. Elements in Group V of the periodic table, having five valence electrons, give rise to an excess of electrons when present substitutionally in the semiconductor lattice (usually germanium or silicon from Group IV). Similarly, elements in Group III create a deficiency of electrons. Germanium and silicon which are substantially free of impurities of either p or n-type are designated intrinsic (i-type) semiconductors. The usual junction ----trarnsistor has

Jan 1, 1958

The reported values of the standard reduction potentials of the Au(NH3)2+/Au(0) and Au(S2O3)23-/Au(0) couples are reviewed to emphasise the experimental difficulties associated with the measurement of reliable values for these quantities. The standard reduction potential for Ag(I)/Ag(0) in ammonia and thiosulphate solutions measured at ionic strength 0.1 and 25oCis used to predict the following relevant stability constants () for gold complexes based on the linear free energy correlations: Au(NH3)2+2 = 1013, Au(S2O3)23-2 = 1024 and Au(NH3)43+4 = 1033. The equilibrium constant ( 10-11) for the reaction Au(S2O3)23- + 2NH3 = Au(NH3)2+ + 2S2O32- based on these stability constants is in reasonable agreement with the measured value (10-9) based on potentiometric and spectroscopic data when excess ammonia was added to a solution of Na3Au(S2O3)2. This also indicates that the stability constant of Au(NH3)2+ is 9 to11 orders of magnitude less than that of Au(S2O3)23-. Relevant species distribution and Eh-pH diagrams based on the revised data are presented.

Jan 1, 2003

Acid heap leaching has been extensively applied to the processing of copper oxide ores, with recovery of copper by solvent extraction and electrowinning. Heap leaching has also been extended to the treatment of secondary sulphide copper ores, where oxidative conditions are generated in aerated heaps by the bacterially-assisted oxidation of ferrous iron to ferric iron. The treatment of low-grade chalcopyrite ores has recently been the focus of research, with Mintek playing a prominent role. When processing chalcopyrite ores, more complex column test work is performed, which incorporates the prediction and simulation of temperature behaviour in pyrite-containing heaps. Mintek has devised a trade-marked column leaching apparatus (SmartColumn?) for the simulation of the natural temperature profile development in pyrite-containing heaps. As heap leach applications are becoming more complex, the parameters that need to be built into the design and operation of heap leach plants are growing in number, and the amount of data to be collected and processed, and the number of decisions to be taken daily, are also increasing. Mintek has therefore developed the HeapStar® administrative advisory software, as a guidance system to ensure that the correct protocols are implemented at various stages of the leach cycle.

Jan 1, 2012

Determine the dust reduction capabilities of various bag valves available to the minerals processing industry. The Problem Many different types of ground mineral products are packaged into 50-and 100-lb paper bags. Although bag technology is continually improving, dust contamination from bags still remains a significant problem for workers. The greatest source of dust is the bag filling valve. Ideally, the bag filling valve should close after it fills the bag with the ground mineral product. However, the valve usually fails to close properly since some mineral product gets trapped inside the valve during filling and ejection. As a result, when the bag has been filled and falls from the fill station, a rooster-tail of product is discharged from the bag valve. As the bag hits the conveyor belt, additional product discharges from the bag valve. The dust from these sources contaminates the air inspired by the workers filling the bags as well as the work area. Dust also clings to the outside of the bag, contaminating the pallet loading station. Because the various commercial bag valves are composed of different materials, a dust analysis was performed on five of these valves to determine their dust reduction capabilities. The five valves analyzed were: standard paper, polyethylene, extended polyethylene, double trap, and foam.

Jan 1, 1986

By Christian Jeger

After recalling the principles underlying fire-damp flow in coal and the essential part played by permeability (Darcy's law) in the intensity of flow, a few theoretical and experimental results showing the possible causes and range of variation of coal seam permeability are presented. The study of firedamp flow into gate roads and of residual gas concentrations in coals as a function of the gate road distance, shows that, in French mines, coal seams in a virgin zone have a very low permeability, but they become permeable when destressed by mine workings, in particular overlying workings. This is the case not only in the fractured zone round a mine excavation in which the gas is released, but also beyond the limit of the zone degassed by the excavation. In the floor of flat seams, upward boreholes can be used for predegassing seams that have been relaxed but not degassed, as the result of an overlying coal face. In this respect we shall describe the predrainage experiment carried out in the Marienau district of the Lorraine coalfield. Predrainage can contribute considerably to the reduction of methane emission in the ventilation of newly opened longwall faces. But to be efficient and useful predrainage should meet certain conditions.

