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By Sharif Jahanshahi

Calcium ferrite slags are often associated with Professor Yazawa due to his pioneering work on the thermodynamics of this type of melts. Over the past years CSIRO has invested some effort in studying physico-chemical properties of such melts to fill in some gaps in our knowledge and explore opportunities for application of the understanding developed. These investigations cover thermodynamics, transport properties of calcium ferrite based slags, as well as the kinetics of reactions of such slags with refractories. The present paper provides an overview of some of these studies and highlights some of the interesting behavior of such melts. The oxidation state of copper and arsenic in calcium ferrite based slags are predominantly Cu+ and As3+, respectively, at oxygen potentials below 10.1 atm. The concentration ofCu2+ in such slags becomes significant at oxygen potentials of greater than 10'1 atm at 1300 ?C. The activities of CuOo.s and AsOl.S in calcium ferrite slags show strong deviations from the Raoultian Law, while that of CoO is very close to ideal behaviour with respect to pure solid CoO. Addition of Si02 to calcium ferrite slags can have significant effects on the activities of FeO and Fe2O3 and hence the stability of magnetite phase. Transfer of oxygen in calcium ferrite slags is fast with diffusivity of 2xlO?3 cm2/s at 1350 °C and activation energy of 16 kcal/mol Presence of solid phases, such as magnetite, has pronounced effect on the viscosity of calcium ferrite slags. The observed dependence on solid loading and shear rate indicates deviation from Newtonian behaviour. The interfacial tension between copper mattes and calcium ferrite slags is strongly dependent on the matte grade, with the determined values being much lower than the corresponding ones for interfacial tension between similar mattes and iron silicate slags. MgO, Cr2O3 and MgCr2O4 have low solubility in calcium ferrite slags and their solubility increases with increasing copper oxide content of the slag at 1300 °c. The oxidation state of the slag has strong effects on phase transformation, dissolution rate and disintegration of refractories in calcium ferrite slags. Other key factors with major impact on slag-refractory interactions include viscosity and surface tension of slags as well as the contact angle between slag and refractory material.

Jan 1, 2003

By Lindsay D. Norman

Four chloride and seven fixed-nitrogen processes for recovering manganese from domestic resources are described. The chloride processes are divided into two classes (leaching and chloridization) depending upon the major operation responsible for converting the manganese minerals to the chloride from which manganese oxide products are obtained. The fixed nitrogen processes, all of which yield high-grade manganese oxide products, are essentially either leaching or roasting processes. The 11 processes include HC1 leach, HC1 chloridization, HC1 chloride volatilization, CaC12 chloride volatilization, NO2 leach, HNO3-NO2 leach, NH3-CO2-H2O system leach, (NH4)2SO4 leach, (NH4)2SO4 roast, and ammonium salt roast.

Jan 1, 1963

By J. W. Paul

Withdrawing timber in coal mines is done for the purpose of inducing the roof to cave in the mined-out areas and thereby relieve stresses in the immediate roof material over the working places adjacent to the breakline of the roof, thus preventing the crushing of the ends of pillars and adding to the safety of those engaged in pillar extraction. A secondary purpose is the recovery of timber for further use either as prop-, crossbars, lagging, sprags or cap pieces. At some mines timber is withdrawn as a precaution against fire which may he of spontaneous origin, because wood always aids a fire of any origin. With some of the power-driven types of machines now in use a greater proportion of mine timber may be recovered, and in mines where pillars are left too narrow for their removal some of the timber in rooms might be salvaged for further use.

Jan 1, 1933

By W. H. Hannay

Introduction The subject matter of this paper will be treated under two heads: (1) experimental work and the development of the purification system, and (2) the operation of the commercial plant. During 1927-28, a two-ton slag-retreating plant was in operation at the smelter for experimental purposes. Details of this operation and of the commercial plant are presented in a paper by G. E. Murray, read before the Annual General Meeting of the Institute in April, 1933 (1). A point which has considerable bearing on the subject of the present paper, and which was not emphasized by Mr. Murray, is the concentration of volatile impurities in the zinc oxide fume produced. The result of the operation of the slag fuming furnace is largely to confine in a closed circuit all the minor constituents of the Sullivan concentrates, both lead and zinc. They pass into the feed of the zinc fuming furnace, with the result that all impurities which volatilize-such as arsenic, antimony, tin, fluorine, etc.-report in the zinc oxide product. The accompanying condensed flow-sheet (Figure 1) will illustrate this. The only outlet for impurities which is not shown is the small tonnage which passes the Cottrell plants. The flow-sheet would indicate the possibility of building up a prohibitive concentration of cathodic impurities in the oxide leaching plant feed. However, after three years' continuous operation this has not occurred. Should this condition arise at some future date, discard of some tonnage of blast furnace slag is indicated. In Mr. Murray's paper, the much greater flexibility of blast furnace operation, due to the slag fuming furnace, is stressed, particularly as to the lead content of the slag. The requirements of our lead refinery call for a bullion containing about 0.70 percent antimony.

