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By Metehan Erdogan, Orhan Gökçe Göksu, Ishak Karakaya

"An experiment (mixture) design was created to optimize the process parameters of the electrochemical reduction of CaW04 to W in molten CaCl2-NaCl eutectic mixture. Temperature, applied voltage and the length of Kanthal wire winding of the CaW04 pellets were selected as the process parameters that were allowed to vary between the predetermined minimum and maximum values. The rates of the electrochemical reductions were interpreted from the variations of current and total charge vs. time graphs under different conditions. The analysis pointed out that 640°C and 2.81 V resulted in the fastest reduction. Itwas seen that the effect of Kanthal wire winding on the output current was less pronounced when compared to the other two parameters.IntroductionFFC Cambridge Process [1] has been applied to a number of metal oxides in laboratory experiments to produce metals. In nearly all of these studies, the electrolysis temperature was around 900°C, the electrolyte was pure CaCl2 or CaCl2 containing salt solutions and the anode was graphite. However, it was recently shown that the electrochemical reduction process of metal oxides in CaCl2 containing electrolytes at the mentioned high temperatures was not suitable for tungsten production [2], It was reported that as soon as WO3 contacts CaCl2, the following reaction occurs:"

Jan 1, 2012

By H. R. Hanley

ONE of the most important contributions to the art of electrolytic zinc production-has been the aluminum cathode. This has been used in all major production: since its commercial development in 1916. The literature is replete with important contributions, some of which may have been replaced by better ones, but thus far there appears no other metal to take the place of aluminum as cathode material. Credit for this innovation goes to Sherard Cowper Coles, of England. When experi-menting on the extraction of-zinc from Broken Hill ore at Hayle, Cornwall, in 1893, he introduced the aluminum cathode, and in 1895 obtained British Patent-No. 20073. The reason for this dominant position of aluminum as cathode mate-rial in zinc sulphate electrolytes is its unique surface, to which electro-deposited metals usually do not tightly adhere. The metal must be of high purity for best results. It is possible to develop a starting-sheet method by which thin electro-deposited sheets of cathode zinc are made and stripped from a smooth aluminum plate. Such thin sheets of cathode zinc may be used as arc tine copper sheets in standard electrolytic copper-refinery practice. However, complications arise because of extreme warping of the zinc starting sheet after a .few hours of deposition, and thus special arrangements must be made to compensate for this abnormality.

Jan 1, 1938

By B Ekberg, R Salmimies, T Kinnarinen, A HSkkinen

The regeneration of the ceramic filter medium used in iron ore dewatering is often done by combining backwashing, ultrasonic cleaning and chemical regeneration. Of these three, the first two are applied more frequently, whereas chemical regeneration is done only when needed, eg once a day. Chemical regeneration of the ceramic filter medium in iron ore processing can involve the use of oxalic acid to dissolve the iron oxide particles. Even while performing simple chemical regeneration, meaning no ultrasound to assist the cleaning, the changes in the performance and in the structure of the filter medium could not be explained solely based on the dissolution or the removal of particles from the surface. Good regeneration results were obtained at 35 and 50¦C, meaning that the final permeability of the filter medium corresponded to that of unused filter medium. Permeability of the medium after regeneration at 15¦C was also good after 12 h, but did fall short of those regenerated at higher temperatures. Changing the acid concentration did not seem to have a significant effect on the regeneration.CITATION:Salmimies, R, Kinnarinen, T, Ekberg, B and HSkkinen, A, 2013. Particle dissolution in the chemical regeneration of the ceramic filter medium used for magnetite dewatering, in Proceedings Iron Ore 2013 , pp 473-478 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