Jan 1, 1980

By McDonough RJ

Mechanical agitation is the preferred system for Carbon-in-Pulp processes. Agitator design requires an understanding of the relationships between energy, shear and flow and the nature of shear rates and shear stress distribution in an agitated tank. Laser techniques are useful when studying these phenomena. The alternatives are open impeller agitation or draft tube circulation. Each has advantages and disadvantages but both require careful choice of impeller and system geometry. Overall the draft tube circulator is the more attractive in many cases. Open impeller agitators are designed in accordance with established procedures for mineral slurries taking due account of shear effects in tanks containing carbon. Preferred tank proportions are 1:1. Circulator design methods were developed in the alumina industry before being applied to CIP processes. Optimum draft tube diameter is critical to power requirements. The overall system must be designed as an axial flow pump operating in a closed circuit. Such a system exhibits quite characteristic behaviour which requires an impeller of varying pitch angle and aerofoil section for best stability and efficiency.' Tank height may be 2 or more times diameter. Resuspension of settled solids can be assisted by a series of slots in the draft tube. These slots have the secondary effect of stabilizing hydraulic behaviour and reducing installed power requirements.

Jan 1, 1982

P.IISTRACTThe Pacific Rim is advantaged by the uniqueness and diversity of its geological features. Why then is geology given so little regard in the education systems of the countries of this region? Not that these countries differ greatly from those in other parts of the world. Papers presented during the Precollege Geoscience Education session at the 28th International Geological Congress (28th IGC) held in Washington, July, 1989, indicated strongly that the problem is universal. There is a marked decline in interest in the Earth sciences and many nations are looking towards methods that might change this trend. Problems affecting geological education include the lack of purpose and direction, its obsolete curricula and the difficulty in attracting gifted students.The world-wide plight of geology comes at the very time when it should be fundamental to a public understanding of the global effect of human population pressure. There is a universal awareness of "the environment" but very little awareness of the science that has supplied most of the data. Geology, as the science of the Earth, is of paramount importance to an understanding of our life on this planet, particularly in its role as the source of our every need.

Jan 1, 1990

Bolivia, due to its turbulent past with a history of constant military coups, has given an image of complete instability to the foreign investor. The effects of this have been several fold, the major one resulting in a complete lack of exploration in modern terms since their revolution in 1952. What was overlooked by the foreign investor was the fact that revolution produced Agrarian Reform which is the foundation of the stability which Bolivia enjoys today. Another factor that is overlooked is the fact that its past history is one of vast mining fortunes having being made. Their political problems resulted in economic chaos in 1985 with an annual inflation rate of 26,000 percent. This resulted in the collapse of the government but the democratic process continued. Then came the so-called"South American Miracle" in 1986 when the government of Dr. Paz Estenssoro enacted an extremely harsh austerity program which consisted of the abolition of wage and price controls, the abolition of monopolies, the right to hire and fire, the weekly auctions of dollars and the free convertibility of currency which yielded a stable government with 8 percent inflation. This was followed by massive personnel reductions in the various mines and other industries.

Jan 1, 1991

By G Cormack

By designing comminution circuits for mineral liberation rather than the final recovery process and by using high mass pull gravity recovery, the concept of underground processing has become a reality. Gekko has found that many ores respond favourably to fine crushing with either high pressure grinding rolls or vertical shaft impactors which when combined with the InLine Pressure Jig gravity separator and coarse flotation results in a narrow, low-head, compact processing plant that can be sensibly fitted in existing underground openings. The focus on fine crushing reduces the power requirements of the plant to approximately 5 kWh/t for a capacity of up to 20 t/h run of mine ore feed. The use of water recycle systems places no extra load on the mineÆs normal water handling system. GekkoÆs underground processing plant, the æPythonÆ, has been designed to be towed down the decline or lowered down a shaft and is capable of being installed in sloping, non-linear drives for placement close to the working face. The overall benefit to mining companies of this concept has been estimated to be a significant operating cost-saving, lower cut-off grade and a significantly smaller environmental footprint.

Jan 1, 2008

By Frank Haehnig

Ground freezing is a technique which is used more and more in tunnelling under complex ground conditions. This paper will present three case studies which highlight different aspects of the ground freezing technique when applied in urban environment. The first project is the City-Tunnel in Leipzig, Germany, which is being built beneath the central station and which is the largest ground freezing project currently under construction in Germany. The second case study is part of the North-South-Line project in Amsterdam, Netherlands where ground freezing will be carried out to al-low the TBM drive through old wooden foundation piles. The freeze tubes for this project will be driven using Horizontal Directional Drilling (HDD). The last project is the Hallandsas Tunnel Sweden where the ground freezing equipment has to be installed against high water pressure. The paper illustrates that ground freezing can be implemented in difficult ground conditions such as soft ground, highly fractured rock and high water pressure. The case studies highlight the importance of good workmanship. With the increasing numbers of large tunnels being constructed in difficult ground conditions the paper concludes that the complex case studies presented will be-come more representative for future tunnel projects in urban environments.