Jan 1, 1934

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

By Sharif Jahanshahi

Calcium ferrite slags are often associated with Professor Yazawa due to his pioneering work on the thermodynamics of this type of melts. Over the past years CSIRO has invested some effort in studying physico-chemical properties of such melts to fill in some gaps in our knowledge and explore opportunities for application of the understanding developed. These investigations cover thermodynamics, transport properties of calcium ferrite based slags, as well as the kinetics of reactions of such slags with refractories. The present paper provides an overview of some of these studies and highlights some of the interesting behavior of such melts, The oxidation state of copper and arsenic in calcium ferrite based slags are predominantly Cu+ and As3+, respectively, at oxygen potentials below 10-7 atm. The concentration of CU2+ in such slags becomes significant at oxygen potentials of greater than 10-7 atm at 1300 °C. The activities of CuO0.5 and AsO1.5 in calcium ferrite slags show strong deviations from the Raoultian Law, while that of CoO is very close to ideal behaviour with respect to pure solid CoO. Addition of SiO2 to calcium ferrite slags can have significant effects on the activities of FeO and Fe2O3 and hence the stability of magnetite phase. Transfer of oxygen in calcium ferrite slags is fast with diffusivity of 2x 103 cm2/s at 1350 °C and activation energy of 16 kcal/mol. Presence of solid phases, such as magnetite, has pronounced effect on the viscosity of calcium ferrite slags. The observed dependence on solid loading and shear rate indicates deviation from Newtonian behaviour. The interfacial tension between copper mattes and calcium ferrite slags is strongly dependent on the matte grade, with the determined values being much lower than the corresponding ones for interfacial tension between similar mattes and iron silicate slags. MgO, Cr2O3 and MgCr2O4 have low solubility in calcium ferrite slags and their solubility increases with increasing copper oxide content of the slag at 1300°C. The oxidation state of the slag has strong effects on phase transformation, dissolution rate and disintegration of refractories in calcium ferrite slags. Other key factors with major impact on slag-refractory interactions include viscosity and surface tension of slags as well as the contact angle between slag and refractory material,

Jan 1, 2003

By W. H. Tavenner

The Bureau of Mines gathered test data on the use of a continuous borer in mining an anthracite bed, which was 30 feet thick on a pitch of 15° to 45°. Gangways were driven with the continuous borer, ventilation openings between gangways were driven with a large-diameter auger, and the blocks of coal between completed gangways were mined by the long-hole method, Conveyors were used to transport the mined coal. The continuous borer operated on a coal floor that was frequently soft because of heaving. The continuous borer could not bore openings on a grade exceeding 27 percent (15° pitch). Because 150 was also the lower limit of the pitch, of the bed, the continuous borer was used only to drive gangways. The continuous borer virtually filled the workplace, leaving insufficient space to place heavy-duty timber and cushioning material between the timber and coal back to allow for normal expansion of the uncut coal. The light? weight yieldable steel arch against the coal back gave inadequate support to control convergence, which in a disturbed area sometimes occurred with explosive violence. This exposed the machine operator to a hazardous condition, since a satisfactory solution could not be found, the company discontinued the use of the continuous borer.

Jan 1, 1966

By O. P. Hood, G. St. J. Perott, S. P. Kinney

"FOREWORD (By O. P. Hood, Chief mechanical engineer).During the war certain suggestions concerning power production were made by Mr. Walter E. Trent to the War Inventions Board, and at the request of the War Department facilities for experimental work were provided on the grounds of the. Bureau of Standards.The experiments were along the line of controlling the conditions of combustion in a closed space. In order to reduce slag troubles, experiments were carried out for removing ash from powdered coal. After the war, work along this line was continued, resulting in the Trent Process, which agitates or beats together powdered coal, water and oil.A new technology had previously been given to ore preparation by the use of small quantities of oil in water with froth flotation, and although the methods, results and mixtures of the Trent Process were quite different, yet the same physical phenomena of differential wetting used, and the possibility of there being interesting results in fuel technologic was evident. A cooperative agreement was entered into, whereby the Bureau of Mines was to investigate the underlying physical and chemical facts and make them public, and the Trent Corporation was to pay the cost of the investigation.The several reports as made have been available to any one interested, and are now to be published. While the Bureau of Mines felt justified in investigating the physical phenomena so far as might be done in a laboratory, and so far as public interest might reach, no attempt was made to discover the commercial possibilities which development might bring. The question of commercial possibilities must be left for commercial enterprise to answer."