THE education of adolescents to perform the duties and assume the responsibilities of maturity has been a characteristic of human society since the dawn of history. In the beginning the members of the immediate family performed this function, and in modern life they still have an important part in it. Possibly religion was the first field in which education began to be functional; young people were sent for instruction to a teacher who had a broader and deeper knowledge of the subject than was possessed by the family. It does not seem necessary for our purpose to attempt to determine how, when, or where instruction in the practical arts first began to become functional, and the brief outline which follows must suffice. The discovery and utilization of mineral substances to improve and maintain the conditions of human living is a practical art, which must have had an almost accidental origin and have been developed by empirical experiments. We do not know, nor would it be useful to try to fancy, how men first learned that they could make use of mineral substances to their benefit, but however that knowledge was initially gained it was certainly trans- mitted through instruction in the family. At fist such activities must have been merely a minor part of the making of a living, bit in time those who excelled found it better to devote them-

Jan 1, 1941

By John A. DesLauriers, Hans J. Broennimann

INTRODUCTION The early record of tunnel excavating machines in hard rock tunneling has not been one to particularly brag about. We have all heard the stories of major difficulties when trying to break hard rock with machines at promised advance rates of several times that of conventional drill and blast. Unfortunately, sometimes this has not happened. It has been through this trial of the past generations disappointments that today's TBM's have evolved to their present high level of performance in a wide range of ground conditions. Today's machines offer much increased reliability and durability. This translates into high availability to the tunnel contractor. Although there still are occasional disappointments being reported, the state of the art is that reliable and predictable machine excavation of rock now is both a reality and well founded expectation. The most recent editions of Atlas Copco's MINI/MIDI Fullfacer, we feel, make a strong contribution to the reliable performance of todays TBM's---especially in small-size rock tunnels. This report will, 1.) explain the equipment and effect of rock both on the cutting technique and machine performance; 2.) list advantages of the non-circular shape, during and after construction; 3.) list applications in civil and mining industries; 4.) discuss North American experiences, performance and costs; 5.) list advantages over drill and blast and; 6.) discuss briefly lease arrangements.

Jan 1, 1979

By H. D. Peterson, G. E. Butts, J. F. Spisak

In 1978, Anschutz Mining Corp. began efforts to develop the Madison Cobalt Project in southeast Missouri. Preliminary metallurgical studies indicated that intermediate grade cobalt products, suitable for shipment to existing refineries, could be recovered from the sulfide mineralization of the ore body. However, tolling and freight charges were significant, as the refineries were located outside the US. These refineries would not satisfy the goal of strategically insulated production of superalloy-grade cobalt. The acquisition of proven, readily available refinery technologies was then evaluated. However, licensing costs were substantial and the "proven" technologies were not directly applicable to the unique chemistry of Madison materials. Faced with these challenges, Anschutz, in conjunction with the Colorado School of Mines Research Institute, embarked on an effort to develop a sulfate-based separation and refining process. CSMRI performed bench-scale and continuous pilot experiments on solutions generated through other pilot campaigns conducted by Lurgi, Hazen Research, and Sherritt Gordon. The results indicated that cobalt could be selectively extracted from sulfate media using a new generation of organophosphates. The solvent extraction system produced a solution suitable for electrolysis of high-purity cobalt. Preliminary cost studies indicated the novel process was competitive with other refinery systems. Plans to develop the detailed engineering-design information required to commercialize the process were abandoned when the price of cobalt collapsed to less than $17.64/kg ($8.00 per lb).

Jan 1, 1985

By B. C. Haimson

The Committee on Rapid Excavation of the National Research Council has recognized in its 1968 report the need for "improvement of rock-mechanics techniques for measuring subsurface stress field in deep boreholes and for determining stress distribution in walls of underground excavations". The technique recommended in this paper as being most suitable for both deep hole and tunnel wall stress determination is Hydraulic Fracturing. Using this method stresses are calculated directly from the fluid pressures necessary to initiate and extend a fracture away from a borehole. Stress determination by hydraulic fracturing is rather insensitive to inhomogeneity or anisotropy, is not limited in depth except by the length of the hole, requires simple equipment which is commercially available, and can be carried out by unskilled personnel. The method has been worked out theoretically and extensively tested and verified in the laboratory. A number of field tests in deep holes ranging from 300 to 6300 ft have yielded surprisingly good results. Preliminary underground tests have been very encouraging and most recent measurements in a tunnel complex at the Nevada Test Site yielded stresses that were both consistent and reasonable when compared with the expected directionsand magnitudes. It is recommended that hydraulic fracturing be considered as a method of in-situ stress measurement both in the pre-excavation stage of design and during tunneling.