Jan 1, 2008

By A. Putz, F. Vincent, A. R. Laplante

"This paper briefly reviews some of the gravity research done at McGill University and current Canadian operating practices, with emphasis on results of interest for operators. The following topics are addressed: security, economics, predicting recovery, circuit optimization, unit selection and final upgrading. Emphasis is placed on the Knelson Concentrator.The topic of security and economics are addressed jointly, in terms of the place of the gravity circuit in the mill flowsheet. Actual plant experience is drawn upon to identify potential problems and actual solutions.Predicting primary recovery is linked with a characterization of the ore, the choice of a circuit, and the fraction of the bleed used. Factors such as feed preparation, preliminary upgrading, fraction of recycle treated, ability to recover fines and location of the bleed are discussed.Final upgrading is achieved almost only by tabling and smelting. This can lead to fine gold recovery problems when more effective units are used upstream. Alternatives are discussed.IntroductionResearch on gold recovery by gravity over the past eight years has associated McGill University with a number of gold producers. This paper attempts to review the information gathered from a practical perspective. Some of the information was generated in McGill University's labs, some gathered at plant site, and some was shared by operators."

Jan 1, 1994

By J. N. Ong, J. P. Ratledge, J. H. Boyce

Since German operators opened the Tsumeb mine in the early 1900's, continuous operation has been interrupted only by enforced shutdowns during two world wars and the depression of the 1930's. Original metallurgical practice was blast furnace smelting. This was applicable only to low zinc ore, leaving large tonnages of high zinc ore to be stockpiled on the surface. A gravity concentrator using tables, buddles, and jigs operated for several years, but differential flotation of the ore did not get beyond the experimental stage. When the property was put up for sale by the South African Custodian of Enemy Property there was an estimated 434,000 tons of ore on surface dumps. The dump material, assaying 4.48 pct Cu, 15.8 pct Pb, and 10.9 pct Zn, had become highly oxidized during a stay of many years on the surface. But these dump ores had to be used in evaluating possible metallurgy because the shaft became flooded after the 1940 shutdown and underground ore was unavailable. Many companies examined Tsumeb but quickly lost enthusiasm because of the formidable metallurgical problems presented by the dump ore. However, on the basis of extensive test work, the present company decided that differential flotation would be successful and purchased the property after competitive bidding.

Jan 4, 1955

By A. F. Colombo

In an effort to maintain an adequate supply of iron to meet national economic and strategic needs, the Bureau of Mines, U.S. Department of the Interior, is conducting research on methods for beneficiating the oxidized taconite resources located on the western Mesabi range in Minnesota, thus expanding domestic iron ore reserves. The selective flocculation and cationic flotation process was investigated in a pilot plant using an ore feed rate of 410 kg/hr (900 1b/hr) and 88 percent recycled water. Lime and a cationic flocculant were used to clarify the waste slurries treated in the water reclamation circuit. An oxidized taconite assaying approximately 36 percent Fe yielded concentrates averaging 63.5 percent Fe and 4.3 percent SiO2 and having an average iron recovery of 84.4 percent. The estimated reagent cost per tonne of concentrate was approximately $1.10. In an attempt to recover more of the iron lost in the flotation tailing, wet high-intensity magnetic (WHIM) separation was incorporated in the pilot plant circuit. The flotation concentrate grades obtained from beneficiation circuits with and without WHIM scavenging were similar, but when WHIM separation was used the overall iron recovery was increased by 2 to 9.5 percent, depending on the iron assay of the flotation tailing.