Jul 1, 1921

By Thomas Lane Carter

THE history of mining in South Africa differs somewhat from that of other countries in the part taken by the aborigines in the development ?of the mineral deposits. The Spaniards in America, and the fortune-seekers of Australia and New Zealand, found large numbers of natives in these new countries, but the inhabitants did not become willing or efficient workers ill the mines which the white men started. The Kaffirs of South. Africa have not shown the same antipathy to labor, nor do they show any signs of dying out in the presence of the white man's civilization. They are a virile race, and so far the vices of civilization have not killed. them. While it is true that the brain and skill necessary for the exploitation of the mineral resources of this sub-continent-have been supplied by the white race, it is also a fact that most of the rough labor in the development of the mining industry of South Africa has been done by the Kaffirs. The Kaffir tribes differ greatly in their mental and physical capabilities. Compare, for instance, a Zulu of Natal with a Bechuana, or a Xosa of Cape Colony with some of the degenerate tribes of Central or East Africa, and you will find that they have little in common, save that their skin is black and that they do not believe in clothes. As a general rule, the tribe's in the milder, healthier climates are far superior, both in mind and body, to the Kaffirs brought up in the hot malarial sections of Central Africa; and it naturally follows that the black men from the temperate zones of the country, are much finer workmen than the degenerates from less favorable sections: It is universal in South Africa to speak. of the .Kaffirs as " boys." No matter if he is 90 years old, the Kaffir is always a " boy," and in this paper the word " boy " is synonymous with Kaffir.

Nov 1, 1908

By A. L. W. Lips, B. P. J. Stevens, T. J. R. Barclay, E. Rothery, S. H. White

Discussion by B.P.J. Stevens of the paper, published in Trans. IMMA, vol.104, 1995, p.B1-B17, is presented together with the authors' response. Stevens questions the authors' radically different interpretation of the structural geology of the Broken Hill Block, considering that the descriptive part of the paper is a useful addition but that the conclusions are unwarranted on the basis of the data presented. A number of major points of disagreement are outlined and half a dozen additional minor points listed. In response, the authors admire Stevens's contribution to unravelling the geology of the area but defend their attempts to take the regional studies a step further, pointing out that he has misquoted what they wrote and arguing that because of the assumptions underpinning the derivation of the present stratigraphy it cannot be used to constrain structural models. With regard to shear zones, they cite the extensive earlier literature and refer to horizontal displacements shown on maps produced by Stevens et al. Detailed discussion follows of the stratigraphy and of the stratigraphic correlation problems resulting from failure to recognise the presence and significance of shears, particularly those parallel to stratigraphy. The remobilised position of the Pb mineralisation in the North Mine open cut is reiterated. It is concluded that there is an urgent need for systematic isotopic dating in the area to constrain the stratigraphy

Apr 1, 1996

Much of the theory upon which the Sublevel Caving (SLC) method is based was developed in Scandinavia many years ago. It was based mainly on æbinÆ theory and æellipsoid of drawÆ configurations derived from sandbox models. In many cases, classical SLC layouts influenced by these early theories obtained relatively poor results. Early dilution entry, low tonnage factors and low recoveries were commonly experienced. SLC soon gained the reputation of being a high dilution, low recovery and development intensive method. This led to SLC falling into disfavour generally, other than as a pillar reclamation method used at the end of the life of mines. More recently a number of mines, notably those in Australia, have adopted SLC as a primary extraction method and have achieved good recovery results. The reason for the better results is believed to be an outcome of modifications in some of the basic design parameters and operational procedures. This has led to questions being raised regarding the original æbin theoryÆ assumptions and classical SLC layout designs. It is clear that the fragmentation and flow characteristics occurring in a choke blast situation (compaction of waste, variable size and shape of fragmentation throughout the ring) conflicts significantly with the assumptions of regular loose flow of uniform, fine grained, material in a bin. Interactive versus independent draw conditions can also materially effect the outcome of a SLC operation. The good results obtained more recently can only be explained by using ænewÆ models of behaviour, which have to a large extent been borrowed from block caving. If these models are correct, they point to a number of design and operational changes that can be applied to improve the effectiveness of SLC. This paper discusses the factors that may not have been fully considered in early SLC design and modelling. It emphasises the importance of delayed dilution entry as a primary objective of sound SLC design and provides a basis for efficient SLC design and operation.