Jan 1, 1974

By Loo R

The Paper discusses the size and extent of in-pit dust suppression problems created by iron ore mining in the Pilbara region of Western Australia. Dust problems associated with drilling, loading, hauling and tipping are discussed indicating the large quantities of water which can be applied for dust control and attempts that have been made to rationalise this water usage to obtain maximum benefits from the applied water. The magnitude of the problem and the quantities of water involved can be appreciated when one realises that 275 000 tonnes of rock are moved on Mt. Whaleback each day and that there are 40 km of haulroad within the open pit. Initially dust suppression was limited to the spraying of haulroads by large water tankers. Now dust suppression is practiced during drilling and after blasting, wind blown dust is reduced by application, using water cannons,of large quantities of water to floor stocks prior to loading operations as well as by the installation of 16 km of automatically controlled fixed sprinkler reticulation on the main semi-permanent haulroads. The methods used to assess the water requirements for in-pit dust suppression are discussed and the extensive development testing used to evolve the present installations are 1. Environmental Superintendent Mt. Newman Mining Co. Pty. Ltd. Newman, W.A. 2. Chartered Consulting Engineer, Perth, W.A.

Jan 1, 1979

By Harry M. Edenborn, Richard W. Hammack

Experiments were done to determine if a mushroom compost-based sulfate reduction system could be used to treat nickel-contaminated mine waters. Sulfate reduction systems were established in columns containing acid-washed mushroom compost. Simulated mine waters containing 2000 mg/L sulfate and 50 to 1000 mg/L nickel were adjusted to pH 4.5 and pumped through the columns at flow rates between 15 and 25 mL/hr. During the first nine days of operation, virtually all influent nickel was removed in the columns by sorption and ion exchange mechanisms. The nickel removal rate then dropped to 18 to 30 mg Ni/day (7.8 to 12.8 nmol/ g-substrate/day), probably due to low sulfate reduction rates. When sodium lactate was added to the inflow, a sustained and seven-fold increase in the nickel removal rate was observed. Bacterial sulfate reduction rates measured in mushroom compost-based wetlands exposed to coal mine drainage are 2 to 20 times faster than the rates observed in this study. Low sulfate reduction rates in the columns may have been due to the inhibition of microbial activity by high nickel concentrations and the removal of labile organic compounds from the mushroom compost substrate during acid-washing. Results of this study indicate that bacterial sulfate reduction can effectively treat nickel concentrations up to 500 mg/L if labile carbon is nonlimiting.

Jan 1, 1992

A. M. CANDY,* Pittsburgh, Pa.-According to the tables on page 532, the deposit obtained with Roebling cold-rolled steel, and Toucan electrodes contained considerably less carbon and manganese than the original electrodes; whereas very little carbon is lost in the case of the hot-rolled steel electrode. When using the hot-rolled steel electrodes, the metal apparently has a tendency, probably due to greater surface tension, to pass through the arc in larger particles than the other electrode materials. This affords greater protection against oxidation, and thereby prevents much loss of carbon. The larger globules tend to increase the arc fluctuations due to greater partial short-circuiting of the arc. Actual oscillographic records show that with the hot-rolled steel electrodes the current peaks were 70 per cent. above normal whereas the peaks for the other electrodes were only about 25 per cent. -above normal. Probably due to the larger globules, a greater proportion of slag in the electrode was carried into the weld. Some four or five test pieces made with the hot-rolled steel electrodes were all considerably below the tensile strength of the samples welded with the other electrodes. These facts indicate that an electrode may not be satisfactory even though of approximately the proper chemical composition. For example; the hot-rolled steel and Roebling electrodes are quite similar in chemical analysis.