Jan 1, 1978

By C. F. Smart

The heat treatment of the bronze composed of 88 per cent. copper, 10 per cent. tin, and 2 per cent. zinc, has been investigated by H. S. and J. G. S. Primrose,' and also by the U. S. Bureau of Standards.2 The results obtained by H. S. and J. G. S. Primrose on dry-sand castings subjected to reheating followed by air cooling, or by quenching in water, are shown in Figs. 1 and 2. The values for tensile strength have been converted from tons per square inch to pounds per square inch. Figs. 3 and 4, have been plotted from values obtained by the Bureau of Standards on material of the same composition and treatment. Both investigations show that the ductility of the cast bronze is improved by heating to 700' C. and cooling in air, the strength not being impaired by this treatment. They are not in agreement, howevcr, as to the effect of quenching, Messrs. Primrose reporting a decrease, and the Bureau of Standards an increase, in both strength and ductility when the cast bronze is heated to 600' or 700' C. and quenched. The present investigation was undertaken to study the effect of annealing followed by different rates of cooling, and, in particular, the

Jan 1, 1921

By David H. Browne

Nickel has always been a fruitful mother of problems. Previous to the year 1906 nickel was regarded as an element replacing iron in copper-mattes, and it was believed that the same laws which governed the elimination of iron could be applied to nickel. This conception has lately undergone a complete change, and nickel in all its stages is now regarded as an element replacing copper; in other words, copper-nickel is considered not as two elements, but as one metal. When we commenced our investigations on Monel metal we made a great many experiment* on the conversion of mattes, both high copper and high nickel. We studied closely the composition of the mattes and the changes produced by the blow. We found in all cases certain agreements which me believe are due to some law. Briefly stated, our conclusions are as follows : 1. Nickel is not an element replacing iron in matte. 2. Nickel-copper alloys act in the matte-blow like one metal. 3. Nickel-copper alloys follow, during the matte-blow, exactly the same laws that govern the behavior of copper alone. This brings up the question: What are the laws governing the production of metallic copper, and what are the relations of copper to sulphur and iron during the Bessemer blow?

Jan 1, 1911

A good blasting result is largely achieved by putting the right amount of explosive in the right place and firing it in the right sequence. The best blast design in the world will not break the rock if the planned blast layout is not achieved in the field. One of the critical inputs into a blast design is the diameter of the blasthole. An assumption that the actual blasthole diameter is equal to the nominal drill bit size is generally made. However, a small deviation in the actual hole diameter from that assumed will have a dramatic effect on the hole's volume and, consequently, where the explosive is placed in the blasthole. Any discrepancy in actual blasthole volume from that assumed will be reflected in 'overloading' or 'underloading' of the blasthole with the calculated explosive quantity and, thus, reflect in explosive distribution and stemming lengths. When loading to a 'collar' in an oversized hole extra explosive will be used, resulting in higher than planned powder factors and explosive costs. A blasthole diameter assumed from a nominal drill bit size is an incorrect assumption. This paper will present some actual blasthole diameter measurements illustrating the variation in hole diameters seen in the field and proposes a practical method for achieving a useful blasthole diameter measurement.

Jan 1, 1990

By J. Patrick Powers

In tunneling through water-bearing formations, the expense of controlling the water can have a major impact on overall project cost. The author has seen the cost of an eight-foot, finished sewer tunnel rise from under $500 per foot to over $1,000 when a water problem, anticipated as modest, became severe. There is need for greater professionalism in the approach to groundwater control. The days of the forked stick should be behind us. The basic technology exists. Its application is not yet widespread. This paper discusses predrainage; that is, the lowering of water in advance of tunnel excavation. Both free air and compressed air tunnels are considered. Examples from recent tunnel projects are described. SPECIAL NATURE OF TUNNEL DEWATERING Tunneling is unlike other excavations below the water table in a number of significant ways. The tunnel excavation is always on the critical path; if production slows or stops, there is no other work for the heading crews, no other work to carry the cost of service crews and job overhead. The dewatering commitment must be made well in advance. Construction of wells, and pumping down take time. After the heading reaches a trouble area, time is not available

Jan 1, 1997

By Whiten WJ

A method that allows data to be mass balanced and screen models to be fitted in a single step is described. The inclusion of several variables to describe the feed data in the fitting procedure allows a mass balance to be conducted at the same time as the fitting of the screen model. Analysis of Groote Eylandt Mining Company screening data has demonstrated that this method is ideally suited to applications where complete stream data are not available. Also, certain random fluctuations in screen model parameters arising from the fitting of consecutive mass balances and screening models are significantly reduced. A cubic spline function with fixed knot positions corresponding to particle sizes and variable (fitted) cumulative percent passing values is used to describe the feed size distribution. When the spline function is interpolated at the experimental feed particle sizes a fitted feed size distribution is obtained. This feed size distribution is then used as input to the screen model calculations from which product size distributions are generated. Since both feed and product size distribution data are used to minimise the residual errors between the observed and fitted stream size distributions, a mass balance is Conducted simultaneously with the screen model parameter fitting.

Jan 1, 1984