Jan 1, 2000

By H. O. HOPMAN

(Canal Zone Meeting, November, 1910.) I. INTRODUCTION. THE substance of this paper was prepared for the Seventh International Congress of Applied Chemistry, held in London, May, 1909, under the title, Some Developments in Blast-Roasting. In the absence of the author, a -short abstract of the paper was read, and the abstract only will appear in the proceedings of the congress. The present paper has been partly rewritten and considerably enlarged by information gained since the original was prepared ; also some illustrations have been added. Blast-roasting' is a generic term for the process of forcing air through finely-divided. metallic sulphide with the object of roasting and agglomerating in a single operation. At first the process was confined to a galena-concentrate ; lime, limestone, or gypsum was added, to serve both as a diluent to keep separate the particles of galena that they might be thoroughly oxidized, and as a flux that the partly-roasted ore might be agglomerated by the formation of some slag. Later it was extended to treat other metallic sulphides. The leading processes were the Huntington-Heberlein and the Savelsberg of Europe, and the Carmichael-Bradford of Australia. In the United States and Canada, the Huntington-Heberlein process has found application in some instances with galena-concentrates, for which it was originally intended; but this class of ore is not often treated alone, hence the process has had to be modified to suit conditions. The Savelsberg process has been transplanted to this country in about its original form. The Carmichael-Bradford is not used at present. The changes called for in the Huntington-Heberlein process to adapt it to the class of lead-bearing ores usually smelted have been the 1 A. S. Dwight, Engineering and Mining Journal, vol. lxxxv., No. 13, p. 649 (Mar. 28, 1908).

Jun 1, 1910

By CIM Mineral Resource

On January 9, 2018, the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Council formed the CIM Mineral Resources and Mineral Reserves Committee (CIM MRMR Committee), which is a combination of the previous Standing Committee on Reserve Definitions and the Best Practices Committee. As part of its mandate, the CIM MRMR Committee updates guidelines for use by Industry, which include the Uranium Practice Guidelines. The 2024 CIM Uranium Leading Practice Guidelines were adopted by CIM Council on November 22, 2024, and supersedes the 2003 version. The main principles and guidelines relating to preparation of Mineral Resource and Mineral Reserve (MRMR) estimates are provided in the CIM Estimation of Mineral Resources and Mineral Reserves Best Practices Guidelines (MRMR BP Guidelines, as updated from time to time). The MRMR BP Guidelines provide information pertaining to metalliferous and other deposits and many sections are readily applicable to the preparation of MRMR estimates for uranium deposits. However, additional guidance is appropriate for uranium deposits due to the radioactive nature of uranium, and its amenability, in some cases, to in situ recovery (ISR) mining methods.

Nov 1, 2024

By Brendan Demich, Joseph McGuire, Emily J. Haas

Near misses recorded and reported by workers can provide awarenessto the potential causes of injury and prompt safety management initiatives. Although most companies require near-miss reporting, it is unclear what the value of these reports are, if any, and how they influence subsequent actions or controls to reduce on-the-job risks. Researchers at the National Institute for Occupational Safety and Health (NIOSH) conducted a case study with an aggregates company in which near-miss reports were analyzed at each of their locations over an entire quarter during the summer of 2018. Within that quarter, workers recorded 249 near misses. Of those, 167 were valid near misses that occurred at work. Researchers coded the reports using a qualitative 5 × 5 risk matrix. Of the 167 near misses, 19% were deemed low risk, 25% moderate risk, 30% high risk, and 26% critical risk. Several patterns in the near-miss incidents were documented, including classification of incidents and common corrective actions referenced (i.e., elimination/substitution, engineering control or redesign, work process/procedures, and personal protective equipment). The analysis provides insight into ways that risk communication and management programs can be improved to reengage workers and their situational awareness on the job.

By A. Paviani

The subject of this session is "Equipment Installa­tion, Recent Developments". This is a subject which is not usually addressed at conferences of Foundation Engineering. It is rare to find sessions dealing with the technological side of deep foundations, a subject which only recently seems to have aroused sufficient interest at national and international conferences. It is therefore natural for the subject of "Equipment", or the tools used to implement the various "technologies", to be over­looked or mentioned only occasionally during the discussion of other issues. At conferences, most of the attention is attached to research and to the theoretical interpretation of the performance and behaviour of deep foundations, as well as to establishing the most suitable calculation algorithms and approaches for the study, design and control of foundation structures. It is almost as if the subject of equipment is felt to be less important or, perhaps, that it is considered to belong more strictly to mechanical engineering than to civil engineering.