Jan 4, 1919

The truly scientific method in the study of such questions at the present day is the reverse of that which was followed in the early days of geology, when after the observation of a few isolated facts, some great geological mind was led to a general theory, and humbler followers were only too apt to do mild violence to nature in order to make her facts conform to it tt accumulates year after year a multitude of facts of patient observation, supported by studies with the microscope, and in the laboratory, avoiding general theories, and only making such deductions in regard to locftl conditions as are supported by the overwhelming evidence of facts. S. F. Emmons, on the geological distribution of minerals in the United States, at the "world's congress" of mining engineers, Chicago. Fig. l.-This exhibits the general stratigraphical characters of the southern lodes. The" Indicator" veins, the great barren lode masses, a later fissure than all of these (" B "), and the auriferous lodes of last series cleaving the wrinkled terraces and the older lodes also are" Indicator" veins. B is a later formed vein that leaves no " depositions" behind. ooe are fragments of the" most ancient'' lode wreckage. Db are the auriferous lodes and correspond with those lodes, also whose auriferous characters are not result of secondary impregnations.

By C. M. Ball

The magnetic concentration of iron-ores has been so often and so widely studied and discussed among the members of the Institute that any remarks concerning its general importance, from an economic standpoint, would be superfluous; but it is thought that a description of the Ball and Norton ore-separator, designed for cobbing and separating magnetic iron-ores, indicating its essential differences from other machines and the advantages claimed for it, together with some account of recent results obtained in its application to the concentration of such ores, will prove of interest. This machine is the joint invention of Mr. Sheldon Norton, of Hokendauqua, Pa., and the writer, and has been patented in the United States, Canada, and other countries. Of the accompanying illustrations, Pig. 1 represents a longitudinal vertical section of the perfected ore-separator, adapted for separating fine ore, and Fig. 2 the same, adapted for cobbing ore of the size of stove- or chestnut-coal. The two designs are identical in principle, and vary from each other in minor details only. The apparatus consists of a partially-closed chest, having an opening at f, from the feed-hopper, h, through which the ore is delivered to the machine from an ore-pocket or storage-bin provided with means for regulating the flow of ore, so that, when the machine

Jan 1, 1891

By A. E. Hall, D. M. Mchaina

This paper outlines a proposed research project to investigate secondary sulphide ignitions. Sulphide dust explosions have resulted in loss of production and considerable capital and equipment replacement cost in Canadian mines. The practical application of laboratory test results to actual mine situations presents a complex problem and is a field requiring immediate investigation. The factors contributing to the outbreak of sulphide ignitions are not clearly understood. This indicates a need for future research to study the influence of blasting parameters, exhaust temperatures, and dust characteristics on secondary ignitions at source. The aim is to establish realistic quantities for each of the parameters and develop a model that will incorporate field and laboratory quantities. It may be possible to predict outcomes of sulphide ignitions when the parameters are known. It is also planned to study the techno-economic feasibility of the preventive and control methods. One aspect of planned future research requires quantification of some terms by obtaining measurements of pollutant concentrations and size distribution of the airborne dust in an underground environment immediately after a main blast. A blast-proof aerosol sampling package to measure the source term will be designed. This sampling package will consist of a sampling section and a shield which will be capable of withstanding a blast explosion. The accuracy in measuring the variables and combination of variables will be the main focus in this proposed study.