Jan 1, 1994

By F. Mulenga, S. Ncube

Rock fragmentation methods in open pit gemstone mining have developed to give priority to safety, environmental sustainability, and crystal integrity. Though effective, traditional drill-and-blast techniques can generate vibrations, adverse emissions, and structural damage, all of which could be detrimental in fragile geological settings. Costs, application in hard rocks, and operational inefficiency remain issues, despite the fact that mechanical excavation and evolving thermal and hydraulic technologies have provided some solutions. In response, there has been a growing interest in non-explosive alternatives, particularly soundless chemical demolition agents. This paper provides a comprehensive evaluation of non-blasting rock fragmentation techniques with an emphasis on the efficiency, economic considerations, and operational constraints of soundless chemical demolition agents SCDAs in gemstone mining. Soundless chemical demolition agents technology has shown promising results in preserving gem purity and reducing environmental impact, despite ongoing challenges. These include increased reaction times that hinder output, decreased performance in saturated or high-stress environments, and temperature sensitivity. The contextual relevance of soundless chemical demolition agent application in lateritic regions, such as Zambia, is discussed based on published studies and reported operational experience. Developments in formulation chemistry, fracture modelling, and borehole design have also demonstrated promise in overcoming current limitations. This review identifies the main factors that affect soundless chemical demolition agent performance and brings together reported strategies that can improve their use in high-value mineral extraction through a comprehensive review of recent studies. Ultimately, this article supports a paradigm change towards excavation techniques based on state-of-the-art non-explosive technology that are safer, cleaner, and more accuracy focused.

May 8, 2026

By Mark Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the Autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of: 1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots. 2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy. 3) Improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by six tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster ?hard ore? (BWI >17), as well as autoclave ?hard ore? (BWI >15). Approximately six million tons of D2M material is expected be shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

May 1, 2003

By B Young

Variable bench heights, interaction with underground workings and a steeply dipping orebody are challenges faced daily by geologists at Xstrata Zinc’s Black Star Open Cut (BSOC) Zinc/Lead/Silver mine in Mount Isa, Queensland.BSOC has been in operation since late 2004 and was developed to extract the surface extents of the Zn/Pb/Ag mineralisation mined in the underground lead mine. To date many large scale stopes and extensive development drives have been intersected and successfully mined. The stratigraphically hosted orebodies strike in a north-north westerly direction, dipping ~75° west. Ore production from the pit is currently at 4.5 Mt/a.Historically, sampling was conducted using a multiple spear technique from blasthole cuttings. This method proved to be relatively reliable when blasting benches at a consistent height, but a requirement to vary bench heights to safely collapse and then mine through underground workings reduced sample representivity to unacceptable levels.The purchase and commissioning of a production rig which had been converted for reverse circulation (RC) has allowed for the flexibility of a small rig, with the capacity to easily drill 48 m holes while ensuring sample quality. Sample quality is not the only benefit of introducing RC grade control. By collecting grade control data well in advance, informed decisions can be made by planning, drill and blast and mining departments weeks beforehand, rather than hours before firing. Additionally, seeking operational value to offset higher drilling costs has proved positive with benefits including increased confidence in orebody wireframes, accurate tonnage and grade for proceeding five benches along with the ability to representatively test metallurgical response on a tight grid spacing.

Aug 22, 2011

By Karl J. C. Harries

13.1. RIGHT TO RECEIVE ROYALTY CONTRACTUAL ONLY1

Jan 1, 2003

By Karl E. Starch

This Bureau of Mines report is a background study of severance taxes on mineral production. The rates, bases, and other features of State severance tax legislation as of March 1978 are presented, as are the amounts of State severance tax collections for fiscal year 1977, Some statistical comparisons between severance tax collections, total State tax collections, and total value of mineral production in the States involved are presented to portray the relative importance of severance taxes both in State tax revenue systems and in mineral industry revenues. A general discussion of the purposes and principles of taxation, the unique nature of a mining enterprise, the various types of taxes imposed on mineral production, and the character and rationale of the severance tax and its impacts on mining firms sets the severance tax in perspective. A bibliography of materials on the severance tax is included.

Jan 1, 1979