Jan 1, 1987

By Jackson R. Pellett

INTRODUCTION The Friedensville mine is situated in Upper Saucon Township, Le- high County, Pennsylvania, in the southern central part of the Allentown quadrangle of the United States Geological Survey, approximately 5 miles southeast of the City of Allentown and 4 miles south of the City of Bethlehem. Zinc was first discovered in the Friedensville area early in the 19th century and several mines were operating during the latter part of the century. Zinc oxide was produced in 1853 and zinc metal in 1859. All mining in the area ceased in 1893 chiefly because of an unfavorable economic situation caused by a severe ground water problem and competition from the higher grade ores in New Jersey. Property acquisition by the New Jersey Zinc Company began in 1899 and periodic exploratory drilling was carried on until 1940 when sufficient reserves were proved for development of a mine. Shaft sinking was undertaken in 1947 and, due to severe hydrologic conditions, was not completed until 1952. Production began in 1958 and today the mine is producing about 64,000 tons of zinc concentrate per annum. The concentrates are trucked to the Company's smelter at Palmerton, Pennsylvania, approximately 30 miles north of Friedensville. The mine also produces from its mill tailings industrial and agricultural grades of limestone for commercial markets.

Jan 1, 1970

By Franklin Bache

It is appropriate to the place of meeting, and of interest to those members of the Institute whose attention has been more or less directed to Virginia during the past eleven years, to know the result of recent developments of the Virginia coal-field. While, during the late " boom," the attention of the industrial pioneers of Virginia was mainly directed to iron-ore deposits and manufacture, it is safe to say that the coal to which, at that time, comparatively little attention was turned, and which did not directly foster a growth of " boom " towns, will prove the most reliable source of mineral wealth in the State. At the time of the last Virginia meeting of the Institute, held at Roanoke, in 1883, the Wise county coal-field was untouched by a railroad, and its economic existence was scarcely considered. Although, in the meantime, a number of reconnaissances had been made, and a fair estimate of the value of the field formed, it was not until 1891, when the Norfolk and Western and the Louisville and Nashville railroads, respectively, completed their Clinch Valley and Norton extensions to a junction at Norton, Wise county, that any development took place, and not until 1892 were shipments of any importance made. The coal-measures of Virginia are confined to the seven counties of Buchanan, Tazewell, Dickenson, Russell, Scott, Wise, and Lee,

Jan 1, 1895

By T. J. Hudson, P. B. Queneau, J. D. Prater

The process parameters for effective utilization of nitric acid as an oxidant for copper-iron sulfides have been developed. Leaching variables found to be important were acid concentration, temperature, time, atmosphere, pressure, mineral type, particle size, and percent solids. Particular attention was devoted to analysis and control of fumes evolving during the oxidation. Data were recorded on metal extraction, elemental sulfur formation and oxidation, product gas composition and evolution rate, reagent consumption, and residue flotation response. The study was concluded by laboratory testing a flowsheet based on the foregoing observations. Ninety-eight percent of the copper contained in a chalcopyrite-bornite concentrate was recovered, requiring 1.6 lb of nitric acid to be regenerated externally per pound of copper extracted. Iron remained in the leach residue as hydrogen jarosite and was ultimately rejected from the system by froth flotation. Sixty percent of the sulfur contained in the copper concentrate reported in the elemental form; the remainder was oxidized to sulfate and eliminated with the hydrogen jarosite in the flotation tails or by neutralization of the solvent extraction raffinate with lime. Nitrogen was evolved primarily as NO and NOD; up to 3% N2O also was present. Gases containing sulfur were absent except when pyrrhotite was solubilized in the absence of soluble copper. In this case, HAS was evolved.

Jan 1, 1974

By J. R. B. Lima

The present work emphasizes the selection in the separation of the apatite/calcite by the direct anionic flotation versus the double flotation, with a reverse second stage of the Jacupiranga phosphate ore. The double flotation would allow the obtaining of two concentrated solutions: one of them mainly constituted by a calcium carbonate material (CaCO3) and the other one, phosphatic (apatite). The calcium carbonate concentrated solution is used for the production of cement. The presence of phosphatic material in the calcium solution is not desirable, phosphor being a harmful element to cement. On the other hand, smaller quantities of calcite in the phosphate concentrate would represent a substantial economy in the processes of production of phosphated fertilizers. These processes make use of sulfuric acid to the solubilization of the apatite and the presence of calcium material consumes acid. Also that, when carbonates are solubilized, unwanted products are formed resulting in losses in the process and diminishing the quality of the fertilizer produced. These characteristics are discussed in the paper and are compared to another Brazilian phosphate ore, the reverse route of which can be considered more adequate. The results are discussed according to recent discoveries, and special emphasis is given to the use of corn starch and its crucial role in promoting the selection in the direct flotation process.

Jan 1, 1993

By James Sheridan

Risk can generally be defined as the possibility or chance of a loss corresponding to uncertainty. Analysis is the process for examining the components and relationships of a complex system in order to determine the impacts of its variables. Risk analysis is therefore a course of action taken to analyze multiple variables of a system that is subject to speculative outcome. When risk analysis is applied to mine development, it becomes the means for assessing and measuring those parameters that contribute to economic viability. Mining can be a risky business. It is composed of an assortment of factors that contribute to its financial outcome. Of these factors, the most consequential output is the net present value (NPV). Applying risk analysis in mine development can identify those factors having the most significant impacts and applying limits to those impacts. Mathematical computer modeling using Monte Carlo techniques is available and can be customized to suit specific mine development ventures. Essentially, those parameters that are not fixed values can have input variability. Rationally deduced engineering estimates should be the basis for determining the initial values applied as inputs in the models. Risk analysis therefore provides the user a means to identify, rationalize and assess the risks in mine development in an informed, calculated, and unbiased format for making economic decisions.

Jan 1, 2002

By Alex Moyano

At present, the Codelco Norte smelter processes in the Teniente Converter and the Flash smelting Furnace 1,420,000 t/y of its Chuquicamata concentrate with an arsenic content of up to 1.5%. In a near future Codelco-Chile is considering different processing options for a new projected concentrates from the Alejandro Hales mine (former Mansa Mina mine with an arsenic content of up to 6%). The main option is the possibility to process 3,000 t/d of mixing concentrates from the Alejandro Hales and the Chuquicamata mines, in the Teniente Converter. The main feature of this smelting unit will be high volatilization of arsenic when processing high arsenic-bearing concentrates. The CN smelter staff carried out a technical feasibility study to evaluate the processing of high arsenic-bearing concentrates directly in the Teniente Converter, thus the low arsenic-bearing concentrates can be processed in the FSF. Accordingly, laboratory scale tests were carried out at the Tohoku University facilities. The lab-scale results allowed an industrial scale test at the Codelco Norte smelter to smelt 2,300 tpd of high arsenic-bearing concentrates in the TC and evaluate the metallurgical impact in the smelting, converting and refining areas of the smelter. The main industrial-scale result confirmed the stabilization of the arsenic content at 0.5% in the 70% Cu produced white metal at the test condition.

Jan 1, 2006

By William L. Grube

PECIMEN preparation for electron metallography involves several steps, such as polishing, etching, replicating, mounting, and shadowing. Although each step must be done with care, the operation requiring the utmost attention is etching. Proper etching is important because the relief pattern developed on the surface of the specimen by the etchant, and reproduced as minute differences in thickness of the replica, determines entirely the amount of detail seen in the final micrograph. The characteristic colored stains, sometimes used in light metallography to simplify identification of certain microconstituents, cannot be tolerated because there is danger of introducing artifacts in the replicating operation. It is also quite difficult to remove plastic replicas from stained specimens. A suitable etchant for electron metallography must, therefore, in all cases exhibit a preferential attack upon each of the microconstituents present sufficient to result in a difference in surface elevation. When only two microconstituents are present, it is not too difficult to find a suitable etchant since their physical or chemical properties are generally sufficiently different to result in a marked difference in attack by the etchant. For example, picral (a saturated solution of picric acid in methanol used as an immersion etch) is a satisfactory etchant for the specimen shown in Fig. 1 consisting of iron carbide particles embedded in a ferrite matrix.'

Jan 1, 1952